01-06-2025

1803CJA101001250007 JA

PART-1 : PHYSICS

SECTION-I(i)

1) Which of the following is unit vector?

(A)
(B)
(C)

(D)

2) The position vector of a particle is given as The time after which the
velocity vector and acceleration vector becomes perpendicular to each other is equal to

(A) 1 sec
(B) 2 sec
(C) 1.5 sec
(D) Not possible

3) A particle moving along x-axis, its v2 and position graph given in the figure. Initial acceleration of

the object is:-

(A) zero
(B) 6 m/s2
(C) 4 m/s2
(D) 3 m/s2

4) You are throwing a ball straight up in the air. At the highest point, the ball's :-

(A) Velocity and acceleration both are zero

(B) Velocity is nonzero but its acceleration is zero
(C) Acceleration is non zero, but its velocity is zero
(D) Velocity and acceleration are both nonzero
5) A drunkard walking in a narrow lane takes 5 steps forward and 3 steps backward, followed again
by 5 steps forward and 3 steps backward, and so on. Each step is 1 m long and requires 1 s. The
time when he will fall into the pit 13 m away from him is :-

(A) 13s
(B) 37s
(C) 40s
(D) 42s

6) Drops of water fall from the roof of a building 9m high at regular intervals of time, the first drop
reaching the ground at the same instant fourth drop starts to fall. What are the distances of the
second and third drops from the roof ?

(A) 6 m and 2 m
(B) 6 m and 3 m
(C) 4 m and 1 m
(D) 4 m and 2 m

SECTION-I(ii)

1) If and , then which of the following may be CORRECT ?

(A)

(B)

(C)

(D)

2) Four vector are shown as figure. Then :

(A) Angle between and is 60°.

(B) Angle between and is 70°.
(C) Angle between and is 50°.
(D) Angle between and is 110°.

3) A freely falling body travelled 35 m in last second of its journey.

(A) The height of the point of release from ground is 80m.
(B) The distance travelled in the first second is 5m.
(C) The maximum speed attained by the body is 40 m/s.
(D) The maximum speed attained by the body is 20 m/s.

4) Which of the following statement(s) is/are true for a uniform motion i.e. motion with
uniform velocity?

(A) The motion is always in same direction

(B) The motion must be along a straight line.
(C) Average velocity is equal to the instantaneous velocity.
(D) Distance covered > |Displacement|

5) An object is moving in a straight line. Its position versus time graph is shown below. There is a
detector at origin which analyze the motion of object between t = 6 and t = 8 seconds, which
statement describes the motion shown in the graph.

(A) detector observes the object to be moving towards origin.

(B) detector observes the object to be moving away from origin.
(C) Detector observes the motion at constant speed.
(D) Detector observes the motion at zero acceleration.

6) For a particle moving in straight line. The position (x) of a particle depends on time (t) as : x = αt2
– βt3. Then choose the correct options regarding the motion of the particle.

(A) The particle will return to its starting point after time α/β
(B) The particle come momentarily at rest at time 2α/3β
(C) The intial velocity of the particle was zero but its intial acceleration was not zero.
(D) Not net force will act on the particle at t = α/3β

SECTION-II

1) The position vectors of two point objects are given by m and m. Find
the distance (in m) between these two objects.
2) If and are two non-collinear unit vectors and , then the value of .
is x. Find the value of x.

3) A body is allowed to fall from a height of 100 m. If the time taken for the first 50 m is t1 and for

the remaining 50 m is t2. Find

4) For a man who walks 720 m at a uniform speed of 2 m/s, then runs at a uniform speed of 4 m/s for
5 minute and then again walks at a speed of 1 m/s for 3 minutes. His average speed is (m/s)

5) The figure shows a velocity-time graph of a particle moving along a straight line

Find distance covered by the particle (in m).

6) A particle is moving on a straight line whose a-t graph is shown in the figure. At t = 0, the velocity

of the particle is –2 ms–1. Find velocity (in m/s)of the particle at = 4s.

PART-2 : CHEMISTRY

SECTION-I(i)

1) Which of the following molecules has an incomplete octet around the central atom in its Lewis dot
structure?

(A) BF3
(B) H2O
(C) NH3
(D) CO2

2) The d- orbitals involved in sp3d hybridisation (trigonal bipyramidal) is :

(A)
(B)
(C) dxy
(D) dxz

3) Choose correct matching :

(A) SO2 → Linear

(B) BF3 → trigonal planar
(C) PCl5 → octahedral
(D) SF6→ tetrahedral

4) Statement-1: Ionisation energy of Cl– is larger than that of F–.

Statement-2: Electron affinity of Cl is higher than that of F.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
(B)
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

5)

The ratio
Then calculate the value of IP1 and IP2 if

(A)

(B)

(C)

(D)

6) Which electronic configuration represents correct ground state electronic configuration :

(A) 1s2 , 2s1 , 2p6 , 3s1

(B) 1s2 , 2s2 , 3s2 , 3p2

(C)
(D)

SECTION-I(ii)

1) Which of the following statements is/are correct ?

(A) The second ionization enthalpy of oxygen element is greater than that of fluorine element.
(B) The third ionization enthalpy of phosphorus is greater than that of aluminium.
(C) The first ionization enthalpy of aluminium is slightly greater than that of gallium.
(D) The second ionization enthalpy of boron is greater than that of carbon.

2) Choose the correct statement(s) :-

All H atom has same formal charge in

(A)

(B) Fluorine has higher electron affinity than chlorine

(C) IE3 (Mg) > IE2 (Na)
(D) CH4 molecule has polar bonds

3) Which of the following compound(s) of Xenon is/are NOT square pyramidal?

(A) XeOF4
(B) XeO2F2
(C) XeO3F2
+
(D) XeF5

4) Which of the following has/have coordinate bond?

(A) CH4
(B) O3
(C)
(D)

5) The set of quantum number of an unpaired electron of nitrogen atom is n = 2, ℓ = 1, m = 0 & s =

+ . Which among the following set of quantum number is possible for other unpaired electrons of
nitrogen atom
n ℓ m s

(A) 2 1 0 –

(B) 2 1 –1 +

(C) 2 1 +1 +
(D) 2 0 1 –

(A) (A)
(B) (B)
(C) (C)
(D) (D)

6) Which of the following statements are CORRECT :

(A) According to (n + ℓ) rule, energy of 3d subshell is less than 4s

(B) According to Aufbau's rule '5s' subshell should be filled just before 4ƒ subshell
(C) Orbit and orbital are not same
– 2–
(D) N3 and CN2 are isoster of each other

SECTION-II

1) Consider y-axis as inter-nuclear axis, how many of following will lead to π bond formation?
(a) py – py (b) px – px
(c) pz – pz (d) dxy – dxy
(e) dyz – dyz (f) px – dxy
(g) dxy – pz (h) dxz – dxz

2) Find the ratio of σ bond to lone pair on central atom of SF4.

3) How many molecules from the following are hypovalent?

BCl3, CH4, NH3, BeCl2, SF6, XeF2, BF3

4) How many of the following species one isoelectronic with Ne.

Na+, Na, F–, N3–, N, O2–, Mg2+, Al+3, K+, Ca2+, Cl–

5) For SO3 total number of lone pair = x, number of pπ - pπ bond = y, number of pπ - dπ bond = z

find .

6) Find the value of , where

x = atomic number of element having zero unpaired e– in 3d series
y = atomic number of element having maximum number of unpaired e– in 3d series

PART-3 : MATHEMATICS

SECTION-I(i)
1) Number of integers satisfying the inequality, is

(A) 2
(B) 4
(C) 6
(D) 8

2) is equal to :-

(A) 1
(B) 2
(C) 3
(D) 4

3) An organization awarded 48 medals in event 'A', 25 in event 'B' and 18 in event 'C'. If these
medals went to total 60 men and only five men got medals in all the three events, then, how many
received medals in exactly two of three events ?

(A) 10
(B) 9
(C) 21
(D) 15

4) The value of c, for which where a and β are roots of 2x2 + 7x + c = 0, is

(A) 2
(B) 6
(C) 5
(D) 4

5) The number of real roots of the equation x|x| – 5|x + 2| + 6 = 0, is

(A) 5
(B) 3
(C) 6
(D) 4

6) Let Then n(S) is equal to

(A) 2
(B) 4
(C) 6
(D) 0

SECTION-I(ii)

1) If x2 – px + 20 = 0 and x2 – 20x + p = 0 have exactly one common root then equation whose roots
are uncommon roots of given equations is

(A) x2 + x + 420 = 0
(B) x2 – (x + 420) = 0
(C) x2 + 18x + 80 = 0
(D) x2 + 41x + 420 = 0

2) For x ∈ [1, 5], y = x2 – 5x + 3 has:

(A) Least value of –1.5

(B) Greatest value = 3
(C) Least value of –3.25

(D)
Greatest value

3)

The set of real numbers x for which x2 – |x + 2| + x > 0 is

(A) (–∞, –2)

(B)

(C) (–∞, –1) ∪ (1, ∞)

(D)

4) Let are solutions of the equation then which

of the followings are correct?

(A) a + b = 12
(B) a2 – b2 = 80
(C) (a + b)2 = 100
(D) a2 + b2 = 80

5) Subsets of the solution set of inequation x(x + 2)2 (x – 1)5 (2x – 3) (x – 3)4 ≥ 0 is/are

(A) [0, 1]

(B)

(C)
(D) (– ∞ , –5]

6) If x, y, z are distinct real numbers, then the value of is

(A)

(B)

(C)

(D)

SECTION-II

1)

If the number of positive integral solutions of |x2 – 3x| + |6 – 2x| = |x2 – 5x + 6| is k then the value of

is :-

2) Let if range of values of t is [α, β], then 3α + β is equal to

3) If (α + 1)2x2 + 2(α + 1) (α + 2)x + 4 > 0 ∀ x ∈ R, then sum of all possible integral values of α is

4) The sum of the cubes of all the roots of the equation x4 – 3x3 – 2x2 + 3x + 1 = 0 is_____.

5) If α, β are roots of the equation x2 – 6x + 4 = 0, then value of is

6) Let α, β are the roots of the equation x2 + ax + b = 0 and γ, δ are the roots of x2 – ax + b – 2 = 0.

If then the value of ‘a’ is

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. B A D C B C

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. A,B,D A,C,D A,B,C A,B,C A,C,D A,B,C,D

SECTION-II

Q. 13 14 15 16 17 18
A. 5.64 to 5.66 0.50 0.41 2.50 180.00 10.5

PART-2 : CHEMISTRY

SECTION-I(i)

Q. 19 20 21 22 23 24
A. A B B A C D

SECTION-I(ii)

Q. 25 26 27 28 29 30
A. A,B,D A,C,D B,C B,C (B),(C) C,D

SECTION-II

Q. 31 32 33 34 35 36
A. 5.00 4.00 3.00 6 8.00 1.50

PART-3 : MATHEMATICS

SECTION-I(i)

Q. 37 38 39 40 41 42
A. D B C B B B

SECTION-I(ii)

Q. 43 44 45 46 47 48
A. B B,C A,B,D B,C A,C A,B,C,D
 SECTION-II

Q. 49 50 51 52 53 54
A. 0.25 9.00 5.00 36.00 257.00 5.00
 SOLUTIONS

PART-1 : PHYSICS

2)

if are perpendicular

3)

Slope =

5) The time taken to move net 2 steps is 8s, and so for 8 steps he takes 32 s. In last 5 steps he
will take 5s and fall into the pit.

7)

8) Angle between and is 60°.

Angle between and is 50°.
Angle between and is 110°.

11) From t = 6 sec to t = 8 sec. velocity of particle is towards – ve x-axis and position is
positive so object to be moving towards origin.

14) a1 = a2 = 1
and

Now,
+ a1a2cosθ
 16) Where s1 = 720 m and = 360s = 6 min.
s2 = (4)(5)(60) = 1200 m, t2 = 300 s
s3 = (1)(3)(60) = 180 m, t3 = 180 s

18)
at t = 0 → v = –2m/s2

a=

area of a–t curve

v+2=
v + 2 = 12.5
v = 10.5 m/s

PART-2 : CHEMISTRY

19)

BF3 ⇒ 6e– in octet

Hypovalent
H2O, NH3, CO2 ⇒ 8e– in octet

20) Atomic orbitals involved are s, px, py, pz,

21) SO2 is Bent

BF3 is trigonal planar
PCl5 is trigonal bipyramidal
SF6 is square bipyramidal
23)

IP1 + IP2 + x = 5x

24)

Ans. (D)

25)

(A) As removal of second electron takes place from half filled valence shell electron
configuration of O+ i.e. 2s22p3.

(B) I.E(III) of 13Al is 2744 kJ mol–1 where as that of 15P is 2910 kJ mol–1. This is because of higher
nuclear charge in phosphorus.

(C) I.E(I) of Al is 577 kJ mol–1 and that of Ga is 579 kJ mol–1. This may be because of their
similar sizes i.e. 1.25 Å in both.

(D) 5B+ = 1s22s2; 6C+ = 1s22s22p1; As s-sub shell electron has high penetration power than p-sub
shell electron. In addition B+ has completely filled 2s sub shell. So I.E (II) of B is 2427 and that
of C is 2354 kJ mol–1.

26) Ans.(A,C,D)

27) (a) XeOF4 is square pyramidal.

(b) XeO2F2 is see-saw.
(c) XeO3F2 is trigonal bipyramidal.
(d) XeF5+ is square pyramidal.

28)

(A) (B)
(C) (D)
B & C has Co-ordinate bond

29)

30)

Ans.(C)

31) py – py → σ-bond
px – px → π-bond
pz – pz →π-bond
dxy – dxy →π-bond
dyz – dyz → π-bond
Px – dxy → π-bond
dxz – dxz → δ-bond
dxy – pz → no-bond

32)

33)

BCl3, BeCl2 & BF3

Hypovalent molecules are short octet
(total electrons on central atom < 8)

34) Na+ → 10
Na → 11
F– → 10
N3– → 10
N → 7
2–
O → 10
Mg2+ → 10
+3
Al → 10
 K+ → 18
Ca2+ → 8
Cl– → 18

35)
x=6
y=1
z=2

36)

Ans : (1.50)

3d-series elements = Sc Ti V Cr Mn Fe Co Ni Cu Zn

Unpaired e–s = 1 2 3 6 5 4 3 2 1 0

PART-3 : MATHEMATICS

37) We have

Integers satisfying above are

So, there are eight integers.

38)
39) n(A) = 48, n(B) = 25, n(C) = 18
n(A ∪ B ∪ C) = 60
n(A ∩ B ∩ C) = 5
n(A ∩ B) + n(B ∩ C) + n(C ∩ A)
= n(A) + n(B) + n(C) + n(A ∩ B ∩ C) – n(A ∪ B ∪ C)
= 48 + 25 + 18 + 5 – 60 = 36
Now exactly two = 36 – 3(5) = 21

40)

⇒ 49 – 8c = 1
⇒ 48 = 8c
⇒c=6

41) x |x| – 5 |x + 2| + 6 = 0
C – 1 : x ∈ [0, ∞]
x2 – 5x – 4 = 0

C – 2 : x ∈ [–2, 0)
–x2 – 5x – 4 = 0
x2 + 5x + 4 = 0
x = –1, –4
x = –1
C – 3 : x ∈ [– ∞, –2)
–x2 + 5x + 16 = 0
x2 – 5x – 16 = 0

42)

Let

x2 – 4 = 2, –2 or x2 = 6, 2
43) x2 – px + 20 = 0 ...(1)
2
x – 20x + p = 0 ...(2)
common root is x = –1 ⇒ p = –21
from (1)
x2 + 21x + 20 = 0 ⇒ x = –1, –20
from (2)
x2 – 20x – 21 = 0 ⇒ x = –1, 21
other uncommon roots are –20, 21
required equation is (x + 20)(x – 21) = 0
x2 – x – 420 = 0

44) y = x2 – 5x + 3

Vertex =
at x = 1, y = 1 – 5 + 3 = –1
at x = 5, y = 25 – 25 + 3 = 3
when x ∈ [1, 5] from graph

y ∈ [–3.25, 3]

45) Case(I) If (x + 2) ≥ 0 ⇒ x ≥ –2 .... (1)

⇒ x2 – x – 2 + x > 0

.... (2)
∴ By (1) ∩ (2)

.... (3)
or
Case (II) If (x + 2) < 0 ⇒ x < –2
⇒ x2 + x + 2 + x > 0
⇒ x2 + 2x + 2 > 0
which is true for ∀ x ∈ R
∴ x < –2 .... (4)
By (3) ∪ (4)
46)

x = 9, 1

47)

⇒ x ∈ [0, 1] ∪ ∪ {–2}

48)

Also

A, B, C, D are all correct.

49) If |a| + |b| = |a + b| then ab ≥ 0

⇒ (x2 – 3x)(6 – 2x) ≥ 0 ⇒ x(x – 3)2 ≤ 0
⇒ x ∈ (–∞, 0] ∪ {3}
∴ only one positive integer solution x = 3

50)
⇒ x2 (t – 1) – 4x + 9(t – 1) = 0
where

– {1}
Now when t = 1
⇒ x = 0 ∈ R ⇒ t = 1 is also included

Hence,

51) for
⇒ 4(α + 1)2(α + 2)2 – 4(α + 1)2 . 4 < 0
⇒ 4(α + 1)2[α + 2)2 – 4] < 0
⇒ 4(α + 1)2(α – 4)(α) < 0
⇒ α ∈ (0, 4)
Also at a = –1 : 4 > 0
∴ final : α ∈ (0, 4) ∪ {–1}
Sum of integral values = –1 + 1 + 2 + 3 = 5

52) x4 – 3x3 – 2x2 + 3x + 1 = 0

x = 0 is not the root of this equation so divide it by x2

x2 – 1 = 0 x2 – 3x – 1 = 0
x = ±1 γ+δ=3

=
= 0 + 3(9 – 3 (–1))
= 3(12) = 36

53) α2 – 6α + 4 = 0 ⇒ (α – 2)2 = 2α

& β2 – 6β + 4 = 0 ⇒ (β – 6) =

Now

54) x2 + ax + b = 0 has roots α, β

Replace x by then equation bx2 + ax + 1 = 0

has roots similarly replacing x by in the equation x2 – ax + b – 2 = 0, we get

equation (b – 2)x2 – ax + 1 = 0 has roots

Now, αβ = b, γσ = b – 2 and
using given conditions we have
⇒a=5