26-03-2026

1001CJA101021250065 JA

PART-1 : MATHEMATICS

SECTION-I

1) Let f(x) = ax2 + bx + c be such that f(–1) = 3, f(3) = 7, f(5) = λ and f(2) – f(–2) + f(4) = 9, then λ is
equal to

(A) 21
(B) –21
(C) 31
(D) 19

2) Let the lines and be co-planar and P be the plane

containing these two lines. Then which of the following points does not lie on plane P.

(A)

(B)

(C)

(D)

3) Assertion : Straight lines L1 : 2x + 3 = 0 and L2 : 2 + 3y = 0 are perpendicular to each other.

Reason : If product of slopes of two lines is equal to –1, then those lines are perpendicular.

(A) Assertion and reason are correct and reason is correct explanation of assertion.
(B) Assertion and reason are correct but reason is NOT correct explanation of assertion.
(C) Assertion is correct, reason is incorrect.
(D) Assertion is incorrect, reason is correct.

4) Let the tangents at two points A and B on the circle x2 + y2 – 4x + 6y + 8 = 0 meet at point P(7,
–3) then area of ΔPAB?

(A) 16
(B) 39
(C) 8
(D) 78

5) The differential equation of the family of circles passing through points (0, 5) and (0, 3) is?
(A)

(B)

(C)

(D)

6) A bag contains 'a' different apples and 'b' different bananas. If the number of ways of selecting 2
apples and 3 bananas from the bag is 144, then (3a + 2b) is equal to

(A) 30
(B) 35
(C) 28
(D) 40

7) If (2 + 59C1 + 59C2 + .......... 59C59) (60C3 + 60C5 + .......... 60C59) = (2m + 1) (2m – m – 1), then m is equal
to?

(A) 58
(B) 59
(C) 60
(D) 61

8) If set of all a∈R for which the equation 3x2 – (2 – a)x + 4 = 2a has no real root, is the interval (p, q)

and A = {x∈I; p < x < q}, then is?

(A) 3312
(B) 3796
(C) 3800
(D) 3316

9) In a complex plane let z = x + iy

List-I List-II

(A) |z – 1| = |z + 1| (I) A straight line passing through the origin

(B) (II) A circle passing through the origin

(C) (III)
A semicircle passing through

(D) (IV) Perpendicular bisector of line joining (–1, 0) and (1,0)

(A) (A) – I, (B) – II,(C) – III,(D) – IV
(B) (A) – IV, (B) – III,(C) – II,(D) – I
(C) (A) – IV, (B) – III,(C) – II,(D) – II
(D) (A) – I, (B) – II,(C) – IV,(D) – III

10) Let the function f(x) = (x2 – 4) |x2 – 7x + a| + cos |x – 1| be not differentiable at the two points x =
α = 3 and x = β, then image of the point (α, β) in the line x + y = 0 is?

(A) (3, 4)
(B) (4, 3)
(C) (–3, – 4)
(D) (– 4, – 3)

11) If all the words with or without meaning made by using all the letters of the word "DIVYANK"
are arranged as in a dictionary, then the word at 501th position in this arrangement is?

(A) AVDYKNI
(B) AVDYNKI
(C) AVDYKIN
(D) AVDYNIK

12) If the image of the point P(1, 0, 2) in line is (α, β, γ) then 13(α + β + γ) is?

(A) An even number

(B) A number divisible by 3
(C) A prime number
(D) Not an integer

13) Let a circle C passes through the points (6, –1) and (4, 1) and it's centre lies on line x + 3y + 7 =
0, then find the length of the chord of the circle C whose mid point is (3, –3)

(A)
(B)
(C)
(D)

14) Let a curve y = f(x) pass through the points (0, 2) and (loge2, k). If the curve satisfies the

differential equation , then k is equal to?

(A)

(B)

(C)
(D)

15) Let A and B be two events such that , and , consider:

Statement-I :

Statement-II :

(A) Statement-I and Statement-II both are correct.

(B) Statement-I is correct and Statement-II is incorrect.
(C) Statement-I is incorrect and Statement-II is correct.
(D) Statement-I and Statement-II both are incorrect.

16) Let the arc AC of a circle subtend a right angle at the centre O. If the point B on the arc AC,

divides the arc AC such that and , then is equal

to

(A)
(B)
(C) 0
(D)

17) If α + iβ and γ + iδ are the roots of x2 – (5 – 5i) x – 13i = 0, , then (αγ + βδ) is equal to

(A) 12
(B) – 12
(C) 6
(D) – 6

18) Let be a point on the parabola x2 = 4ay and PQ be the focal chord of parabola. If M
and N are the foot of perpendiculars drawn from P and Q respectively on a line passing through (1,
–4) and parallel to the directrix of the parabola. Then the area of the quadrilateral PQMN is equal
to?

(A)

(B)

(C)

(D)
19) is equal to

(A)

(B)

(C)

(D)

20) If , then 125(a3 + b3 + c3) is equal to

(A) –729
(B) 701
(C) 812
(D) 629

SECTION-II

1) Let the position vectors of three vertices of a triangle be , and

. If the position vectors of circumcentre and the orthocentre of the triangle are

and , then α + 2(β + γ) is equal to

2) If the domain of the function log7(25x –x2 – 136 ) + is (α, β)∪(γ, δ), then
α + β + γ + δ is equal to

3) Let . If I(17) – I(27) = , a, b, c ∈N, then a + b + c is equal

to

4) Let α, β be roots of x2 + 3x + 7 = 0. If An = αn – βn ; n ∈ N then

is equal to
5) Let A be a symmetric matrix such that |A| = 3 and . If sum of all elements
of A is P, then the value of 7P is

PART-2 : PHYSICS

SECTION-I

1) A uniform rod of mass 400 gram and length 3 feet is hinged smoothly at 1 foot from one end. The
rod is released from horizontal position. Find hinge reaction just after it is released. [Take g = 10
m/s2]

(A) zero
(B) 1N
(C) 4/3N
(D) 3N

2) A 5kg block is hanging from centre of an ideal pulley (as shown in diagram). A spring of spring
constant K1 is connected to centre of the pulley. Find time period (in seconds) of vertical small

oscillations of the block. [K1 = K2 = 4π2 N/m]

(A) 1
(B) 2

(C)

(D)

3) Assertion : Thin film such as soap bubble or a thin layer of oil on water show beautiful colours
when illuminated by monochromatic light.
Reason : Colour in film are obtained due to interference between reflected light from the upper and
lower layer of film.

(A) Assertion and reason are correct and reason is correct explanation of assertion.
(B) Assertion and reason are correct but reason is NOT correct explanation of assertion.
(C) Assertion is correct, reason is incorrect.
(D) Assertion is incorrect, reason is correct.

4) Two projectiles are projected at 37° and 90° with the horizontal having same time of flight. The
ratio of maximum heights attained by the two projectiles respectively is :-

(A) 3 : 5
(B) 4 : 5
(C) 9 : 25
(D) 1 : 1

5) An aluminium rod with Young's modulus Y = 7 × 1010 N/m2 undergoes elastic strain of 0.01%. The
energy per unit volume stored in the rod in S.I. unit is :-

(A) 700
(B) 350
(C) 350 × 104

(D)

6) A diverging lens of focal length f1 = 60 cm is separated by 82.5cm from a converging mirror of

focal length f2 = 60 cm. Where should an object be placed from the lens so that a final real image is
formed at the object itself ?

(A) 100 cm

(B)

(C) 60 cm
(D) 220 cm

7) Find magnitude of along a circular path x2 + z2 = 9 due to a straight current carrying

wire along y-axis from point (0, –4, 0) to point (0, 4, 0). Current in the straight wire is I.

(A) 0.6 μ0I

(B) 0.8 μ0I
(C) μ0I
(D) Zero

8) Two charged particles are allowed to pass through a uniform magnetic field perpendicular to the
direction of motion. Ratio of their kinetic energies is 2 : 3 and ratio of their charges is 5 : 2. If ratio
of their radii (of circular path) is 4 : 3 then find ratio of their masses.

(A) 50 : 3
(B) 20 : 9
(C) 1 : 1
(D)
9) Consider following circuit :

List-I
List-II
Ideal
Reading (in amperes)
Ammeter

(I) A1 (a) 1

(II) A2 (b) 2

(III) A3 (c) 3

(IV) A4 (d) 4
(A) (I) - (a) ; (II) - (b) ; (III) - (c) ; (IV) - (d)
(B) (I) - (d) ; (II) - (a) ; (III) - (b) ; (IV) - (c)
(C) (I) - (c) ; (II) - (d) ; (III) - (a) ; (IV) - (b)
(D) (I) - (b) ; (II) - (c) ; (III) - (d) ; (IV) - (a)

10) Find magnetic flux through circular area of circle x2 + y2 = 1 due to magnetic field

. [Consider all values in S.I. units]

(A)

(B)

(C) π

(D)

11) The De-Broglie wavelength of a molecule in a gas at temperature 200K is λ0. If the temperature
of the gas is increased to 600K, then the De-Broglie wavelength of the same gas molecule becomes :-

(A) λ0

(B)

(C)

(D) 3λ0

12) Radius of 4th orbit of He+ of Bohr's model is r1 and that of 3rd orbit of Li2+ is r2. Ratio is :-
(A) 1 : 1
(B) 2 : 1
(C) 16 : 9
(D) 8 : 3

13) If a semiconductor photodiode can detect a photon with a maximum wavelength of 500 nm, then
its band gap energy is :- [Planck's constant h = 6.63 × 10–34 Js, Speed of light c = 3 × 108 m/s]

(A) 2.5 eV
(B) 2.0 eV
(C) 3.1 eV
(D) 1.1 eV

14) In the given circuit, current in steady state through the battery will be :

D1, D2, D3 are ideal diodes.

C = 4μF = capacitance
L = 6H = inductance

(A) 2A
(B) 3A
(C) 3.6A
(D) 4A

15) Statement-I : An object of mass m accelerate uniformly from rest to a velocity vf in time tf. The

work done on the object upto time t (t < tf) is

Statement-II : Work done by spring force is always negative.

(A) Statement-I and Statement-II both are correct.

(B) Statement-I is correct and Statement-II is incorrect.
(C) Statement-I is incorrect and Statement-II is correct.
(D) Statement-I and Statement-II both are incorrect.

16) A steel rod 100 cm long is clamped at its middle. The fundamental frequency of longitudinal
vibrations of the rod are given to be 2.53 kHz. The speed of sound in steel is :-

(A) 333 m/s

(B) 5060 m/s
(C) 2530 m/s
(D) 10120 m/s
17) Calculate the value of mean free path (λ) for Helium molecules at temperature 127°C and
pressure 0.45 × 105 pa. Assume the molecular diameter 0.25 nm and the gas is ideal. (Boltzmann
constant k = 1.38 × 10–23 J/k)

(A) 442 nm
(B) 625 nm
(C) 138 nm
(D) 400 nm

18) Find percentage error in parallel combination of resistances R1 = (20 ± 0.02)Ω and R2 = (30 ±
0.06)Ω.

(A)

(B)

(C) 0.3%
(D) 0.14%

19) Consider a mixture of 3 moles of an ideal monoatomic gas and 2 moles of an ideal diatomic gas.
The mixture does a work of 50 Joules when heated at constant pressure. The change in its internal
energy is :- (neglecting vibrational degrees of freedom)

(A) 1.9 J
(B) 95 J
(C) 200 J
(D) 1000 J

20) A body of mass m is projected at an angle 60° with the ground with velocity times of escape
velocity. Find maximum height from the earth surface of the body. Consider m << M.
M = mass of the earth
R = radius of the earth
g = acceleration due to gravity on the surface of the earth

(A)

(B)

(C)

(D)

SECTION-II

1) Find the x-coordinate (in metres) of the centre of mass of the shaded uniform surface, which is a
segment of circle of radius 3(π – 2) metre.

2) A sphere of radius 1 metre having density ρ = 3 × 103 rn kg/m3, (r = distance from centre of the
sphere), neither float nor sink in water. Find value of n. (density of water is 103 kg/m3)

3) 72 gram ice at –10°C is mixed with 93 gram water at 80°C. Find final temperature (in degree
celsius).
[Sice = 0.5 cal/g–°C
Swater = 1.0 cal/g–°C
Lfusion = 80 cal/g]

4) A point charge is placed at the centre of a cylinder of radius R and height H. Electric flux through
curved surface is η times the electric flux through plane surfaces (of both circular surfaces). If 8R =
3H then find value of η.

5) Find irms (in amperes) of alternating current amperes.

PART-3 : CHEMISTRY

SECTION-I

1) For a certain gas undergoes a process for which, the molar heat capacity is given by C = Cv + aT,
where 'a' is constant. If n moles of this gas are heated from T1 to T2 in this process, what is change in
entropy ?

(A)

(B) na (T2 – T1)

(C)

(D)

2) In the following reaction :

K2Cr2O7 + HCl → CrCl3 + KCl + Cl2 + H2O
What is equivalent mass of HCl ?

(A) 85.17
(B) 170.33
(C) 36.5
(D) 73

3) Assertion : In Hoffmann bromamide degradation amide gives amine as a product with same
number of carbon.
Reason : During product formation carbon is lost in form of bicarbonate ion.

(A) Assertion and reason are correct and reason is correct explanation of assertion.
(B) Assertion is incorrect, reason is correct.
(C) Assertion is correct, reason is incorrect.
(D) Assertion is incorrect, reason is incorrect.

4) For a reaction : A → Product, following graph is plotted in which variation of concentration of A

with time is shown :

Activation energy of the reaction is 831.4 J mol–1. If slope is –0.20 at 400K, what is slope at 500K
(Take e0.05 = 1.05 and R = 8.314 J mol–1)

(A) – 0.04
(B) – 0.11
(C) – 0.21
(D) – 0.29

5) Molar conductivity of 0.1 M weak monobasic acid HA is 2 Scm2mol–1. It's limiting molar
conductivity is 200 Scm2mol–1. If solution is diluted 100 time, what is new molar conductivity ?
[Consider degree of dissociation is always (α << 1) negligible]

(A) 0.2 Scm2mol–1

(B) 2 Scm2mol–1
(C) 20 Scm2mol–1
(D) 40 Scm2mol–1

6) 1 litre of an aqueous solution containing H2C2O4 and NaHC2O4 require 2 liter of 2M NaOH solution
for complete reaction. In an another experiment it require 2 litre of 3N KMnO4 solution. Find pH of
original solution. (log(2) = 0.3, pKa1(H2C2O4) = 4.7)

(A) 5.3
(B) 4.7
(C) 4.4
(D) 5
7) Which of the following statements are correct ?
(i) V2O4 dissolves in acid to give VO2+ salts.
(ii) V2O5 react with alkalies as well as acids to give and respectively.
(iii) Mn2O7 and CrO3 react with water to form corresponding oxoacids.
(iv) In 3d-series beyond group 7, metals do not form oxides in oxidation states higher than their
group number due to instability of high oxidation state.
(v) V can show its highest oxidation state in it's fluorides.

(A) i, ii, iii, iv only

(B) All are correct
(C) i, ii, iv, v only
(D) i, ii, v only

8) The complex [Co(en)2Cl2] shows different colours in solution, which of the following statements is
correct ?

(A) It shows only geometrical isomerism and both isomers absorb light of same wavelength.
It shows both geometrical as well as optical isomerism and cis-isomer shows different colour
(B)
due to different Δ0 values.
It shows both geometrical isomerism as well as optical isomerism and both isomers absorb light
(C)
of same wavelength.
(D) It shows only optical isomerism and colour is independent of ligand arrangement.

9) Match the given lists and selection option :

List-I List-II

(I) Canary yellow PPT with ammonium molybdate (a)

(II) Positive griss illosvay test (b) Br–

(III) Purple/violet colour with sodium nitroprusside (c) S–2

After reacting with H2SO4 a gas is liberated which turns

(IV) (d)
starch paper yellow.
(A) I → d , II → b , III → c , IV → a
(B) I → d , II → b , III → a , IV → c
(C) I → d , II → a , III → c , IV → b
(D) I → b , II → c , III → d , IV → a

10) Assertion : Cr(VI) compounds are stronger oxidising agent than Mn(VII) compounds in acidic
medium.
Reason : The standard reduction potential of the couple is greater than that of
.

(A) Assertion and reason are correct and reason is correct explanation of assertion.
(B) Assertion and reason are correct but reason is NOT correct explanation of assertion.
(C) Assertion is correct, reason is incorrect.
(D) Assertion and reason both are incorrect.

11) Total number of optically active isomers possible for [Co(en)(NH3)2Cl2]+ is :

(A) 2
(B) 4
(C) 6
(D) 8

12) Which of the following structure is non planar ?

(A) Na3B3O6
(B) I2Cl6
(C) SiO2
(D) Inorganic graphite layer

13) The first (ΔiH1) and the second (ΔiH2) ionisation enthalpy (kJmol–) and the (ΔegH) electron gain
enthalpy (kJmol–) of a few elements are given below :-

Elements ΔH1 ΔH2 ΔegH

P 1681 3374 – 328

Q 419 3051 – 48

R 2372 5251 + 48

Which of the above elements is likely to be most reactive metal & most reactive nonmetal
respectively?
(A) Q,P
(B) R,P
(C) Q,R
(D) R,Q

14) Which of the following method(s) is used to prepare p-bromo aniline as major product ?

(A)

(B)
(C)

(D)

15) Statement-I : Two aqueous solution containing two different non-volatile solutes having same
concentration at same temperature are always isotonic.
Statement-II : Osmotic pressure depends on association or dissociation of non-volatile solute in
solvent.
Choose correct option :

(A) Statement-I and Statement-II are correct and Statement-II is correct explanation of Statement-I.
Statement-I and Statement-II are correct but Statement-II is NOT correct explanation of
(B)
Statement-I.
(C) Statement-I is correct, Statement-II is incorrect.
(D) Statement-I is incorrect, Statement-II is correct.

16) Choose correct structure of compound C, in following reaction :

(A)
(B)

(C)

(D)

17)
Which of the following option is incorrect ?

(A) HCOOH is more acidic than A

(B) B gives 2,4-DNP test positive
(C) B gives tollen's test positive
(D) C is a fruity smell compound.

18)
Choose correct option :

(A) C gives positive Fehling solution test

(B) C does not exhibit tautomerism
(C) B gives FeCl3 test positive
(D) B is soluble in NaHCO3 solution
19)
Out of following option which is correct ?

(A) A gives Lucas test and form turbidity immediately

(B) C does not exihibit geometrical isomerism
(C) B is optically active
(D) C is optically active

20)
Which of the statement is correct about A.

(A) It has 5 sp2 hybridized carbon

(B) It has three 3° carbon
(C) Degree of unsaturation is 4
(D) It is a conjugated diene.

SECTION-II

1) How many of following statements are correct ?

(i) Dependence of heat capacity of solids on temperature can be explained by particle nature of light.
(ii) γ-rays are produced when electrons strike the dense metal anode during cathode ray experiment.
(iii) Intensity of radiation of different wavelengths by a hot body depends on temperature.
(iv) The element Ar was discovered in the Sun by spectroscopic method.
(v) All four quantum numbers are required to explain spectrum of multi electronic species.
(vi) The wave function of an electron corresponding to that energy state contains all the information
about that electron.
(vii) Probability of finding the electron at nucleus is maximum for in 1s orbital among all orbitals.
(viii) The schrodinger equation cannot be solved exactly or completely for multi electron species.
(ix) Boundary surface diagram of an orbital encloses a region in which probability of finding the
electron is about 90%.
(x) Schrodinger equation is valid for all microscopic particles, even for free electrons.

2) A close rigid container is divided into equal halves, and SPM is fixed which allow only Ne(g) to
cross it. The entire system is at equilibrium. C(g) & B(g) are obtained
only from dissociation of A(s). The final total pressure of gases in containers I & II are 7 atm & 4 atm,
respectively.
Calculate Kp (in atm3) of following reaction :
A(s) B(g) + 2C(g)

3) How many of the following species in which central atom used their d-orbital for bond formation.
XeO4, Borax, , [Cu(NH3)4]2+, PCl5

4) Calculate total number of elements which have electron gain enthalpy (ΔegH) is more negative
than oxygen.
S, F, Se, Te, P, Cl, N

5) How many statements are correct ?

(i) α-D-glucose have higher melting point than that of β-D-glucose.
(ii) α-D-glucose and β-D-glucose are enantiomers
(iii) Amylopectin is insoluble in water and It contain C1 – C4 and C1 – C6 glycoside linkage
(iv) Deficiency of Vitamin B2 cause cheilosis
(v) DNA contain uracil base
(vi) Keratin and myosin are globular protien
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B B C B B B A C D C C B C A B A B C A

SECTION-II

Q. 21 22 23 24 25
A. 3 54 17 100 12

PART-2 : PHYSICS

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D A D D B A B A A D B D A D B B A D B A

SECTION-II

Q. 46 47 48 49 50
A. 2 6 8 4 5

PART-3 : CHEMISTRY

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D A D C C D B B C D A C A B D B C C D B

SECTION-II

Q. 71 72 73 74 75
A. 7 4 4 5 2
 SOLUTIONS

PART-1 : MATHEMATICS

1)

f(–1) = a – b + c = 3 ....(1)
f(3) = 9a + 3b + c = 7 ....(2)
f(2) – f(–2) + f(4) = 16a + 8b + c = 9 ....(3)
from 1, 2 & 3
a = 1, b = –1, c = 1
f(x) = x2 – x + 1
f(5) = 25 – 5 + 1 = 21

2)
lines are co-planer, so

Normal of plane
Equation of plane : x + y + 2z – 7 = 0
check the points and verify the answer (B)

3) If one line is parallel to x-axis and other is parallel to y axis then m1m2 ≠ –1 but lines are
perpendicular, so given reason is not correct explanation

4)
x2 + y2 – 4x + 6y + 8

5) Family of circle passing through (0, 5) & (0, 3) is

x2 + y2 – 8y + 15 + λx = 0
divided by x, we get

diff. w.r.t. x

on solving, we get

6) aC2 × bC3 = 144

a = 9, b = 4
3a + 2b = 35

7)

(2 + 259 – 1) (260 – 1 – 60C1)

(259 + 1)(259 – 59 – 1)
m = 59

8)

3x2 + (a – 2) x + 4 – 2a = 0
D<0
(a – 2)2 – 12(4 – 2a) < 0
(a – 2) (a + 22) < 0
a∈(–22, 2)
p = – 22, q = 2
A = {–21, – 20, – 19, ........ 0, 1}
(21)2 + (20)2 + ........ 22 + 12 + 02 + 12
= 3312

9) (A)|x + iy – 1| = |x + iy + 1|
(x – 1)2 + y2 = (x + 1)2 + y2
⇒ x = 0 ⇒ y-axis

(B)
(C)
|x + iy|2 + x + iy + x – iy = 0
x2 + y2 + 2x = 0

(D)

x2 + y2 – 2x = 0

10) f(x) is not differentiable, where

α=3
(3)2 – 7(3) + a = 0 ⇒ a = 12
x2 – 7x + 12 = 0
(x – 3) (x – 4) = 0 ⇒ 3, 4
β=4
point (3, 4)
Image of (3, 4) in x + y = 0

h=–4 k=–3

11) A, D, I, K, N, V, Y

AD - - - - - 5! = 120
AI - - - - - 5! = 120
AK - - - - - 5! = 120
AN - - - - - 5! = 120
AVDI - - - - 3! = 6
AVDK - - - - 3! = 6
AVDN- - - - 3! = 6
AVDYIKN =1
AVDYINK =1
AVDYKIN =1
word at 501th position is AVDYKIN
12)

<1 + 3λ, –1 – λ, – 4 + 4λ> . <3, –1, 4> = 0

λ = 13

13)
mOM × mAB = – 1 ⇒ α = – 3
centre (2, – 3)

Length of chord =

14) After re-arranging

7 + e2x = t ⇒ 2e2x dx = dt
Passing through (0, 2) ⇒

15)

Now,
S–I P(A'∪B) = P(A') + P(B) – P(A'∩B)
1–P(A) + P(B) – [P(B) – P(A∩B)]
1–P(A) + P(A∩B)]

S–II
1–P(A) – P(B) + P(A∩B)

16)

take dot with

0 = αr2 + βr2 cos30º

 ....(1)
take dot with

r2 cos60° = αr2 cos30° + βr2

.....(2)
from (1) & (2)

17)

2i = a2 – b2 + 2abi
⇒ a2 – b2 = 0 and 2ab = 2
⇒ a = b = 1 or a = b = – 1

α = 3, β = –2, γ = 2, δ = – 3

18)

for focal chord t1t2 = – 1

Area of PQMN=

19)

by king property, x →

sin x = t
cos x dx = dt
20)

21)

22) 25x – x2 – 136 > 0

(x – 17) (x – 8) < 0
x∈(8, 17)
and

(8, 17) ∩ x > 5∩x∈(–∞, 5/2)∪(9, 12)∪(16, ∞)

⇒ x∈(9, 12)∪(16, 17)

23) Multiply and divide denominator by

Now, substitute
 24) By Newton's theorem
An + 3An–1 + 7An–2 = 0
for n = 9 A9 + 3A8 + 7A7 = 0
for n = 8 A8 + 3A7 + 7A6 = 0

25) Let

PART-2 : PHYSICS

26)
27)
mω2x = (4k2 + k1)x

T = 1 sec

28) Different colours are observed when illuminated by white light.

29)

30)

Energy per unit volume,

e= × Stress × Strain

= 350

31)
First image must be formed out C.O.C. of mirror.

x = 100 cm
32)

33)

34)

3Ω & 6Ω are in parallel

Hence equivalent circuit is

⇒ A3 = 3A
A1 = 1A
A2 = 2A
A4 = 4A
35)

36)

37)

38)

39)
At steady state equivalent resistance across battery = 3Ω

40)

⇒ S1 is correct
S2 is incorrect

41)

f = 2530 Hz
⇒ V = λf = 5060 m/s

42)

= 4.4 × 10–7 m

43)

= 0.06 + 0.08 = 0.14%

44)
nR·ΔT = 50 J
nCVΔT = n × 1.9R × ΔT = 1.9 × 50 = 95 J

45)
⇒ R1 + R2 = 2R .... (1)

.... (2)

... (3)
46)

Quarter circle

Triangle

47)

⇒n+3=9
⇒n=6

48)

72 × 0.5 × 10 + 72 × 80 + 72 × 1 × T
= 93 × 1 × (80 – T)

= 8°C

49)

η+1=5⇒η=4
 50)

i2 = 125 sin2 (100 t) + 45 cos2 (100t + 53°) + 150 sin (100t)·cos (100t + 53°)
= 125 sin2 (100 t) + 45 cos2 (100t + 53°) – 75 (sin 53° – sin (200t + 53°)

<i2> = 125 × + 45 × – 75 × + 75 × 0
= 85 – 60 = 25

PART-3 : CHEMISTRY

51)

52) K2Cr2O7 + 14HCl → 2KCl + 2CrCl3 + 3Cl2 + 7H2O

n-factor of HCl =

equivalent mass =

53) Assertion: In Hoffmann bromamide degradation amide gives amine with the same number
of carbon atoms.
❌ False.
In the Hoffmann bromamide (Hofmann rearrangement) reaction, an amide is converted into
a primary amine with one carbon less than the original amide.
Reason: During product formation carbon is lost in the form of bicarbonate ion.
❌ False (as stated).
The carbon is actually lost as carbon dioxide (CO2) during hydrolysis of the isocyanate
intermediate. In basic medium, CO2 may later form carbonate/bicarbonate ions, but it is not
lost directly as bicarbonate.

54) ℓn At = ℓnA0 – kt
Slope = –k

= 0.05
k2 = 0.2 e0.05 = 0.21

55)
= 10–5
When solution is diluted, Ka remain same
Ka = C′(α′)2

α′ = 0.1

56) H2C2O4 + NaHC2O4

x mol y mol
gm. eq. of NaOH = gm. eq. of H2C2O4 + gm. eq. of NaHC2O4
2×2×1=x×2+ y×1 ...(i)
gm. eq. of KMnO4 = gm. eq. of H2C2O4 + gm. eq. of NaHC2O4
⇒3×2=x×2+y×2 ....(ii)
Solving eq. (i) and (ii)
y=2
x=1

57) NCERT Statement

58) Δo of cis and trans isomers are different that's why different color visible in both isomers.

59) Direct from lab manual

60) = +1.52V
= +1.33V

61)

[M(AA) a2b2] type complex.

optically active isomers = 2

62)

Na3B3O6 = cyclic structure (Planner)

I2Cl6 = Planner structure
SiO2 = SP3 hybridisation (Tetrahedral non-planner structure)
Inorganic graphite layer = Planner
63)

Most reactive metal = Least ΔiH1 value

Most reactive non-metal = More negative ΔegH value.

64)
65) For isotonic solution i1C1 = i2C2

66)

67)
68)

69)

70)

71) (i), (iii), (v), (vi), (viii), (ix) and (x) are correct

72)

partial pressure of Ne will be same in both part.

(PNe)I = (PNe)II = 4 atm
∴ PB + PC = 7 – 4 = 3 atm
B & C are formed in 1 : 2 mole ratio.
Hence PB = 1 atm
PC = 2 atm
Kp = (PB)1 (PC)2 = 1 × 22 = 4

73)

XeO4 = for π bond formation

= for π bond formation
[Cu(NH3)4]2+ = dsp2 hybridisation
PCl5 = sp3d hybridisation
74) S, F, Se, Te, Cl

75)

(i) Incorrect
α-D-glucose β-D-glucose
M.P. 419K 423K
(ii) Incorrect
Both are Diastereomers
(iii) Correct
(iv) Correct
(v) Incorrect
(vi) Incorrect