20/03/2026 A

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MM : 695 Solution_12th_Topicwise Question Time : 100 Min.

Introduction & Concentration Terms

1. Among the following, choose the one which is not a 9.

colligative property.
(A) Elevation in boiling point
(B) Osmotic pressure Molality of 28% urea by mass is nearly
(C) Depression in freezing point (A) 2.2 m (B) 6.5 m
(D) Vapour pressure of pure liquid (C) 9.2 m (D) 8.4 m
2. A : When ethanol is added to water, boiling point of water 10. The mass of urea required in making 4 kg of 0.4 molal
increases. aqueous solution is
R : When a volatile solute is added to a volatile solvent, (A) 96 g (B) 93.75 g
elevation in boiling point is observed. (C) 90 g (D) 100 g
(A) Both Assertion & Reason are true and the reason is 11. The concentration term which is independent of
the correct explanation of the assertion temperature, is
(B) Both Assertion & Reason are true but the reason is (A) Molality (B) Molarity
not the correct explanation of the assertion (C) (
w
)% (D) (
V
)%
(C) Assertion is true statement but Reason is false V V

(D) Both Assertion and Reason are false statements 12. If the density of H2SO4 solution is 1.84 gm/cc and
3. A : For 0.1 molal aq. NaCl and 0.1 molal aq. benzoic acid contains solute 49% by mass, then the molarity of H2SO4
solution the ebullioscopic constant is different. solution is
R : Ebullioscopic constant depends on the nature of (A) 18.4 (B) 10.8
solute. (C) 9.2 (D) 4.9
(A) Both Assertion & Reason are true and the reason is
13. The temperature independent concentration term is
the correct explanation of the assertion
(A) Molarity (B) Mole fraction
(B) Both Assertion & Reason are true but the reason is
(C) Normality (D) % (w/v)
not the correct explanation of the assertion
14. Mole fraction of carbon in diamond is
(C) Assertion is true statement but Reason is false
(A) 0.5 (B) 1
(D) Both Assertion and Reason are false statements
(C) 0.25 (D) 0.34
4. The temperature independent concentration term is
15. Molality of aqueous solution having mole fraction of solute
(A) Molarity (B) Mole fraction
equal to 0.1 is
(C) Normality (D) %(w/v)
(A) 5.55 m (B) 6.17 m
5. Which of the following relation holds true for solution
(C) 2.78 m (D) 3.08 m
showing negative deviation from Raoult's law?
16. A solution containing 18 g/dm3 of glucose is isotonic with
(A) ΔHmix > 0 (B) ΔVmix > 0
(C) ΔS > 0 5% ( ) solution of a nonvolatile, nonelectrolytic solute.
w

(D) PA > PAo XA v

The molar mass of the solute is

6. When two solutions of concentration C1 and C2 (C1 > C2)
(A) 250 g mol–1 (B) 150 g mol–1
are separated by semipermeable membrane then
(A) Flow of solvent molecules occurs from C2 to C1 only (C) 400 g mol–1 (D) 500 g mol–1
(B) Flow of solvent molecules occurs from C1 to C2 only 17. Benzene and toluene form an ideal solution at room
temperature. For this process, the incorrect statement is
(C) Flow of solvent molecules occurs from C1 to C2 and
(A) ΔVmix = 0 (B) ΔSsystem = (+)ve
C2 to C1 also
(C) ΔHmix = 0 (D) ΔGmix = (+)ve
(D) Flow of solute molecules occurs from C1 to C2
18. A : The osmotic pressure of a solution is the excess
7. For the electrochemical cell pressure that must be applied to a solution to prevent
M|M2+||X|X2– , E ∘
= +0.76 V,
2
E∘ 2
= 0.33 V. osmosis.
M /M X/X
R : For dilute solution osmotic pressure is proportional to
From this data we can deduce that
molarity.
(A) Ecell = 0.43 V
(A) Both Assertion and Reason are true and the reason is
(B) M++ + X– – →M + X is a spontaneous reaction the correct explanation of the assertion
(B) Both Assertion and Reason are true but the reason is
(C) M + X → M++ + X– – is a spontaneous reaction
not the correct explanation of the assertion
(D) E = +0.43 V
∞

cell (C) Assertion is true statement but Reason is false

8. The mole fraction of urea in its 0.1 molal aqueous solution (D) Both Assertion and Reason are false statements
is approximately
(A) 1

655.5
(B) 1

596.5

(C) 1

556.5
(D) 1

535.5

1
Solution_12th_Topicwise Question

19. A : The solutions which show large negative deviation from 22. 0.5 M AgNO3 and 1 M KI are mixed in 1 : 3 volume ratio.
Raoult's law form minimum boiling azeotrope. The depression of freezing point of the resulting solution
R : The solutions which show large positive deviation from
will be [Kf(H2O) = 1.86 K kg mol–1] (Assume dilute
Raoult's law form maximum boiling azeotrope.
(A) Both Assertion and Reason are true and the reason is solution)
the correct explanation of the assertion (A) 0.279 K (B) 27.9 K
(B) Both Assertion and Reason are true but the reason is (C) 0.0279 K (D) 2.79 K
not the correct explanation of the assertion 23. If two liquids A and B are completely immiscible with each
(C) Assertion is true statement but Reason is false other at constant temperature and pressure are present in
(D) Both Assertion and Reason are false statements a closed vessel having PÅ= 125 torr and P = 275 torr.
∘ 0
B

20. The total vapour pressure of a binary solution is given by P

The total vapour pressure of the system will be
= (120XA + 250XB) mm Hg where XA and XB are the
(A) Between 125 to 275 (B) Greater than 275 torr
mole fraction of components A and B in solution torr
respectively. This indicates that the (C) Less than 125 torr (D) 400 torr
(A) Vapour pressure of solution is less than that of pure
24. In benzene solvent 50% of acetic acid dimerises while rest
component A
ionises. The value of van't Hoff factor i is
(B) Vapour pressure of solution is more than that of pure
(A) 1.5 (B) 1.75
component B
(C) 2.5 (D) 1.25
(C) Vapour pressure of pure A and B are 250 mm Hg and
120 mm Hg respectively 25. The mass percentage of an element M is 53 in its oxide of
(D) Vapour pressure of pure A is 120 mm Hg and that of molecular formula M2O3. The atomic mass of M is
pure B is 250 mm Hg (A) 45 (B) 27
21. The freezing point of an aqueous solution (in °C) having (C) 18 (D) 36
6% urea and 18% glucose by weight is (Given, Kf water =
1.86 K kg mole–1)
(A) –4.89 (B) –3.51
(C) –2.44 (D) –1.22

Abnormality in Mass & Solubility

26. 0.3 molal aqueous solution of a salt AX2 is 40% ionized. If 34. If 'i' is the van't Hoff factor and 'α' is degree of dissociation
Kb for water is 0.52 K kg mol–1 then the boiling point of of weak electrolyte AxBy, then relation between 'α' and 'i'
the solution will be is
(A) α = (B) α =
i−1 i−1
(A) 100.28°C (B) 101.42°C (x+y) (x+y−1)

(C) 100.61°C (D) 101.81°C

27. The Van't Hoff factor (i) for a dilute aqueous solution of the (C) α =
1−i

(x+y−1)
(D) α =
i−1

(x+y+1)

strong electrolyte Na3AlF6 is 35. The degree of association of an electrolyte is α and its
(A) 10 (B) 5 van’t Hoff factor is i. The number of solute particles
(C) 4 (D) 3 combine to form one molecule in associated form will be
28. The van’t Hoff factor (i) for infinitely dilute aqueous solution (A) i – α – 1 (B) α

i−1+α

of Al2(SO4)3 is
(C) i−1+α
(D) α

(A) 2 (B) 3 α i−α

(C) 4 (D) 5 36. A 0.2 molal aqueous solution of electrolyte AB2 freezes at
29. The van’t Hoff factor (i) for a dilute solution of strong –0.88°C. If Kf for H2O is 1.86 K kg mol–1 then degree of
electrolyte K [Fe (CN) ]
4 6
dissociation of AB2 is
(A) 1 (B) 2
(A) 0.52 (B) 0.68
(C) 4 (D) 5
(C) 0.76 (D) 0.84
30. If 0.1 m aqueous solution of calcium phosphate is 80%
37. van’t Hoff factor for Na2SO4 solution having 60%
dissociated then the freezing point of the solution will be
dissociation is
(Kf of water = 1.86 K kg mol–1) (A) 3 (B) 2.2
(A) –0.78°C (B) –1.25°C (C) 1.8 (D) 2.5
(C) –1.75°C (D) –2.5°C 38. The ratio of van't Hoff factor of acetic acid in water at
31. Value of van’t Hoff factor i, for a weak binary electrolyte infinite dilution and in benzene can be
having 40% dissociation is (A) 1 : 2 (B) 4 : 1
(A) 0.8 (B) 0.6 (C) 2 : 3 (D) 1 : 1
(C) 1.4 (D) 2 39. Ratio of a particular colligative property measure for 0.1 M
32. If degree of dissociation of CH3COOH is 0.2 then its KCl, 0.1 M CaCl2 and 0.1 M K4[Fe(CN)6] will be
abnormal molar mass is (A) 1 : 1 : 1 (B) 2 : 3 : 5
(A) 30 g mol–1 (B) 48 g mol–1 (C) 1 : 2 : 3 (D) 2 : 3 : 11
40. When CO2 (g) is dissolved in water, heat is liberated. The
(C) 50 g mol–1 (D) 72 g mol–1
33. van't Hoff factor of 0.1 M aqueous solution of Al2(SO4)3 solubility of CO2 (g) will increase at
which undergoes 80% dissociation is (A) High pressure, low temperature
(A) 3.6 (B) 3.2 (B) Low pressure, low temperature
(C) 4.2 (D) 4.8 (C) Low pressure, high temperature
(D) High pressure, high temperature

2
Solution_12th_Topicwise Question

41. If the Henry's law constant for the solubility of O2 gas in 51. 0.1 molal aqueous solution of aluminium sulphate is 50%
dissociated. The van’t Hoff factor of aluminium sulphate
water at 25°C is 5.0 × 106 atm. The mole fraction of O2 in
will be
air is 0.2. The number of moles of O2 from air dissolved in (A) 4.5 (B) 5
10 moles of water at 25°C and 4 atm pressure is (C) 3 (D) 2.5
(A) 1.6 × 10–6 (B) 2.4 × 10–5 52. Highest freezing point will be observed for which aqueous
solution?
(C) 5.2 × 10–3 (D) 3.2 × 10–4 (A) 0.1 M K4[Fe(CN)6] (B) 0.5 M NaCl
42. A solute AB2 dissociate 50% and associate 30%
(C) 0.2 M CaCl2 (D) 0.01 M Urea
(trimerize). The value of vant Hoff factor will be
(A) 3 (B) 2.2 53. At infinite dilution, the Van't Hoff factor for HCN is
(C) 1.8 (D) 1.2 (A) 1 (B) 2
(C) 3 (D) Infinite
43. 24 g of difluoroacetic acid in 400 g of water has observed
freezing point depression by 1.4°C. The van't Hoff factor 54. van’t Hoff factor of 0.1 molal CaCl2 solution will be
(A) 2 (B) 4
for difluoroacetic acid is (Kf of water = 1.86 K kg mol–1;
(C) 1 (D) 3
Atomic weight of F = 19)
55. If K4[Fe(CN)6] ionized to 10% then total number of
(A) 1.20 (B) 1.05
(C) 1.45 (D) 0.85 particles obtained, per mole of K4[Fe(CN)6] is
44. The values of observed and calculated molecular weights (A) 1.2 (B) 1.6
of silver nitrate are 90 and 170 respectively. The degree of (C) 1.4 (D) 2.4
dissociation of silver nitrate is 56. The solubility of a gas in liquid increases with
(A) 80% (B) 75.46% (A) Decrease of pressure
(C) 95.73% (D) 88.89% (B) Increase of temperature
45. Let gas(A) present in air is dissolved in 20 moles of water (C) Amount of liquid taken
at 298 K and 20 atm pressure. The mole fraction of gas (D) Decrease of temperature and increase of pressure
(A) in air is 0.2 and the Henry's law constant for solubility 57. Out of the following aqueous solutions, which one will
exhibit the lowest freezing point depression?
of gas(A) in water at 298 K is 1 × 105 atm. The number of
(A) 0.1 m NaCI (α = (B) 0.2 m K2SO4 (α =
mole of gas (A) dissolved in water will be
50%) 20%)
(A) 8 × 10–5 (B) 4 × 10–4 (C) 0.1 m Urea (D) 0.2 m Glucose
(C) 8 × 10–4 (D) 6 × 10–5 58. If freezing point depression of aqueous solution of 0.2 m
46. Given below are two statements. One is labelled as aluminium sulphate is 1.674 K then the van’t Hoff factor
Assertion (A) and other is Reason (R). will be
Assertion (A): Solubility of gases in liquid decreases with (Kf of water = 1.86 K kg mol–1)
rise in temperature.
Reason (R): Solubility of gases in liquid is an exothermic (A) 3.5 (B) 4.5
process so solubility decreases with rise in temperature, (C) 2.5 (D) 3.9
according to Le-chatelier's principle. 59. Observed molar mass of acetic acid which is dimerizes
In the light of above two statements choose the correct 75% in benzene solvent, is
option. (A) 60 (B) 96
(A) Both Assertion & Reason are true and the reason is (C) 37.5 (D) 30
the correct explanation of the assertion 60. Which of the following aqueous solution will show highest
(B) Both Assertion & Reason are true but the reason is boiling point when each is 0.2 M?
not the correct explanation of the assertion (A) K2SO4 (B) NH2CONH2
(C) Assertion is true statement but Reason is false (C) AlPO4 (D) Na3AlF6
(D) Both Assertion and Reason are false statements
61. The van’t Hoff factor for 0.1 M Ba(NO3)2 is 2.74.
47. Van’t Hoff factor of 0.1 molal CaCl 2 solution will be
Percentage degree of dissociation is
(A) 2 (B) 4 (A) 91.3% (B) 87%
(C) 1 (D) 3 (C) 75% (D) 63.5%
48. Which one of the following electrolytes has the maximum 62. The van’t Hoff factor (i) for infinitely dilute aqueous solution
value of van't Hoff factor? of Al2(SO4)3 is
(A) K [Fe (CN) ], 50% ionised
4 6
(A) 2 (B) 3
(B) K SO , 80% ionised
2 4 (C) 4 (D) 5
(C) K [Fe (CN) ], 60% ionised
3 6 63. Pressure exerted by vapours above the surface of liquid in
(D) Al (NO ) , 70% ionised
3 3
liquid gas equilibrium depends on
49. Aqueous solution of aluminium sulphate is 20% (A) Temperature (B) Surface area
dissociated. The van’t Hoff factor of aluminium sulphate (C) Nature of liquid (D) Both (1) and (3)
will be 64. Which of the following is/are based on Henry’s law?
(A) 1.8 (B) 2.4 (A) Soda water bottle sealed under high pressure of CO2
(C) 1.2 (D) 2.5 (B) Tank of scuba divers are filled with air diluted with
50. For solution of concentration of 0.01 m, which one has Helium
highest value of van’t Hoff factor? (C) Low concentration of oxygen in the blood at high
(A) NaCl (B) KCl altitude
(C) MgSO4 (D) K2SO4 (D) All of these

3
Solution_12th_Topicwise Question

65. Solubility of gas in a liquid can be increased by 70. Which of the following statement is incorrect with respect
(A) Increasing partial pressure of gas to phenomenon of solubility of gas in liquid?
(B) Increasing temperature (A) Value of Henry’s law constant at 293 K is more than
(C) Decreasing partial pressure of gas value of Henry’s law constant at 303 K for N2.
(D) Both (2) and (3) (B) The value of Henry’s law constant for given gas
66. When 20 g naphthoic acid, C11H8O2, is dissolved in 50 g follows the order Ar > CO2 > HCHO.
of benzene (Kf = 1.72 K kg mol–1), a freezing point Aquatic species are more comfortable in cold water
depression of 2 K is observed. The van’t Hoff factor (i) is (C) rather than in warm water because of high solubility of
O2 at low temperature.
(A) 0.5 (B) 1.5
(C) 0.2 (D) 1.3 (D) Henry’s law constant and solubility of gas in liquid are
67. Consider the following statements. inversely proportional.
(a) CaCl2 undergoes 60% dissociation in water. The value 71. The values of observed and calculated molecular weights
of silver nitrate are 90 and 170 respectively. The degree of
of i for CaCl2 is 2.2.
dissociation of silver nitrate is
(b) Ethanoic acid undergoes 60% dimerisation in benzene. (A) 80% (B) 75.46%
The value of i is 0.7. (C) 95.73% (D) 88.89%
(c) For dissociation i > 1 and for association i < 1. 72. Three gases X, Y and Z have their Henry's law constant
The correct statements are values as 200 bar, 500 bar and 900 bar respectively. The
(A) (a) and (b) (B) (b) and (c) gas which will be most soluble in water is
(C) (a) and (c) (D) (a), (b) and (c) (A) Gas X
68. If 0.1 molal aqueous solution of Al2(SO4)3 is 30% (B) Gas Y
dissociated then the van’t Hoff factor of the salt is (C) Gas Z
(A) 1.5 (B) 2.2 (D) All these gases will show same solubility
(C) 4.5 (D) 3.8 73. van't Hoff factor for AlCl3 aqueous solution is 2.8.
69. Consider the following two statements. Percentage dissociation of AlCl3 is
Statement I: Molecules of ethanoic acid dimerise in
(A) 60% (B) 75%
benzene due to H-bonding.
(C) 80% (D) 90%
Statement II: Due to association, the number of particles
is reduced. 74. If 0.1 M calcium phosphate solution, dissociates by 70%
Select the correct option among the following. then the van’t Hoff factor of the solution will be
(A) Both statements I and II are correct (A) 2.7 (B) 3.8
(B) Statement I is correct but statement II is incorrect (C) 1.5 (D) 4.5
(C) Statement I is incorrect but statement II is correct 75. A : Molecules of ethanoic acid demerise in benzene.
(D) Both statements I and II are incorrect R : There is intermolecular hydrogen bonding between
ethanoic acid molecules.
(A) Both Assertion & Reason are true and the reason is
the correct explanation of the assertion
(B) Both Assertion & Reason are true but the reason is
not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements

Vapour Pressure, Ideal & Non-Ideal Solution

76. Among the following which gas will show maximum 80. At 79ºC the vapour pressure of pure liquid 'A' is 520 mm of
negative deviation at moderate pressure? Hg and that of pure liquid 'B' is 1000 mm of Hg. If a
(A) He (B) O2 mixture of A and B boils at 79ºC at 760 mm of Hg then the
(C) CH4 (D) CO2 mole percent of A in the solution is
(A) 25% (B) 50%
77. If the vapour pressure of CH3Cl and CH2Cl2 are 360 mm
(C) 48% (D) 52%
and 480 mm of Hg respectively at a given temperature. If 81. Which of the following statements is correct regarding a
202 g of CH3Cl is mixed with 170g of CH2Cl2 at the same solution of two components A and B exhibiting positive
temperature, then vapour pressure of the solution will be deviation from ideal behaviour?
(A) 420 mm (B) 400 mm (A) ΔmixV = 0 at constant T and P.
(C) 480 mm (D) 360 mm (B) Intermolecular attractive forces between A-A and B-B
78. A solution is made by two volatile components are equal to those between A-B.
A (P° = 100 mm Hg) and B (P°B = 200 mm Hg) . Find (C) Intermolecular attractive forces between A-A and B-B
​A
are stronger than those between A-B.
out the mole fraction of A in vapour phase if solution is (D) ΔmixH = 0 at constant T and P.
made by mixing equal moles of A and B.
82. Vapour pressure of a binary solution of A and B (in mm
(A) 1

2
(B) 1

3 Hg) is equal to 140 + 120 XA. Pure form vapour pressures

(C) 2

3
(D) 1

4
of A and B respectively are
(A) 140 mm Hg, 260 mm (B) 260 mm Hg, 140 mm
79. If an azeotropic solution of two liquids has higher boiling
point than either of solute and solvent, then the solution Hg Hg
(A) Is immiscible (C) 240 mm Hg, 120 mm (D) 120 mm Hg, 240 mm
(B) Shows positive deviation from Raoult’s law Hg Hg
(C) Shows negative deviation from Raoult’s law
(D) Follow Raoult’s law

4
Solution_12th_Topicwise Question

83. The mixture of solution that forms minimum boiling 94. Vapour pressure of carbon tetrachloride at a particular
azeotrope is temperature is 400 mm of Hg. A non-volatile, non-
(A) Ethanol and water electrolyte solid weighing 0.8 g when added to 77 g of
(B) Nitric acid and water carbon tetrachloride the vapour pressure of the solution
(C) Benzene and Toulene becomes 390 mm of Hg. The molar mass of solute is
(D) Bromoethane and Chloroethane (Molar mass of CCl4 is 154 g mol–1. Assume solution to
84. For ideal solution which of the given relation is incorrect?
be dilute.)
(A) ΔHmix < 0 (B) ΔSmix > 0
(A) 120 g mol–1 (B) 64 g mol–1
(C) ΔGmix < 0 (D) ΔVmix = 0
85. An ideal solution is made by mixing 10 mol of x and 20 mol (C) 50 g mol–1 (D) 32 g mol–1
of y. The vapour pressure of the solution is [in torr] 95. In a binary solution of A(PAº = 700 torr) and B(PBº = 500
o o
( Px = 200 torr, Py = 100 torr) torr), if A and B were added in molar ratio of 2 : 3 then
(A) 100 (B) 200 vapour pressure of B in the solution will be
(A) 280 torr (B) 300 torr
(C) 200

3
(D) 400

3 (C) 580 torr (D) 680 torr

86. If two volatile liquids A( P
o
= 400 mmHg) and 96. Positive deviation is observed in case of
A

(A) HNO3 + H2O (B) CHCl3 + (C2H5)2O

= 300 mmHg) are mixed in the molar ratio of 2 : 5
o
B( P
B

then vapour pressure of A in liquid mixture will be (C) CH3COCH3 + (D) C6H6 + CH3COCH3
(A) 400 mm Hg (B) 300 mm Hg C6H5NH2
(C) 328.57 mm Hg (D) 114.3 mm Hg 97. Solution which shows positive deviation from Raoult’s law
87. Among the following which mixture form solution of high is
boiling azeotrope? (A) CHCl3 + (CH3)2CO (B) C6H14 + C5H12
(A) Benzene and toluene (C) CH3COCH3 + (D) C6H5OH +
(B) n-hexane and n-heptane C2H5OH C6H5NH2
(C) Hydrochloric acid and water
(D) Acetone and Carbon disulphide 98. A solution which will show positive deviation from Raoult’s
88. Which thermodynamic property is incorrect for dilute law is
solution of ethyl alcohol and water? (A) Ethanol-acetone (B) Water-nitric acid
(A) ΔHmix > 0 (B) ΔSmix > 0 (C) Chloroform -acetone (D) Benzene-toluene
(C) ΔVmix > 0 (D) ΔGmix > 0 99. Two liquids A and B have P and P in the ratio of 1 : 4
o
A
o
B

and the ratio of the number of moles of A and B in liquid

89. Which among the following will show positive deviation
phase are 1 : 5. Then the mole fraction of B in vapour
from Raoult’s law?
phase in equilibrium with the solution is equal to
(A) CH3COCH3 + (B) C6H5OH +
(A) (B)
20 18

CHCl3 C6H5NH2 21 19

(C) C2H5OH + (D) HNO3 + H2O (C) 19

21
(D) 18

21

CH3COCH3 [Link] ideal solution contains 10 mol of A and 20 mol of B.

90. The solution which forms minimum boiling azeotrope is The vapour pressure of the solution is ( P = 100 torr,
∘
A

(A) CHCl3 + CHBr3 (B) HNO3 + H2O P ∘

B
= 200 torr)
(C) HCl + H2O (D) C6H5OH + H2O (A) 133.3 torr (B) 150 torr
91. Which of the following aqueous solutions has highest (C) 166.7 torr (D) 300 torr
vapour pressure? [Link] volatile liquids A and B are mixed in the molar ratio of
(A) 0.02 M glucose at (B) 0.005 M MgCl2 at 2 : 3. If vapour pressure of pure liquids A and B is 300 mm
20°C Hg and 400 mm Hg respectively then the vapour pressure
15°C
of the solution in mm Hg will be
(C) 0.05 M KCl at 60°C (D) 0.005 M MgCl2 at
(A) 360 (B) 380
60°C (C) 340 (D) 390
92. A : 68% nitric acid and 32% water by mass forms 102.A : Azeotropic mixture cannot be separated by fractional
minimum boiling azeotrope. distillation.
R : Decreasing escaping tendency of molecules for each R : Azeotropic mixture has a definite composition and boils
component in mixture decreases the vapour pressure as like a pure liquid.
well as boiling point of mixture. (A) Both Assertion & Reason are true and the reason is
(A) Both Assertion & Reason are true and the reason is the correct explanation of the assertion
the correct explanation of the assertion (B) Both Assertion & Reason are true but the reason is
(B) Both Assertion & Reason are true but the reason is not the correct explanation of the assertion
not the correct explanation of the assertion (C) Assertion is true statement but Reason is false
(C) Assertion is true statement but Reason is false (D) Both Assertion and Reason are false statements
(D) Both Assertion and Reason are false statements [Link] vapour pressure of two liquids X and Y are 100 and
93. For a solution of volatile liquids, the partial vapour 200 torr respectively. The total vapour pressure of solution
pressure of each component in the solution is containing 20 mol of X and 10 mol of Y is
(A) Inversely proportional to temperature (A) 100 torr (B) 133.3 torr
(B) Inversely proportional to its mole fraction (C) 150 torr (D) 166.7 torr
(C) Directly proportional to total number of moles [Link] common salt is dissolved in water, the vapour pressure
(D) Directly proportional to its mole fraction of the solution will
(A) Increase (B) Decrease
(C) Remain unchanged (D) Can not be predicted

5
Solution_12th_Topicwise Question

[Link] an ideal solution of n-hexane and n-heptane, the [Link] solution showing positive deviation from ideal
incorrect option is behaviour is
(A) ΔVmix = 0 (A) CH3COCH3 + CS2 (B) HCl + H2O
(B) ΔGmix < 0 (C) HNO3 + H2O (D) CH3COCH3 +
(C) ΔHmix = 0 C6H5NH2
(D) ΔS = 0
mix [Link] negative deviation from Raoult's law, which of the
(system) following thermodynamic relation is incorrect?
[Link] two liquids A (boiling point = t1°C) and B (boiling point = (A) (ΔG)mix < 0 (B) (ΔS)mix > 0
t2°C) on mixing forms azeotropic solution which shows (C) (ΔV)mix > 0 (D) (ΔH)mix < 0
positive deviation from Raoult's law, then boiling point of [Link] a mixture of A and B, components show positive
azeotropic solution will be [Given, t1 > t2) deviation when
(A) > t1 (B) > (t1 + t2) (A) A–B interaction is stronger than A–A and B–B
interaction
(C) = t1 (D) < t2 (B) A–B interaction is weaker than A–A and B–B
107.(Ethanol + water) mixture can form interaction
(A) Minimum boiling azeotrope having same composition (C) ΔVmix < 0, ΔSmix > 0
in liquid and vapour phase (D) ΔVmix = 0, ΔSmix > 0
(B) Maximum boiling azeotrope which boils at a constant
temperature [Link] the vapour pressure of A and B in pure state if
(C) Maximum boiling azeotrope which shows a large expression for total vapour pressure of a solution of A and
positive deviation from Raoult’s law B is PTotal = 100 + 70 xA
(D) Minimum boiling azeotrope which shows a large (A) º
P
º
= 170, P
B
= 150 (B) P
º
= 100, P
º
B
= 170
A A
negative deviation from Raoult’s law º º (D) P∘ = 170, P∘ = 150
[Link] solution showing positive deviation from ideal (C) P
A
= 150, P
B
= 170 A B

behaviour is [Link] 50°C, the vapour pressure of a pure liquid A (molar

(A) CH3COCH3 + CS2 (B) HCl + H2O mass = 80 g mol–1) is 100 torr, while that of pure liquid B
(C) HNO3 + H2O (D) CH3COCH3 +
is 40 torr (molar mass = 60 g mol–1). The vapour pressure
C6H5NH2 of solution at 50°C containing 40 g of each A and B is
[Link] boiling azeotrope (A) 59.8 torr (B) 69.2 torr
(A) Shows positive deviation from Raoult’s law (C) 65.7 torr (D) 34.5 torr
(B) Shows negative deviation from Raoult’s law [Link] of the following statements about the composition
(C) Follows Raoult’s law of the vapour over an ideal solution having 1 : 2 molar
(D) Has unequal composition in liquid and vapour states mixture of component A and B is correct?
[Link] pressure of an ideal solution if it contains 0.75 Assume that temperature is constant at 25°C. (Given
mole fraction of solvent is (P°solvent = 200 torr, P°solute = vapour pressure data at 25°C, component A = 10 kPa,
100 torr) component B = 20 kPa)
(A) 100 torr (B) 150 torr (A) The vapour will contain equal mole fraction as of mole
(C) 175 torr (D) 200 torr fraction in solution phase
[Link] an ideal solution which thermodynamic relation is (B) The vapour will contain equal amount of components
incorrect? A and B
(C) Number of moles of B is four times than the number of
(A) ΔmixH = 0 (B) ΔmixV = 0
moles of A in vapour phase
(C) ΔmixS = 0 (D) ΔmixG < 0 (D) Number of moles of A is four times than the number of
[Link] mixture that forms minimum boiling azeotrope is moles of B in vapour phase
(A) Hydrochloric acid + Water [Link] the mixture which does not show negative deviation
(B) Water + Nitric Acid from Raoult’s law.
(C) Water + Ethanol (A) H2O + HCl (B) H2O + HNO3
(D) Acetone + Aniline (C) Benzene + toluene (D) Acetone + aniline
[Link] an ideal solution, the correct option is [Link] ideal solution has 2 : 3 mole ratio of two volatile liquids
(A) Δmix S = 0 at constant T and P A and B. The vapour pressure of pure liquids A and B at
(B) Δmix V ≠ 0 at constant T and P 25°C are 220 mm of Hg and 180 mm of Hg respectively.
(C) Δmix H = 0 at constant T and P The mole fraction of A in the vapour phase would be
(D) Δmix G = 0 at constant T and P (A) 0.45 (B) 0.90
(C) 0.36 (D) 0.72
[Link] pressure exerted by vapours on the liquid surface in
[Link] of the following is correct for an aqueous solution of
equilibrium with the liquid depends upon
benzene and toluene at 298 K?
(i) Temperature
(A) ΔmixH = 0 (B) ΔmixV > 0
(ii) Nature of liquid
(iii) Surface area (C) ΔmixG > 0 (D) ΔmixS < 0
(A) (i) only (B) (ii) & (iii) only
(C) (i), (ii) & (iii) (D) (i) & (ii) only
[Link] boiling points of liquids A, B, C and D are 63°C, 97°C,
101°C and 85°C respectively. Which of the following will
have highest vapour pressure at room temperature?
(A) A (B) B
(C) C (D) D

6
Solution_12th_Topicwise Question

[Link] below are two statements one is assertion(A) other

is reason (R).
Assertion (A): Mixture of chloroform and acetone shows
positive deviation from Raoult’s law.
Reason (R): Chloroform and acetone form intermolecular
hydrogen bond.
In the light of above statements, choose the correct
answer.
(A) Both assertion and reason are correct statements, and
reason is the correct explanation of the assertion.
(B) Both assertion and reason are correct statements, but
reason is not the correct explanation of the assertion.
(C) Assertion is correct, but reason is wrong statement.
(D) Assertion is wrong, but reason is correct statement.

Colligative Properties

[Link] mass of urea to be dissolved in 100 g of water (Kb = [Link] 2 moles of glucose is dissolved in 2 L of water, then
boiling point of solution will be _____, if kb for water is
0.52 K kg mol–1) to prepare a solution having boiling point
101°C, is 0.512 K kg mol–1.
(A) 10.26 g (B) 4.2 g (A) 100.512°C (B) 100.512 K
(C) 11.54 g (D) 14.66 g (C) 0.512°C (D) 373.512°C
127.0.2 molal aqueous solution of K3[Fe(CN)6] ionizes to 40%. [Link] n2 moles of non-volatile solute are dissolved in n1
Depression in freezing point of solution will be (Kf(H2O) = moles of solvent, then vapour pressure of pure solvent
1.86 K molal–1) (po) changes to p (vapour pressure of solution). The
(A) 0.82 K (B) 0.45 K correct relation(s) for such solution is/are
(C) 1.23 K (D) 0.63 K (A) pº = p x1 (B) All of these
[Link] 2 g urea is added to 100 g of water (Kf = 1.86 Kkg/mole),
∘ ∘
p −p n2 p −p n2
(C) p
=
n1
(D) p
=
n1 + n2

then how much ice will separate out at –10°C?

(A) Zero (B) 93.8 g [Link] best suited colligative property to determine the
(C) 9.38 g (D) 4.82 g molecular mass of polymers is
(A) Elevation of boiling point
129.3.6 g of glucose is present in 250 ml aqueous solution. (B) Depression of freezing point
The osmotic pressure of the solution at 27 °C will be (R = (C) Relative lowering of vapour pressure
0.082 L atm K–1 mol–1; molar mass of glucose = 180 g (D) Osmotic pressure
mol–1) 138.A : Osmotic pressure is proportional to the molality of the
(A) 4.0 atm (B) 3.0 atm solution.
(C) 2.0 atm (D) 5.0 atm R : Osmotic pressure is independent of temperature.
[Link] among the following is a colligative property? (A) Both Assertion & Reason are true and the reason is
(A) Vapour pressure (B) Boiling point the correct explanation of the assertion
(C) Freezing point (D) Osmotic pressure (B) Both Assertion & Reason are true but the reason is
131.5 g of a non-volatile, non-electrolyte solute is dissolved in not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false
250 g of water. If molar mass of solute is 80 g mol–1 then (D) Both Assertion and Reason are false statements
the freezing point of the solution will be 139.0.5 M solution of MgCl2 will have the same osmotic
(Kf of water = 1.86 K kg mol–1) pressure as (consider complete dissociation of
(A) –1.52°C (B) –0.46°C electrolytes)
(C) –0.12°C (D) –2.5°C (A) 1 M NaCl (B) 1.5 M KCl
[Link] molality of a dilute solution is doubled then the value of (C) 1.5 M urea (D) 1 M AlCl3
molal elevation constant (Kb) becomes 140.A : People taking a lot of salt or salty food experience
(A) Doubled (B) Halved water retention in tissue cells and intercellular space.
(C) Tripled (D) Unchanged R : There is phenomena of osmosis in tissue cells and
[Link] colligative property widely used to determine molar intercellular space.
mass of polymers is (A) Both Assertion & Reason are true and the reason is
(A) Osmotic pressure the correct explanation of the assertion
(B) Elevation in boiling point (B) Both Assertion & Reason are true but the reason is
(C) Depression in freezing point not the correct explanation of the assertion
(D) Relative lowering of vapour pressure (C) Assertion is true statement but Reason is false
134.A : When red blood cells are placed in distilled water, (D) Both Assertion and Reason are false statements
water flows into the cells. [Link] properties of solution depends on
R : Direction of osmosis is from hypertonic solution to (A) Nature of solute particles
hypotonic solution. (B) Number of solute particles
(A) Both Assertion & Reason are true and the reason is (C) Number of solvent particles
the correct explanation of the assertion (D) Volume of the solution
(B) Both Assertion & Reason are true but the reason is
not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements

7
Solution_12th_Topicwise Question

[Link] the given properties of solution, how many are [Link] the correct statement among the following.
colligative properties? (A) Plant cell when placed in hypotonic solution, it will
Osmotic pressure, Relative lowering in vapour pressure, shrink
Boiling point, Elevation in boiling point, Vapour pressure (B) Osmotic pressure associated with 0.9% mass/volume
of NaCl solution is equivalent to fluid inside the blood
(A) 3 (B) 4
cell
(C) 1 (D) 2 (C) As compared to other colligative properties, magnitude
[Link] colligative property is the best method for the of elevation in boiling point is large even for very dilute
determination of molar masses of macromolecules? solution
(A) Elevation in boiling point (D) Molal elevation constant always larger than molal
(B) Depression in freezing point depression constant
(C) Relative lowering in vapour pressure [Link] the following 0.2 m aqueous solutions, which one will
(D) Osmotic pressure
exhibit largest freezing point depression?
144.A 0.1 molal aqueous solution of a monobasic acid is 9% (A) Glucose (B) Sucrose
ionized. The freezing point of solution will be (molecular (C) Urea (D) NaCl
weight of the acid 200, Kf = 1.86 K mol–1 kg) [Link] concentration of glucose solution which shows an
(A) 0°C (B) –0.20 °C osmotic pressure of 8.21 atm at 27°C is,
(C) –0.02 °C (D) – 2.02 °C (A) 0.081 M (B) 0.062 M
[Link] which is not colligative, is (C) 0.333 M (D) 0.358 M
(A) Relative lowering of vapour pressure 157.0.1 molal aqueous solution of an electrolyte AB3 is 80%
(B) Boiling point ionized. The boiling point in kelvin of solution at 1 atm is
(C) Depression in freezing point (Kb = 0.52K kg/mol)
(D) Osmotic pressure (A) 298.176 (B) 373.177
[Link] is not a colligative property? (C) 374.198 (D) 299.198
(A) Relative lowering of vapour pressure 158.1.0 molal aqueous solution of an electrolyte XY is 100%
(B) Freezing point ionised. The boiling point of the solution is (Kb for H2O =
(C) Osmotic pressure
0.52 K kg/mol)
(D) Elevation of boiling point
(A) 375.5 K (B) 374.04 K
[Link] of the following is used as antifreeze in automobile? (C) 377.12 K (D) 373.25 K
[Link] Osmotic pressure of 0.1 M solution of glucose at 27°C
(A) Phenol (B) Ethylene glycol
is
(C) Acetone (D) Benzene
(A) 1.5 atm (B) 0.75 atm
[Link] of sea water can be done by (C) 3.5 atm (D) 2.46 atm
(A) Filtration (B) Osmosis
[Link] solutions have same
(C) Reverse osmosis (D) Diffusion
(A) Boiling temperature (B) Vapour pressure
[Link] cells do not shrink in blood because blood is (C) Freezing (D) Osmotic pressure
(A) Hypertonic (B) Isotonic temperature
(C) Equimolar (D) Hypotonic
[Link] molecular weight of benzoic acid in benzene is
150.A : 1.5% (w/v) glucose is isotonic with 1.5% (w/v) of urea determined by depression in the freezing point method
solution at room temperature. corresponds to
R : Solutions having similar % (w/v) are said to be isotonic (A) Tetramerisation of benzoic acid
solutions. (B) Dimerisation of benzoic acid
(A) Both Assertion & Reason are true and the reason is (C) Trimerisation of benzoic acid
the correct explanation of the assertion (D) Ionisation of benzoic acid
(B) Both Assertion & Reason are true but the reason is
162. Mass of a non-volatile solute (molar mass = 45 g mol–1)
not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false that should be dissolved in 90 g water to reduce its vapour
(D) Both Assertion and Reason are false statements pressure to 75% is
[Link] the following aq. dilute solution in the increasing (A) 75 g (B) 45 g
order of vapour pressure (C) 25 g (D) 15 g
(a) 10% (w/v) glucose [Link] solution of which of the following has lowest
(b) 10% (w/v) sucrose freezing point? (Kf(H2O) = 1.86 K molal–1)
(c) 10% (w/v) urea (A) 0.1 m NaCl (B) 0.01 m NaCl
(A) (a) < (b) < (c) (B) (a) < (c) < (b)
(C) 0.001 m NaCl (D) 0.0001 m NaCl
(C) (c) < (b) < (a) (D) (c) < (a) < (b)
[Link] mercuric iodide is added to the aqueous solution of
[Link] solutions are those which have potassium iodide, the
(A) Same vapour (B) Same boiling point (A) Boiling point of solution remains same
pressure (B) Freezing point of solution remains same
(C) Same freezing point (D) Same osmotic (C) Freezing point of solution is raised
pressure (D) Freezing point of solution is lowered
[Link] osmotic pressure of 18% (w/v) solution of glucose at
27ºC is
(A) 24.63 atm (B) 30.25 atm
(C) 19.19 atm (D) 20.41 atm

8
Solution_12th_Topicwise Question

165.A : For 0.1 M aq. NaOH and for 0.1 M aq. CH3COOH 171. 30 g of urea (M = 60 g mol–1) is dissolved in 846 g of
solution, the ebullioscopic constant is different. water. Calculate the vapour pressure of water for this
R : Ebullioscopic constant depends on the nature of solution if vapour pressure of pure water at 298 K is 23.8
solute. mm Hg.
(A) Both Assertion & Reason are true and the reason is 172.A : Osmosis involves movement of solvent molecules from
the correct explanation of the assertion higher concentration of solution to its lower concentration.
(B) Both Assertion & Reason are true but the reason is R : Solutions having different osmotic pressures are called
not the correct explanation of the assertion isotonic solutions.
(C) Assertion is true statement but Reason is false (A) Both Assertion & Reason are true and the reason is
(D) Both Assertion and Reason are false statements the correct explanation of the assertion
[Link] is the freezing point of a solution containing 8.1 g (B) Both Assertion & Reason are true but the reason is
HBr in 100 g water, assuming the acid to be 90% ionised? not the correct explanation of the assertion
(Kf of water = 1.86 K mol–1, Atomic mass of Br = 80) (C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements
(A) 0.85°C (B) –3.53°C
(C) 0°C (D) –0.35°C [Link] lowering of vapor pressure of a solution
[Link] among the following aqueous solutions has highest containing non-volatile solute can be expressed as (A -
solvent, B - solute)
freezing point? (Given Kf of water = 1.86 K kg mol–1) (A) Both (C) and (D) (B) P = P X
s
∘
B
A

(A) 0.1 m glucose (B) 0.1 m NaCl solution 0 P

∘
− Ps nB

solution (C)
P
A
− Ps

=
nB
(D) A

PA
∘
=
nA
Ps nA

(C) 0.1 m CaCl2 solution (D) 0.2 m NaOH solution

[Link] molecular weight of benzoic acid in benzene as
[Link] of the following aq. solutions will freeze at highest determined by depression in freezing point method
temperature? corresponds to
(A) 0.1 m NaCl (B) 0.1 m glucose (A) Solvation of benzoic acid
(C) 0.1 m CaCl2 (D) 0.1 m AlCl3 (B) Trimerization of benzoic acid
[Link] of an aqueous NaCl solution is 0.30 mol/L (C) Dimerization of benzoic acid
at 37°C, the osmotic pressure of the solution is (D) Ionization of benzoic acid
(A) 0.6 bar (B) 7.7 bar [Link] percentage of phenol dimerised in benzene if 18.8 g
(C) 15.6 bar (D) 27.2 bar of phenol in 1 kg benzene exhibits a freezing point
170. When depression of 0.70 K, is
1

2
mole of solute is dissolved in 2 kg of solvent, K−kg

boiling point of solution is found to be 100.125°C. Kb (in K (Given that kf benzene = 5.12 mol
and MW of phenol =
94)
kg mol–1) for solvent (boiling point of solvent in pure state (A) 64% (B) 73%
is 100°C) is (C) 91% (D) 47%
(A) 0.8 (B) 0.7
(C) 0.5 (D) 2