MOLE CONCEPT

1. Complete combustion of 1.80 g of an oxygen 8. The mole fraction of a solute in a 100 molal
containing compound (CxHyOz) gave 2.64 g of aqueous solution _______ × 10–2.
CO2 and 1.08 g of H2O. The percentage of oxygen (Round off to the Nearest Integer).
in the organic compound is: [Given: Atomic masses: H : 1.0 u, O : 16.0 u]
[JEE Main - 2021] [JEE Main - 2021]
(A) 51.63 (B) 63.53
(C) 53.33 (D) 50.33

9.
2. The formula of a gaseous hydrocarbon which
requires 6 times of its own volume of O2 for
Consider the above reaction where 6.1 g of
complete oxidation and produces 4 times its own
benzoic acid is used to get 7.8 g of m-bromo
volume of CO2 is CxHy. The value of y is benzoic acid. The percentage yield of the product
_______. is_____.
[JEE Main - 2021] (Round off to the Nearest integer)
[Given: Atomic Masses: C = 12.0u, H : 1.0u,
3. When 35 mL of 0.15 M lead nitrate solution is O : 16.0u, Br = 80.0 u]
mixed with 20 mL of 0.12 M chromic sulphate [JEE Main - 2021]
solution, ________ × 10–5 moles of lead sulphate
precipitate out. (Round off to the Nearest 10. A 6.50 molal solution of KOH (aq.) has a density
Integer). of 1.89 g cm–3. The molarity of the solution is
[JEE Main - 2021] ________ mol dm–3.
(Round off to the Nearest Integer).
[Atomic masses: K :39.0 u; O :16.0 u; H :1.0 u]
4. The number of significant figures in 50000.020
[JEE Main - 2021]
× 10–3 is _____.
[JEE Main - 2021]
11. The number of significant figures in 0.00340 is:
[JEE Main - 2021]
5. The number of chlorine atoms in 20 mL of
chlorine gas at STP is_____1021. (Round off to 12. Complete combustion of 3 g of ethane gives
the Nearest Integer). x × 1022 molecules of water. The value of x is
[Assume chlorine is an ideal gas at STP ______. (Round off to the Nearest Integer).
R = 0.083 L bar mol–1 K–1, NA = 6.023 ×1023] [Use: NA = 6.023 × 1023; Atomic masses in
[JEE Main - 2021] u : C : 12.0 ; O : 16.0 ; H : 1.0]
[JEE Main - 2021]
6. 4g equimolar mixture of NaOH and Na2CO3
contains x g of NaOH and y g of Na2CO3. The 13. An aqueous KCl solution of density 1.20 g mL–1
has a molality of 3.30 mol kg–1. The molarity of
value of x is _______ g. (Nearest integer)
the solution in mol L–1 is ________.
[JEE Main - 2021]
(Nearest integer)
[Molar mass of KCl = 74.5]
7. 250 mL of 0.5 M NaOH was added to 500 mL of [JEE Main - 2021]
1 M HCl. The number of unreacted HCl
molecules in the solution after complete reaction 14. Consider the complete combustion of butane, the
is ____ × 1021. (Nearest integer) amount of butane utilized to produce 72.0 g of
(NA = 6.022 × 1023) water is ________ × 10–1 g. (in nearest integer)
[JEE Main - 2021] [JEE Main - 2021]

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15. Sodium oxide reacts with water to produce 21. Compound A contains 8.7% Hydrogen, 74%
sodium hydroxide. 20.0 g of sodium oxide is Carbon and 17.3% Nitrogen. The molecular
dissolved in 500 mL of water. Neglecting the formula of the compound is _____.
change in volume, the concentration of the [Given: Atomic masses of C, H and N are 12, 1
resulting NaOH solution is _____ × 10–1 M. and 14 amu respectively. The molar mass of the
compound A is 162 g mo1–l]
(Nearest integer)
[JEE Main - 2022]
[Atomic mass: Na = 23.0, O = 16.0, H = 1.0]
(A) C4H6N2 (B) C2H3N
[JEE Main - 2021] (C) C5H7N (D) C10H14N2

16. If 80 g of copper sulphate CuSO4·5H2O is 22. Using the rules for significant figures, the correct
dissolved in deionised water to make 5 L of 0.02858  0.112
answer for the expression will
solution. The concentration of the copper 0.5702
sulphate solution is x × 10–3 mol L–1. The value be:
of x is _________. [JEE Main - 2022]
[Atomic masses Cu : 63.54 u, S : 32 u, O : 16 u, (A) 0.005613 (B) 0.00561
H : 1 u] (C) 0.0056 (D) 0.006
[JEE Main - 2021]
23. Production of iron in blast furnace follows the
following equation
17. 100g of propane is completely reacted with
Fe3O4 (s) + 4CO(g) → 3Fe(l) + 4CO2 (g)
1000g of oxygen. The mole fraction of carbon
when 4.640 kg of Fe3O4 and 2.520 kg of CO
dioxide in the resulting mixture is x × 10–2. The
value of x is _____. (Nearest integer) are allowed to react then the amount of iron (in g)
produced is:
[Atomic weight: H = 1.008; C = 12.00; O = 16.00]
[Given: Molar Atomic mass (g mol–1) : Fe = 56
[JEE Main - 2021]
Molar Atomic mass (g mol–1) : 0 = 16
Molar Atomic mass (g mol–1) : C = 12
18. 120 of an organic compound that contains only [JEE Main - 2022]
carbon and hydrogen gives 330 g of CO2 and (A) 1400 (B) 2200
270 g of water on complete combustion. The (C) 3360 (D) 4200
percentage of carbon and hydrogen, respectively
are. 24. The compound(s) that is(are) removed as slag
[JEE Main - 2022] during the extraction of copper is:
(A) 25 and 75 (B) 40 and 60 [JEE Main - 2022]
(A) CaO (B) FeO
(C) 60 and 40 (D) 75 and 25
(C) Al2O3 (D) ZnO
(5) NiO
19. Which one of the following is a water soluble
Choose the correct answer from the options given
vitamin, that is not excreted easily? below:
[JEE Main - 2022] [JEE Main - 2022]
(A) Vitamin B2 (B) Vitamin B1 (A) (3), (4) Only (B) (A1, (2), (5) Only
(C) Vitamin B6 (D) Vitamin B12 (C) (1), (2) Only (D) (2) Only

20. A commercially sold conc. HCl is 35% HCl by 25. Haemoglobin contains 0.34% of iron by mass.
mass. If the density of this commercial acid is The number of Fe atoms in 3.3 g of haemoglobin
1.46 g/mL, the molarity of this solution is: is:
(Given: Atomic mass of Fe is 56 u, NA in 6.022 ×
(Atomic Mass: Cl = 35.5 amu, H = 1 amu)
1023 mol–1)
[JEE Main - 2022]
[JEE Main - 2022]
(A) 10.2 M (B) 12.5 M (A) 1.21 × 10 5
(B) 12.0 × 1016
(C) 14.0 M (D) 18.2 M (C) 1.21 × 10 20
(D) 3.4 × 1022

Page [2]
26. Consider the above reaction, the limiting reagent 32. 1 L aqueous solution of H2SO4 contains 0.02 m
of the reaction and number of moles of NH3 mol H2SO4. 50% of this solution is diluted with
formed respectively are: deionized water to give 1 L solution (A). In
[JEE Main - 2022] solution (A), 0.01 m mol of H2SO4 are added.
(A) H2, 1.42 moles (B) H2, 0.71 moles Total m mols of H2SO4 in the final solution is
(C) N2, 1.42 moles (D) N2, 0.71 moles
____× 103 m mols.
[JEE Main - 2022]
27. 116 g of a substance upon dissociation reaction,
yields 7.5 g of hydrogen, 60g of oxygen and
33. CNG is an important transportation fuel. When
48.5g of carbon. Given that the atomic masses of
100 g CNG is mixed with 208 oxygen in vehicles,
H, O and C are 1, 16 and 12 respectively. The data
agrees with how many formulae of the following? it leads to the formation of CO2 and H2O and
[JEE Main - 2022] produces large quantity of heat during this
(A) CH3COOH (B) HCHO combustion, then the amount of carbon dioxide,
(C) CH3OOCH3 (D) CH3CHO produced in grams is________. [Nearest Integer]
[Assume CNG to be methane]
28. If a rocket runs on a fuel (C15H30) and liquid [JEE Main - 2022]
oxygen, the weight of oxygen required and CO2
released for every litre of fuel respectively are: 34. The moles of methane required to produce 81 g
(Given: density of the fuel is 0.756 g/mL) of water after complete combustion is _____
[JEE Main - 2022] × 10–2 mol. [Nearest Integer]
(A) 1188 g and 1296 g
[JEE Main - 2022]
(B) 2376 g and 2592 g
(C) 2592g and 2376 g
35. Two elements A and B which form 0.15 moles of
(D) 3429 g and 3142 g
A2B and AB3 type compounds. If both A2B and
29. Consider the reaction AB3 weigh equally, then the atomic weight of A
4HNO3(l) + 3KCl(s) → Cl2(g) + NOCl(g) + is _____ times of atomic weight of B.
2H2O(g) + 3KNO3(s) [JEE Main - 2022]
The amount of HNO3 required to produce 110.0g
of KNO3 is:
(Given: Atomic masses of H, O, N and K are 1, 36. 56.0 L of nitrogen gas is mixed with excess of
16, 14 and 39, respectively.) hydrogen gas and it is found that 20 L of
[JEE Main - 2022] ammonia gas is produced. The volume of unused
(A) 32.2 g (B) 69.4 g nitrogen gas is found to be ____ L.
(C) 91.5 g (D) 162.5 g [JEE Main - 2022]

30. A protein ‘A’ contains 0.30% of glycine

37. Chlorophyll extracted from the crushed green
(molecular weight 75). The minimum molar mass
leaves was dissolved in water to make 2 L
of the protein ‘A’ is________ × 103 g mol–1
solution of Mg of concentration 48 ppm. The
[nearest integer]
number of atoms of Mg in this solution is x × 1020
[JEE Main - 2022]
atoms. The value of x is________. (Nearest
31. The number of N atoms is 681 g of C7H5N3O6 is Integer)
x × 1021. The value of x is _____. (Given: Atomic mass of Mg is 24 g mol–1,
(NA = 6.02 × 1023 mol–1) (Nearest Integer) NA = 6.02 × 1023 mol–1)
[JEE Main - 2022] [JEE Main - 2022]

Page [3]
 44. When 0.01 mol of an organic compound
containing 60% carbon was burnt completely, 4.4
g of CO2 was produced. The molar mass of
38. compound is _________g mol–1)
(Nearest integer).
[JEE Main - 2023]

In the above reaction, 5 g of toluene is converted

45. The volume of HCl , containing 73 g L−1 ,
into benzaldehyde with 92% yield. The amount
of benzaldehyde produced is____×10—2 g. required to completely neutralise NaOH
(Nearest integer) obtained by reacting 0.69 g of metallic sodium
[JEE Main - 2022] with water, is_________ mL .(Nearest Integer)
(Given: molar Masses of Na, Cl, O, H, are 23,
39. In the following reaction 35.5, 16 and 1g mol−1 respectively)
[JEE Main - 2023]

46. Zinc reacts with hydrochloric acid to give

hydrogen and zine chloride. The volume of
hydrogen gas produced at STP from the reaction
The % yield for reaction I is 60% and that of of 11.5g of zinc with excess HCl is______ L
reaction II is 50%. The overall yield of the (Nearest integer)
complete reaction is ___% [nearest integer]
(Given : Molar mass of Zn is 65.4 g mol−1 and
[JEE Main - 2022]
Molar volume of H 2 at STP = 22.7 L )
40. In the given reaction, [JEE Main - 2023]
X + Y + 3Z XYZ3
if one mole of each of X and Y with 0.05 mol of 47. A sample of a metal oxide has formula M0.83O1.00
Z gives compound XYZ3. (Given: Atomic masses . The metal M can exist in two oxidation states
of X, Y and Z are 10, 20 and 30 amu, +2 and +3 . In the sample of M0.83O1.00 , the
respectively). The yield of XYZ3 is ________ g.
percentage of metal ions existing in +2 oxidation
(Nearest integer)
state is % . (nearest integer)
[JEE Main - 2022]
[JEE Main - 2023]
41. On complete combustion of 0.492 g of an organic
48. Assume carbon burns according to following
compound containing C, H and O, 0.7938 g of
equation:
CO2 and 0.4428 g of H2O was produced. The %
2C(s) + O2( g) → 2CO(g)
composition of oxygen in the compound is
_____. when 12 g carbon is burnt in 48 g of oxygen,
[JEE Main - 2022] the volume of carbon monoxide produced is
10−1 L at STP [nearest integer]
42. 2L of 0.2 M H2SO4 is reacted with 2L of 0.1 M [Given: Assume CO as ideal gas, Mass of C is
NaOH solution, the molarity of the resulting
12 g mol−1 , Mass of O is 16 g mol−1 and molar
product Na2SO4 in the solution is ____
millimolar. (Nearest integer). volume of an ideal gas at STP is 22.7 L mol−1 ]
[JEE Main - 2022] [JEE Main - 2023]

43. A 1.84 mg sample of polyhydric alcoholic 49. The density of 3 M solution of NaCl is 0.1 g
compound 'X' of molar mass 92.0 g/mol gave mL–1 Molality of the solution is
1.344 mL of H2 gas at STP. The number of ________________×10–2 m (Nearest Integer)
alcoholic hydrogens present in compound 'X' Given; Molar mass of Na and Cl is 23 and 35.5 g
is____. mol–1 respectively.
[JEE Main - 2022] [JEE Main - 2023]

Page [4]
50. Some amount of dichloromethane ( CH2Cl2 ) is 55. When a hydrocarbon A undergoes complete
combustion it requires 11 equivalents of oxygen
added to 671.141mL of chloroform ( CHCl3 ) and produces 4 equivalents of water. What is the
to prepare 2.6 10−3 M solution of CH2Cl2 molecular formula of A ?
[JEE Main - 2023]
(DCM). The concentration of DCM is______
(A) C11H4 (B) C11H8
ppm (by mass).
Given: (C) C9 H8 (D) C5H8
atomic mass: C = 12
H=1 56. If 5 moles of BaCl2 is mixed with 2 moles of
Cl = 35.5 Na3PO4, the maximum number of moles of
density of CHCl3 = 1.49 g cm−3 Ba3(PO4)2 formed is………….
(Nearest integer)
[JEE Main - 2023]
[JEE Main - 2023]

51. A 300 mL bottle of soft drink has 0.2MCO2 57. 0.5 g of an organic compound (X) with 60%
dissolved in it. Assuming CO2 behaves as an carbon will produce __________× 10–1 g of CO=
on complete combustion.
ideal gas, the volume of the dissolved CO2 at
[JEE Main - 2023]
STP is ____________ mL . (Nearest integer)
Given: At STP, molar volume of an ideal gas is 58. Which of the following have same number of
−1
22.7 L mol significant figures ?
[JEE Main - 2023] (a) 0.00253 (b) 1.0003
(c) 15.0 (d) 163
52. The molality of a 10%(v / v) solution of di- Choose the correct answer from the options given
bromine solution in CCl4 (carbon tetrachloride) below
[JEE Main - 2023]
is ' x '. x = 10−2 M . (Nearest integer) (A) a, b and c only
[Given: molar mass of Br2 = 160 g mol−1 (B) c and d only
atomic mass of C = 12 g mol−1 (C) a, c and d only
(D) b and c only
atomic mass of Cl = 35.5 g mol−1
density of dibromine = 3.2 g cm−3 59. Lime reacts exothermally with water to give ‘A’
which has low solubility in water. Aqueous
density of CCl4 = 1.6 g cm−3 ]
solution of ‘A’ is often used for the test of CO2, a
[JEE Main - 2023] test in which insoluble B is formed. If B is further
reacted with CO2 then soluble compound is
53. The number of units, which are used to express formed ‘A’ is
concentration of solutions from the following is [JEE Main - 2023]
___________ (A) Quick lime (B) Slaked lime
Mass percent. Mole, Mole fraction. Molarity, (C) Lime water (D) White lime
ppm. Molality
[JEE Main - 2023] 60. The number of molecules and moles in 2.8375
litres of O2 at STP are respectively
54. Number of hydrogen atoms per molecule of a [JEE Main - 2023]
hydrocarbon A having 85.8 % carbon is 22
(A) 7.527 × 10 and 0.250 mol
_________ (B) 1.505 × 1023 and 0.250 mol
(Given: Molar mass of A = 84 g mol–1) (C) 7.527 × 1023 and 0.125 mol
[JEE Main - 2023] (D) 7.527 × 1022 and 0.125 mol

Page [5]
61. Given below are two statements: one is labelled 67. 1g of a carbonate (M2 CO3 ) on treatment with
as Assertion A and the other is labelled as Reason R. excess HCl produces 0.01 mol of CO2 . The molar
Assertion A: 3.1500g of hydrated oxalic acid mass of M2 CO3 is ______ g mol −1.
dissolved in water to make 250.0 mL solution (Nearest integer)
will result in 0.1 M oxalic acid solution. [JEE Main - 2023]
Reason R: Molar mass of hydrated oxalic acid is
126 g mol–1. 68. Consider the following reaction:
In the light of the above statements, chose the 3PbCl2 + 2(NH4)3 PO4 → Pb3(PO4)2 + 6NH4Cl
correct answer from the options given below: If 72 mmol of PbCl2 is mixed with 50 mmol of
[JEE Main - 2023]
(NH4)3PO4, then the amount of Pb3(PO4)2 formed
(A) Both A and R are true but R is NOT the
is _______ mmol (nearest integer).
correct explanation of A.
[JEE Main - 2024]
(B) A is false but R is true.
(C) A is true but R is false.
69. 10 mL of gaseous hydrocarbon on combustion
(D) Both A and R are true and R is the correct
gives 40 mL of CO2 (g) and 50 mL of water vapour.
explanation of A.
Total number of carbon and hydrogen atoms in
62. Match List–I with List–II. the hydrocarbon is ______. [JEE Main - 2024]
List – I List – II
a 16g of CH4(g) p Weighs 28 g 70. Following Kjeldahl's method, 1 g of organic
b 1g of H2(g) q 60.2×1023 electrons compound released ammonia, that neutralised 10
c 1 mole of N2(g) r Weighs 32g mL of 2MH2SO4. The percentage of nitrogen in
d 0.5 mol of s Occupies 11.4 L the compound is _______%.
SO2(g) volume at STP [JEE Main - 2024]
Choose the correct answer from the options given
below: [JEE Main - 2023] 71. The quantity which changes with temperature is:
(A) a–p, b–r, c–q, d–s (B) a–q, b–r, c–s, d–p [JEE Main - 2024]
(C) a–q, b–s, c–r, d–p (D) a–q, b–s, c–p, d–r (A) Molality (B) Mole fraction
(C) Molarity (D) Mass percentage
63. The volume of hydrogen liberated at STP by
treating 2.4 g of magnesium with excess of 72. 9.3 g of aniline is subjected to reaction with
hydrochloric acid is × 10−2 L excess of acetic anhydride to prepare acetanilide.
Given: Molar volume of gas is 22.4 L at STP. The mass of acetanilide produced if the reaction
Molar mass of magnesium is 24 g mol−1. is 100% completed is _________× 10–1g.
[JEE Main - 2023] (Given molar mass in g mol–1 N : 14, O : 16,
C : 12, H : 1) [JEE Main - 2024]
64. A metal chloride contains 55.0% of chlorine by
weight. 100 mL vapours of the metal chloride at 73. The mass of sodium acetate (CH3COONa)
STP weigh 0.57 g. The molecular formula of the required to prepare 250 mL of 0.35M aqueous
metal chloride is (Given : Atomic mass of solution is _______ g.
chlorine is 35.5u) [JEE Main - 2023] (Molar mass of CH3COONa is 82.02 g mol–1)
(A) MCl2 (B) MCl4 [JEE Main - 2024]
(C) MCl3 (D) MCl
74. A sample of CaCO3 and MgCO3 weighed
65. An organic compound gives 0.220 g of CO2 and
2.21g is ignited to constant weight of 1.152 g .
0.126 g of H2 O on complete combustion. If the
% of carbon is 24 then the % hydrogen is ______ The composition of mixture is:
× 10−1. (Nearest integer) [JEE Main - 2023] (Given molar mass in g mol–1 CaCO3 : 100,
MgCO3 : 84) [JEE Main - 2024]
66. 0.400 g of an organic compound (X) gave (A) 1.187 g CaCO3 +1.187 g MgCO3
0.376 g of AgBr in Carius method for estimation of
(B) 1.023g CaCO3 +1.023g MgCO3
bromine. % of bromine in the compound (X) is
______. (C) 1.023g CaCO3 +1.187 g MgCO3
(Given: Molar mass AgBr = 188 g mol−1 (D) 1.187 g CaCO3 +1.023g MgCO3
Br = 80 g mol−1 ) [JEE Main - 2023]

Page [6]
75. The Molarity (M) of an aqueous solution 79. The number of moles of methane required to
containing 5.85 g of NaCl in 500 mL water is: produce 11g CO2(g) after complete combustion
–1
(Given: Molar Mass Na : 23 and Cl : 35.5 g mol ) is:
[JEE Main - 2024] (Given molar mass of methane in g mol–1 : 16)
(A) 20 (B) 0.2 [JEE Main - 2024]
(C) 2 (D) 4 (A) 0.75 (B) 0.25
(C) 0.35 (D) 0.5
76. Choose the Incorrect Statement about Dalton's
Atomic Theory 80. The density of 'x' M solution ('x' molar) of NaOH
[JEE Main - 2024] is 1.12 g mL–1. while in molality, the
(A) Compounds are formed when atoms of concentration of the solution is 3 m (3 molal).
different elements combine in any ratio Then x is
(B) All the atoms of a given element have (Given: Molar mass of NaOH is 40 g/mol)
identical properties including identical mass [JEE Main - 2024]
(C) Matter consists of indivisible atoms (A) 3.5 (B) 3.0
(D) Chemical reactions involve recorganization (C) 3.8 (D) 2.8
of atoms
81. Molality (m) of 3 M aqueous solution of NaCl is:
77. The incorrect postulates of the Dalton's atomic (Given : Density of solution = 1.25 g mL–1, Molar
theory are: mass in g mol–1 : Na-23, Cl-35.5)
[JEE Main - 2024] [JEE Main - 2024]
(A) Atoms of different elements differ in mass. (A) 2.90 m (B) 2.79 m
(B) Matter consists of divisible atoms. (C) 1.90 m (D) 3.85 m
(C) Compounds are formed when atoms of
different element combine in a fixed ratio. 82. Molality of an aqueous solution of urea is 4.44 m.
(D) All the atoms of given element have Mole fraction of urea in solution is x × 10–3.
different properties including mass. Value of x is _______. (integer answer)
(E) Chemical reactions involve reorganization [JEE Main - 2024]
of atoms.
Choose the correct answer from the options given 83. A solution is prepared by adding 1 mole ethyl
below: alcohol in 9 mole water. The mass percent of
(A) (B), (D), (E) only solute in the solution is _______ (Integer
(B) (A), (B), (D) only Answer)
(C) (C), (D), (E) only (Given : Molar mass in g mol–1 Ethyl alcohol : 46,
(D) (B), (D) only water : 18)
[JEE Main - 2024]
78. Ail organic compound has 42.1% carbon, 6.4%
hydrogen and remainder is oxygen. If its 84. Molarity (M) of an aqueous solution containing x
molecular weight is 342, then its molecular g of anhyd. CuSO4 in 500 mL solution at 32°C is
formula is: 2 × 10–1 M. Its molality will be ______× 10–3 m.
[JEE Main - 2024] (nearest integer).
(A) C11H18O12 (B) C12H20O12 [Given density of the solution = 1.25 g / mL .]
(C) C14H20O10 (D) C12H22O11 [JEE Main - 2024]

Page [7]
 ANSWER KEY
MOLE CONCEPT
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. C 8 525 7 1 1 226 64 78 9 4 18 3 464 13
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 64 19 D D C D B C D C C B C C 25
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 5418 0 143 225 2 46 24 530 30 2 46 25 3 or 6 200 15
Que. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 4 59 227 364 221 1362 139 5 12 C 1 11 C B D
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. D D 224 A 56 40 100 24 14 56 C 135 7 D B
Que. 76 77 78 79 80 81 82 83 84
Ans. A D D B B B 74 22 0.215

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