XII : TEST-1

Time : 3 hrs. M.M. : 180

PAR,CRJ,ML
TOPIC COVERED :
PHYSICS : Electrostatics
CHEMISTRY : Halogen Derivatives
MATHEMATICS : Matrices and Determinants

GENERAL INSTRUCTIONS :
1. The paper contains 15 subjective type questions.
2. There are Three Subjects (Physics Chemistry & Mathematics) in the question paper.
3. Figures in the bracket against the question indicate the marks it carries.
4. No student is permitted to leave examination hall before the time is complete.
5. Use of calculator is not permitted.
6. Answer every question at one place only and in the same sequence as in question paper.
7. Rough work should be done at a separate place on the answer-sheet.

PHYSICS
1. A system consists of a uniformly charged sphere of radius R and a surrounding medium filled by a charge with
the volume density  = /r, where  is a positive constant and r is the distance from the centre of sphere. Find
the charge q of the sphere for which the electric field intensity E outside the sphere is independent of r. Find the
value of E. [12]

2. A circular ring of radius R with uniform positive charge density  per unit length is located in the Y-Z plane with
its centre at the origin O. A particle of mass m and positive charge q is projected from the point
P (R 3 , 0, 0) on the positive X-axis directly towards O, with initial velocity v. Find the smallest (non-zero) value
of the speed v such that the particle does not return to P. [12]
3. Draw approximately the electrostatic field lines of a charge 2Q and another charge –Q kept at some distance
apart, also find out the null point and the locus of the point where potential is 0. [12]

4. (a) A cone of base radius R and height h is located in a uniform electric field
parallel to its base as shown in figure. What is the electric flux entering the
cone ? [6]
(b) An electron (charge = –e) is ejected, at an angle  to the normal
towards an infinite insulating plate which carries a negative surface y

charge density – . The electron’s initial kinetic energy is K0 . –––––––––––––––––

The electron is ejected a distance l0 away from the plane. What
l0
is the minimum distance from the plate l0 at which the electron
should be ejected to inorder to miss the plate? (neglect gravity). x [6]
ejection point

[1]
5. (a) Derive the expression for electric field due to uniform charge distribution on a long straight line at a distance
r from the line. [6]
(b) A thin conducting ring of radius a has an electric charge +Q distributed uniformly over its length. What
would be the increase in the tension T of the wire if a point charge +q is kept at the centre of ring ? [6]

CHEMISTRY
6. (a) Identify and draw structures of all the possible monochloro structural as well as stereo isomers expected
to be formed on free radical monochlorination of (CH3)2CHCH2CH3. [6]
(b) Write the products of the following reactions: [3]

(i) (ii) CH3 –CH2–CH = CH2 + HCl 





Peroxide
(iii)  

(c) Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination
yields [3]
(i) A single monochloride. (ii) Three isomeric monochlorides.
(iii) Four isomeric monochlorides.
7. (a) Draw the structures of major monohalo products in each of the following reactions: [6]
CH2CH3
Br , Heat or hv
(i) (ii) 
2

or NBS
O 2N

(iii) (iv)

Br , Heat or hv
(v) CH3CH2Br + NaI  (vi) 
2

or NBS
(b) Identify chiral and achiral molecules in each of the following pair of compounds. [3]

(c) Which alkyl halide from the following pairs would you expect to react more rapidly by an S N2
mechanism? [3]

[2]
8. (a) Identify A, B, C, D, E, R and R1 in the following [7]

(b) In the following pairs of halogen compounds, which compound undergoes faster SN1 reaction? [2]

(c) How the following conversions can be carried out? [3]

(i) Propene to propan-1-ol (single step)
(ii) Benzyl alcohol to 2-phenylethanoic acid (three steps)
(iii) Aniline to chlorobenzene (two steps)
9. (a) Show how are the following alcohols prepared by the reaction of a suitable Grignard reagent on methanal?
OH
CH2OH
H 3C – C – CH 3
(i) CH3  CH  CH 2OH (ii) (iii) [3]
|
CH3
(b) Write structures of the products of the following reactions: [3]

+
(i) H 2 O/H
CH3 – CH = CH2  (ii)


(iii)

(c) Write products (A,B,C) of the following reactions [3]

+
H /H2O
A
CH3
(CH3COO)2Hg
CH3 – CH – CH = CH2 NaBH4/OH
– B
B2H6–THF
H2O2/OH
– C
(d) Give reasons of the following [1½ + 1½ =3]
(i) Chlorobenzene is less reactive towards nucleophilic substitution.
(ii) Electron withdrawing groups ease the nucleophilic substitution of chloro benzene.
10. (a) Write down the possible mechanism of Hydration of alkene in presence of H +/H 2 O showing
rearrangement. [6]

OH Br

(b) Write down the mechanism of acid catalysed conversion of into . [6]

[3]
 MATHEMATICS

2  3
11. (a) Show that A =   satisfies the equation A2 – 6A + 17I = 0. Hence, find A–1. [6]
 3 4 

(b) If a, b, c are three consecutive terms of a decreasing A.P., prove that the following system of equations
in x, y cannot be consistent:
x y 1
   0; ax + by + c = 0; x+y+1=0 [6]
a b c

a 1 n 6 n
2
12. Let a = (a  1) 2n 2 4n  2 . Show that  a is a constant. [12]
(a  1) 3 3n 3 3n 2  3n a 1

13. Find the inverse of each of the following matrices by using elementary row operations

0 1 2  2  1 3
5 2    
A=  , B= 1 2 3 and C = 1 2 4  . [12]
2 1 3 1 1  3 1 1 
   

14. Consider the system of linear equations in x, y, z:

(sin 3)x – y + z = 0
(cos 2)x + 4y + 3z = 0
2x + 7y + 7z = 0.
Find the value of  for which this system has a nontrivial solution. [12]

a 0 1 a 1 1 f a 2 
       
15. A = 1 c b , B =  0 c d  , U =  g  , V =  0  . If there is vector matrix X, such that
1 d b f g h  h 0
     

AX = U has infinitely many solutions, then prove that BX = V cannot have a unique solution. If
afd  0 then prove that BX = V has no solution. [12]

[4]