Stochiometry Code 2
Stochiometry Code 2
26 Diferentiate between atomte welght and 9. 17, (o) Aveselcontalns Nmolecules of oayyn
at a ceraln tempenatere and prernere.
actual weight of one atom. Row may molecsle of nipharHortde
an the Dessel acoomodate at the same
.7. What is the value ofavogdro's number? temperste and prere?
Q.& While stating the volume of a gas, the
pressure and temperature should alsobe given. () Each of the tuo flasks contabs 2.0 g of
Why ? gus at the same temperatune and pressure
Oneflask contatns oxygen and the other
0.9. The number of atomsin certaln volume of hydrogen.
hydrogen is twice'the nunber of atoms in the (0 Which sample contains the greater.
same volume of heliumat the same mmber of molecules ?
temperature and pressure. Why ? (i) If the hydrogen sample contains N
molecules, how many molecules are
10. How does Avogadro's law explatn Gay.
present in oxygen sanmple ?
lussac's law of gaseous volumes ?
2.J1. Explain the terms : (a) Gram atom Q. 18. Under the oane cOnditlons oft p t r
(b) Gram molecule pressure you collect 2itres oforton Bocidle
3Htres ofchlorte, 5lHtres of hytroga,4Btres
af nitroga and 1litne of nykr bu
12. Defne emplrical formulaand molecular uhieh gas sANple will here be
formuda ofa compound. () the reateat nanbr of molecue;
(6) the leut nmber of molecalea.
1
Q.17
be required to
voluw of oygenwokld
0.10. Whatcompletaly 400 ML of acetylene (CoH)?
burm dBoxide
NUMERICAL PROBLEMS: volume ofcarbon
Also calculate the
to give formed 4CO,+ 2H,0 (D
reacta with kydrogenamnonia
Q.1. Nitrogen Calalate 2C,H, + 5O,
the volne of
aNDROnIa:
reatts tolth6 ltnes
guforme when sitrogen betrg measTed ut
hyarogen and
of oxyge# and explodedtn and
of aydrogos AU DOne
Q, 11. 20 ml each
monaxldeare
S,TP. 10ml, ofoarbon the volume and
enclosure. What wlllbe thegases when
oguined to contposltlon ofthe mixture of
Q.2 alarlate te vome of oygn temperature ?
bun completely a nistunt of22.4 d of CH, they ar cooled to room
being
and 11.2 d f H, (ell volumes c
measrdat STP] nttragen monozide gnd 200
0 12. 50 cr of mixd togrth and igaited.
af oxygen are compositon of the nsulting
Q.3. Calculate the mass of 2.8 litres of CO; at Calculatethe
mxtura.
S.T.P.
Q,4 Calculate the pumber of atoms present 0, 13. Calculate the volume ofO, at [Link]. requsd
in 117 gof K. for the complate combustlon of 100 litres of
carbonnonaxde at the same temperature and
pressure
Q.5. 80 c of methaneare mixed wth 200 cof
pure oYSeN at similar temperature and
pmessre The mixtuneis than gntted Calculate [Link] may be oxidized to nitrogen
the compostlon of resulting mixture if it is monolde tn the presence of a catalyst
cooled to initial room tensperature an actordtng to the followtig eguation :
pressune. 4NH, + 50, 4NO + 6H,O
CH, + 20 cO; +2H,0 y27 Ubnes of reactans arg consamed, what
polume of nitrogen monaxide is produce at
the same tmparature and presSure ?
cc of
Q.6. 2500 cc of oæygen was Nsed with600
ethans (CH), C¡lcslattthe volume of unused 0.15. Cormect the statement, Iregnired.
oxygen and volune of carbon diotáeformed, (0 One inole of Cklorine contain$
after writing the balanced equatloi. 6.023 Io atoms of chlorine.
Ethae +Oygen Carbondioxde +water (4) [Link] conditions of teusperature
and presuI, tuo polumes of hyrogn
combine with two volmes of oxygen to
Q.7. What volune of oxygen at [Link]. &reired give two volumes of water aposr.
toaffectatthe combustion of11 litresfthylene (ti) Relative atomic mas of ar clmat is a
(C,H) 276°C and 380 of Hg presre?
CzHy+ 3O, ’2CO, + 2H0
nNmber of times one molecule of an
elmnt heavier than 22 tà Mars of an
atom af carbon (C)
Q, 8. Caleulate the volme of HCtgas formed and (te) Uneer the aase condions af the
chlortne gas requied uhen 40 mL of methane tampnatre and praaure aqu¡l valkme
reacts completely with chlorte at 5.T.P, of all ga coNtats the sane number of
CH, +2CCH,Ch +2HCI atous
2
gaphtte
2. 28. A studnt pts hts stgnatre withignature
.17. What volsme of atr (contatning 20% O,by carbon tn the
Dolume) wll be reqlred to bam completely penell f the mass of nember of casbon
10cm ech of methane and acetylene ? is 10-1g Calenlate the
atoms in the oignatre
Q, 18. ((a) Calclate the maN of nttrogen pplled
to sotlby 5 Kg of s[CONH)
(O 16, N 4 c 1 2 R 1) aó,Calcalete the Rilattoe molecar mas of
volne occuples ty &z of Ammontm dloroplathate, NH), (PC,)
(3) Calcttte the S2,õ161
sMphur [Link] ST.P. (a-
.
cSE 201)
3
of Sodism(Nal t
[Link] the parcpntage
the Na,B,0,10H,0,
empirlcal formule of42% H-4B 11,0=16 N23
37. Determine the byresass ts :
compoundwhosecomgHosition
9% leydroget.
nitrogen, 43% arygm and (CSE 20O) nitrogm4 ammONia and
chlortne,
(H-L N14016 0.45. The gasss collectedunderthesame
sulyhur dloxtdean and pressureCopy
formwla Na,CO; condttions of temperaturegtves the volumes
Q.38. Wasking sode has theanhydrons sodium whlck
thefollowtng table theniberofnolecules
IOH,0. What msss of collectedand
carbonate sleft wken all the water of ofgases
ofnitrogen VaMare to compiste
arystallization is expelled try keating 57.2g of O0 in 20 1litres number of niolecules in
washlng soda ? the table glulng the ofX Following table
the other gass in terms
ofgasesCollectedand
sdded whtck giDEs thevölumes 0tn 20 #tres of
Q.39. When acess lead nitrate soluton was the number of molecules
toasolutionofsodiam sulphate,1515goflead the tablegiving
sukphatewere [Link] ofsodium nitrogen Y¡N are to coinpiete
other gases in
sulpkate zs presentitheongtalsolutian ? the namber of molaculesin th¹
Na,sO,+Pb NO),’ PbsO, +2NaNO, tems ofX.
molecules
[H-;C=12; O =16; Na =23; S=32; Pb=207] Gs Valume (tti) Number of
[ICSE 2000] Chlorine 10
20 X
Nitrogen
Q40. What volune ofaxygen wouldbe requtredfor Ammoria
the camplets combustion of100 litresof ethane Sulphur ioxig
according to the folowing equation?
2CH +70O, ’Co,+ 6H,0
Q 46. 0 Calcilate the percentage of phosphorus
Q.41. Thecompound Ahas thefollowing percextage in thé fertiltzar superphospha te
composttion by mass:carbon 26.7%, öygên Ca H,POr
71.1%, ydrogen 2.2%. Determtne the
empirical jormala of A(Work to ane decinal (u) A metal M forms a volatile chloride
place) H-1; ( 12; O = 16). Ifthe relattoe containing 65.5% chlorine. If the density
molecylar mass of A s,90, whet is the of the chloride relative to hydrogen is
mplecular fomnulaofA? 162.5, find the molecular formula of the
chlortde M561 TCSE 2001)
Q2 Ammonia bur ozygen: cnd the
combustiomyin tkapnseNce ife catalýst, iay
Q47. Thenesction:N,0+CRcO, +2H,0+N,
be represnted' by takes place in the gaseos state. ð all
¬2NO+3H,0. volumes Are measuedatthesame temperabune
Whtnass of team is producad ohen 1.5g of
ntrogen sÝnoxtde isfonned ? and pressure caleulate the volume of
TH-1, N-4,016T dinitrogen oxide (N,0) which gives 150 cm of
steam
Q.43 Water caa be splitinto kydroge and oxygan Q. 48. Samples of the gases O Ny Co, aad Co
undsr. giitable condttions. The eque tlon Mnderthe 4anne conditons of tmperatung And
representng the change fp: pressuE COHtan tg same
ZH,O II) 2H, Igl+0,(gh The Noecul ofaysNRMNbofmolecule
PcCypy V esand
IhaveaMAS Of8&, Under th qame contitions
Ife gtoen apariment nsulty tn 2500 ce f of the tnperature ad pressure :
hydrogen betng producad, what volune of what y the vÍlume oçupisd by :
orygen ts llberatedat the sane timg uider the () X molecules af Ny
same condNons of teperature and presure 7 (r) 3X molecules of Co,
(Hy What ts the mass ofCO, in
grams ?
(ip) In suErng the above questions,
aw kave you uIed ? which
4
Q.49. (0 Calcutett the peroentage of platnum 0.36. Gve the chenlcal eguatlon,
tn ammonium chtoroplatinate KPO, +AlONO), -’ IKNO, +A1 PO
NH), (PCL. How many moles of potassim nitrate
(0 Ihe percitge cpmpooittoR of odtum Are producd when twO mols of potasstum
phoaphate detirmtned by anelyats t uphate rnact wlth twomoles of alxminium
421% 1odsm, 18.9W phorphors and nttnate ?
39% oyg Fnt the emptrtoal fomule
of tlhecompomd (TcSE 2002)
per
Q, 52. A kydroperbon cattra 105gof carbon
cnptrical Q.6L. What percentage of water is found tn
gram of yrogen. Calcutate the Na,s.9,0 ?
formala
5
contatns artmun
nitroges
Q66. If a crop of oheat nemopes 20kg fmass (0 Whick sainple of gas
per hsctare of [Link] thé ofCa number of molecules?
NOJ, Tqutrad to eplace xitogen tn 20 () If the temperature And pressurs of
gas A
hectars fleld are kept constant, then what wl
happen
(N4D16 Cg= Ansor to the naarst k
to the volume ofA when the nunber of
moleeule is doubled?
Q 67. (a) ADessel contains N molecsls of oxygen
at acprtatr tennpenature and pressure. (tH) ð thls ratio of gas volumes refers to the
Hoto may nolecules af sxiphur dloxlde reactants and products gf a reactlon,.
can the DEM acCoGodatt at the sAme which gas law ls belng obgerved ?
tenperatre and ppresaure ?
) Each oftoflasks contatns 2.0g of gasat (o) If the volume of Ais ctualy 5.6 dn at
the same tenperstur and resure. Ons S.T.P., calculate the number of molecules
flask contelns oxygen and the other tn the acthual polumne ofD at [Link].
(Avogadros nanher ig 6 *1023)
(0 Wiichaanpe cowtatns thegeternmber
ofmolacves ? (u) Usingyor answerfrom ()state the ass
() If the lyrogen sanple contains Nmole ofD f thê gasts qinitrogen oxide (N,O).
ala, hotU Ay Molecules aN rsnt ts N140=16) [ICSE 2005]
the oxyg sAnple ?[H-;0 164
0. 68. Concentrated attric acd oxtdises phosphorg Q.L0 Detarhajne the emptrical formula of a
to phosphorle gctd scording to tiefolowing compound containtng.47.9% potassiun,
qatian : s5%berylliunand 46.6%fluorine by mass.
P+ SINO,’ ,PO, +5NO,*H,o Atomte tpeight of Ee 9;F 19, K= 39)
Work to otie décimalplace
What mes of phohorie acidcan be (t) Gioen that the relative molecular mass of
copper oxide is 80, what volume of
prparedfrom 2g f pleosphars? Qmmana (measuned at [Link]) is rguired to
(D What masg of nitrle ecd wii! be
connedat hemm tine ? completslyredics120g ofcopperoxide?
(40 What woa be tke pols [Link] The equation for the reaction is :
moduced at the ane t f g e d 3Cu0 +2NH, ’ 3Cu+ 3H,0+N,
H-N= 14;0 16;P1 (Volume ocCupied by 1mole ofga at STP.
is 22.4 litres) ((CSE 2006)
Q.69. Find the percetage of oxy~en in acetie
acid. 03. The equations siven belotw relste to the
manufacture ofsodtum carbonate (Molecular
Q.70. How maay iiolecules are there in 1 litre of weight of Na,Ca, 106)
1. NaCl+NH, +CO,+H0’NaHcO,+NH,CI
74,4 Jolegthe formala [COi, has papour 2 2NalHCO, Na, co+H,0+CO,
denstiy rqualto 70. Find the value of Onestions fa) srd (8) are based o the,
productton of 21.2of sodiuscarbonate
Q.72 What weight of sulphwricadd wll be raqutred (a) Whatass ofeotus kydrogen ctrbonata
to dixsolve 3g of magnesiym carbonate 1
MgcO,+ HS0,t Mg80,+ H,o+ Co, tmust be keated to soa 21.2g of sadiun
(Mg 24C12,O-16) carbonate (Molecular weight* of
NaHCO, )?
0.73. The volumes of gassA,B, and D are in (b) To prdaude the mAgs af sodum kydrogeR
the natio 1224 vnder the same conditlons of carbanat caleulated in (), wkat vone
temperature and prsure af carbon diostde, measured at S.T.P.
tbould be required ? (ICSE 2005)
6
Q:76.(0 Calculate the petctage èf
sodium almittum fuorlde soium in () Determine the percentage of oxygen tn
(NaAJ conect to the nearett whole ammontum nitrate (0-16), TCSE 2007)
nmber..
F19; NE 23; Al 27)
Q.78.(a) A compound Xconsists of 4.8%. Carbon
(i0 B60 mL of carbon monoxide is mized witk And99.2Y bromine by mn.
500 mL ofoygenand igrtted. The chehical t9 Deteramine the 'empiriel formnla of fhds
equatton for the reaction ts asfolloDS : compound worldng correct to one deckmal
place (C 12; Br= 0)
2 CO+O, +2c0, () If the vapor dnsity of the compound is
Calculate the volume of oxygen xted and 252, what is thé moleculr formula of the
carboniotdeformedba the abooereaction compound ?
CSE 2006) (li) Name the type of chenicnl reacton by
whick Xcn be prepared from tthane
Q. 77. A sample ofamaontm nttrate when hested TcSE 2007)
yields 896 1tro ofsteam (measured at $TP)
NHNO,N0+ 20
(0 What volume of dinitrogen oxide ts
producedat the yame tine as 8.96 #tres of
steam ?
(H) Whst mas of ammonium nitrate shovld
be heated to piodue 8.96 ltres of
steam Relative moleculr mass of
ammonlum iinatets 80)
Q79. The reactlon gioen below takes place only in the gaseons itate
N,0+ CH ’C0, +2H,0 +N,
fall the bolunes ane measured at sane temperature and prere, calculate
oxtde negustred to glve150 c ofstean thevolume of dnitrogen
Q. 80. The ges lao which relates the volume of a gas to the number of
molecules of the gas is :
(a) Avogadro's Law
6) Gay- Lxriad's Law
(e)' Boyies Latw
() Charids Law
(ICSE 20087
7
by mags this
foloolng peroextAge composltHon
Detemnine the cmpilcalformula of
Cmpond ksthe S%
Q 2 () () A 1.2% and phlorine (H 1)C 1yA 33)
Caron KM
hyog place. thmolucular formla?
Work comct to 1 deaienal 168, s0 whst a
cono comtyoud s
mòlelar mas ofthls compond be obtatned from
ethymei(TcSE20081
(29 e nluto
coll
ractlon
Q) By phat hype of
(b) From the cguatlos
2S0,
C+ 2H,SO,’c0+2H,0 + molselar masS of
Calcxl: niphulc acd (C 12 lattE
ortdd by 49 g of
0 the mass of parbon
mpte acld 9). Wbenated at the same ttme
vongofsalpkr dlode measNgd at stp, (uCSE 20081
(40 The a gas sty is 224 dt).
(Voline ocCpled by 1 mols of
Sotve t I
L. The number ofoxytea itoms in l molecule of ozone
2 0.2moli_ ofwater weighs i
3, Atomic weight ofchiorine is 35.5. I Vapour density is
4Enpiicil toronula of hegane ts .
5. Valumd at5.T.P. occupiad by 16g of oxy gep is
6. 44.8 tres of nitrogen contain. noles.