1. 1 mole of an ideal gas expands 6.
2 moles of an ideal gas expand
isothermally at 300 K from 10 L to 20 L (R isothermally and reversibly from V to 2V at
= 8.314 J mol⁻¹ K⁻¹). Work done is: 300 K. Entropy change is:
1) 1.73 kJ 1) 2R ln2
2) 2.48 kJ 2) R ln2
3) 3.45 kJ 3) 2R
4) 5.76 kJ 4) R
2. A system absorbs 500 J heat and does 7. ΔH = –40 kJ, ΔS = –100 J K⁻¹. At 300 K,
200 J work. Change in internal energy is: ΔG is:
1) 700 J 1) –10 kJ
2) 300 J 2) –70 kJ
3) –300 J 3) –40 kJ
4) –700 J 4) +10 kJ
3. For an adiabatic expansion, if work done 8. Entropy at 0 K is zero for:
by system is 400 J, then ΔU is: 1) Elements in stable form
1) +400 J 2) Perfectly crystalline solids
2) –400 J 3) Substance at 1 atm, 25°C
3) 0 4) N₂O
4) +200 J
4. For an ideal gas, Cp – Cv = R. If Cv = 20.8 J 9. Highest entropy:
mol⁻¹ K⁻¹, Cp is: 1) Water
1) 12.5 2) Graphite
2) 20.8 3) Mercury
3) 29.1 4) Hydrogen
4) 41.6
5. If ΔU = 100 J and Δn(g) = 2 at 300 K (R = 10. If 500 J work is done on the system and
8.314), then ΔH is: it releases 200 J heat, ΔU is:
1) 100 J 1) 300 J
2) 4984 J 2) 700 J
3) 5098 J 3) –300 J
4) 120 J 4) –700 J