Dr Sayan Chemistry Home Work Sheet
Q1. Calculate the mass percentage of benzene ( ) and carbon tetrachloride ( ) if 22 g
of benzene is dissolved in 122 g of carbon tetrachloride.
Q2. The vapor pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350
K. Find out the composition of the liquid mixture if total vapor pressure is 600 mm Hg. Also
find the composition of the vapor phase.
Q3. Vapor pressure of pure water at 298 K is 23.8 mm Hg. 50 g of urea ( ) is
dissolved in 850 g of water. Calculate the vapor pressure of water for this solution and its
relative lowering.
Q4. Concentrated nitric acid used in laboratory work is 68% nitric acid by mass in aqueous
solution. What should be the molarity of such a sample of the acid if the density of the
solution is 1.504 g/ml?
Q5. A solution of glucose in water is labelled as 10% w/w, that would be the molality and
mole fraction of each component in the solution? If the density of solution is 1.2 g/ml then
what shall be the molarity of the solution?
Q6. How many ml of 0.1 M HCl are required to react completely with 1 g mixture of
and containing equimolar amounts of both?
Q7. An antifreeze solution is prepared from 222.6 g of ethylene glycol ( ) and 200g of
water. Calculate the molality of the solution. If the density of the solution is 1.072 g/ml,
then what shall be the molarity of the solution?
Q8. An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the
normal boiling point of the solvent. What is the molar mass of the solute?
Q9. Heptane and octane form an ideal solution. At 373 K, the vapor pressure of the two
liquid components is 105.2 kPa and 46.8 kPa respectively. What will be the vapor pressure
of a mixture of 26.0 g of heptane and 35.0 g of octane?
Q10. The vapor pressure of water is 12.3 kPa at 300 K. Calculate vapor pressure of 1 molal
solution of a non-volatile solute in it.
Q12. Calculate the mass of a non-volatile solute (molar mass 40 g/mol) which should be
dissolved in 114 g octane to reduce its vapor pressure to 80%.
Q13. Calculate the amount of benzoic acid ( ) required for preparing 250 mL of
0.15M solution in methanol.
Q14. Vapor pressure of water at 293 K is 17.535 mm Hg. Calculate the vapor pressure of
water at 293 K when 25 g of glucose is dissolved in 450 g of water.