29-06-2025

5401CJM202021250005 JM

PART- 1 : PHYSICS

SECTION-A

1) A small body of mass m is projected from the surface of a given planet as shown in the figure. If
small body has velocity which is just sufficient to get out from gravity of planet then time taken by

small body to reach at height of 3R from the surface of planet is :

(A)

(B)

(C)

(D)

2) Time period of simple pendulum increases by an amount times at height 'h' from the surface
of earth. Then the value of h is :

(A) 0.25 R
(B) 0.4 R
(C) 0.5 R
(D) R

3) A planet revolving in elliptical orbit has :

(A) a constant velocity of revolution.
(B) has the least velocity when it is nearest to the sun.
(C) its areal velocity is directly proportional to its velocity.
(D) areal velocity is inversely proportional to its velocity.
(E) to follow a trajectory such that the areal velocity is constant.
Choose the correct answer from the options given below :

(A) A only
(B) D only
(C) C only
(D) E only

4) In the circuit shown below, initiallly the switch is open and the capacitors are uncharged. The
ratio of current through 2Ω resistor, just after the switch is closed and a long time after the switch is

closed :

(A) 2 : 1
(B) 1 : 2
(C) 3 : 1
(D) 1 : 3

5) In figure an arrangement of three identical capcitors is shown along with a switch S and a battery
B. If the switch S is closed, then the ratio of the energy of the capacitors system in the final steady

state to the initial state is :

(A) 2 : 1
(B) 4 : 3
(C) 3 : 2
(D) 3 : 4

6) Intially, switch S is connected to position 1 for a long time shown in figure. The net amount of
heat generated in the circuit after it is shifted to position 2 is :-
(A)

(B)

(C)

(D)

7) In the circuit shown here C1 = 6μF, C2 = 3μF and battery B = 20 V. The switch S1 is first closed. It

is then opened and afterwards S2 is closed. What is the charge on C2

(A) 120 μC
(B) 80 μC
(C) 40 μC
(D) 20 μC

8) In the figure switch S is closed and steady state is reached. Now at t = 0 voltage V2 is increased
according to equation V = t + 10; upto the breakdown stage. The correct plot of charges q1 and q2

with respect to t will be :-

(A)

(B)

(C)

(D)

9) Two identical capacitors are connected in series as shown in the figure. A dielectric slab ( K > 1)
is placed between the plates of the capacitor B and the battery remains connected. Select correct
statement

(A) The charge supplied by the battery increases.

(B) The capacitance of the system decreases
(C) The electric field in the capacitor B increases.
(D) The electrostatic potential energy decreases.
10) The equivalent capacitance between P and Q if is

(A)
(B)
(C)
(D)

11) The figure shows a network of capacitance consisting of several repetitive units of capacitance
C1 connected at end. The value of C1 such that the equivalent capacitance between A and B is
independent of number of units.

(A) C1=4C
(B) C1=3C
(C) C1=2C
(D) C1=C

12) Two particles each of mass m are placed at points P and Q as shown in the figure. R is the mid-
point of PQ = ℓ. The gravitational force on the third particle of mass m placed at point S on the

perpendicular bisector of PQ at distance ℓ from R is:-

(A)

(B)

(C)

(D)
13) In the circuit shown in figure the reading of ideal ammeter is :-

(A) 1A
(B) 2A
(C) 3A
(D) 4A

14) For a wheatstone bridge shown; R1 > R2 and R3 = R4. The direction of current in wire AB is :

(A) From A to B
(B) No current flows in AB
(C) From B to A
(D) Data is not sufficient

15) In the given circuit find the magnitude of current flowing through arm 'AB' :

(A) 4.5A
(B) 1.5 A
(C) 3.5A
(D) 4 A

16) Figure shows 3 identical bulbs with switch S closed. The brightness of bulb 1 is B1, bulb 2 is B2
and net brightness of system is BT. If switch is now opened :-
(A) B1 remains same, B2 increases and BT increases.
(B) B1 remains same, B2 decreases & BT decreases
(C) B1 decreases, B2 increases & BT decrease
(D) B1 decrease, B2 increase & BT increase

17) In the given circuit which resistor consumes maximum power :-

(A) 2Ω
(B) 3Ω
(C) 4Ω
(D) All consumes equal/over

18) In the adjacent circuit, AB is a potentiometer wire of length 40 cm and resistance per unit
length 50 Ω/m. As shown in the figure, the free end of an ideal voltmeter is touching the
potentiometer wire. What should be the velocity of the jockey as a function of time so that reading in

the voltmeter varies with time as (2 sin πt)?

(A) (10 π sin πt) cm/s

(B) (10 π cos πt) cm/s
(C) (20π sin πt) cm/s
(D) (20 π cos πt) cm/s

19) A battery of internal resistance 8Ω is connected to network as shown. In order to deliver

maximum power to network R should be :

(A) 8 Ω
(B) 4Ω
(C) 2 Ω
(D) None of these

20) A hollow spherical conductor have inner radius ‘a’ and outer radius ‘b’. A constant potential
difference is applied across inner and outer shell, due to which current flows radially. Select the

correct statement :-

(A) Drift velocity remains constant

(B) Drift velocity increases radially
(C) Drift velocity decreases radially
(D) Potential gradient [electric field] increases radially

SECTION-B

1) In the circuit shown, each resistances is . The potential V1 as indicated in the circuit, is equal

to…….V

2) Current flowing in a wire varies with time as shown in the graph. Total charge flown through
cross-section of the wire is 17n. Find the value of n
3) If in steady state the energy stored in the capacitor (as shown in figure) is N × 10–8 J. Then find

the value of N.

4) Two planets A and B are orbiting around their sun in circular orbit of radii r and 4r. In a quarter
year of planet B, how many revolutions will then planet A make?

5)

Variation of current (I) and voltage (V) in a conductor has been shown in figure. The resistance of
the conductor is

PART- 2 : CHEMISTRY

SECTION-A

1) Following mechanism has been proposed for a reaction : 2A + B → D + E

Step - I : A + B → C + D (slow)
Step - II : A + C → E (fast)
The rate law expression for the reaction is –

(A) r = k[A]2 [B]

(B) r = k[A] [B]
(C) r = k[A]2
(D) r = k[A][C]

2) A2 + 2 B → 2 AB

[A2] [B] {–d[A2]/dt}

0.1 0.2 1 × 10–2 Ms–1
0.2 0.2 2 × 10–2 Ms–1
0.2 0.4 8 × 10–2 Ms–1
Order of reaction w.r.t. A2 and B are respectively :
(A) 1, 2
(B) 2, 1
(C) 1, 1
(D) 2, 2

3) The rate constant of nth order reaction has units

(A) litre1–n mol1–n sec–1

(B) moln–1 litre1–n sec–1
(C) mol1–n litren–1 sec–1
(D) None

4) For the reaction , A + B → 2C + D which one is the incorrect statement ?

(A) Rate of disappearance of A = Rate of disappearance of B

(B) Rate of disappearance of A = Rate of appearance of D
(C) Rate of disappearance of B = 2 × Rate of appearance of C
(D) Rate of disappearance of B = 1/2 × rate of appearance of C

5) For a reaction, A + B → products, the rate of the reaction was doubled when the concentration of
A was douubled, when the concentration of A and B doubled, the rate was again doubled, the order
of the reaction with respect to A and B are :

(A) 1, 2
(B) 2, 0
(C) 1, 0
(D) 0, 1

6) The rate of a reaction is expressed in different ways as follows :

The reaction is :
(A) 4 A + B —→ 2C + 3D
(B) B + 3 D —→ 4 A + 2 C
(C) A + B —→ C + D
(D) B + D —→ A + C

7) Arrange the following three chlorides in decreasing order towards reactivity ?

(A)

(B)

(C)

(A) A > B > C`

(B) B > C > A
(C) B > A > C
(D) C > B > A

8) Which of the following is most reactive towards SN2 reaction ?

(A)

(B)

(C)

(D)

9)
Reactivity towards SN1 :-

(A) a > b > c

(B) b > a > c
(C) b > c > a
(D) c > b > a

10)

Which of the following will be most reactive for SN1

(A)

(B)

(C)

(D)

11) Order of stability of following carbocation:

(A) c > b > a

(B) a > b > c
(C) b > c > a
(D) c > a > b

12) Which of the following representation have an R configuration ?

(A)

(B)
(C)

(D)

13) Which of the following is a meso compound :-

(A)

(B)

(C)

(D)

14) Zeigler natta catalyst is :

(A) Pt/PtO
(B) Al(C2H5)3 + TiCl4
2
(C) K(PtCl3(η – C2H4)]
(D) Pt/Rh

15) From the magnetic behaviour of [NiCl4]2– (paramagnetic) and [Ni(CO)4] (diamagnetic), choose the
correct geometry and oxidation state.

[NiCl4]2– : NiII, square planar

(A)
[Ni(CO)4] : Ni(0), square planar
[NiCl4]2– : NiII, tetrahedral
(B)
[Ni(CO)4] : Ni(0), tetrahedral
[NiCl4]2– : NiII, tetrahedral
(C)
[Ni(CO)4] : NiII, square planar
[NiCl4]2– : Ni(0), tetrahedral
(D)
[Ni(CO)4] : Ni(0), square planar

16) Which of the following does not have transition metal?

(A) Haemoglobin
(B) Vitamin B12
(C) Cis – platin
(D) Chlorophyll

17) Geometrical isomerism in coordination compounds is exhibited by:

(A) Square planar and tetrahedral complexes

(B) Square planar and octahedral complexes
(C) Tetrahedral and octahedral complexes
(D) Square planar, tetrahedral and octahedral complexes

18) Number of stereoisomers exhibited by is

(A) 2
(B) 5
(C) 3
(D) 4

19) The electronic configuration of Pt (atomic number 78) is:

(A) [Xe] 4f14 5d9 6s1

(B) [Kr] 4f14 5d10
(C) [Xe] 4f14 5d10
(D) [Xe] 4f14 5d8 6s2

20) The basic character of the transition metal monoxide follows the order:-

(A) VO > CrO > TiO > FeO

(B) CrO > VO > FeO > TiO
(C) TiO > FeO > VO > CrO
(D) TiO > VO > CrO > FeO

SECTION-B

1)

SO3 decomposes into SO2 & O2 according to this equation (V = 1 litre).

At time = 20 min rate of appearance of O2 was 20 g L-1 per minute at that instant is reported

as [Link] value of 'x' is?

2) Consider the general reaction: and the following average rate data over some time
period

If the coefficient of A is 2, then sum of

3) Identify total number of stereoisomers for the following compound:

4) How many non-axial d-orbitals are involved in hybridisation of CrO2Cl2.

5) How many ligands are didentate among given ?

Gly–1 , , , en , , , , , , PPh3 , bipy

PART- 3 : MATHEMATICS

SECTION-A

1) The value of

(A)

(B)

(C) 0
(D) None of these

2) when α ∈ Q is equal to :

(A) e–α
(B) –α
(C) e1 – α
(D) e1 + α

3) The value of (where [.] represents the greatest integral function) is

(A) 199
(B) 198
(C) 0
(D) None of these

4) For each let [x] be the greatest integer less than or equal to x.
Then is equal to

(A) – sin1
(B) 0
(C) 1
(D) sin1

5) Value of + + + .... + is :

(A) 1

(B)

(C)

(D) can't be determined

6) The value of is

(A) –1
(B) 1
(C) 0
(D) 2

7) If , then the ordered pair (a, b) is:

(A)

(B)

(C)

(D)

8) equal to :

(A)
(B)

(C)

(D)

9) is equal to :

(A)

(B)

(C)

(D)

10) Let ℝ be defined as

f(x) =
If f is continuous at x = 0, then the value of 6a + b2 is equal to :

(A) 1 – e
(B) e – 1
(C) 1 + e
(D) e

11) Let, be given by where denotes the greatest integer

less than or equal to t. The number of points, where f is not continuous, is:

(A) 5
(B) 6
(C) 4
(D) 3

12) The function f(x) = [x]2 – [x2] (where [y] is the greatest integer less than or equal to y), is
discontinuous at :

(A) all integers

(B) all integers except 0 & 1
(C) all integers except 0
(D) all integers except 1
13) The function f : \{0} → given by f(x) = can be made continuous at x = 0 by
defining f(0) as-

(A) 2
(B) –1
(C) 0
(D) 1

14) The values of p and q for which the function f(x) = is continuous for
all x in , are :-

(A)
p=– ,q=

(B)
p= ,q=

(C)
p= ,q=–

(D)
p= ,q=

15)

If the function is continuous at x = 5, then the value of a – b is :-

(A)

(B)

(C)

(D)

16) Let ƒ : [–1,3] → R be defined as ƒ(x) = ,

where [t] denotes the greatest integer less than or equal to t. Then, ƒ is discontinuous at:

(A) four or more points

(B) only one point
(C) only two points
(D) only three points

17) Let f : R → R be a function defined as : f(x) = . Then, f is :

(A) continuous if a = 5 and b = 5

(B) continuous if a = –5 and b = 10
(C) continuous if a = 0 and b = 5
(D) not continuous for any values of a and b

18) If ∠A = 90° in ΔABC ; then =

(A) 0
(B) 1

(C)

(D)

19) If a function f(x) defined by be continuous for some a, b, c ∈ R

and f′(0) + f′(2) = e, then the value of of a is :

(A)

(B)

(C)

(D)

20) For each let [x] be the greatest integer less than or equal to x. Then

is equal to [JEE(Main)-2019]

(A) – sin1
(B) 0
(C) 1
(D) sin1

SECTION-B
1) Number of points of discontinuity of in [0, 20] is -
(where [.] & {.} denote greatest integer function and fractional part function respectively)

2) If L = then the value of 2L is

3) Let Then no. of points of discontinuity of f(x) in

[0,1] is [ [.] denotes G.I.F]

4) If x2 + 2x + n > 10 + sin–1(sin9) + tan–1(tan9) for all real x, then the least integral value of n is-

5) For value of
λ is
 ANSWER KEYS

PART- 1 : PHYSICS

SECTION-A

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B D C B C C A A C C C A C D C B D B C

SECTION-B

Q. 21 22 23 24 25
A. -9.00 2.00 6.00 2.00 3.00

PART- 2 : CHEMISTRY

SECTION-A

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B A C C C B B D A A A A A B B D B C A D

SECTION-B

Q. 46 47 48 49 50
A. 5 9.00 8.00 3.00 4.00

PART- 3 : MATHEMATICS

SECTION-A

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B C B A B B B C C C C D D A A D D C D A

SECTION-B

Q. 71 72 73 74 75
A. 10 5.00 4.00 12 2
 SOLUTIONS

PART- 1 : PHYSICS

1)

Speed of projection ....(i)

....(ii)

2)

h2 + 2hR – R2 = 0

3) As per Keppler's 2nd law, Areal velocity is constant.

4)

At t = 0

At t = ,

5)
6)

7) Initially charge on C1 = 6 × 10–6 × 20

= 120 mC

Finally

∴ Charge
= 40 μC

8) After closing the switch, the final charges on both capacitors are as shown.
Now when V2 starts incraesing, then only q2 starts increasing, but q1 remains unaffected.

∴ q2 = C2V2
q2 = 6 (t + 10)

9) As capacity of system increases so the charge supplied by the battery increases.

10)

Exploiting the symmetry about PQ, the circuit can be redrawn as:

Hence, by the parallel and series formal

11) The equivalent capacitance between A and B will be independent ot number of units if
addition of one or more units to C1 does not change its value. The situation is shown in figure.
The equivalent between A' and B' is still C1.
12)

= 2Fg cos θ

13) The equivalent resistance between A and B = 4Ω.

Current I =
The current divides into different branches as shown in the figure. It is clear that the ammeter

will read . So the correct choice is (1)

14)

As
∴ VB > VA ⇒ current from B to A
15)

Current in branch AB 4 A

16)
Finally

Since current through B1 decrease, it becomes drive, B2 increase, it becomes bright & current
through battery decreases,
∴ total brightness decreases.

17)

Question Explanation :
We have to identify the resistor consuming maximum power in the given circuit.

Concept :
This question is based on Electric power and circuit analysis.

Solution :
For 2Ω resistor

P1 =
For 2Ω resistor

P2 =
For 4Ω resistor

P3 =
Maximum power will be consumed in 3Ω resistor.

Hence,
Option (2) is correct

18) Question Explanation :

We have to calculate velocity of Jokey as a function of time for given variation of voltmeter
reading.

Concept :
This question is based on Potentiometer.

Solution :

Iwire = = 0.2 A
Potential difference across voltmeter, V = Ir – 2

2 sinπt = 0.2 × 50 x –2
2 πcosπt = 10 V
V = 20 π (cosπt) cm/s

Hence,
Option (4) is correct

19) Wheatstone bridge

2R = 8
⇒ R = 4Ω

20)

i = ne AVd

21)
Current flows in anticolockwise direction in the loop.
Therefore 0 – 1 × 2 – 1 × 2 – 5 = V1
V1 = –9 V

22) Q = Area

Q = 20 +14 = 34
⇒ 17n = 34
n=2

23)

ΔV = 0.2 V

U=

=
= 6 × 10–8 J

24)

25)

Resistance R =
PART- 2 : CHEMISTRY

26) Order of complex reaction are calculated according to R.D.S. (Slow steps).

27)

Let, m and n is the order of reaction w.r.t. A2 and B respectively.

So,
Now : from given data,
1 × 10–2 M/s = k[0.1]m[0.2]n …(1)
2 × 10–2 M /s = k[0.2]m[0.2]n …(2)
8 × 10–2 M /s = k[0.2]m[0.4]n …(3)
Divide (2) by (1) we get
2m = 2, ⸫ m = 1
Similarly divide (3) by (2) we get
4 = 2n , 22 = 2n
⸫n=2

28) For an nth order reaction,

rate = k[A]n; substituting units

=
⇒ k = mol(1–n) l(n – 1) sec–1

29)

For the given reaction

A + B → 2C + D

From above equation,

(a) correct

(b) correct

(c) but it is

So, it is incorrect

(d) correct

30)
The order of the reaction with respect to A is 1 and with respect to B is 0

31) Rearranging the above expression

⇒ B + 3D → 2C + 4A

32) Reactivity for SN1 reaction µ stability of carbocation.

33) Reactivity in SN2 ∝ Stability of transition state

∝ (–)I, (–)H, (–)M ∝

34) Reactivity of SN1, R∝n ∝ stability of

35)

Leaving group ability of I- and stability of carbocation

36)

37)
38)

39)

Concept Zeigler Natta catalyst is used in polymerisation of olefins and it is mixture of Al(C2H5)3
+ TiCl4

40)

[NiCl4]2–
0
Ni+2 – [Ar] 3d8 4s → sp3, Tetrahedral

Number of unpaired electron = 2 paramagentic [Ni(CO)4],

0
Ni(0) → [Ar] 3d10 4s (After rearrangement)

No unpaired electron
sp3, Tetrahedral, Diamagnetic

41) Haemoglobin → Fe
Cis – Platin → Pt
Vitamin B12 → Co
Chlorophyll → Mg

42) Square planar and octahedral complex has different bond angle.

43)

44) Question Explanation:

Question is asking to write electronic configuration of Pt.

Concept:
This question is based on n+ℓ rule and its exceptions.

Solution:
Pt → [Xe] 4f14 5d9 6s1
Final Answer:
The correct option is (1)

45) Basic character and Ionic character

Ionic character and Size of cation.
Size of cation : Ti+2 > V+2 > Cr+2 > Fe+2

46)

Solution
The value of 'x' is

0.6250.625
0.625

47)

48)
Stereogenic centre = 3
Total number of stereoisomer = 23 = 8

49) Hyb. of Cr in CrO2Cl2 is d3s in which ns, (n – 1)dxy, (n – 1)dyz and (n – 1)dzx orbitals are
participating in hybridisation. And these d-orbitals (dxy, dyz and dzx) are non oxial orbitals

50)

Question Explanation – The question asks you to identify how many of the listed ligands are
bidentate, meaning they can form two bonds to a central metal atom in a coordination
complex.

Concept – the bidentate ligands are:

Gly⁻¹, C₂O₄²⁻, en, bipy

Final Answer – This means there are 4 (bidentate ligands)

PART- 3 : MATHEMATICS

51)

52) 1∞ form :

Consider ; put n =

(using binomial)

53) We know that .

So,
= 100 + 98 = 198

54)

55) Applying sand with theorem,

Let Pn = + + + .... +

so

Pn

So Pn =

56)
57)
⇒a>0

Now,

⇒
⇒ 1 – a2 = 0 ⇒ a = 1

Now

(a, b) =

58) ×

.
Put x = cosθ

59)
Apply L-Hopital Rule :

: Again apply L-Hopital rule

60)

(6a + b2) = (1 + e)

61)

62)

f(x) = [x]2 – [x2]

at x = 0;
f(0) = 0 – 0 = 0
f(0+) = [0+]2 – [(0+)2] = 0 – 0 = 0
f(0–) = [0–]2 – [(0–)2] = (–1)2 – 0 = 1
∴ Discontinuous at x = 0.
at x = 1; f(1) = [1]2 – [12] = 0
f(1+) = [1+] – [(1+)2] = 1 –1 = 0
f(1–) = [1–]2 – [(1–)2] = 0 – 0 = 0
∴ continuous at x = 1
at x = n,
f(n) = [n]2 – [n2] = 0
f(n+) = [n+]2 – [(n+)2] = n2 – n2 = 0
f(n–) = [n–]2 – [(n–)2] = (n – 1)2 – (n2 – 1)
= n2 – 2n + 1 – n2 + 1
= –2n + 2
for continuity
∴ f(n) = f(n+) = f(n–)
0 = 0 = –2n + 2 ⇒ n = 1
∴ Discontinuous at all integers except 1.

63)

64) F(x) =

i)
Use lopital

ii)

⇒q= =p+2

⇒p=

65)
a|π – 5| + 1 = b|5 – π| + 3
a(5 – π) + 1 = b(5 – π) + 3
(a – b) (5 – π) = 2

66)
function discontinuous at x = 0,1,3

67)

f(x) =
f(1) = 5, f(1–) = 5, f(1+) = a + b
f(3–) = a + 3b, f(3) = b + 15, f(3+) = b + 15
f(5–) = b + 25 ; f(5) = 30 f(5+) = 30
from above we concluded that f is not continuous for any values of a and b.

68)

( ∵ a2 = b2 + c2)

69)
For continuity at x = 1
⇒ ⇒ ...(1)
For continuity at x = 3

⇒ 9c = 9a + 6c
⇒ c = 3a ...(2)
f'(0) + f'(2) = e
(aex – bex)x = 0 + (2cx)x = 2 = e
⇒ ...(3)
From (1), (2) & (3)
a – 3ae + ae2 + 12a = e
⇒ a(e2 + 13 – 3e) = e

70)

71) f(x) is discontinuous at

x = 2, 4, 8, 10, 14, 16, 3, 9, 15, 20
and f(x) is continuous x = 6, 12, 18.

72) If L =
 ⇒ 2L = 5

73)

f(x) = [4x] which will become discontinuous at

74) x2 + 2x + n > 10 + 3π – 9 + 9 – 3π ∀ x ∈ R
x2 + 2x + n – 10 > 0 ∀ x ∈ R
∴ D<0
∴ 4 – 4n + 40 < 0
11 < n
∴ Minimum integral value = 12

75) Here, R.H.S. =

⇒λ=2