Org Chem Project
Org Chem Project
Introduction
CARBOHYDRATES
(degree of
polymerization)
Oligosaccharides (3 Malto-
Maltodextrins
–9) oligosaccharides
Raffinose, stachyose,
Other
fructo-
oligosaccharides
oligosaccharides
Polysaccharides (>9
Starch Amylose, amylopectin, modified starches
)
Glycogen, Cellulose, H
Non-starch
emicellulose, Pectins,
polysaccharides
Hydrocolloids
Carbohydrate consumed in food yields 3.87 kilocalories of energy per gram for
simple sugars, and 3.57 to 4.12 kilocalories per gram for complex carbohydrate
in most other foods. Relatively high levels of carbohydrate are associated with
processed foods or refined foods made from plants, including sweets, cookies
and candy, table sugar, honey, soft drinks, breads and crackers, jams and fruit
products, pastas and breakfast cereals. Lower amounts of carbohydrate are
usually associated with unrefined foods, including beans, tubers, rice, and
unrefined fruit. Animal-based foods generally have the lowest carbohydrate
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PROTEINS
Proteins are large bimolecular and macromolecules that comprise one or more
long chains of amino acid residues. Proteins perform a vast array of functions
within organisms, including catalyzing metabolic reactions, DNA
replication, responding to stimuli, providing structure to cells and organisms,
and transporting molecules from one location to another. Proteins differ from
one another primarily in their sequence of amino acids, which is dictated by
the nucleotide sequence of their genes, and which usually results in protein
folding into a specific 3D structure that determines its activity. Proteins are
made up of building blocks called amino acids. There are about 20 different
amino acids that link together in different combinations. Your body uses them
to make new proteins, such as muscle and bone, and other compounds such
as enzymes and hormones. It can also use them as an energy source. Some
amino acids can be made by your body – there are 11 of these and they’re
known as non-essential amino acids. There are 9 amino acids that your body
cannot make, and they are known as essential amino acids. You need to
include enough of these in your diet so that your body can function. The
nutritional value of a protein is measured by the quantity of essential amino
acids it contains. Different foods contain different amounts of essential amino
acids. Generally:
Animal products (such as chicken, beef or fish and dairy products) have all of
the essential amino acids and are known as ‘complete’ protein (or ideal or
high-quality protein).
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Soy products, quinoa and the seed of a leafy green called amaranth
(consumed in Asia and the Mediterranean) also have all of the essential
amino acids.
Plant proteins (beans, lentils, nuts and whole grains) usually lack at least one
of the essential amino acids and are considered ‘incomplete’ proteins. People
following a strict vegetarian or vegan diet need to choose a variety of protein
sources from a combination of plant foods every day to make sure they get an
adequate mix of essential amino acids. If you follow a vegetarian or vegan
diet, as long as you eat a wide variety of foods, you can usually get the protein
you need. For example, a meal containing cereals and legumes, such as baked
beans on toast, provides all the essential amino acids found in a typical meat
dish.
‘lean meat and poultry, fish, eggs, tofu, nuts and seeds and legumes/beans’
group
‘Milk, yoghurt, cheese and/or alternatives (mostly reduced fat)’ group.
As part of a healthy diet, the Guidelines recommend particular serves per day
from each of the 5 food groups. The human body can’t store protein and will
excrete any excess, so the most effective way of meeting your daily protein
requirement is to eat small amounts at every meal.
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So, what is a serve? A standard serving size of ‘lean meat and poultry, fish,
eggs, nuts and seeds, and legumes/beans’ is one of:
65 g cooked lean meats such as beef, lamb, veal, pork, goat or kangaroo
(about 90 to 100 g raw)
80 g cooked lean poultry such as chicken or turkey (100 g raw)
100 g cooked fish fillet (about 115 g raw weight) or one small can of fish
2 large eggs
1 cup (150 g) cooked dried beans, lentils, chickpeas, split peas or canned
beans (preferably with no added salt)
170 g tofu
30 g nuts, seeds, peanut or almond butter or tahini or other nut or seed paste
(no added salt).A serve of ‘milk, yoghurt, cheese and/or alternatives (mostly
reduced fat)’ could include:
250 ml (1 cup) fresh, UHT long life, reconstituted powdered milk or buttermilk
120 ml (1/2 cup) evaporated milk
200 g (3/4 cup or 1 small carton) yoghurt
40 g (2 slices) hard cheese such as cheddar
120 g (1/2 cup) ricotta cheese.
Protein requirements for children and teenagers change as they grow. Read
about the recommended number of serves for children, adolescents
and toddlers for all 5 food groups.
If you’re looking for ways to get more protein into your diet, here are some
suggestions:
Try a peanut butter sandwich. Remember to use natural peanut butter (or any
other nut paste) with no added salt, sugar or other fillers.
Low-fat cottage or ricotta cheese is high in protein and can go in your
scrambled eggs, casserole, mashed potato or pasta dish. Or spread it on your
toast in the morning.
Nuts and seeds are fantastic in salads, with vegetables and served on top of
curries. Try toasting some pine nuts or flaked almonds and putting them in
your green salad.
Beans are great in soups, casseroles, and pasta sauces. Try tipping a drained
can of cannellini beans into your favorite vegetable soup recipe or casserole.
A plate of hummus and freshly cut vegetable sticks as a snack or hummus
spread on your sandwich will give you easy extra protein at lunchtime.
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Greek yoghurt is a protein rich food that you can use throughout the day. Add
some on your favorite breakfast cereal, put a spoonful on top of a bowl of
pumpkin soup or serve it as dessert with some fresh fruit.
Eggs are a versatile and easy option that can be enjoyed on their own or
mixed in a variety of dishes.
Protein deficiency means not getting enough protein in your diet. Protein
deficiency is rare in Australia, as the Australian diet generally includes far more
protein than we actually need. However, protein deficiency may occur in
people with special requirements, such as older people and people following
strict vegetarian or vegan diets.
From around 50 years of age, humans begin to gradually lose skeletal muscle.
This is known as sarcopenia and is common in older people. Loss of muscle
mass is worsened by chronic illness, poor diet and inactivity.
Meeting the daily recommended protein intake may help you maintain muscle
mass and strength. This is important for maintaining your ability to walk and
reducing your risk of injury from falls. To maintain muscle mass, it’s important
for older people to eat protein ‘effectively’. This means consuming high-quality
protein foods, such as lean meats.
LIPIDS
The simplest fatty acids are unbranched, linear chains of CH2 groups linked by
carbon-carbon single bonds with one terminal carboxylic acid group. The
term saturated indicates that the maximum possible numbers of hydrogen
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atoms are bonded to each carbon in the molecule. Many saturated fatty acids
have a trivial or common name as well as a chemically descriptive systematic
name. The systematic names are based on numbering the carbon atoms,
beginning with the acidic carbon. The table gives the names and typical
biological sources of the most common saturated fatty acids. Although the
chains are usually between 12 and 24 carbons long, several shorter-chain fatty
acids are biochemically important. For instance, butyric acid (C4) and caproic
acid (C6) are lipids found in milk. Palm kernel oil, an important dietary source
of fat in certain areas of the world, is rich in fatty acids that contain 8 and 10
carbons (C8 and C10).
number of carbons in
trivial name systematic name typical sources
chain
n-hexadecanoic
palmitic acid 16 olive oil, animal lipids
acid
Unsaturated fatty acids have one or more carbon-carbon double bonds. The
term unsaturated indicates that fewer than the maximum possible numbers of
hydrogen atoms are bonded to each carbon in the molecule. The number of
double bonds is indicated by the generic name—monounsaturated for
molecules with one double bond or polyunsaturated for molecules with two or
more double bonds. Oleic acid is an example of a monounsaturated fatty acid.
Common representative monounsaturated fatty acids together with their
names and typical sources are listed in the table. The prefix cis-9 in the
systematic name of palmitoleic acid denotes that the position of the double
bond is between carbons 9 and 10. Two possible conformations, cis and trans,
can be taken by the two CH2 groups immediately adjacent to the double-
bonded carbons. In the cis configuration, the one occurring in all biological
unsaturated fatty acids, the two adjacent carbons lie on the same side of the
double-bonded carbons. In the trans configuration, the two adjacent carbons
lie on opposite sides of the double-bonded carbons.
number of carbons
trivial name systematic name typical sources
in chain
cis-13-docosenoic
erucic acid 22 rapeseed oil
acid
number of carbons
trivial name systematic name typical sources
in chain
acid tissue
number of typical
trivial name systematic name
carbons in chain sources
corn oil,
cis-9-, cis-12- animal
linoleic acid 18
octadecadienoic acid tissues,
bacteria
5,8,11-eicosatrienoic 20
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number of typical
trivial name systematic name
carbons in chain sources
acid
8,11,14-eicosatrienoic
20 brain tissue
acid
7,10,13-
22 phospholipids
docosatrienoic acid
8,11,14-
22
docosatrienoic acid
4,7,10,13-
22 brain tissue
docosatetraenoic acid
4,7,10,13,16,19-
22 brain tissue
docosahexaenoic acid
The main source of fatty acids in the diet is triglycerides, generically called fats.
In humans, fat constitutes an important part of the diet, and in some countries
it can contribute as much as 45 percent of energy intake. Triglycerides consist
of three fatty acid molecules, each linked by an ester bond to one of the three
OH groups of a glycerol molecule. After ingested triglycerides pass through the
stomach and into the small intestine, detergents called bile salts are secreted
by the liver via the gall bladder and disperse the fat as micelles. Pancreatic
enzymes called lipases then hydrolyze the dispersed fats to give
monoglycerides and free fatty acids. These products are absorbed into the cells
lining the small intestine, where they are resynthesized into triglycerides. The
triglycerides, together with other types of lipids, are then secreted by these
cells in lipoproteins, large molecular complexes that are transported in the
lymph and blood to recipient organs. In detail, the process of triglyceride or fat
absorption from dietary sources is quite complex and differs somewhat
depending upon the animal species.
Food Science
Food science is the basic science and applied science of food; its scope starts at
overlap with agricultural science and nutritional science and leads through the
scientific aspects of food safety and food processing, informing the
development of food [Link] science brings together multiple
scientific disciplines. It incorporates concepts from fields such
as chemistry, physics, physiology, microbiology, and biochemistry. Food
technology incorporates concepts from chemical engineering, for
[Link] of food scientists include the development of new food
products, design of processes to produce these foods, choice of packaging
materials, shelf-life studies, sensory evaluation of products using survey
panels or potential consumers, as well as microbiological and chemical
testing. Food scientists may study more fundamental phenomena that are
directly linked to the production of food products and its
[Link] Institute of Food Technologists defines food science as “the
discipline in which the engineering, biological, and physical sciences are used
to study the nature of foods, the causes of deterioration, the principles
underlying food processing, and the improvement of foods for the consuming
public”. The textbook Food Science defines food science in simpler terms as
“the application of basic sciences and engineering to study the physical,
chemical, and biochemical nature of foods and the principles of food
processing”.“Feeding the World Today and Tomorrow: The Importance of Food
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frozen foods
canned foods
microwave meals
milk which keeps
snacks
nutritious new foods
more easily prepared traditional foods
above all, VARIETY in our diets.
The Food Scientist helps supply this bounty by learning to apply a wide range
of scientific knowledge to maintain a high quality, abundant food supply. Food
Science allows us to make the best use of our food resources and minimize
waste.
Most food materials are of biological origin. How they behave in harvesting,
processing, distribution, storage and preparation is a complex problem. Full
awareness of all important aspects of the problem requires broad-based
training. To be a Food Scientist and help handle the world’s food supply to
maximum advantage, you need some familiarity with
Chemistry
Microbiology
Biochemistry
Engineering
Some specialized Statistics.
With this special training in the applied Food Science, many exciting and
productive careers with a wide range of employment opportunities exist for
the trained professional, such as
Toxicologist
for those consumers who may worry about ingesting chemicals when they eat
fruits and vegetables. Another major advantage to biotech crops is they
require less tilling, or plowing, to control weeds since many are modified to be
inherently resistant to herbicides, which can be used more selectively. The use
of conservation tillage, where much or all of the crop residue is left in the field
and tilling is reduced or eliminated, helps to conserve water from rainfall and
irrigation, increase water absorption, limits soil erosion and compaction, and
creates healthier soil. All of these benefits aid in maximizing crop yields and
minimizing water usage2. Additionally, conservation tillage releases less
carbon dioxide, or CO2, into the environment compared to conventional tillage
and helps to sustain habitats beneficial for insects, birds, and other animals 3.
Finally, biotechnology can help to limit deforestation. This is due to the fact
biotech crops produce higher yield and therefore require less acreage to
produce the same amount of product. In addition, researchers are working on
modified growing traits, such as drought resistance, to aid in growing food in
less arable areas.
omega-3 fatty acids, while still having the first generation growing traits, which
give rise to hardy, high-yield crops. Would consumers be likely to eat biotech
foods? According IFIC’s 2008 Food Biotechnology: A Study of US Consumer
Trends, the majority (53 percent) of consumers have neutral impressions of
plant biotechnology. A majority would purchase foods produced through
biotechnology for specific benefits including providing more healthful fats (78
percent), like Omega-3, reducing trans (76 percent) and saturated fat (75
percent); and making foods taste better or fresher (67 percent).
Bibliography
1. [Link]
2. [Link]
3. [Link]
4. [Link]
5. [Link]
6. [Link]