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CLASSIC STUDY
Class Paper Type Chapter/course Total Marks Time
1st year Chemistry Subjective Chapter 09 40 1:50 hrs
Q.2: Give the short Answer. (12x2=24)
i. Why relative lowering of vapour pressure is ii Justify the statement: 100 g of 98% H 2 SO4 has a
independent of the temperature although vapour volume of 54.34cm3 of H 2 SO4 because its density is
pressure is affected by temperature? 1.84 gcm3
iii. Why one molal solution of urea in water is dilute as iv. Differentiate between continuous and discontinueos
compared to one molar urea solution although the solubility curve. Why some substances show
no. of solute particles are same in both cases? discontinuous solubility curve?
v. Differentiate between ideal and non-ideal solutions. vi. The boiling point of one molal sugar solution is
Give criteria. 100.52 C , but the boiling point of two molal sugar
solution is less than 101.04 C . Why?
vii. Why aqueous solution of NH 4 Cl is acidic but Na2 CO3 viii. Why heat of solution of a substance is measured at
is basic? infinite dilution?
ix. Define the following: x. Why the freezing point of a solution is always less than
(a) conjugate solution (b) critical solution the pure solvent?
temperature
xi. Define the following: xii. Why some solutions are called azeotropic and
(a) ebullioscopic constant (b) cryoscopic constant zeotropic?
Give the answers to the following in detail.
Q. 3: (a) What are Colligative properties? Describe elevation of boiling point in detail. (03)
(b) How T f is measured experimentally? (03)
(c) Calculate the molality of the solution obtain by mixing 250g of 20% solution of NaCl with
200g of 40% solution of NaCl. (02)
Q. 4 (a) What is Raoult’s Law? Describe its various forms. (03)
(b) Define the following terms and give example; (05)
(i) Mole fraction (ii) Molarity (iii) Molality (iv) Hydrolysis (v) Hydrates
Best Of Luck
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Class Paper Type Chapter/course Total Marks Time
1st year Chemistry Objective Chapter 09 10 10 min
Name: Roll No.
[Link]. 1. Encircle the correct option. Cutting erasing and overwriting is not allowed.
1. The freezing point of 0.1m aq. solution of a non-electrolyte and non-volatile solute is;
a. 0.093 C b. 0.186 C c. 0.93 C d. 1.86 C
2. Which one of the following will form minimum boiling azeotrop?
a. C2 H 5OH H 2O b. H 2O HCl c. Benzene + ether d. H 2O CH 3OH
3. The vapour pressure of aq. solution of ethanol is ;
a. Equal to ethanol b. equal to water
c. more than that of water d. less than that of water
4. The molarity of a solution obtained by dissolving 40g NaOH in 500cm 3 of solution.
a. 0.1 b. 0.5 c. 1.0 d. 2.0
5. Molal freezing point depression constant is the ratio of depression in freezing point to;
a. Molarity b. normality c. mole fraction d. molality
6. A solution contains 10 % glucose in water the volume in which one mole of glucose is dissolved will be;
a. 1000cm 3 b. 1800cm 3 c. 200cm3 d. 900cm3
7. Which of the following give basic solution when dissolved in water?
a. K b. PO43 c. SO42 d. NH 4
8. A solution having lowest boiling point?
a. 5.85 % NaCl soln b. 18% glucose soln c. 6% urea soln d. All have same b.p
9. Amount of H 2 SO4 required to prepare 500cm 3 of 0.1 M ;
a. 9.8 g b. 49 g c. 2.45 g d. 4.9 g
10. Which of the following represents correct formula of hydrate?
a. MgSO4 .5H 2O b. AlCl3 .6 H 2O c. Na2CO3 .5H 2O d. MgCl2 .2H 2O
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