ASSIGNMENT-9 ATOMIC STRUCTURE
General Introduction :
1. Isotones are :
(A) The atoms of different elements
(B) Have same number of neutrons
(C) Have same number of (neutrons + protons)
(D) Have same difference of mass number and atomic number
Quantum number
2. For an electron present in which of the following orbital for which (n + l) value is maximum.
(A) 3p (B) 5p (C) 4d (D) 5s
3. Correct set of four quantum numbers for valence electron of rubidium( Z = 37) is
1 1 1 1
(A) 5, 0, 0, + (B) 5, 0, 0, – (C) 5, 1, 1, + (D) 6, 0, 0, +
2 2 2 2
4. The correct set of quantum numbers for the unpaired electron of chlorine atom is
n l m n l m
(A) 2 1 0 (B) 2 1 1
(C) 3 1 1 (D) 3 1 0
5. Which of the following sets of quantum numbers represent an impossible arrangement ?
n l m ms n l m ms
1 1
(A) 3 3 –2 (B) 4 0 0
2 2
1 1
(C) 3 2 –3 (D) 5 3 0
2 2
6. The quantum numbers for the 19th electron of Cr (Z = 24) are
(A) n = 3, l = 0, m = 0, ms = + ½ (B) n = 4, l = 0, m = 0, ms = + ½
(C) n = 3, l = 2, m = 2, ms = + ½ (D) n = 4, l = 0, m = 0, ms = – ½
7. The maximum number of electron having n × l × m = 0 in Zn2+ is equal to the -
(A) Atomic number of Mg
(B) 12
(C) Total number of electron in Zn which have n + l = 0
(D) 'p' electrons in Ar
Electronic Configuration
8. The species which have same number of electrons in outer most and penultimate shell -
(A) Ca (B) Ar (C) V+3 (D) Sc3+
9. Which sub-shell fill completely before the 4f?
(A) 6s (B) 5p (C) 5d (D) 4d
10. The electronic configuration of a carbon atom is 1s2, 2s2, 2p2 and consider the following four
arrangements of the 2p electrons. Which arrangement have lowest energy ?
(A) (B) (C) (D)
11. Hund’s rule is applicable for :-
(A) d-subshell (B) p-subshell (C) s-subshell (D) f-subshell
12. Which of the following has maximum number of unpaired electron.
(A) Fe (B) Fe (II) (C) Fe (III) (D) Mn (II)
13. Mn (Z = 25) = 1s3 1p9 2s3 2p9 2d1
Which of the following change is required so that Mn have above ground state electronic configuration :
(A) Change in the value of l (azimuthal quantum number) for any subshell
(B) Change in the possible values of l (azimuthal quantum number)
(C) Change in the Pauli rule
(D) Change in the (n + l) rule
14. The number of d- electrons in Mn2+ is equal to that of
(A) p-electrons in N (B) s-electron in Na
(C) d-electrons in Fe+3 (D) p-electrons in O–2
15. Select incorrect statement(s) :
(A) d z2 orbital has different shape from rest of all d-orbitals
(B) For the formation of cation electrons are always removed from 4s.
(C) Zinc is a p-block element.
(D) Principal quantum number depend upon the value of azimuthal quantum number
ANSEWR KEY
Que. 1 2 3 4 5 6 7 8 9 10
Ans. A, B, D B, C A, B C, D A, C B, D A, B, D B, D A, B, D C, D
Que. 11 12 13 14 15
Ans. A, B, D C, D B, C, D B, C B, C, D