20-07-2025

5401CJA101021250004 JA

PART- 1 : PHYSICS

SECTION-I (i)

1) From a uniform semicircular thin disc of radius R, a semicircular portion of radius R/2 is removed
and placed in a new position as shown in figure. Taking O as origin and x and y axis as shown in

figure, centre of mass of new setup is at :-

(A)

(B)

(C)

(D)

2) A Thin glass rod is bent into a semicircular shape of radius R.A charge Q is uniformly distributed
along the upper half and a charge–Q is uniformly distributed along the lower half as shown in figure

the electric field at the centre P is

(A)

(B)

(C)
(D)

3) In the circuit shown, ammeter and voltmeter are ideal so reading of ammeter and voltmeter will

be

(A)

(B) 0, V
(C) 0, 0

(D)

4) Effective capacitance between A and B shown in figure is

(A) 5C
(B) 3C

(C)

(D)

5) Consider the figure below, initially distance between plates is ‘d’ and ‘A’ is area of plates. In this
state spring is at its natural length. Now, charges +Q & –Q are given to plates and system is allowed
to reach mechanical equillibrium. Find potential difference between plates in this state of

equillibrium.
(A)

(B)

(C)

(D)

6) The magnetic field intensity at the point O of a loop with current i, whose shape is illustrated

below is :

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) A particle of unit mass collides elastically with ground at an angle 45°. Then :-

(A) Change in magnitude of linear momentum is 20 kgm/s.

(B) Change in magnitude of linear momentum is zero.
(C) Magnitude of change in linear momentum is 20 kg m/s
(D) Magnitude of change in linear momentum is zero.

2) A neutral conductor of radius R has a spherical cavity of radius and its centre lies at from
centre of conductor. A charge Q is kept at the centre of cavity.

Electric field due to charges induced on inner surface of cavity at centre of conductor is
(A)

Net field at a radial distance of 2R from centre of sphere is

(B)

(C) Net force on the surface charges of conductor due to all the charges of cavity is zero.
(D) Net force on the charges induced on the surface of cavity is zero.

3) In a potentiometer wire experiment the emf of a battery in the primary circuit is 20V and its
internal resistance is 5Ω. There is a resistance box in series with the battery and the potentiometer
wire, whose resistance can be varied from 120Ω to 170Ω. Resistance of the potentiometer wire is
75Ω. The following potential differences can be measured using this potentiometer.

(A) 5V
(B) 6V
(C) 7V
(D) 8V

4) A conductor (shown in the figure) carrying constant current I is kept in the x-y plane in a uniform
magnetic field . If F is the magnitude of the total magnetic force acting on the conductor, then the

correct statement(s) is (are)

(A) If is along , F ∝ (L + R)
(B) If is along , F = 0
(C) If is along , F ∝ (L + R)
(D) If is along ,F=0

5) n parallel plate capacitors having capacitances are connected in series. Each of

these capacitors can withstand a maximum potential drop of V0 across their respective plates. This
combination is to be connected with an ideal battery of emf V :-
 Maximum value of V without breakdown in any capacitor is
(A)

Maximum value of V without breakdown in any capacitor is

(B)

(C)
Maximum charge on each capacitor without breakdown is

(D) 0
If V = 3V , then minimum number of capacitors in series is five

6)

An electron is at P at t = 0. It is circulating in anti clockwise direction with a constant angular speed

ω along the shown circular path. Magnetic field at Q(CQ = 2R), where R is radius of the circle) will
be recorded as zero at times.

(A)

(B)

(C)

(D)

SECTION-II

1) Two men of masses 80 kg and 60 kg are standing on a wood plate of mass 100 kg, that has been
placed over a smooth surface. If both the men start moving toward each other with speeds 1 m/s and

2 m/s respectively, then the velocity of the plate by which it starts moving is m/s find x.
2) Potential at point A due to dipoles is then find the value of β + γ ?

3) Find the current shown by ammeter (ideal) in ampere.

4) In potentiometer experiment, balance length (ℓ) is x and 2x when variable resistor R is set at

value 10Ω and 24 Ω. Resistance of potentiometer wire AB is (in Ω)

5) A particle of mass 1 kg and charge 0.5 C, is projected in a magnetic field of magnitude 2T, with a
velocity 3 m/s making an angle of 30° with the field. Find radius of curvature of path traced out by
the particle (in metres) [neglect gravity].

6) In the given circuit all resistors are identical. Their resistance is equal to 20Ω. Find the equivalent

resistance between A & B in Ω.

PART- 2 : CHEMISTRY
 SECTION-I (i)

1) For a reversible reaction:

graph of is given below:

[Kf = Rate constant of forward reaction, Kb = Rate constant of backward reaction] (Give R =
2)

then enthalpy of given reaction is:

(A) –6.21 cal mol–1

(B) 6.21 cal mol–1
(C) 3.106 cal mol–1
(D) –3.106 cal mol–1

2) For a given sequential first order reaction A → B → C, t1/2 for A & B are 4 and 2 minutes
respectively. How much time would be required for the B to reach maximum concentration.

(A) 2 min
(B) 6 min
(C) 4 min
(D) 8 min

3) Markownikoff's rule is not applicable on which of the following alkene :

(A)

(B)

(C)
(D)

4) In which of the following reaction, Markownikoff's rule is violated ?

CH3–O–CH=CH2
(A)

(B)
CH3–NH–CH=CH2

(C)
CH3–S–CH=CH2
O2N–CH=CH2
(D)

5)

[SiF6]–2 is known where as [SiCl6]–2 not because

–2 +4
(A) In [SiCl6] interaction between lone pair of chloride ion and Si is very strong
–2
(B) In [SiCl6] back bonding is not possible
(C) Six large chloride ions cannot be accomodated around Si+4 due to limitation of its size
(D) Si has no vacant orbital for accepting lone pair

6) The right order of ionization potential of Li, Be, B & C is :

(A) C > Be > B > Li

(B) C > B > Be > Li
(C) C > B > Li > Be
(D) B > C > Be > Li

SECTION-I (ii)

1) For the reaction A → B, the rate law expression is = k [A]1/2. If initial concentration of [A] is
[A]0, then

(A)
The integrated rate expression is k =

(B)

The graph of vs t will be

(C)
The half life period,

(D)
The time taken for 75% completion of reaction

2) For the gas phase reaction : R – H + X2 → R – X + HX, following mechanism has been proposed

Based on this, select the correct option (s)

(A)
Effective rate constant for the formation of RX is k3k4

(B)

(C) Overall order of the reaction is 3/2

(D)

3)
Which of the following best describes the product mixture ?

(A) It is racemic mixture

(B) It is a mixture of diastereomers
(C) It is optically inactive
(D) It is optically active

4) Cycloalkanes are not planar except cyclopropane. They exist in various arrangement by ring
flipping & these arrangements are known as conformation. Cyclohexane has various conformations

known as chair, Boat, Twist boat, Half chair etc.

Conformation corresponding to 'Q' can be :
(A)

(Twist boat form)

(B)

(Chair form)

(C)

(Boat form)

(D)

(Half chair form)

5) The compound(s) that exhibit(s) geometrical isomerism is/are :

(A) [Co(NH3)5SO4]Cl
(B) [Pt(en)2Cl2]Cl2
(C) [Cr(CN)6]
(D) [Co(NH3)3Cl3]

6) Which of the following statements is correct?

(A) The order of splitting energy is

(B) is colourless whereas is coloured

(C) will exhibit geometrical isomerism
(D) The magnetic moment of is B.M

SECTION-II

1) A gas phase reaction is, A(g) + 2B(g) → C(g) The reaction was carried out with stoichiometric
proportions of A and B and the following data is obtained

Half life (min) 10 160

Initial Pressure of A (atm) 40 atm 10 atm

What is overall order of reaction?
2) For a first order reaction A → B, A is optically active and B is optically inactive, and following
experimental data were observed
Time 0 60 min ∞
Optical rotation 82° 22° 2°
If some impurity is present, find optical rotation after 2 hours

3) How many number of moles of H2 is used for the complete hydrogenation of 1 mole of the given
compound in the presence of a metal catalyst?

4) Total number of following carbocation which will undergo rearrangement ?

(a) (b)

(c) (d)

(e) (f)

(g) (h)

(i) (j)

5)

Find total no. of oxygen atom which are in –1 oxidation state in CrO5.

6) How many maximum Cr – O bonds are equivalent in dichromate anion ?

PART- 3 : MATHEMATICS

SECTION-I (i)
1) For n ∈ N, let xn be defined as then equals

(A) 1

(B)

(C)

(D) 0

2) If , then the sum of integral values of a for

which equation

, possess solution(s), is

(A) 6
(B) 7
(C) 9
(D) 10

3) If a is even natural number, b is odd natural number and

(where [x] represents greatest integer function of x), then k1 + k2 equals

(A) 2
(B) 3
(C) 4
(D) 5

4) Consider f(x) = tan–1 ,x∈ . A normal to y = f(x) at x = also passes through

the point :

(A)

(B) (0, 0)

(C)

(D)

5) Let g(x) = ln f(x) where f(x) is a twice differentiable positive function on (0, ∞) such that f(x + 1) =
x f(x). Then for N = 1, 2, 3,........,
g" – g" =

(A)
–4

(B)
4

(C)
–4

(D)
4

6) Let the line x + y = 1 meet the axes of x and y at A and B, respectively. A right angled triangle
AMN is inscribed in the triangle OAB, where O is the origin and the points M and N lie on the lines

OB and AB, respectively. If the area of the triangle AMN isof the area of the triangle OAB and AN :
NB = λ : 1, then the sum of all possible value(s) of is λ :

(A)

(B)

(C)

(D) 2

SECTION-I (ii)

1) If the parameters a, c, b (c > 0) are in G.P. and p be the length of the perpendicular from origin

to the line of the family x(c4 – (2ab – 1) ab + a2b2) + – 10c = 0, then maximum
value of p is :

(A) 9
(B) 10
(C) 20
(D) 30

2) Let f be a function given by . Then,

(A) f is continuous on R
 f is differentiable on R and equals
(B)

(C) f is not differentiable at x = 0

f is differentiable on R and equals

(D)

3) Consider a function be a twice differentiable function such that

, then which of the following is/are correct?

(A) There exists a such that

(B) There exists a such that

(C)
There exists a such that f"(c) = 0

(D) There exists a such that

4) If where & , then the

possible value(s) of α is/are

(A)

(B)

(C)

(D)

5) A parabola of the form y = ax2 + bx + c with a > 0 intersects the graph of f (x) = . Number
of possible distinct intersection(s) of these graph is

(A) 0
(B) 2
(C) 3
(D) 4

6) Let f(x) = . x, then

(A) f '(10) = 1
(B) f '(3/2) = –1
(C) domain of f(x) is x ≥ 1
(D) none

SECTION-II

1) Let P(x) = x2 – αx + 8 with α a positive integer, and suppose that P has two distinct real roots r
and s. Points (r, 0), (0, s), and (t, t) for some positive integer t are selected on the coordinate plane to
form a triangle with an area of 2021. Determine the minimum possible value of (α + t – 122).

2) If , then the value of can be

expressed in the lowest form as . Find the value of .

3) If the least positive value of α for which |6x + 25α| . (4 + x2) ≥ 50x, ∀ x ∈ R is k and

where β, γ are co-prime. Then value of is (where is

greatest integer function)

4) Let . If and , then find the

value of .
[Note: {k} denote the fractional part of k.]

5) If the curves cut at right angles, then is equal to _______.

6) Let be defined on set of real number

(where ). If and K be minimum number

of zeroes of the equation , then is :

 ANSWER KEYS

PART- 1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. C D B C A A

SECTION-I (ii)

Q. 7 8 9 10 11 12
A. B,C C,D A,B,C A,B,C B,C,D A,C,D

SECTION-II

Q. 13 14 15 16 17 18
A. 4.00 5.00 1.00 4.00 6.00 9.00

PART- 2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. A C C D C A

SECTION-I (ii)

Q. 25 26 27 28 29 30
A. A,B,D C,D C A B,D A,D

SECTION-II

Q. 31 32 33 34 35 36
A. 3.00 7.00 7.00 6.00 4.00 6.00

PART- 3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. B D B C A D

SECTION-I (ii)

Q. 43 44 45 46 47 48
A. B A,B A,B,D B,C B,C,D A,B
 SECTION-II

Q. 49 50 51 52 53 54
A. 7.00 167 506.00 0004 4.00 1.25
 SOLUTIONS

PART- 1 : PHYSICS

1)

mass of removed = =m

Centre of mass initially at 0,

Now =

∴ Now position = =

2)
Take PQ as the x - axis and PA as the y - axis. Consider two elements EF and E’F’ of width
dθ at angular distance θ at angular distance θ above and below PO, respectively The
magnitude of the filed at P due to either element is

Resolving the fields, we find that the components along PO sum up to zero and hence, the
resultant field is along PB.
Therefore, field at P due to pair of elements = 2d E sin θ

3) As no current will be flowing due to high resistance

of ideal voltmeter readings will be zero.
4)

5)

6)

Concept : Biot-Savart Law

Solution :

7)

8)
(A)

(B)
(C) Electric field outside the conducting cavity due to charges kept inside the cavity and
induced charges on the inner surface of the cavity is always zero. (electrostatic sheilding)
(D) Because the charge at the surface of conductor is uniformly distributed so electric field
due to them inside conductor will be zero so net force on the charges induced on the surface of
cavity is zero.

9) If resistance of resistance box is 170W current in

wire AB is
Case I

VAB =
So max. 6V or less than 6V can be measured
Case II
if R = 120

VAB = 0.1 × 75 = 7.5

so 7V can be measured.

10)
As magnetic field is uniform

When is along y or z axis

F ∝ (L + R)
When is along x-axis
F=0
∴ (A,B,C)

11)

Correct Ans. is (B,C,D)

12)
cos α =

13)

–60 × 2 + 80 × 1 + 100 V = 0

V=

14) ;
⇒ β = 3 and γ = 2 then β + γ = 5

15)
Find equivalent

16) At balance condition (Resistance of wire AB = r)

⇒ (24 + r) (x) = (10 +r) (2x)

⇒ r = 4Ω

17) New Ans. (1.5) By Yashwant Sir

 18) Equivalent circuit

Req =

PART- 2 : CHEMISTRY

19)

Slope =
Eaf = 3 cal

= 9.21 cal
ΔH = Eaf – Eab
= 3 – 9.21 = – 6.21 cal

20)

Calculations

A. Calculate k_A and k_B:

A. k_A = ln(2) / 4 min⁻¹
B. k_B = ln(2) / 2 min⁻¹
B. Substitute into the t_max formula:
A. t_max = ln( (ln(2) / 4) / (ln(2) / 2) ) / ( (ln(2) / 4) - (ln(2) / 2) )
B. t_max = ln(1/2) / (ln(2) / 4 - ln(2) / 2)
C. t_max = ln(1/2) / ( (1-2) * ln(2) / 4)
D. t_max = ln(1/2) / (-ln(2) / 4)
E. t_max = -ln(2) / (-ln(2) / 4)
F. t_max = 4

21) Explanation - Question is asking about, Markovnikov's rule is not applicable.

Concept - Markovnikov's rule is not applicable on symmetrical alkene.
Solution - This rule states that negative part of adding molecule gets attached to that carbon
atom which possesses less number of hydrogen atom.
 A. → unsymmetrical alkene

B. → unsymmetrical alkene

C. → symmetrical alkene

D. → unsymmetrical alkene

Final Answer - Option 3 is correct

22) Presence of –M group violate Markovinikoff's rule

23)

[SiCl6]2– not exist due to steric repulsion beween Cl – Cl atom.

24)

Generally In a period, Zeff so I.E.

But for half filled and fully filled configurations I.E.
So Be > B
Correct order
I.E. ⇒ C > Be > B > Li

25) (A)
(B)
y = c + mx

(C) at

(D) at t = 75% A =

26) X2
(slowest)
By RDS

From =

Order of reaction = 1 +

27)

28) A is conformation corresponding to Q

 29)

Concept : Geometrical isomers ⇒ Isomers in which distance between two ligands are
different.
(A) [Co (NH3)5 SO4] Cl No G.I.
(B) [Pt (en)2 Cl2] G.I. possible

Trans cis
(C) [Cr (CN)6] No G.I.
(D) [Co (NH3)3 Cl3] G.I. possible

Mer fac

30) C is incorrect it does not show geometrical isomerism.

is coloured due to d-d transition.

31)

t1/2 ∝
10 × 40n – 1 = 160 × 10n–1
4n–1 = 16 = 42
⇒n=3

32)

A. Determine the rate constant (k):

A. For a first-order reaction, the integrated rate law is: ln(R₀ - Rᵥ) - ln(Rt - Rᵥ) = kt, where
R₀ is the initial rotation, Rᵥ is the rotation when the reaction is complete, and Rt is the
rotation at time t.
B. In this case, R₀ = 82°, Rᵥ = 2°, and at t = 60 min, Rt = 22°.
C. Substituting these values: ln(82 - 2) - ln(22 - 2) = k * 60
D. This simplifies to: ln(80) - ln(20) = 60k
E. Therefore, ln(80/20) = 60k => ln(4) = 60k => k = ln(4) / 60 ≈ 0.0231 min⁻¹
F. 2. Calculate the optical rotation after 2 hours (120 minutes):
A. Using the same formula with t = 120 min: ln(82 - 2) - ln(Rt - 2) = k * 120
 B. Substituting the value of k: ln(80) - ln(Rt - 2) = 0.0231 * 120
C. This simplifies to: ln(80) - ln(Rt - 2) = 2.772
D. ln(80 / (Rt - 2)) = 2.772
E. 80 / (Rt - 2) = e^(2.772) ≈ 16
F. Rt - 2 = 80 / 16 = 5
G. Therefore, Rt = 5 + 2 = 7°

33)

34) Explanation - Question is asking about total number of carbocation which will undergo
rearrangement.
Concept - A lens stable carbocation rearrange to form more stable carbocation via
(a) Ring expansion
(b) alkyl shift ( -H > -R > -ph)

Solution -

(A)

(B)

(c)

(d)
(e)

(f)

(g)

(h)

(i)
 (j)

Final Answer - 6 [b,d,e,f,g,j]

35)

36) Question Explanation:

Question is asking for number of Cr – O bonds in dichromate ion which are similar.

Concept:
This question is based on structural formula.

Solution:

These 6 bonds are similar due to resonance.

Final Answer:
The correct answer is 6.

PART- 3 : MATHEMATICS

37)
Take ln on both sides
using expansion

38) Clearly,

Now domain of equation

So,

So, and minimum and maximum is attained at x = 0 and x = -1

Also,

Hence, sum of integral values of a = 10.

39) Given series

have (b – 1) terms
First term + last term =

=
=a–1
Similarly
second term + second last term

=
=a–1

So required sum =
⇒ k1 + k2 = 3

40) Consider ⇒

⇒ ⇒

⇒ ⇒

∴ f(x) = tan–1 ⇒ f(x) = tan–1

∵ ⇒ ⇒

∴ Modulus opens with positive sign and tan–1 (tanM) = M, ∀

⇒ f(x) = = y (line); Nomal at x = is y – = –2

41) ∵ g(x) = ln(f(x))

⇒ g(x + 1) = ln(f(x + 1))
⇒ g(x + 1) = ln(x.f(x))
⇒ g(x + 1) = ln(x) + ln(f(x))
⇒ g(x + 1) = ln(x) + g(x)

⇒
Differ. w.r.t.(x) two times

⇒
put
Add

=–

42)

Area of ΔAOB =

Area of ΔAMN =
Equation of AB is x + y = 1
OA = 1, AM = sec(45° – θ)
AN = sec(45° – θ) cosθ
MN = sec(45° – θ) sinθ

Ar(ΔAMN) = sec2(45° – θ)sinθ.cosθ

⇒ tanθ = 2,
tanθ = 2 is rejected

43) c2 = cb (given)
x(c4 – (2ab – 1) ab + a2b2)

+ – 10c = 0
4 2 2 4
⇒ x (c – (2c – 1) c + c )
+ y (c2 + 2c – 2c2) – 10 c = 0
⇒ c2 · x + y (2c – c2) – 10 c = 0
⇒ c2 (x – y) + 2c(y – 5) = 0

⇒x–y+ (y – 5) = 0,
L1 + λL2 = 0 (Form)
L1 : x – y = 0, L2 : y = 5.
∴ Variable line passes through (5, 5).
Maximum distance from the origin of the variable line is

44)
45)

All values in will be attained

46)

As

as

47)

Let us consider

on plotting a graph we get

Also,
y = ax2 + bx + c is given with a > 0.
so, it has three possibilities which shown in the graph below.
 so, from possibility-1 we have 2 point of intersection.
from possibility-2 we have 3 point of intersection .
from possibility-3 we have 4 point of intersection.
⇒ option B, option C and option D are correct

48)
Add & subtract 1 in

Case 1: &x–1≥0 Case 1: &x–1≥0

x–1>1&x≥1 x–1<1&x≥1
x>2&x≥1 x<2&x≥1
∴ x∈(2, ∞) ∴ x∈[1, 2)
⇒ f (x) = x; x ∈ (2, ∞) ⇒ f (x) = – x; x ∈ [1, 2)

f' (10) = 1 and

Since 2∉ domain so option (C) is incorrect.

49) For simplicity, let A = (r, 0), B = (0, s), and C = (t, t). By a standard distance formula, the

altitude from C to has length Substituting 8 = rs and α = r + s gives the

altitude's length as Now, since the area of triangle ΔABC is equal to

 We are given that this area is 2021, so |αt - 8| = 4042, and αt = 4050 or -4036. Since
both α and t are positive integers, we can ignore the latter case and conclude that αt = 4050.
The minimum value of α + t is thus obtained when the positive difference between them is as
small as possible, which occurs when α = 75 and t = 54 (or vice versa). Hence, α + t ≥ 75 + 54
= 129.

50)

Coefficient of should be 0
Coefficient of should be 0
⇒ coefficient of in numerator and denominator is equal.
…(i)
…(ii)

⇒ …(iii)
Add (i) + (ii)

5(ii) + (iii)

⇒
⇒

51)
100 – 25h2 = 3 (16 + 8h2 + h4)
3h4 + 49h2 – 52 = 0
(3h2 + 52) (h2 – 1) = 0 ⇒ h = ± 1
h = 1; k = 1/5

Now,

52)

=4

53)
54)

is an odd function (check yourself)

Also, as ; and ;

Hence no of zeroes of f(x) = 0 is 5