1.

Consider the following statements about cathode rays:

(a) They are negatively charged particles
(b) The characteristics of cathode rays do not depend upon the material of electrodes used.
(c) They start from anode and move towards cathode. The correct statements are:
(1) (a) and (b) only (2) (b) and (c) only
(3) (a) and (c) only (4) (a), (b) and (c)
2. Which of the following particles has maximum de-Broglie wavelength if all are moving with same
speed?
(1) Electron (2) Neutron
(3) Proton (4) Alpha particle
3. Bohr theory is not applicable for:
(1) H (2) 𝐻𝑒 +
2+
(3) 𝐿𝑖 (4) 𝐵𝑒 2+
4. Assertion: Proton is ionised hydrogen atom.
Reason: α-particle is the unionized helium atom.
(1) Both Assertion & Reason are true and the reason is the correct explanation of the assertion
(2) Both Assertion & Reason are true but the reason is not the correct explanation of the assertion
(3) Assertion is true statement but Reason is false
(4) Both Assertion and Reason are false statements
5. Out of the following set of quantum numbers, choose the one which does not exist
1
(1) 𝑛 = 1, 𝐼 = 0, 𝑚 = 0, 𝑠 = −
2
1
(2) 𝑛 = 4, 𝐼 = 0, 𝑚 = 0, 𝑠 = + 2
1
(3) 𝑛 = 3, 𝐼 = 3, 𝑚 = 0, 𝑠 = + 2
1
(4) 𝑛 = 3, 𝐼 = 0, 𝑚 = 0, 𝑠 = − 2
6. The longest wavelength of Paschen series of 𝐿𝑖 2+ ion is:
4 16
(1) 3𝑅 (2) 7𝑅
7𝑅 36
(3) (4)
16 𝑅
7. The orbital diagram in which a Aufbau principle is violated is:

(1)

(2)

(3)

(4)
8. Select the correct statement regarding photoelectric effect:
(1) Number of ejected electrons are independent of intensity of light.
(2) Kinetic energy of electrons are independent of intensity of light.
(3) Kinetic energy of electrons are independent of frequency of light.
(4) Number of ejected electrons depends on the frequency of light.
9. Which of the following pairs of d-orbitals will have electrons density along the axes:
(1) 𝑑𝑧2 , 𝑑𝑥 2 −𝑦2 (2) 𝑑𝑥𝑦 , 𝑑𝑥 2 −𝑦2
 (3) 𝑑𝑧2 , 𝑑𝑦 (4) 𝑑𝑥𝑦 , 𝑑𝑦𝑧
10. What is the maximum number of electrons that can be associated with following set of quantum numbers
𝑛 = 4, 𝐼 = 2:
(1) 2 (2) 5
(3) 14 (4) 10
11. Statement-I: Chromium and copper both have exceptional electronic configuration.
Statement-II: Total number of d electrons in copper and chromium are 10 and 5 respectively.
In the light of above statements, choose the most appropriate answer from the options given below:
(1) Both statement I and statement II are correct
(2) Both statement I and statement II is incorrect
(3) Statement I is correct but statement II is incorrect
(4) Statement I is incorrect but statement II is correct
12. The wave number for the shortest wavelength transition in the Paschen series of atomic hyderogen is
(𝑅𝐻 : 𝑅𝑦𝑑𝑏𝑒𝑟𝑔 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡)
𝑅
(1) 𝑅𝐻 (2) 𝐻
9
7𝑅 9
(3) 𝐻 (4) 𝑅𝐻
144 7
13. Statement I: Splitting of the spectral lines in magnetic field is known as Stark effect.
Statement-II: Splitting of the spectral lines in electric field is known as Zeeman effect.
(1) Both statement I and statement II are correct
(2) Both statement I and statement II is incorrect
(3) Statement I is correct but statement II is incorrect
(4) Statement I is incorrect but statement II is correct
14. The number of photons emitted in one second by a 10 watt bulb, which emits monochromatic light of
wavelength 662 nm, is:
(ℎ = 6.62 × 10−34 𝐽𝑠)
(1) 6.28 × 1016 (2) 3.33 × 1019
18
(3) 5.21 × 10 (4) 7.25 × 1017
15. The correct order of energy of given orbitals for multielectronic species is:
(1) 7𝑠 > 6𝑝 > 4𝑓 > 5𝑝
(2) 4𝑓 > 7𝑠 > 6𝑝 > 5𝑝
(3) 4𝑓 > 6𝑝 > 7𝑠 > 5𝑝
(4) 7𝑠 > 6𝑝 > 5𝑝 > 4𝑓
16. Consider the following statements:
a. Principal quantum number determines the size of atomic orbital.
b. Number of degenerate orbitals in third shell of 𝐻𝑒 + ion is 9.
c. Magnetic orbital quantum number determines the three-dimensional shape of the orbital.
d. Maximum number of electrons present in a 𝜌 − 𝑜𝑟𝑏𝑖𝑡𝑎𝑙 is 2.
The correct statements are:
(1) a, c and d only (2) b, c and d only
(3) a, b and d only (4) a, b, c and d
17. Correct order of energy of the given radiations is:
(1) X-rays > IR > Microwave > Radio waves
(2) Radio wave > Microwave > IR > X-rays
(3) Microwave > Radio waves > IR > X-rays
(4) Radio waves > IR > Microwave > X-rays
18. Statement I: For a given value of 𝑙, 𝑚𝑙 has (2𝑙 + 1) values
Statement II: For 𝑙 = 0, the only permitted value of 𝑚𝑙 = 0.
The correct option is:
(1) Both statement I and statement II are correct
 (2) Both statement I and statement II is incorrect
(3) Statement I is correct but statement II is incorrect
(4) Statement I is incorrect but statement II is correct
19. 𝑀𝑔2+ is isoelectronic with:
(1) 𝑁𝑎+ (2) 𝐶𝑎2+
2+
(3) 𝐵𝑒 (4) 𝐾 +
20. The maximum number of electrons that can be identified with the quantum number
ℓ = 2 𝑓𝑜𝑟 𝐹𝑒 3+ ion will be
(1) 3 (2) 4
(3) 5 (4) 6
21. Maximum possible electron(s) in 𝑀𝑛, for which 𝑛 + 𝑙 + 𝑚 = 5 is:
(1) 1 (2) 2
(3) 3 (4) 10
22. Given below are the two statements:
Statement – I: The characteristics of cathode rays do not depend upon the material of electrodes used
Statement – II: In absence of electrical or magnetic field, cathode rays travel in straight lines
(1) Statement I is correct but statement II is incorrect
(2) Statement I is incorrect but Statement II is correct
(3) Both statement I and statement II are correct
(4) Both statement I and statement II are incorrect
23. Consider the following statements:
14 14
(a) 𝐶 𝑎𝑛𝑑 𝑁 are isobars
6 7
(b) A tritium atom contains 1 proton and 2 neutrons
(c) All the isotopes of a given element show same chemical behavior
The correct statements are:
(1) a and b only (2) b and c only
(3) a and c only (4) a, b and c
24. Which of the following can be explained by wave nature of electromagnetic radiation?
(1) Black body radiation
(2) Photoelectric effect
(3) Line spectra of hydrogen atom
(4) Interference
25. The potential energy of an electron in the H-atom is −6.8 𝑒𝑉. In which excited state, the electron is
present?
(1) First excited state (2) Second excited state
(3) Third excited state (4) Forth excited state
26. Ratio of the radius of first orbit of 𝐿𝑖 2+ to the third orbit of 𝐻𝑒 + ions will be:
(1) 1: 5 (2) 2: 5
(3) 3: 8 (4) 2: 27
27. Ratio of total energy of electron of 1st orbit of hydrogen (H) , 2nd orbit of 𝐻𝑒 ⊕ion and 3rd 𝐿𝑖 2+ ion will be
(1) 1: 2: 3 (2) 1: 1: 1
(3) 1: 4: 9 (4) 3: 2: 1
28. Orbital angular momentum of 3p orbital is:
(1) 2h (2) √2 ℏ
(3) 2√3ℏ (4) 6h
29. The total number of node(s) in 4𝑝𝑥 orbital is:
(1) 1 (2) 2
(3) 3 (4) 4
30. Match the species given in List- I with number of unpaired electrons given in List- II
 List – I List- II

(a) 𝐶𝑟 2− (i) 2

(b) 𝑉 2+ (ii) 5
(c) 𝑀𝑛2+ (iii) 3
(d) 𝑁𝑖 2+ (iv) 4

The correct match is

(1) a(iv), b(iii), c(i), d(ii)
(2) a(iv), b(iii), c(ii), d(i)
(3) a(iii), b(iv), c(ii), d(i)
(4) a(ii), b(iii), c(iv), d(i)
31. In which of the following orbital diagram, only Hund’s rule of maximum multiplicity is violated?

(1) (2)

(3) (4)
32. Which is the correct statement related to cathode rays?
(1) These rays move from anode to cathode
(2) These rays consist of positively charged particles called protons
(3) Characteristics of these rays depends upon the nature of the gas present in the cathode ray tube
(4) These rays travel in straight line in the absence of electric and magnetic field

33. In hydrogen spectrum, the series of line which lies in the ultraviolet region is:
(1) Lyman series (2) Balmer series
(3) Paschen series (4) Brackett series
34. The wavelength of radiations 𝜆1 and 𝜆2 are 10 nm and 20 nm respectively. The relation between their
energies E1 and E2 will be:
(1) E1 = E2 (2) 2E1 = E2
(3) E1 = 2E2 (4) E1 = 10E2
35. The maximum kinetic energy of photoelectrons emitted when a light of frequency 1 × 1016 Hz is
irradiated on a metal surface with threshold frequency (𝑣0 ) 2 × 1015 Hz is:
(1) 3.6 × 10-18 J (2) 1.7 × 10-20 J
(3) 7.5 × 10-19 J (4) 5.3 × 10-18 J

36. Which of the following transitions in the hydrogen spectrum will give photon of maximum energy?
(1) 𝑛 = 3 to 𝑛 = 2 (2) 𝑛 = 4 to 𝑛 = 3
(3) 𝑛 = 3 to 𝑛 = 1 (4) 𝑛 = 6 to 𝑛 = 5

37. The de Broglie wavelength of a ball of mass 0.02 kg moving with a velocity of 20 ms-1 is:
(h = 6.6 × 10-34 Js)
(1) 1.65 × 10-33 m (2) 6.6 × 10-28 m
(3) 6.6 × 10-34 m (4) 1.65 × 10-34 m

38. The total number of radial nodes is given by:

(1) n (2) 𝑙
(3) n – 1 (4) n – 𝑙 – 1
39. Electromagnetic radiation having maximum wavelength among the following is:
(1) Cosmic rays (2) 𝛾-rays
(3) Microwaves (4) Radio waves
40. The angular momentum of electron in 𝑝-orbital is equal to:
ℎ
(1) √2ℎ (2) 2
(3) Zero (4) √3ℎ
41. If uncertainty in position and momentum are equal, then uncertainty in momentum is:
1 ℎ ℎ
(1) 2 √𝜋 (2) √2𝜋
1 ℎ 1 ℎ
(3) 𝑚 √𝜋 (4) 2𝑚 √𝜋

42. The correct order of energy of the orbitals in hydrogen atom is:
(1) 3𝑠 < 3𝑝 < 3𝑑 < 4𝑠
(2) 3𝑠 < 3𝑝 < 4𝑠 < 3𝑑
(3) 3𝑠 = 3𝑝 = 3𝑑 < 4𝑠
(4) 3𝑠 = 3𝑝 = 3𝑑 > 4𝑠
43. If for a microscopic particle ∆𝑥 = 4∆𝑃, then uncertainty in its linear momentum is
1 ℎ 1 ℎ
(1) 2 √𝜋 (2) 4 √2𝜋
1 ℎ ℎ
(3) 4 √𝜋 (4) 4√𝜋
44. Number of electrons in nitrogen atom for which azimuthal quantum number(𝑙) is 1, is
(1) 7 (2) 3
(3) 4 (4) 6
45. Pair of isotonic species is
(1) 18𝐴𝑟 40 and 20𝐶𝑎40 (2) 7𝑁14 and 6𝐶 13
15 15
(3) 7N and 8O (4) 7N15 and 9F19