24-01-2025

1001CJM240125MRG JM

PART-1 : PHYSICS

SECTION-I

1) Consider a parallel plate capacitor of area A (of each plate) and separation 'd' between the plates.
If E is the electric field and ε0 is the permittivity of free space between the plates, then potential
energy stored in the capacitor is :-

(A)

(B)

(C)
2
(D) ε0E Ad

2) What is the relative decrease in focal length of a lens for an increase in optical power by 0.1 D
from 2.5 D ? ['D' stands for dioptre]

(A) 0.04
(B) 0.40
(C) 0.1
(D) 0.01

3) An air bubble of radius 0.1 cm lies at a depth of 20 cm below the free surface of a liquid of density
1000 kg/m3. If the pressure inside the bubble is 2100 N/m2 greater than the atmospheric pressure,
then the surface tension of the liquid in SI unit is (use g = 10 m/s2)

(A) 0.02
(B) 0.1
(C) 0.25
(D) 0.05

4) For an experimental expression , where all the digits are significant. Then to
report the value of y we should write :-

(A) y = 1326.2
(B) y = 1326.19
(C) y = 1326.186
(D) y = 1330

5) During the transition of electron from state A to state C of a Bohr atom, the wavelength of emitted
radiation is 2000 Å and it becomes 6000 Å when the electron jumps from state B to state C. Then the
wavelength of the radiation emitted during the transition of electrons from state A to state B is :-

(A) 3000 Å
(B) 6000 Å
(C) 4000 Å
(D) 2000 Å

6) Consider the following statements :

A. The junction area of solar cell is made very narrow compared to a photo diode.
B. Solar cells are not connected with any external bias.
C. LED is made of lightly doped p-n junction.
D. Increase of forward current results in continuous increase of LED light intensity.
E. LEDs have to be connected in forward bias for emission of light.

(A) B, D, E Only
(B) A, C Only
(C) A, C, E Only
(D) B, E Only

7) The amount of work done to break a big water drop of radius 'R' into 27 small drops of equal
radius is 10 J. The work done required to break the same big drop into 64 small drops of equal
radius will be :-

(A) 15 J
(B) 10 J
(C) 20 J
(D) 5 J

8) An object of mass 'm' is projected from origin in a vertical xy plane at an angle 45° with the x-axis
with an initial velocity v0. The magnitude and direction of the angular momentum of the object with
respect to origin, when it reaches at the maximum height, will be [g is acceleration due to gravity]

(A)
along negative z-axis

(B)
along positive z-axis

(C)
along positive z-axis

(D)
along negative z-axis

9) The Young's double slit interference experiment is performed using light consisting of 480 nm and
600 nm wavelengths to form interference patterns. The least number of the bright fringes of 480 nm
light that are required for the first coincidence with the bright fringes formed by 600 nm light is :-
(A) 4
(B) 8
(C) 6
(D) 5

10) A car of mass 'm' moves on a banked road having radius 'r' and banking angle θ. To avoid
slipping from banked road, the maximum permissible speed of the car is v0. The coefficient of friction
µ between the wheels of the car and the banked road is :-

(A)

(B)

(C)

(D)

11) A uniform solid cylinder of mass 'm' and radius 'r' rolls along an inclined rough plane of
inclination 45°. If it starts to roll from rest from the top of the plane then the linear acceleration of
the cylinder axis will be :-

(A)

(B)

(C)

(D)

12) A thin plano convex lens made of glass of refractive index 1.5 is immersed in a liquid of
refractive index 1.2. When the plane side of the lens is silver coated for complete reflection, the lens
immersed in the liquid behaves like a concave mirror of focal length 0.2 m. The radius of curvature
of the curved surface of the lens is :-

(A) 0.15 m
(B) 0.10 m
(C) 0.20 m
(D) 0.25 m

13) A particle is executing simple harmonic motion with time period 2s and amplitude 1 cm. If D and

d are the total distance and displacement covered by the particle in 12.5 s, then is :-

(A)
(B) 25
(C) 10

(D)

14) A satellite is launched into a circular orbit of radius 'R' around the earth. A second statellite is
launched into an orbit of radius 1.03 R. The time period of revolution of the second satellite is larger
than the first one approximately by :-

(A) 3 %
(B) 4.5 %
(C) 9 %
(D) 2.5 %

15) A plano-convex lens having radius of curvature of first surface 2 cm exhibits focal length of f1 in
air. Another plano-convex lens with first surface radius of curvature 3 cm has focal length of f2 when
it is immersed in a liquid of refractive index 1.2. If both the lenses are made of same glass of
refractive index 1.5, the ratio of f1 and f2 will be :-

(A) 3 : 5
(B) 1 : 3
(C) 1 : 2
(D) 2 : 3

16) An alternating current is given by

I = IA sin ωt + IB cos ωt.
The r.m.s. current will be :-

(A)

(B)

(C)

(D)

17) An electron of mass 'm' with an initial velocity enters an electric

field . If the initial de Broglie wavelength is λ0, the value after time t would be :-

(A)

(B)
(C) λ0

(D)

18) A parallel plate capacitor was made with two rectangular plates, each with a length of ℓ = 3 cm
and breath of b = 1 cm. The distance between the plates is 3 µm. Out of the following, which are the
ways to increase the capacitance by a factor of 10 ?
A. ℓ = 30 cm, b = 1 cm, d = 1 µm
B. ℓ = 3 cm, b = 1 cm, d = 30 µm
C. ℓ = 6 cm, b = 5 cm, d = 3 µm
D. ℓ = 1 cm, b = 1 cm, d = 10 µm
E. ℓ = 5 cm, b = 2 cm, d = 1 µm
Choose the correct answer from the options given below :

(A) C and E only

(B) B and D only
(C) A only
(D) C only

19) A force F = α + βx2 acts on an object in the x-direction. The work done by the force is 5J when
the object is displaced by 1 m. If the constant α = 1N then β will be

(A) 15 N/m2
(B) 10 N/m2
(C) 12 N/m2
(D) 8 N/m2

20) An ideal gas goes from an initial state to final state. During the process, the pressure of gas
increases linearly with temperature.
A. The work done by gas during the process is zero.
B. The heat added to gas is different from change in its internal energy.
C. The volume of the gas is increased.
D. The internal energy of the gas is increased.
E. The process is isochoric (constant volume process)
Choose the correct answer from the options given below :-

(A) A, B, C, D Only
(B) A, D, E Only
(C) E Only
(D) A, C Only

SECTION-II

1) A square loop of sides a = 1 m is held normally in front of a point charge q = 1C. The flux of the
electric field through the shaded region is , where p is :-

2)

The least count of a screw guage is 0.01 mm. If the pitch is increased by 75% and number of
divisions on the circular scale is reduced by 50%, the new least count will be _____ × 10–3 mm.

3) A wire of resistance 9 Ω is bent to form an equilateral triangle. Then the equivalent resistance
across any two vertices will be __ohm.

4) A current of 5A exists in a square loop of side . Then the magnitude of the magnetic field B
at the centre of the square loop will be p × 10 T. where, value of p is ______. [Take µ0 = 4π × 10–7 T
–6

mA–1].

5) The temperature of 1 mole of an ideal monoatomic gas is increased by 50°C at constant pressure.

The total heat added and change in internal energy are E1 and E2, respectively. If then the
value of x is _______.

PART-2 : CHEMISTRY

SECTION-I

1) For the given cell

Fe2+(aq) + Ag+(aq) → Fe3+ (aq) + Ag(s)
The standard cell potential of the above reaction is Given :
0
Ag+ + e– → Ag E = x V
0
Fe2+ + 2e– → Fe E =yV
0
Fe3+ + 3e– → Fe E =zV

(A) x + y – z
(B) x + 2y – 3z
(C) y – 2x
(D) x + 2y

2) Following are the four molecules "P", "Q", "R" and "S".
Which one among the four molecules will react with H-Br(aq) at the fastest rate ?

(A) S
(B) Q
(C) R
(D) P

3) One mole of the octahedral complex compound Co(NH3)5Cl3 gives 3 moles of ions on dissolution in
water. One mole of the same complex reacts with excess of AgNO3 solution to yield two moles of
AgCl(s). The structure of the complex is :

(A) [Co(NH3)5Cl]Cl2
(B) [Co(NH3)4Cl].Cl2.NH3
(C) [Co(NH3)4Cl2]Cl.NH3
(D) [Co(NH3)3Cl3].2NH3

4) Which one of the carbocations from the following is most stable ?

(A)

(B)

(C)

(D)

5) Which of the following linear combination of atomic orbitals will lead to formation of molecular
orbitals in homonuclear diatomic molecules [internuclear axis in z-direction] ?
A. 2pz and 2px
B. 2s and 2px

C.
D. 2s and 2pz

E.

(A) E Only
(B) A and B Only
(C) D Only
(D) C and D Only
6) Which of the following ions is the strongest oxidizing agent ?
(Atomic Number of Ce = 58, Eu = 63, Tb = 65, Lu = 71]

(A) Lu3+
(B) Eu2+
(C) Tb4+
(D) Ce3+

7) Ksp for Cr(OH)3 is 1.6 × 10–30. What is the molar solubility of this salt in water?

(A)

(B)

(C)

(D)

8) Let us consider an endothermic reaction which is non-spontaneous at the freezing point of water.
However, the reaction is spontaneous at boiling point of water. Choose the correct option.

(A) Both ΔH and ΔS are (+ve)

(B) ΔH is (–ve) but ΔS is (+ve)
(C) ΔH is (+ve) but ΔS is (–ve)
(D) Both ΔH and ΔS are (–ve)

9) Given below are two statements I and II.

Statement I : Dumas method is used for estimation of “Nitrogen” in an organic compound.
Statement II : Dumas method involves the formation of ammonium sulphate by heating the organic
compound with conc H2SO4.
In the light of the above statements, choose the correct answer from the options given below

(A) Both Statement I and Statement II are true

(B) Statement I is false but Statement II is true
(C) Both Statement I and Statement II are false
(D) Statement I is true but Statement II is false

10) Which of the following Statements are NOT true about the periodic table?
A. The properties of elements are function of atomic weights.
B. The properties of elements are function of atomic numbers.
C. Elements having similar outer electronic configuration are arranged in same period.
D. An element's location reflects the quantum numbers of the last filled orbital.
E. The number of elements in a period is same as the number of atomic orbitals available in energy
level that is being filled.
Choose the correct answer from the options given below:

(A) A, C and E Only

(B) D and E Only
(C) A and E Only
(D) B, C and E Only

11) The carbohydrates “Ribose” present in DNA, is

A. A pentose sugar
B. present in pyranose from
C. in “D” configuration
D. a reducing sugar, when free
E. in α-anomeric form
Choose the correct answer from the options given below :

(A) A, C and D Only

(B) A, B and E Only
(C) B, D and E Only
(D) A, D and E Only

12) Preparation of potassium permanganate from MnO2 involves two step process in which the 1st
step is a reaction with KOH and KNO3 to produce

(A) K4[Mn(OH)6]
(B) K3MnO4
(C) KMnO4
(D) K2MnO4

13) The large difference between the melting and boiling points of oxygen and sulphur may be
explained on the basis of

(A) Atomic size

(B) Atomicity
(C) Electronegativity
(D) Electron gain enthalpy

14) For a reaction, N2O5(g) → 2NO2(g) + O2(g) in a constant volume container, no products were
present initially. The final pressure of the system when 50% of reaction gets completed is

(A) 7/2 times of initial pressure

(B) 5 times of initial pressure
(C) 5/2 times of initial pressure
(D) 7/4 times of initial pressure

15) Which of the following arrangements with respect to their reactivity in nucleophilic addition
reaction is correct?

benzaldehyde < acetophenone

(A)
< p-nitrobenzaldehyde < p-tolualdehyde
 acetophenone < benzaldehyde
(B)
< p-tolualdehyde < p-nitrobenzaldehyde
acetophenone < p-tolualdehyde
(C)
< benzaldehyde < p-nitrobenzaldehyde
p-nitrobenzaldehyde < benzaldehyde
(D)
< p-tolualdehyde < acetophenone

16) Aman has been asked to synthesise the molecule . He thought of

preparing the molecule using an aldol condensation reaction. He found a few cyclic alkenes in his
laboratory. He thought of performing ozonolysis reaction on alkene to produce a dicarbonyl
compound followed by aldol reaction to prepare “x”. Predict the suitable alkene that can lead to the
formation of “x”.

(A)

(B)

(C)

(D)

17) Consider the given plots of vapour pressure (VP) vs temperature (T/K) Which amongst the
following options is correct graphical representation showing ΔTf, depression in the freezing point of
solvent in a solution ?
(A)

(B)

(C)

(D)

18) Which of the following statement is true with respect to H2O, NH3 and CH4?
A. The central atoms of all the molecules are sp3 hybridized.
B. The H–O–H, H–N–H and H–C–H angles in the above molecules are 104.5º, 107.5º and 109.5º
respectively.
C. The increasing order of dipole moment is
CH4 < NH3 < H2O.
D. Both H2O and NH3 are Lewis acids and CH4 is a Lewis base
E. A solution of NH3 in H2O is basic. In this solution NH3 and H2O act as Lowry-Bronsted acid and
base respectively.
Choose the correct answer from the options given below :

(A) A, B and C only

(B) C, D and E only
(C) A, D and E only
(D) A, B, C and E only

19) Given below are two statements :

Statement-I : The conversion proceeds well in the less polar medium.

CH3–CH2–CH2–CH2–Cl CH3–CH2–CH2–CH2–OH + Cl–

Statement-II : The conversion proceeds well in the more polar medium.

CH3–CH2–CH2–CH2–Cl CH3–CH2–CH2
In the light of the above statements, choose the correct answer from the options given below.

(A) Both statement I and statement II are true

(B) Both statement I and statement II are false
(C) Statement I is false but statement II is true
(D) Statement I is true but statement II is false

20) The product (A) formed in the following reaction sequence is :

(A)

(B)

(C)

(D)

SECTION-II

1) 37.8 g N2O5 was taken in a 1 L reaction vessel and allowed to undergo the following reaction at
500 K
2N2O5(g) → 2N2O4(g) + O2(g)
The total pressure at equilibrium was found to be 18.65 bar. Then, Kp = _______ × 10–2 [nearest
integer] Assume N2O5 to behave ideally under these conditions
Given : R = 0.082 bar L mol–1 K–1

2) Standard entropies of X2, Y2 and XY5 are 70, 50 and 110 J K–1 mol–1 respectively. The temperature
in Kelvin at which the reaction

→ XY5 ΔH– = – 35 kJ mol–1

Will be at equilibrium is ____ (Nearest integer)

3) X g of benzoic acid on reaction with aq. NaHCO3 release CO2 that occupied 11.2 L volume at STP.
X is _____ g.

4) Among the following cations, the number of cations which will give characteristic precipitate in
their identification tests with K4[Fe(CN)6] is :
Cu2+, Fe3+, Ba2+, Ca2+, NH4+, Mg2+, Zn2+

5) Consider the following reaction occurring in the blast furnace.

Fe3O4(s) + 4CO(g) → 3Fe(l) + 4CO2(g)
‘x’ kg of iron is produced when 2.32 × 103 kg Fe3O4 and 2.8 × 102 kg CO are brought together in the
furnace. The value of ‘x’ is ____. (nearest integer)
{Given : Molar mass of Fe3O4 = 232 g mol–1 ; Molar mass of CO = 28 g mol–1 ;
Molar mass of Fe = 56 g mol–1}

PART-3 : MATHEMATICS

SECTION-I

1) Let , and be three vectors such that is coplanar with and . If the
vector is perpendicular to and , then is equal to

(A)

(B) 18
(C) 16

(D)

2) In I(m, n) = , m, n > 0, then I(9, 14) + I(10, 13) is

(A) I(9, 1)
(B) I(19, 27)
(C) I(1, 13)
(D) I(9, 13)

3) Let f : – {0} → be a function such that . If the ;

α, β ∈ , then α + 2β is equal to

(A) 3
(B) 5
(C) 4
(D) 6

4) Let upto n terms. If the sum of the first six terms of an A.P. with first
term –p and common difference p is , then the absolute difference between 20th and
15th terms of the A.P. is

(A) 25
(B) 90
(C) 20
(D) 45

5) Let f(x) = . Then the value of is equal to

(A) 118
(B) 92
(C) 102
(D) 108

6) If α and β are the roots of the equation 2z2 – 3z – 2i = 0, where , then

is equal to

(A) 398
(B) 312
(C) 409
(D) 441

7) is

(A) 0

(B)
(C)

(D)

8) Let in a ΔABC, the length of the side AC be 6, the vertex B be (1, 2, 3) and the vertices A, C lie on

the line . Then the area (in sq. units) of ΔABC is

(A) 42
(B) 21
(C) 56
(D) 17

9) Let y = y(x) be the solution of the differential equation dx + (1 + x2)dy = 0,

y(0) = 0. Then is equal to

(A)

(B)

(C)

(D)

10) Let the product of the focal distances of the point on the ellipse , (a > b),

be . Then the absolute difference of the eccentricities of two such ellipses is

(A)

(B)

(C)

(D)

11) A and B alternately throw a pair of dice. A wins if he throws a sum of 5 before B throws a sum of
8, and B wins if he throws a sum of 8 before A throws a sum of 5. The probability, that A wins if A
makes the first throw, is

(A)
(B)

(C)

(D)

12) Consider the region

. The area, of the largest rectangle of sides parallel to the

coordinate axes and inscribed in R, is :

(A)

(B)

(C)

(D)

13) The area of the region {(x, y) : x2 + 4x + 2 ≤ y ≤ |x + 2|} is equal to

(A) 7
(B) 24/5
(C) 20/3
(D) 5

14) For a statistical data x1, x2, …, x10 of 10 values, a student obtained the mean as 5.5 and

. He later found that he had noted two values in the data incorrectly as 4 and 5, instead
of the correct values 6 and 8, respectively. The variance of the corrected data is

(A) 7
(B) 4
(C) 9
(D) 5

15) Let circle C be the image of x2 + y2 – 2x + 4y – 4 = 0 in the line 2x – 3y + 5 = 0 and A be the

point on C such that OA is parallel to x-axis and A lies on the right hand side of the centre O of C. If
B(α,β), with β < 4, lies on C such that the length of the arc AB is (1/6)th of the perimeter of C, then
is equal to

(A) 3
(B)
(C)
(D) 4

16) For some n ≠ 10, let the coefficients of the 5th, 6th and 7th terms in the binomial expansion of (1 +
x)n+4 be in A.P. Then the largest coefficient in the expansion of (1 + x)n+4 is :

(A) 70
(B) 35
(C) 20
(D) 10

17) The product of all the rational roots of the equation (x2 – 9x + 11)2 – (x – 4) (x – 5) = 3, is equal to
:

(A) 14
(B) 7
(C) 28
(D) 21

18) Let the line passing through the points (–1, 2, 1) and parallel to the

line intersect the line at the point P. Then the distance of P from the point
Q(4, – 5, 1) is :

(A) 5
(B) 10
(C)
(D)

19) Let the lines 3x – 4y – α = 0, 8x – 11y – 33 = 0, and 2x – 3y + λ = 0 be concurrent. If the image of

the point (1, 2) in the line 2x – 3y + λ = 0 is , then |αλ| is equal to :

(A) 84
(B) 91
(C) 113
(D) 101

20) If the system of equations

2x – y + z = 4
5x + λy + 3z = 12
100 x – 47 y + µz = 212,
has infinitely many solutions, then µ – 2λ is equal to

(A) 56
(B) 59
(C) 55
(D) 57

SECTION-II

1) Let f be a differentiable function such that

2(x + 2)2f(x) – 3(x + 2)2 = 10

x ≥ 0. Then f(2) is equal to _____.

2) If for some α, β; α ≤ β, α + β = 8 and sec2(tan–1α) + cosec2(cot–1β) = 36, then α2 + β is ______.

3) The number of 3-digit numbers, that are divisible by 2 and 3, but not divisible by 4 and 9, is

4) Let be a 3 × 3 matrix such that XT AX = O for all nonzero 3 × 1 matrices X = .

If , and det (adj(2(A + I))) = 2α3β5γ, α, β, γ , ∈ N, then

α2 + β2 + γ2 is

5) Let S = {p1, p2……, p10} be the set of first ten prime numbers. Let A = S ∪ P, where P is the set of
all possible products of distinct element of S. Then the number of all ordered pairs (x, y), x ∈ S, y ∈
A, such that x divides y , is ______.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A D D A D A D D C C B B B B C A A C B

SECTION-II

Q. 21 22 23 24 25
A. 48 35 2 8 15

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B A B C C A A D A A D B D C A C A A B

SECTION-II

Q. 46 47 48 49 50
A. 962 700 61 3 420

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D D C A A D D B A C B C C A D B A D B D

SECTION-II

Q. 71 72 73 74 75
A. 19 14 125 44 5120
 SOLUTIONS

PART-1 : PHYSICS

1)

Ans. (1)

2) When P = 2.5 D

When P' = 2.6 D

Relative decrease in focal length

Ans. (1)

3) T is surface tension

P in air bubble =

= 0.05
Ans. (4)

4)
Last significant digits are 3 in operands so results should rounded off to 3 digits.
∴ y = 1330
Ans. (4)
5)

….. (i)

and ….. (ii)

Now

λAB = 3000Å
Ans. (1)

6) Conceptual
Ans. (4)

7) W = ΔU = SΔA
One drop to n drop

So

For on drop to 27 drops

….. (i)
For one drop to 64 drops

… (ii)
(ii)/(i)

Ans. (1)
8)

L = mvh

Ans. (4)

9)
n 480 = m 600
nmin = 5
Ans. (4)

10)

Ncosθ – f sinθ = mg

Rgtanθ + µRg = v2 – v2µtanθ

Ans. (3)

11)

Ans. (3)
12)

Ans (2)

13) A = 1 cm

∴ D = 4 × 6 + 1 = 25
d=1

Ans. (2)

14) T2 = KR3

Ans. (2)

15)

f2 = 12
f1 : f2 = 4 : 12 = 1 : 3
Ans. (2)
16)

17)

Ans. (1)

18)
A : plate area
d : distance between the plates.
Capacitance initial

units
Option 'C' ℓ = 6 cm
b = 5 cm
d = 3 cm
Capacitance = 10 ∈0 units
Option 'E' ℓ = 5 cm
b = 2 cm
d = 1 cm
Capacitance = 10 ∈0 units
∴ Ans is option (1)

19) F = α + βx2

Work done
20) Given that
P = kT

= constant
∴ Volume is constant or isochoric process.
∴ WD = 0
∴ Q = ΔU
Also temperature increases hence internal energy increases.

21)

Total flux through square

Lets divide square is 8 equal parts.
Flux is same for each part.

∴ Flux through shaded portion is (Total flux)

∴ required Ans. is 48

Note : Distance of charge from square loop is not mentioned we have assume it as .

22)

Given least count of Screw Gauge = 0.01 mm

L.C = = 0.01 mm

New pitch =
= (0.01) 3.5
= 0.035 mm
= 35 × 10–3 mm
∴ Ans. is 35
23)

9Ω is the resistance of whole wire

∴ resistance of each wire = 3Ω.
∴ Equivalent resistance = 2Ω

24)
Let B be the magnetic field due to single side

then

∴ Bnet at centre O = 4B
= 8 × 10–6
∴ p = 8 Ans.

25) Given that process is isobaric ΔT = 50°C

Q in isobaric process = nCPΔT = E1
ΔU in isobaric process = nCVΔT = E2

Given, gas is monoatomic

∴g=1+

=
Now, as per question.
 x = 15

PART-2 : CHEMISTRY

26) Fe2+(aq) + Ag+(aq) → Fe3+ (aq) + Ag(s)

0
–3F(–z) = –2F(–y) + ΔG2

Also

for reaction will be

= x + 2y –3z
Option (2)

27) Addition of H-Br(aq) to alkene follows electrophilic addition mechanism. In the rate
determining step a carbocation intermediate is formed. Among P, Q, R & S compound Q will
form most stable carbocation intermediate since it is resonance stabilized.

28)
[Co(NH3)5Cl]Cl2(aq.) + 2AgNO3(aq.) →
[Co(NH3)5Cl](NO3)2(aq.) + 2AgCl(s)

29) Carbocation intermediate is stabilised by +I, +M & hyperconjugation effect. Since in

option 2 carbocation is in conjugation with stronger +M group –OCH3 hence it will be most
stable.

30) A :
31) Tb4+ is strongest oxidising agent

32)
At eq : s 3s
Ksp = (s).(3s) = 27s4
3

27s4 = 1.6 × 10–30

Option (1)

33) Reaction is spontaneous at relatively high temperature and non-spontaneous at low

temperature ΔG = ΔH – TΔS
It is only possible when ΔH and ΔS both are positive.
Option (1)

34) In Dumas method nitrogen present in organic compound is converted into N2 gas whose
volumetric analysis gives the percentage of nitrogen atom in the organic compound.

35) Properties of elements are periodic function of their atomic number. Elements having
similar outer electronic configuration are arranged in same group. Number of elements in a
period is not equal to number of atomic orbitals available in energy level that is being filled.
Hence, A, C & E are incorrect
36) In Ribose carbohydrate present in DNA is β-2-Deoxy-D-Ribose whose structure is

which is a reducing D-sugar in β anomeric form & it is a pentose sugar.

37)

38) Oxygen exists as O2 (Atomicity = 2)

Sulphur exists as S8 (Atomicity = 8)
Hence, Melting point & Boiling point of sulphur are significantly large compared to oxygen.

39)
t=0 P0 – –

t=t P0–x 2x

Ptotal = =
Option (4)

40) The rate of nucleophilic addition decreased due to steric crowding around carbonyl carbon
& increased by electron withdrawing group if the steric crowding is same hence the reactivity
towards nucleophilic addition will be
41)

42) On adding non-volatile solute in a solvent, the freezing point of solution decreases.

F.P. of solution < F.P. of pure solvent

Also V.P. of solution decreases on adding non-volatile solute in a solvent.

43)
Dipole moment H2O > NH3 > CH4
H2O & NH3 are Lewis Bases
NH3 act as Lowry- Bronsted base
Hence, A, B & C are correct

44)
⇒ This reaction will proceed faster in less polar medium which will not increase the activation
energy value.
⇒ This reaction will proceed faster in more polar medium which will decrease the activation
energy value.

45)

46) Initial pressure of N2O5

t = 0 14.35
t = eq 14.35 –2P 2P P
PTotal at eqb = 14.35 + P = 18.65
P = 4.3

Ans. 962

47)

= 110 – 160 = – 50 JK–1 mol–1

0
ΔG = 0 at eqb
0 0 0
ΔG = ΔH – TΔS
0 = –35000 – T(–50)
T = 700 Kelvin
Ans. 700
 48) C6H5COOH+NaHCO3→ C6H5COO–Na+ +H2O + CO2
x gm 11.2 L

mole of C6H5COOH = mole of CO2 =

mass of C6H5COOH = x = 0.5 × 122 = 61 gm
Ans. 61

49) Only Cu2+, Fe3+, Ca2+ & Zn2+ form precipitate with K4[Fe(CN)6]

50) moles of

moles of

CO is L.R.

mole of Fe =

mass of Fe =
Ans. 420

PART-3 : MATHEMATICS

51)
=
= =
=
=
= Given
=

52)
Let x = sin2θ dx = 2sinθcosθdθ
I(m,n) =

I (9, 14) + I (10, 13) = 2

=
= I (9, 13)

53) F(x) – 6f(1/x) = ……(1)

Replace x →

F(1/x) – 6(x) = ……(2)

Using (1) & (2)

f(x) = – 2x –

B=

=
α = 3, β = ½
So, α +2β = 3 + 1 = 4

54) Sn = …. N terms S2025 = =

= ........

=
= = 45

Given :
9p = 45
p=5
|A20 –A15| = |–5 + 19 × 5| – [–5 + 14 × 5]
= |90 – 65|= 25

55) f(x) =
f(x) =

f(x) =

f(4 – x) =

f(x) + f(4 – x) =

So,

Similarly =

⇒
Ans. 118

56)

⇒
Similarly

Real =
Im = 9
Ans. 441
57)

58)
Let M (3 λ + 6, 2 λ + 7, – 2λ + 7)

Area = = 21

59)

∴ I.F. =

∴
∴

y(0) = 0 ⇒ 0 = 0 + C ⇒ C = 0

60) Product of focal distances = (a + ex1) (a – ex1)

=

= a2 – 3e2 = ⇒ a2 = + 3e2
⇒ 4a2 = 7 + 12e2

& lines on

12(1– e2) + 1 = 4a2 (1 – e2)

13 – 12 e2 = (7 + 12e2) (1 – e2)
⇒ 13 – 12 e2 = 7 – 7e2 + 12e2 – 12e4
⇒ 12 e4– 17e2 + 6 = 0

∴ difference =

61) p(S5) =

p(S5) =

required prob = + …∞
62)

A=

⇒ 11 t2 + 2t – 9 = 0
11 t2 + 11t – 9t – 9 = 0

t=–1&t=

∴ =

∴ largest area =

63)

x2 + 4x +2 ≤ y ≤ |x + 2|
The area bounded between y = x2 + 4x + 2 = (x + 2)2 –2 and y = |x + 2|
is same as area bounded between y = x2–2 and y = |x|
For P.O.I |x|2 – 2 = |x|
⇒ |x| = 2 ⇒ x = ± 2

∴ Required area = –

=
=

64) Mean

= 55 – (4+5)+(6+8) = 60

= 371 –(42 + 52) + (62 + 82) = 430

Variance

σ2 = 43 – 36
σ2 = 7

65)
Centre (1, –2), r = 3
Reflection of (1, –2) about 2x – 3y + 5 = 0

x = –3, y = 4
Equation of circle ‘C’
C : (x+3)2 + (y– 4)2 = 9
A.T.Q.
 (arcAB) =

rθ =

(α + 6)2 + (β – 4)2 = 27
(α +3)2 ± (β – 4)2 = 9
___________________
(α + 6)2 – (α + 3)2 = 18
⇒ 6α = –9

⇒ ,
∴

=4

66) (1 + x)n+4
n+4
C4, n+4C5,n+4C6 → A.P.
⇒ 2 × n+4C5 = n+4C4 + n+4C6
⇒ 4 × n+4C5 = ( n+4C4 + n+4C5) +( n+4C5 + n+4C6)
⇒ 4 × n+4C5 = n+5C5 + n+5C6

⇒
⇒ n2 + 11n + 30 = 24 n
⇒ n2 – 13 n + 30 = 0
⇒ n = 3, 10(rejected)
n ≠ 10
∴ Largest binomial coefficient in expansion of (1 + x)7

( n + 4 = 7) is coeff. of middle term

⇒ 7C4 = 7C3 = 35
67) (x2 – 9x + 11)2 – (x2 – 9x + 20) = 3
Let
⇒ x2 – 9x = t
⇒ t2 + 22t + 121 – t – 20 – 3 = 0
⇒ t2 + 21t + 98 = 0
⇒ (t + 14)(t + 7) = 0
⇒ t = – 7, – 14
So, x2 – 9x = – 7, – 14
x2 – 9x + 7 = 0 or x2 – 9x + 14 = 0

Product of all rational roots = 7 × 2 = 14

68) Equation of line through point (–1, 2,1) is →

⇒ – (2) = λ

So,

By (1) → (Let)

So,
For intersection point ‘P’
x = 2λ – 1 = 3μ – 2
y = 3λ + 2 = 2μ + 3

z=4λ+1=μ+4
So, point P(x, y, z) = (1, 5, 5) & Q(4, – 5, 1)
∴ PQ =
= =

69)
PM = QM
So, =
M lies on the time
2x – 3y + λ = 0

⇒ 3(–11λ –99) + 4 (8λ + 66) – α(–24 + 22) = 0

⇒ 33λ – 297 + 32λ + 264 + 24α –22α = 0
⇒ –λ + 2α – 33 = 0 …..(1)
∴λ=–7
– (–7) + 2α – 33 = 0
2α = 26
α = 13
∴ |αλ| = |13 ×(–7)| = 91

70) Δ = 0 ⇒
2(λμ+141) + (5μ –300) –235 –100λ = 0 …(1)

Δ3 = 0 ⇒
6λ = –12 ⇒ λ = –2
Put λ = 2 in (1)
2(–2μ + 141) + 5μ – 300 – 235 + 200 = 0
μ = 53
∴ 57

71) Differentiate both sides

4(x+2) f(x) + 2(x+2)2f'(x) – 6(x+2)= 10(x+2) f(x)
2(x+2)2f’(x) – 6(x+2)f(x) = 6(x+2)

(x+2)
ln (y+1) = 3 ln(x+2) + C
(y + 1) = C(x+2)3

f(2) = 19

72) If(tan(tan–1(α)) + 1 (cot(cot–1β))2 = 36

α2 + β2 = 34
αβ = 15
α = 3, β = 5
∴ α2 + β = 9 + 5 = 14

73) No. of 3 digits = 999 – 99 = 900

No. of 3 digit numbers divisible by 2 & 3 i.e. by 6

No. of 3 digit numbers divisible by 4 & 9 i.e. by 36

∴ No. of 3 digit numbers divisible by 2 & 3 but not by 4 & 9

150 – 25 = 125

74) XTAX = 0

(xyz)

(xyz)
x(a1x +a2y + a3z) + y(b1x + b2y + b3z) + z(c1x + c2y + c3z) = 0
a1 = 0, b2 = 0 c3 = 0
a2 + b1 = 0, a3 + c1 = 0, b3 = c2 = 0
A = skew symm matrix

⇒
x+y=1
–x + z = 4
y+z=5

2x + y = 0 x = –1
–x + z = 4 y=2
–y –2z = –8 z=3

2(A+I) =
2(A+I)=120 ⇒ det |adi(2(A+I))|
= 1202 = 26.32.52
α = 6, β = 2, γ = 2

75) Let
y = λx
= 10 × (9C0 + 9C1 + 9C2 + 9C3 + …. +9C9)
= 10 × (29)
10 × 512 = 5120