18-01-2026

6001CJA10102225015RT JA

PHYSICS

SECTION-I

1) A point mass m is connected to an ideal spring on a horizontal frictionless surface. The mass is
pulled a short distance and then released. Which of the following is the most correct plot of the
kinetic energy as a function of potential energy ?

(A)

(B)

(C)

(D)

2) The Kα X-ray emission line of tungsten occurs at The energy difference between K
and L levels in this atom is about :-

(A) 0.51 MeV

(B) 1.2 MeV
(C) 59 keV
(D) 136 eV

3) Moment of inertia of a uniform hollow hemi-sphere about given axis is IA & IB then:
(A) IA > IB
(B) IA = IB
(C) IA < IB
(D) Cann't be predicted

4) A current carrying wire in the form of 'V' alphabet is kept as shown in the figure. Magnetic field

intensity at point P which lies on the angular bisector of V is

(A)

(B)

(C)

(D)

5) In YDSE experiment with a white light with a plane wavefront,the light reaching the screen at
position y = 1mm (distance from central maxima on the screen) is passed through a prism and its
spectrum is obtained. Find the missing lines in the visible region of this spectrum. [Given D = 1m, d
= 0.9mm, where symbol has usual meanings]

(A) 600 nm
(B) 700 nm
(C) 750 nm
(D) 560 nm

6) A circular rope of weight 'W' and radius is resting on a smooth sphere of radius R. The
tension in the rope is

(A)

(B)

(C)

(D)

7) Two rods, one of aluminium and the other made of steel, having initial length are
connected together to form a single rod of length . The coefficients of linear expansion for
aluminium and steel are respectively. If the length of each rod increases by the same

amount when their temperature are raised by toC, then find the ratio .

(A)

(B)

(C)

(D)

8) A mercury barometer has a cylindrical capillary tube of radius inverted vertically on

the mercury in the trough. Atmospheric pressure is 76 cm of mercury but the level of mercury in the
capillary is 75cm. The portion of the tube without mercury is 10cm in length. Considering that this
region is occupied by ideal gasses, the number of moles of the ideal gas will be :
[Given : Density of mercury = 13.6 g/cc, surface tension of mercury = 0.5 N/m, temperature = 37°C,
g = 10 m/s2, universal gas constant = R, angle of contact of mercury on tube = 135°]

(A)

(B)
(C)

(D)

9) An ammeter and a voltmeter are initially connected in series to a battery of zero internal
resistance. When switch S1 is closed the reading of the voltmeter becomes half of the initial, whereas
the reading of the ammeter becomes double. If now switch S2 is also closed, then reading of

ammeter becomes :-

(A) 3/2 times the initial value

(B) 3/4 times the value after closing S1
(C) 3/4 times the initial value
(D) 3/2 times the value after closing S1

10) On a pulley of mass M hangs a rope with two masses m1 and m2 (m1 > m2) tied at the ends as
shown in the figure. The pulley rotates without any friction, whereas the friction between the rope
and the pulley is large enough to prevent any slipping. Which of the following plots best represents
the difference between the tensions in the rope on the two sides of the pulley as a function of the

mass of the pulley ?

(A)
(B)

(C)

(D)

11) A monochromatic light source of wavelength λ is placed at S. Three slits S1, S2 and S3 are
equidistant from the source S and the point P on the screen. Given that: S1P – S2P = λ/6 and S1P –
S3P = 2λ/3. If I be the intensity at P when only one slit is open, the intensity at P when all the three

slits are open is:

(A) 3 I
(B) 5 I
(C) 8 I
(D) Zero

12) Figure shows v/s s curve for a particle of mass 2 kg moving in a straight line. If the time (in
seconds) taken by the particle to achieve a displacement of 10 m from start is t. (v = velocity, s =

displacement), then find the value of (t – 20).

(A) 1 s
(B) 21 s
(C) 3 s
(D) 42 s

13) Parallel light rays are falling on the plane surface of semi cylindrical rod made of glass of
refractive index 2.0 at an angle of incident of 60° in such a plane which is perpendicular to the axis
of semi-cylinder as shown in figure. If ϕ is position where the rays are emerging out of cylindrical

surface after refraction then ϕ lies between : [Given sin–1 = 25º]

(A) 85° < ϕ < 145°

(B) 145° < ϕ < 180°
(C) 75° < ϕ < 105°
(D) 25° < ϕ < 90°

14) Liquid is completely filled in a vessel up to height H and a hole is made at a depth h below the
free surface of the liquid. Given that area of container is A and area of orifice is A0. Match the entries
of List-1 with the entries in List-2.

List-1 List-2

Proportional
(P) Velocity of efflux (1)
to

The range of liquid comming

Proportional
(Q) out of the orifice & filling on (2)
to A0
the ground

If the hole is at the bottom of Proportional

(R) the tank, time t taken to empty (3)
the tank is to

Horizontal thrust force on the

system (Liquid + Container) Proportional
(S) (4)
due to the liquid flowing out of to
container
(A) (P)→(1), (Q)→(3), (R)→(4), (S)→(2)
(B) (P)→(2), (Q)→(1), (R)→(4), (S)→(3)
(C) (P)→(3), (Q)→(1), (R)→(4), (S)→(2)
(D) (P)→(3), (Q)→(2), (R)→(4), (S)→(1)

15) A plane electromagnetic wave of wavelength λ has an intensity I. It is propagating along the
positive Y-direction. The allowed expressions for the electric and magnetic fields are given by :-
(A) ; =+

(B) ;

(C) ;

(D)
;

16) Two particles of mass m and 3m tied together with a very light string of mass density μ are
dropped from a high rise tower as shown. A constant air friction force F acts on both of them. If the

length of string is ℓ, the time taken by a pulse to go from bottom to top of string will be

(A)

(B)

(C)

(D)

17) A uniform conducting circular disc of mass m and radius a is hinged at centre. A resistance R is
connected between centre and circumference by a slider. A uniform magnetic field is applied
perpendicular to plane of disc. Now disc is given initial angular speed ω0, then initial angular

acceleration of disc is (neglect resistance of disc)

(A)

(B)

(C)

(D)

18) Charge is distributed throughout a sphere with the charge density given by ρ = ρ0 for r < a, ρ =
ρ0 (r – R)/(a – R) for a < r < R, and ρ = 0 for R < r. Choose the correct graph for the electric field as

a function of r. Use R = 3a.

(A)

(B)

(C)

(D)

19) For each electromagnet at the left of the drawing, find whether it will be attracted to or repelled
from the permanent magnet at the right.

The electromagnet in figure (a) will be attracted to the magnet but the electromagnet in figure
(A)
(b) will be repelled by the magnet.
The electromagnet in figure (b) will be attracted to the magnet but the electromagnet in figure
(B)
(a) will be repelled by the magnet.
(C) The electromagnet in figure (a) as well as (b) will be attracted to the magnet.
(D) The electromagnet in figure (a) as well as (b) will be repelled by the magnet.

20) A p-n junction diode operates in first and third quadrant as shown by dot in the graph below. The

diode can be:

(A) Photo diode

(B) Light emitting diode
(C) Rectifier
(D) Solar cell

SECTION-II

1) Two identical charged speres suspended from a common point by two massless strings of length I,
are initially at a distance d(d << I) apart because of their mutual repulsion. The charge begins to
leak from both the spheres at a constant rate. As a result, the spheres approach each other with a
velocity v. Then v varies as a function of the distance x between the spheres as then find
the value of n.

2) Two small rings each of mass 'm' are connected to a small block of same mass 'm' through
inextensible light strings. Rings are constrained to move along a smooth horizontal rod. Initially
system is held at rest (as shown in figure) with the strings just taut. Length of each string is ' '. The
system is released from the position shown. If the ratio of speed of the block (v) and speed of the
rings (u) when the strings make an angle of with vertical is Find n (Take g 10 m/s2)

3) In the circuit shown, the maximum energy stored in the capacitor is n μJ. The value of n is
_________.

4) In the figure shown switch S1 remains connected and switch S2 remains open for a long time. Now
S2 is also closed. Assuming ε = 10V and L = 1H. Find the magnitude of rate of change of current (in

A/s) in inductor just after the switch S2 is closed.

5) A non-conducting uniformly charged spherical shell is kept on a rough non-conducting horizontal

surface. Mass of shell is 2kg and charge on it is 4C and friction coefficient between surface and shell
is 0.18. Take g = 10m/s2. The minimum value of external uniform horizontal electric field so that
shell starts sliding on the surface is E0 in SI units. Mark 100 E0 in answer.

CHEMISTRY

SECTION-I

1) What will be the pH of 1% (w/w) aqueous solution of salt NaA ?

[Given: Ka(HA) = 10–6 , density of solution = 1.2 gm/ml, Molecular mass of HA = 98, Atomic mass of
Na = 23].

(A) 4.5
(B) 9
(C) 10.5
(D) 9.5

2) Consider following solutions in given solvents :

I : 0.3 M aqueous glucose solution
II : 0.2 M aqueous sodium chloride solution
III : 0.3 M aqueous ammonium phosphate solution
IV : 0.4 M benzoic acid in benzene (dimerises upto 50%)
Select incorrect statement from given options for the above given solutions :

(A) I and IV are isotonic solutions.

(B) III is hypertonic as compared with each of I, II and IV.
(C) IV is hypotonic as compared with each of I, II and III.
(D) II is hypotonic as compared with III but hypertonic as compared with I and IV.
3) Assertion : Although the shapes of 2s and 2p orbitals are different, an electron has the same
energy when it is in the 2s orbital as when it is present in 2p orbital for all single electron species.
Reason : The energy of an electron in a hydrogen atom is determined solely by the principal
quantum number.

(A) Assertion is false but Reason is true.

(B) Assertion is true but Reason is false.
(C) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(D) Both Assertion and Reason are true and Reason is NOT the correct explanation of Assertion.

4) The conductivity of saturated solution of Ba3(PO4)2 is 1.2 × 10–5 Ω–1 cm–1. The limiting equivalent
conductivities of BaCl2, K3PO4 and KCl are 160, 140 and 100 Ω–1 cm2 eq–1, respectively. The solubility
product of Ba3(PO4)2 is :

(A) 1 × 10–5
(B) 1.08 × 10–23
(C) 1.08 × 10–25
(D) 1.08 × 10–27

5) Which of the following statement is incorrect?

(A) Only oxidizing acids (nitric and hot concentrated sulphuric) react with Cu
(B) The high energy to transform Cu(s) to Cu2+(g) is balanced by its hydration enthalpy

(C) Both, the observed as well as calculated values for Cu are highest as compared to other
3d-series elements.
(D) Among all 3d series elements, only Zn has more 3rd IE value than 3rd IE of Cu

6) Which of the following actinoid elements contains no electron in "6d" subshell.

(A) Americium (Am = 95)

(B) Curium (Cm = 96)
(C) Lawrencium (Lr = 103)
(D) Protactinium (Pa = 91)

7)

X, Y and Z will be :

(A) CH2 = CH2 , CH3 – CH3, CH3CH2–I

(B) CH3–CH2–I, CH3 – CH3 , CH2 = CH2

(C)
CH3–CH2–I, , CH2 = CH2

(D)
CH3–CH2–I, CH2 = CH2,

8) Which of the following complex show stereo isomerism.

(I) [Ni(en)3]Cl2
(II) [CoCl2(en)2]Cl
(III) [NiCl2(Ph3P)2]
(IV) [Co(H2O)3F3]

(A) II & IV only

(B) I, II, III, & IV
(C) I, II & III only
(D) I, II & IV only

9) The compound A in the following reaction is :

(A)

(B)

(C)

(D)

10)

List - I (Compound) List - II (Test)

 (1) +ve Iodoform test
(P)

(2) +ve Isocynide test

(Q)

(3) +ve Liebermann nitroso test

(R)

(4) +ve Tollen's test

(S)
(A) P→1, Q→3, R→2, S→4
(B) P→4, Q→2, R→3, S→1
(C) P→1, Q→2, R→3, S→4
(D) P→4, Q→3, R→2, S→1

11) The reagents, NH4Cl and aqueous NH3 will precipitate :

(A) Ca2+
(B) Al3+
(C) Mg2+
(D) Zn2+

12) For a chemical reaction A + B → Product, the order is 1 with respect to A and B.

Rate [A] [B]

mol L–1 s–1 mol L–1 mol L–1

0.10 20 0.5

0.40 x 0.5

0.80 40 y
What is the value of x and y ?
(A) 80 and 2
(B) 40 and 4
(C) 160 and 4
(D) 80 and 4
13) Major product X ; Product X is :

(A)

(B)

(C)

(D)

14) What is the decreasing order of rate of reaction with HBr for the following benzyl alcohol and its
derivative:

(A) A > C > D > B

(B) A > C > B > D
(C) D > C > B > A
(D) A > B > C > D

15) Consider the following reactions :

(I) O–(g) + e– → O2–(g) , ΔH1
(II) F(g) + e– → F–(g) , ΔH2
(III) Cl(g) + e– → Cl–(g) , ΔH3
(IV) O(g) + e– → O–(g) , ΔH4
Select the INCORRECT statements

(A) ΔH4 is less negative than ΔH2

(B) ΔH3 is more negative than ΔH2 and ΔH4
(C) ΔH3 and ΔH4 are negative whereas ΔH1 and ΔH2 are positive
(D) ΔH2 , ΔH3 and ΔH4 are negative whereas ΔH1 is positive

16) Statement-1 : Work done (W) by the system during isobaric reversible and irreversible
processes from same initial state to same final state is equal.
Statement-2 : As the pressure is constant so W = –P(ΔV) for both the processes.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
 Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation
(B)
for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

17) A(g) ⇌ B(g) + C(g)

If initially A(g) is taken at 12 atm pressure in a rigid vessel at constant temperature then total
pressure at equilibrium will be ?
(Given : ΔG°f [A(g)] = 150 kJ/mole, ΔG°f [B(g)] = 60 kJ/mole, ΔG°f [C(g)] = 90 kJ/mole)

(A) 12 atm
(B) 15 atm
(C) 18 atm
(D) 9 atm

18) Select the correct statement(s).

3– 3+ 3–
(A) Stability order of complexes is [Cr(ox)3] < [Cr(H2O)6] < [CrF6]
The octahedral complex formed by joining the CN– ligands to Fe+3 ion has theoretical value of
(B)
spin magnetic moment equal to 1.73 B.M.
(C) In CuSO4.5H2O both Cu–O and Cu–S coordinate bonds are present
2+ 2+
(D) Stability of complex is : [Ni(NH3)6] > [Ni(en)3]

19) For the given compound , the nucleophilic substitution by C2H5OH occurs by

(A) SN1 mechanism

(B) SN2 mechanism
(C) SN1 & SN2 both
(D) No reaction will occur

20) Which of the ester shown, after reduction with LiAlH4 and aqueous work up, will yield two
molecules of only a single alcohol ?

(A) CH3CH2CO2CHCH3
(B) C6H5CO2C6H5
(C) C6H5–CO2–CH2C6H5
(D) HCO2C2H5

SECTION-II

1) How many reaction correctly matched with their major product :

(i)

(ii)

(iii)

(iv) CH3–CHO CH3–CH=CH–CHO

(v)

(vi)

(vii)

(viii) Cl3C–CHO Cl3C–CH2OH + Cl3C–COONa

2) Identify total number of compounds which are soluble in aq-NaOH and aq-NaHCO3 both :

, , , , , HCl, , ,

3) If 5 moles of BaCl2 is mixed with 2 moles of Na3PO4, the maximum number of moles of Ba3(PO4)2
formed is………….(Nearest integer)

4)
For the above balanced reaction, value of (a + b) is

5) Find the number of species which are diamagnetic and having fractional bond order.
N2 , C2 , , CN– , , F2 , NO⊕

MATHEMATICS

SECTION-I

1)

If , then is equal to -

(A)

(B)

(C)

(D)

2) If y = ƒ(x) is the solution of the differential equation x2dy + xydx = dx such that then

equals to

(A) e–1

(B)

(C)

(D)

3)
 If three letters can be posted to any one of the 5 different addresses, then the Probability that the
three letters are posted to exactly two addresses is………

(A)

(B)

(C)

(D)

4) The total number of positive integral solutions (x, y, z) such that xyz = 24 is :

(A) 36
(B) 24
(C) 45
(D) 30

5) Let z be a complex number such that then maximum value of |z| equals

(A)

(B)

(C)

(D)

6) is equal to -

(A)

(B)

(C) 2

(D)

7) The coefficient of x53 in the expansion of , is

100
(A) C47
100
(B) C53
 100
(C) – C53
100
(D) – C57

8) If α and β are the roots of equation x2 – 5x – 3 = 0 and An = αn + βn, also An+2 + µAn+1 + νAn = 0, (n
∈ N) then (µ + ν) is equal to-

(A) 0
(B) 1
(C) 8
(D) –8

9) The distance of the point having position vector from the straight line passing through
the point (2, 3, –4) and parallel to the vector, is :

(A) 7
(B)
(C)
(D) 6

10)

If A = , then value of Tr is equal to

(here adj(X) denotes adjoint of matrix X and Tr(X) denotes trace of matrix X)

(A) 2
(B) 1

(C)

(D)

11) The average marks of 10 students in a class was 60 with a standard deviation 4, while the
average marks of other ten students was 40 with a standard deviation 6. If all the 20 students are
taken together, their standard deviation will be approximately

(A) 5
(B) 7.5
(C) 9.8
(D) 11.2

12) Given quadratic equation mx2 + (2m – 1)x + m – 1 = 0 has real roots of opposite sign, then range
of 'm' is -

(A) m ∈ ϕ
(B) m ∈ R
(C) –1 < m < 0
(D) 0 < m < 1

13) If , then -

(A) I1 > 1, I2 > ℓn2

(B) I1 < 1, I2 > ℓn2
(C) I1 < 1, I2 < ℓn2
(D) I1 > 1, I2 < ℓn2

14) A point at a distance of from the origin which lies on the straight
line will be

(A) (1, -1, 2)

(B) (1, 2, -1)

(C)

(D)

15) If the equation of the parabola, whose vertex is at (5, 4) and the directrix is 3x + y – 29 = 0, is x2
+ ay2 + bxy + cx + dy + k = 0, then a + b + c + d + k is equal to

(A) 575
(B) –575
(C) 576
(D) –576

16) A light ray emits from the origin making an angle 30° with the positive x-axis. After getting
reflected by the line x + y = 1, if this ray intersects x-axis at Q, then the abscissa of Q is

(A)

(B)

(C)

(D)

17) A circle C1 passes through the origin O and has diameter 4 on the positive x-axis. The line y = 2x
gives a chord OA of a circle C1 . Let C2 be the circle with OA as a diameter. If the tangent to C2 at the
point A meets the x-axis at P and y-axis at Q, then QA : AP is equal to
(A) 1 : 4
(B) 1 : 5
(C) 2 : 5
(D) 1 : 3

18) Let C be the centre of the circle and P be a point on the circle. A line

passes through the point C, makes an angle of with the line CP and intersects the circle at the
points Q and R. Then the area of the triangle PQR (in unit2) is

(A) 2
(B)

(C)

(D)

19) If the ellipse meets the line on the x-axis and the line on
the y-axis, then the eccentricity of the ellipse is

(A)

(B)

(C)

(D)

20) Let the foci of the ellipse and the hyperbola coincide. Then the length
of the latus rectum of the hyperbola is

(A)

(B)

(C)

(D)

SECTION-II

1) Let R be a relation from A = {2,3,4,5} to B = {3,6,7,10} defined by R = {(a,b) | a divides b, a ∈ A,

b ∈ B}, then number of elements in R–1 will be-
2) If x, y & z are different even integers and minimum value of

is N, then is

3) Given 2x – y + 2z = 1; x – 2y + z = –4; & x + y + λz = 4. Then the value of λ such that the given
system of equation has no solution is

4) If for non-zero x, , then where a, b, c are co-prime

then the value of (a + b + c).

5) Let z1, z2, z3 be complex numbers such that z12 + z22 + z32 = z1z2 + z2z3 + z3z1 and | z1 + z2 + z3| =
21. Given that |z1 – z2| = 2 , |z1| = 3 . Then |z2|2 + |z3|2 is
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D C B D A C C A D C A A A C A B A B D C

SECTION-II

Q. 21 22 23 24 25
A. 2 3 75 10 225

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D C C B B A B D C D B A C D C A B B D C

SECTION-II

Q. 46 47 48 49 50
A. 6 6 1 7 0

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B C B D A C C D A B D D B B D B A B A D

SECTION-II

Q. 71 72 73 74 75
A. 5 8 1 12 132
 SOLUTIONS

PHYSICS

1) KE =

PE =

∴ KE =

2)

ΔE =
= 59 × 103 eV = 59 keV

3)

IA = IB = ICM + M

4)

5) Question Explanation : The missing wavelength from the white light would be that
wavelength which interfere destructively at that particular point.
Concept :
This question is based on YDSE

Solution :
Condition for missing lines

Hence,
Option (1) is correct

6)

7) Given,
Or

Or

8)
Let the pressure at the top of mercury be P

P = 76 cm of Hg – 75 cm of Hg
= 860 N/m2

No of moles of gas

9) Let rA & rV are resistance of ammeter & voltmeter when both switches are open.

voltmeter reading

When S1 is closed.

....(i)
Voltmeter reading g

.....(ii)
When S2 is closed.

Solving (i) + (ii)

10)
m1g – T1 =(m1)(a)
T2 – m2g = (m2) (a)

(T1 –T2) = (I)

(m1 – m2)g = (m1 + m2 + )a

a=

(T1 – T2) = =

(T1 – T2) =

⇒ (T1 – T2) =
M = 0 ⇒ (T1 – T2) = 0; and M → ∞, T1 – T2 = (m1 – m2)g

11)

12) = = 2t = 8 × 4 + × 10 × 2
t = 21 s
t – 20 = 1 s

13) Rays left of O sin 60º = sin r × 2

∴ r = sin–1 = 25º
ϕ = 180 – [90 – r + θc]

Where θc = = 30º
ϕ = 180º – [90º – 25º + 30º] = 85º

Rays right of O 180º – ϕ + 90º + r + θc = 180º

–ϕ + 90º + 25º + 30º = 0
ϕ = 145º
85º < ϕ < 145º will be ans
85º < ϕ < 145º

14) Velocity of efflux =

Range = =

Time to empty container =

0
15) If E is magnitude of electric field then

direction of will be along + .

16) 4 mg – 2F = 4 ma
3 mg – F – T = 3 ma
T = 3 mg – F – 3ma

= 3 mg – F –3m

= 3 mg – F – 3 mg + =

v= =

t= =

17) Initially emf induced between center and periphery is

Current through resistor is i =

(∵ i1 + i2 + ………..= i)
18)
For a to R

Emax at

19)

The electromagnet in figure (a) as well as (b) will be repelled by the magnet.

20)

21) The correction option is C

The electrostatic force of repulsion between spheres is given as,

Applying the equilibrium condition on the sphere, T sin θ = F ...(1)
T cos θ = mg ...(2)

Or, tan θ =
When the charge starts to leak, the separation between spheres changes.
Let it be 'x' at some point of time

Therefore, ....(3)
From ΔABC I >> d hence I >> x

From Eq. (3) and (4),

.....(5)

Differentiating equation (5),

Since the charged spheres are approaching each other with speed v, the velocity of approach will
be

That means the separation between them is reducing at a rate of 2v

Substituting it we get,

Given that charge leaks at a constant rate, = constant = C

Substituting we get,

22)

(2) COE:

23) I1 =

I2 =

VA –VC = 3I1 = 3V ....(1)

VA – VD = 2 × 4 = 8V ....(2)
 Subtracting eq. (1) from eq. (2)
VC – VD = 5V ⇒ V = 5V

U = CV2 = × 6 × 52 = 75 μJ

24)
i1 + i2 = ε/R
VB = X

⇒X=–ε
Using kvℓ

= – 10 A/s

25)
F – f = ma

f .R = ⋅α

= ⋅

⇒ f= ma

∴ F = qE = f + ma = f≤ μmg

∴ E≤ . = 2.25

CHEMISTRY

26)

Let 100 gm solution

= 0.1 M NaA
As pH = 7 + pKa + log C

=7+ ×6+ log 0.1 = 9.5

27)

For Glucose (i1C1) = 1 × 0.3 = 0.3

For NaCl (i2C2) = 2 × 0.2 = 0.4
For Na3PO4 (i3C3) = 4 × 0.3 = 1.2

For Benzoic acid (i4C4) = = 0.3

28)

Both Assertion and Reason are true and Reason is the correct explanation of Assertion.

29) , Ba3(PO4)2 = 160 + 140 – 100 = 200 S cm2 eq–1

, Ba3(PO4)2 = 6 × 200 = 1200 S cm2 min–1

Ksp = (3s)3 × (2s)2 = 1.08 × 10–23.

30)

The high energy to transform Cu(s) to Cu2+(g) is balanced by its hydration enthalpy

31)

32)

33)

I, II & IV only

34)

35)
P→4, Q→3, R→2, S→1

36) The KSP of Al(OH)3 is low as compared to that of the hydroxides of other metals. The OH–
concentration provided by ammonium hydroxide in presence of NH4Cl is just sufficient to
precipitate Al3+ as Al(OH)3.
Al3+ + NH3 + H2O Al(OH)3↓ (gelatinous white) + NH4+ .

37) r = K[A]1[B]1
0.1 = K(20)1 (0.5)1 …(i)
0.40 = K(x)1 (0.5)1 …(ii)
0.80 = K(40)1 (y)1 …(iii)
From (i) and (ii)
x = 80
From (i) and (iii)
y=2

38)

39) Rate of reaction ∝ stability of carbocation formed

Electron donating group increases and electron withdrawing group deceases the stability of
carbocation hence order of stability

40)

41) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
statement-1.

42) ΔG°reaction = –RT ln Kp = ΔG°f B + ΔG°f C – ΔG°f A

= 60 + 90 – 150 = 0
So KP = 1
A(g) ⇌ B(g) + C(g)
t=0 12
t = t 12–p p p
 solving p = 3
So ptotal = 12 + p = 15 atm.

43)

44) In the given compound, SN2 reaction does not occur due to impossibility of attack of
nucleophile from rear side while SN1 reaction is also not possible because the carbocation
formed after ionization is not stable as the bridge head carbon having one carbon bridge
cannot be sp2 hybridized.

45) Lithium aluminium hydride reduces an ester (RCOOR’) to a mixture of two alcohols i.e.,
RCH2OH and R'OH. In the given problem both the alcohols are same. Therefore, the ester

must be of the type RCOOCH2R.

46)

47)

48)

3BaCl2 + 2Na3PO4 → Ba3 (PO4)2 + 6NaCl

5 2
Na3PO4 is limiting reagent.
2 mole Na3PO4 gives 1 mole of Ba3(PO4)2
Ans: 1

49)

50)

MATHEMATICS
51)

simillarly

⇒ (ƒoƒoƒo....oƒ)(x)

52) x2dy + xydx = dx

xy = ℓnx + c

Put x = e,
c=0

53)

We have 3 letters and 5 addresses ,where 3 letters are posted to exactly 2 addresses.
First ,we will select 2 addresses in ways.
Now ,3 letters can be posted to exactly 2 addresses in 6 ways.

Probability .

54) xyz = 23 × 31
Let

Now α1 + α2 + α3 = 3.
No. of non-negative intergal sol = 5C2 = 10
& β1 + β2 + β3 = 1
No. of non-negative intergal soln = 3C2 = 3
Total ways = 10 × 3 = 30.

55) ⇒

|z|max =
56) _____

, .

= ( By L’Hospital Rule)

= = 2.

57)

The above is the general term of

Hence re-writing the general term we get

Now the term consisting of is

58)

∵ An+2 = αn+2 + βn+2

= (αn+1 + βn+1)(α + β) – (αn+1β + βn+1α)
⇒ An+2 = (α + β)(αn+1 + βn+1) – αβ(αn + βn)
An+2 = [Link]+1 + 3An
⇒ An+2 – [Link]+1 – 3An = 0
⇒ µ + ν = –5 – 3 = –8

59) Any point on the line will be

p(2 + 6λ, 3 + 3λ, –4 – 4λ) Q(–1, 2, 6)
d.r. of PQ is (3 + 6λ, 1 + 3λ, –10 – 4λ)
6(3 + 6λ) + 3(1 + 3λ) – 4(–10 – 4λ) = 0
λ = –1
⇒ point P is (–4, 0, 0)
Distance =

60)

(AadjA)A= |A|IA = 2A

∴ [(AadjA)A]–1A = (2A)–1A =

∴
61) n1 = 10, n2 = 10
average m1 = 60, m2 = 40
σ1 = 4, σ2 = 6
Standard deviation of combined series

62)

Required condition is
m.ƒ(0) < 0, where ƒ(x) = mx2 + (2m–1)x + m–1
⇒ m(m – 1) < 0 ⇒ 0 < m < 1

63) ∵ ln(x + 1) < x

⇒ ⇒ I1 < 1

Now x + 1 < ex ⇒ ⇒ I2 > ℓn2

64)

Any Point P on the line given line is of the form . If O is the origin and
we have

If t = 0 then .

If then

65) Vertex (5, 4)

Directrix : 3 x+ y – 29 = 0
Co-ordinates of B (foot of directrix)
x=8,y=5
S = (2, 3) (focus)
Equation of parabola
PS = PM
So, equation is

66) Slope of reflected ray = tan 60° =

Line intersect at
Equation of reflected ray is

Put

67)

C2 is a circle with OA as diameter

So, tangent at A on C2 is perpendicular to OR
Let OA = ℓ
68)
QR = 2r = 4

Area of

69) meets the line on the x-axis

So, a = 7

and meets the line on the y-axis.

So,

Therefore,
70)

71) R = {(2,6), (2,10), (3,3), (3,6),(5,10)}

∴ 5 elements in R–1

72) Given determinant is

= (x – y)2(y – z)2(z – x)2

minimum value is 256
(take x = 2, y = 0, z = –2)

73)
⇒λ=1

74) ....(1)
replace x → to get

....(2)
Solving (1) and (2) we get

Hence a = 3, b = 7, c = 2
∴ (a + b + c) = 12

75) The vertices z1, z2, z3 form an equilateral triangle.

Now take,
|z1 – z3|2 + |z1 – z2|2 + |z2 – z3|2 = 2 (|z1|2 + |z2|2 + |z3|2) – 2Re ....(i)
Again
|z1 + z2 + z3|2 = 441
⇒ |z1|2 + |z2|2 + |z3|2 + 2Re ....(ii)
From (i) & (ii)