31-03-2026

1001CJA101021260006 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) If f(x) = , x ≠ 0 and f(0) = 2 is continuous at x = 0, then the number of ordered

pairs (a, b) is

(A) 1
(B) 2
(C) 3
(D) 4

2) The value of cot(cos–1(|sinx| + |cosx|) + sin–1(–|cosx| – |sinx|)) is equal to

(A) 0
(B) 1
(C) –1
(D)

3) If , α, β, γ ∈ R, then the value of α – β – γ is

(A) 6
(B) 7
(C) 8
(D) 9

4) Let Sk = . Then is equal to :

(A)

(B)

(C)

(D) tan–1(3)

SECTION-I (ii)
1) Let a, b, c be positive numbers such that a + b + c = 15. Then the value
of can be

(A) 5
(B) 4

(C)

(D) 6

2) If f(x) = x2sinx and g(n) = , n ∈ N (where [.]

represent greatest integer function), then

(A)

(B)

(C)

(D)

3) Which of the following statement(s) is(are) correct ?

(A)
Period of f(x) = cosec + sec + cot + tan + cos + sin is 420π

(B)
If g(x) = then g(g(x)) = g(x) ∀ x ∈ R
(C) Let f : [–1, ∞) → (0, ∞) defined by f(x) = then f(x) is many one into
(D) Let f : R → R defined by f(x) = Min. (|x|, 1 – |x|) then f(x) is neither even nor odd

SECTION-I (iii)

1) Consider the following lists :

List-I List-II

(P) (1) has one element

(Q) (2) has two elements

has three
(R) (3)
elements
 (S) (4) has four elements

(5) has six elements

(A) P → 5;Q → 2;R → 4;S → 1
(B) P → 1;Q → 2;R → 4;S → 5
(C) P → 5;Q → 3;R → 2;S → 1
(D) P → 1;Q → 3;R → 2;S → 5

2) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) (1) 2

(Q) (2) 6

(R) (3) –3

(S) (4) 0

(5) does not exist

(A) P → 5;Q → 2;R → 3;S → 4
(B) P → 4;Q → 2;R → 3;S → 1
(C) P → 5;Q → 3;R → 2;S → 4
(D) P → 4;Q → 3;R → 2;S → 1

3) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

Maximum and minimum values of

(7 + 6tanθ – tan2θ)/(1 + tan2θ)
(P) (1) 3
(for all real θ ≠ (2n + 1) , n ∈ Z)
respectively λ and μ then λ + 2μ is

(Q) If the function f(x) = for x ≠ 0, (2) 4

is continuous at x = 0 then 4f(0) must be equal to

(R) (3) 5
If then a + b =
 If satisfies the inequality

(S) (4) 6

then =
(where [.] denotes greatest integer function)

(5) 7
(A) P → 2;Q → 5;R → 3;S → 4
(B) P → 1;Q → 5;R → 2;S → 4
(C) P → 1;Q → 1;R → 2;S → 5
(D) P → 2;Q → 1;R → 3;S → 5

SECTION-II

1) If is equal to (where a and b are coprime), then value of

is

2) Let f(x) = , then the value of is equal to -

3) If {.} denotes the fractional part function then the number x = simplifies
to -

4) Considering only the principal values of the inverse trigonometric functions, the value of

is then value of λ is

5) If f(x) = and and , then the value of is (where [.]

denote the greatest integer function and take base of log as e)

6) Let f(x) = where {.} denotes fraction part function is continuous at x = 2,

then p + q is

PART-2 : PHYSICS

SECTION-I (i)

1) The cube shown below has edge lengths of 1.4 m and is placed such that the hidden corner is at
the origin of the coordinate system. If N/C , where is in units of newtons/coulomb and y

is coordinate in meters, what is ?

(A) 5.88 N-m2/C

(B) 0
(C) 8.23 N-m2/C
(D) 4.2 N-m2/C

2) Three right angled prisms of refractive indices n1,n2 and n3 are fixed together using an optical
glue as shown in figure. If a ray passes through the prisms without suffering any deviation, then-

(A) n1 = n2 = n3
(B) n1 = n2 ≠ n3
(C) 1 + n1 = n2 +n3
(D)

3) In the given figure, string, spring and pulleys are massless. Block A, performing SHM of
amplitude 1 m and time period π/2 sec. If block B remains at rest, then minimum value of co-efficient
of friction between block B and surface will be (g = 10 m/s2)

(A)

(B)

(C)

(D)

4) What minimum speed does a 100 g particle need at point B to reach point A ? The graph shows

potential energy versus position.

(A) m/s
(B) m/s
(C) 10 m/s
(D) 5 m/s

SECTION-I (ii)

1) A linear object AB is at a distance of 36 cm from an equi-convex lens of focal length 30cm. In front
of lens there is a plane mirror which is inclined at an angle 45° with the principal axis of the lens at
a distance ℓ = 100cm from the mirror as shown in figure. A container with water layer d = 20 cm is
placed as shown in the figure. Then choose the correct statement(s). Take the refractive index of

water as .
(A) After reflection from the mirror the image of AB will be parallel to principal axis of the lens.
After reflection from the mirror the image of AB will be perpendicular to principal axis of the
(B)
lens.
The value of H for which the sharp image of AB can be obtained at the bottom of the container
(C)
is 80 cm.
The value of H for which the sharp image of AB can be obtained at the bottom of the container
(D)
is 85 cm.

2) A particle of mass m is projected with a speed u at an angle θ with the horizontal. At any instant

angle subtended by particle from horizontal becomes . Then find out at this instant:

(A)
Radius of curvature

(B)
Magnitude of tangential acceleration

(C)
Magnitude of normal acceleration
Power of gravitational force =
(D)

3) A charged ball of charge +q1 is revolving around another charge +q as shown in a conical

pendulum. The motion is in a horizontal plane :-

(A) Tension in the string is greater than the weight of the ball
(B) The tension in the string is greater than the electrostatic repulsive force
(C) If the charge is removed, the speed of ball has to be increased to maintain the angle
(D) If the charge is removed, the speed of ball has to be decreased to maintain the angle

SECTION-I (iii)

1) A ray of light may undergo deviation in reflection or refraction. List-I contains different
phenomenas and list-II contains variation of angle of deviation with angle of incidence. Choose
correct combination.

List-I List-II
 (P) (1)

(Q) (2)

(R) (3)

(S) (4)

(5)

(A) P → 5;Q → 1;R → 3;S → 2

(B) P → 4;Q → 1;R → 3;S → 2
(C) P → 5;Q → 1;R → 2;S → 3
(D) P → 5;Q → 2;R → 1;S → 3

2) In list-I different configurations of object and spring are shown. In list-II corresponding time
periods (in second) of small oscillations are given.

List-I List-II
(P) (1)

mass m = 1kg, spring constant k = 5 N/m.

There is no friction between string & pulley.
String & pulley are massless. String is inextensible. There is no
friction between block and surface.

(Q) (2) 8π

A uniform disc of mass m can roll without slipping. C is the centre

of disc, m = 3kg, k = 10 N/m.

(R) (3)

mass m = 1kg, spring constant k = 1 N/m.

There is no friction between string & pulley. String & pulley are
massless. String is inextensible.

(S) (4) 2π

System is in vertical plane

L is the length of rod.

Mass of rod is m, spring constant k =

m = 1kg, k = 1N/m

None of
(5)
these
(A) P → 2;Q → 4;R → 1;S → 3
(B) P → 2;Q → 4;R → 3;S → 1
(C) P → 4;Q → 3;R → 2;S → 1
(D) P → 4;Q → 2;R → 1;S → 3
3) Acceleration versus x and potential energy versus x graph of a particle of mass 1kg moving along
x-axis are shown in figure. Assume that at x = 0, the velocity of the particle is 4ms–1, match the

following at x = 8m.

List-I List-II

(P) Kinetic energy (1) 12 J

(Q) Work done by conservative forces (2) 240 J

(R) Total work done (3) 20 J

(S) Work done by non-conservative forces (4) 112 J

(5) –228 J
(A) P → 1;Q → 2;R → 3;S → 5
(B) P → 4;Q → 5;R → 3;S → 1
(C) P → 3;Q → 2;R → 1;S → 5
(D) P → 3;Q → 2;R → 4;S → 5

SECTION-II

1) A rod AB of length L and mass m is uniformly charged with a charge Q, and it is suspended from
end A as shown in Fig. The rod can freely rotate about A in the plane of the figure. An electric field E
is suddenly switched on in the horizontal direction due to which the rod gets turned by a maximum

angle of 90o. Then magnitude of E is equal to Find the value of n.

2) A point charge q = 2C and mass m = 1 kg is released from rest in a uniform electric field E = 6
N/C. Find the momentum of the particle after 0.5 s in kg m/s.
3) Two masses 8kg and 4kg are suspended together by a masslesss spring of force constant 1000
N/m. When the masses are in equilibrium 8kg is removed without disturbing the system. The

amplitude of oscillation is : (in cm)

4) A positive charge +Q is fixed at a point A. Another positively charged particle of mass m and
charge +q is projected from a point B with velocity u as shown in the figure. The point B is at large
distance from A and at distance 'd' from the line AC. The point C is at very large distance from A.
Find the minimum distance (in meter) of +q from +Q during the motion. Take Qq = 4π∈0mu2 d and d

=( – 1) meter.

5) A point P moves in counter clockwise direction on a circular path as shown in the figure. The
movement of 'P' is such that it sweeps out a length s = t3 + 5, where s is in metres and t is in
seconds. The radius of the path is 20 m. The acceleration (in m/s2) of 'P' when t = 2s is nearly :-

6) The potential energy of a body is given by U = (40 + x2 + y2 + z2) J, where x, y, z in meter.

Calculate the magnitude of the conservative force (in N) associated with the potential energy when
the body is at position (1.0 m, 0.5 m, –1.0 m).

PART-3 : CHEMISTRY

SECTION-I (i)

1) At a certain temperature when some amount of glucose is dissolved in water, it is observed that
lowering in vapour pressure is 0.6 mm Hg for this solution. What will be the vapour pressure of

same glucose solution if its molality is mol kg–1 ?

(A) 200 mm Hg
(B) 300 mm Hg
(C) 600 mm Hg
(D) 720 mm Hg

2)
Correct choice according to above sequence reaction-

(A)

A= ,D=

(B)

A= ,B=

(C)

A= ,C=

(D)

A= ,D=

3) Stability of the species increases in the order of

(A)
(B)
(C)
(D)

4)

S can decolorise bromine water.

Incorrect statement regarding P, Q, R, S is/are

(A) R = CH3–OH
(B)
Q=
S=
(C)

(D) P can not be prepared by williamson ether synthesis

SECTION-I (ii)

1) 2.8 gm of N2 (g) was taken in a 4 L vessel. 40% of the molecules were dissociated into atoms when
temperature of the gas was raised to 1527°C. The correct option(s) is/are : [Given : R = 0.08 L-atm
mol–1 K–1]

(A) Total number of moles in container is 0.14

(B) Total number of molecules of nitrogen gas in container is 3.61 × 1022
(C) Total number of moles in container is 0.06
(D) Final pressure in the vessel is 5.04 atm

2) Which reaction is/are representing correct major product-

(A)

(B)

(C)
(D)

3)

For a homonuclear diatomic molecule, the correct statement(s) about the molecular orbitals formed
by the overlap of two 2pz orbitals is(are)

(A) σ bonding molecular orbital has a total of zero nodal planes.

(B) σ* orbital has a total of three nodal planes.
(C) π bonding molecular orbital has a total of one nodal plane.
(D) π* orbital has two nodal planes and both are perpendicular to each other.

SECTION-I (iii)

1) Match the List.

List-I List-II

(P) NaCl structure (1) Anion forming FCC and Cation in all octahedral voids

Anion forming FCC and cation in alternate tetrahedral

(Q) Zinc Blende structure (2)
voids

Cation forming FCC and anion in alternate

(R) Cesium chloride structure (3)
tetrahedral voids.

Anion forming simple cubic lattice & cation in cubical

(S) Flourite structure (4)
voids.

(5) Cation forming FCC & anion in all tetrahedral voids.

Which of the following option is correct match?
(A) P → 1;Q → 2;R → 4;S → 5
(B) P → 1;Q → 2;R → 3;S → 5
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 3;Q → 4;R → 2;S → 5

2) Match the list-

List-I List-II
(Reaction) (About reaction Mechanism)

(P) (1) Carbocation formation

 (Q) (2) Carbanion character formation

(R) (3) Rearrangement of carbocation

(S) (4) Single step reaction

Substitution product is
(5) favoured over elimination
product
(A) P → 4;Q → 2;R → 1;S → 3
(B) P → 1;Q → 3;R → 5;S → 2
(C) P → 2;Q → 3;R → 1;S → 4
(D) P → 5;Q → 4;R → 3;S → 2

3)

List-I List-II
(Pair of species) (Same characteristics in pair)
d-orbital participation in
(P) (NF3, OF2) (1) hybridisation of central atom
is observed
Tetrahedral electron
(Q) (PCl5, ICl3) (2)
geometry of central atom
Total number of lone pair
(R) (BeF2, SO3) (3)
equal
(S) (CO2, SO2) (4) pπ – pπ bond is present
Both molecules have same
(5)
hybridisation on central atom
(A) P → 1;Q → 4;R → 3, 5;S → 2
(B) P → 2, 5;Q → 1, 5;R → 3;S → 4
(C) P → 2;Q → 1;R → 4;S → 3
(D) P → 3;Q → 4;R → 1, 5;S → 2

SECTION-II

1) At constant pressure when temperature of a gas sample is increased from 200 K to 800 K its
collision frequency (Z11) becomes 'X' times of its initial value then find value of '12 X'?

2) At 300 K, the vapour pressure of an ideal solution containing 3 moles of liquid A and 2 moles of
liquid B is 600 torr. At the same temperature, if 1.5 mole of liquid A & 0.5 mole of solid solute C
(non-volatile) are added to this solution the vapour pressure of solution increases by 30 torr. What is
the value of in torr?
3) Normal boiling point of a liquid is 327 °C. Also, vapour pressure of this liquid at 27 °C is 190 mm
Hg. Find enthalpy of vaporisation of the liquid in Kcal / mol. Given (R = 2 cal/mol-K & ℓn2 = 0.7)

4)

Among the following total number of planar and polar molecules is / are
Cl2O , P(CH3)3 , N(CH3)3 , I2Cl6 , NO2 , NCl3

5) Find the number of pair(s) having wrong order of indicated property

(i) SF6 < TeF6 (tendency of hydrolysis)
(ii) H2 > He (boiling point)
(iii) BF3 < BCl3 (bond angle)
(iv) CaCO3 > BaCO3 (thermal stability)
(v) PbO < PbO2 (oxidizing property)

6) What is the total number of correct order as per given statement- (i)

(Rate of aqueous hydrolysis)

(ii)
(Rate of reaction with KCN/DMSO)

(iii)
(Rate of reaction with Anhydrous ZnCl2 + HCl)

(iv)
(Rate of reaction with Br2/CCl4)

(v)
(Rate of reaction with ethoxide in ethanol on heating)

(vi)
(Rate of reaction with H+/Δ)

(vii)
(Rate of reaction with HI)
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4
A. B A D C

SECTION-I (ii)

Q. 5 6 7
A. A,B,C A,C,D A,B,C

SECTION-I (iii)

Q. 8 9 10
A. B C A

SECTION-II

Q. 11 12 13 14 15 16
A. 4.50 4.00 1.00 2.25 5.00 0.00

PART-2 : PHYSICS

SECTION-I (i)

Q. 17 18 19 20
A. C D B C

SECTION-I (ii)

Q. 21 22 23
A. A,D A,B,C,D A,B,C

SECTION-I (iii)

Q. 24 25 26
A. C C C

SECTION-II

Q. 27 28 29 30 31 32
A. 1.00 6.00 8.00 1.00 13.95 to 14.02 3.00

PART-3 : CHEMISTRY
 SECTION-I (i)

Q. 33 34 35 36
A. C C B D

SECTION-I (ii)

Q. 37 38 39
A. A,B,D A,B,C,D B,C,D

SECTION-I (iii)

Q. 40 41 42
A. A A B

SECTION-II

Q. 43 44 45 46 47 48
A. 1.50 90.00 1.68 2.00 2.00 7.00
 SOLUTIONS

PART-1 : MATHEMATICS

1) For existence of limit

⇒a=1

Since it is continuous at x = 0

⇒ = 2 ⇒ b = ±5
⇒ Number of ordered pairs (a, b) = 2

2) F(x) = cot(cos–1(|sinx| + |cosx|) + sin–1(–|cosx| – |sinx|))

But |sinx| + |cosx| ∈ ∀x∈R

∴ (As F(x) = 0, ∀ x ∈ DF)

3)

For limit to exist

.....(i)

Put in (i)

⇒α=6
⇒ α = 6, β = 6, γ = –9
⇒α–β–γ=9

4) Sk =
Divide by 32r
Let

Sk =

5) Let (1∞ form)

Since and a + b + c = 15
⇒L≤5

6) g(n) =

= 13 + 23 + 33 + ... + n3

∴ g(n) =
7) (A) Period of f(x) = LCM
= LCM (4π, 6π, 4π, 5π, 12π, 14π)
= 420π

(B)
But g(x) ≥ 0 ∀ x ∈ R

= g(x) ∀ x ∈ R
(C) Given f(x) = , x ∈ [–1, ∞)
2
∵ f(–1) = e = f(1)
& x2 + |x| ≥ 0 ∀ x ∈ [–1, ∞)
⇒ Rf = [1, ∞)
∴ f(x) is many one into function
(D) f(x) = min (|x|, 1 – |x|)

⇒ f is even function

8) (P)
cosx + sinx = 1

;n∈Z

⇒ x = 2nπ ; x = 2nπ + ;n∈Z

⇒x∈ in given range has one solution

(Q)
 in given range has two solutions

(R)
cosx – sinx = –1

;n∈Z

⇒ x = 2nπ + or x = 2nπ – π ; n ∈ Z

⇒ four solutions in given range

(S)
2cos2x =

;n∈Z

;n∈Z

six solutions in given range

9) (P)
As x → ∞
L = D.N.E.

(Q)
As x → ∞
L = –3

(R)
As x → –∞
2x → 0

L=6
(S)
x → –∞

L=0

10) (P) 7cos2θ + 6sinθcosθ – sin2θ ∈ [–2, 8]

⇒ λ = 8, μ = –2

(Q) f(0) =

(R)

For limit to exist a2 – 1 = 0 ⇒ a = ±1

Let a = 1

Then

which is not possible

∴ a = 1 is rejected
Let a = –1

Then

So a + b = –1 + 6 = 5

(S) Only is the solution

= tan(tan–110π) = 10π
11)

12) When x is then

13)
14)

and

∴ Expression

15)

Similarly we can get

16) f(x) = f(x) = f(2)

For RHL =

RHL =

For LHL =
(∵ {–x} = {–(2 – h)} = {–2 + h})
 ⇒p=q=0
So p + q = 0

PART-2 : PHYSICS

17) ϕ =
= 3.00yj × (1.4)2
= 3 × 1.4 × (1.4)2
= 8.23 Nm2 / C

18) At B : sin i = n1sin r1 sin2 i = n12 sin2 r1 ...(i)

At C : n1 sin (90 – r1) = n2sin r2 n22 sin2 r2 = n12 cos2 r1 ...(ii)

At D : n2 sin (90–r2) = n3 sin r3 ⇒ n22 cos2 r2 = n32 sin2 r3 ...(iii)
At E : n3 sin (90 – r3) =(1) sin (90–1) ⇒ cos2 i = n32 cos2 r3 ...(iv)
Adding (i), (ii), (iii) and (iv) we get 1 + n22 = n12 + n32

19) Maximum tension in string =

20) To reach at point A particle must cross the peak point.

Loss in KE = gain in PE

v2 = 100
v = 10 m/s

21)

Correct Answer is (A,D)

22)

23)
T cos α = Mg

T sin α – Fe =

24)

Theoritical

25) (P) E =

E=

T=

T=

(Q) E =
T=

T=

T=

T=

(R)
2x1 + 2x2 + 2x3 + 2x4 = x

x1 = x2 = x3 = x4 =

a=

T=
=
= (2π)(4)
T = 8π

(S)

τ = 2kx L cos θ + kx cosθ – mg sinθ

x=
t=
θ → small

τ=

k=

τ=

a=

26) area under a-x graph = 12 ms–1

Work done by all the forces

Work done by conservative force

Work done by external force i.e. is given by

27)

from energy conservation

28)

p = mv = m at = Ft
p = q Et
 = 2 × 6 × 0.5
= 6 kg m/s

29)

30)
Li = Lf about O
mud = mvr
ui + ki = uf + kf

31)

Correct Answer is (13.95 to 14.02)

32)

PART-3 : CHEMISTRY

33)

Ps =
= 600 mm Hg
34) The correct answer is option (C)

35)

Bond order

Bond order

Bond order
Stability order is
(Molecule having more electron in ABMO with same bond order have less stability)

36) The correct answer is option (D)

37)

N2 → 2N
0.1 –
0.06 0.08
ntotal = 0.14 mol

38) The correct answer is option (A), (B), (C), (D)

39) Question Explanation:

For diatomic molecule, the correct statement(s) about the molecular orbitals formed by the
overlap of two 2pz orbitals is(are)

Concept:
This question is based on M.O.T.

Solution:
Final Answer: The correct option is (1), (2), (3) and (4).

40)

Theory based

41) The correct answer is option (A)

42) Question Explanation: Match pairs of species to their shared characteristics.

Concept: Molecular geometry, hybridization, and bonding.
Solution:
NF3 - sp3 ; OF2 - sp3
PCl5 - sp3d ; ICl3 - sp3d
BeF2 - sp ; SO3 - sp2
CO2 - sp ; SO2 - sp2
The matches are: P → 2, 5
Q → 1, 5
R→3
S→4

43) Z11 ∝
⇒X=

44)

600 =
= 3000

& 630 =
4.5
= 4410
1.5 = 1410 ; = 940 & = 90

45) T1 = 300 K T2 = 600 K

ΔH = 1.68 K cal/mol

46) NO2 , Cl2O

47) Explain question:

Find the number of pair(s) having wrong order of indicated property

Concept:
Properties of compound

Solution:
(i) SF6 is very inert, almost no hydrolysis TeF6 hydrolyses readily
(ii) BP : H2 > He
(iii) Bond Angle BF3 ≈ BCI3
(iv)CaCO3 < BaCO3 (thermal stability)
(v) PbO2 is strong oxidizing Agent (Pb+4)

Final Answer: Option (2)

48) The correct answer is 7.00