02-04-2025

1001CJM020425EVE JM

PART-1 : PHYSICS

SECTION-I

1) Given below are two statements : one is labelled as Assertion (A) and the other is labelled as
Reason (R).
Assertion (A) : Net dipole moment of a polar linear isotropic dielectric substance is not zero even in
the absence of an external electric field.
Reason (R) : In absence of an external electric field, the different permanent dipoles of a polar
dielectric substance are oriented in random directions.
In the light of the above statements, choose the most appropriate answer from the options given
below :

(A) (A) is correct but (R) is not correct

(B) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
(C) Both (A) and (R) are correct and (R) is the correct explanation of (A)
(D) (A) is not correct but (R) is correct

2) In a moving coil galvanometer, two moving coils M1 and M2 have the following particulars :
R1 = 5 Ω, N1 = 15, A1 = 3.6 × 10–3 m2, B1 = 0.25 T
R2 = 7 Ω, N2 = 21, A2 = 1.8 × 10–3 m2, B2 = 0.50 T
Assuming that torsional constant of the springs are same for both coils, what will be the ratio of
voltage sensitivity of M1 and M2 ?

(A) 1 : 1
(B) 1 : 4
(C) 1 : 3
(D) 1 : 2

3) The moment of inertia of a circular ring of mass M and diameter r about a tangential axis lying in
the plane of the ring is :

(A)

(B)

(C)

(D) 2 Mr2

4) Two water drops each of radius 'r' coalesce to from a bigger drop. If 'T' is the surface tension, the
surface energy released in this process is :
(A)

(B)

(C)

(D)

5) An electron with mass 'm' with an initial velocity (t = 0) (v0 > 0) enters a magnetic field
. If the initial de-Broglie wavelength at t = 0 is λ0 then its value after time 't' would be :

(A)

(B)

(C)

(D) λ0

6) A sinusoidal wave of wavelength 7.5 cm travels a distance of 1.2 cm along the x-direction in 0.3
sec. The crest P is at x = 0 at t = 0 sec and maximum displacement of the wave is 2 cm. Which
equation correctly represents this wave ?

(A) y = 2cos(0.83x – 3.35t) cm

(B) y = 2sin(0.83x – 3.5t) cm
(C) y = 2cos(3.35x – 0.83t) cm
(D) y = 2cos(0.13x – 0.5t) cm

7) Given a charge q, current I and permeability of vacuum μ0. Which of the following quantity has the
dimension of momentum ?

(A) qI /μ0
(B) q μ0 I
2
(C) q μ0 I
(D) qμ0/I

8) A solenoid having area A and length 'ℓ' is filled with a material having relative permeability 2. The
magnetic energy stored in the solenoid is :

(A)

(B)
(C) B2Aℓ

(D)

9) Two large plane parallel conducting plates are kept 10 cm apart as shown in figure. The potential
difference between them is V. The potential difference between the points A and B (shown in the

figure) is :

(A)

(B)

(C)

(D) 1 V

10) Identify the characteristics of an adiabatic process in a monoatomic gas.

(A) Internal energy is constant.
(B) Work done in the process is equal to the charge in internal energy.
(C) The product of temperature and volume is a constant.
(D) The product of pressure and volume is a constant.
(E) The work done to change the temperature from T1 to T2 is proportional to (T2 – T1)
Choose the correct answer from the options given below :

(A) (A), (C), (D) only

(B) (A), (C), (E) only
(C) (B), (E) only
(D) (B), (D) only

11) Assuming the validity of Bohr's atomic model for hydrogen like ions the radius of Li++ ion in its

0
ground state is given by where X = ______. (Where a is the first Bohr's radius.)

(A) 2
(B) 1
(C) 3
(D) 9

12) Energy released when two deuterons (1H2) fuse to form a helium nucleus (2He4) is :
(Given : Binding energy per nucleon of 1H2 = 1.1 MeV and binding energy per nucleon of 2He4 = 7.0
MeV)
(A) 8.1 MeV
(B) 5.9 MeV
(C) 23.6 MeV
(D) 26.8 MeV

13) In the digital circuit shown in the figure, for the given inputs the P and Q values are :

(A) P = 1, Q = 1
(B) P = 0, Q = 0
(C) P = 0, Q = 1
(D) P = 1, Q = 0

14) Two identical objects are placed in front of convex mirror and concave mirror having same radii
of curvature of 12 cm, at same distance of 18 cm from the respective mirrors. The ratio of sizes of
the images formed by convex mirror and by concave mirror is :

(A) 1/2
(B) 2
(C) 3
(D) 1/3

15) A sportsman runs around a circular track of radius r such that he traverses the path ABAB. The

distance travelled and displacement, respectively, are

(A) 2r, 3πr

(B) 3πr, πr
(C) πr, 3r
(D) 3πr, 2r

16) A body of mass 1kg is suspended with the help of two strings
making angles as shown in figure. Magnitude of tensions T1 and T2, respectively, are (in N) :

(A) 5,
(B) ,5
(C) ,

(D) 5, 5

17) A bi–convex lens has radius of curvature of both the surfaces same as 1/6 cm. If this lens is
required to be replaced by another convex lens having different radii of curvatures on both sides (R1
≠ R2), without any change in lens power then possible combination of R1 and R2 is :

(A)
and

(B)
and

(C)
and

(D)
and

18) If μ0 and ε0 are the permeability and permittivity of free space, respectively, then the dimension

of is :

(A) L/T2
(B) L2/T2
(C) T2/L
(D) T2/L2

19) Match List-I with List-II.

List-I List-II

(A) Heat capacity of body (I) J kg–1

(B) Specific heat capacity of body (II) JK–1

(C) Latent heat (III) J kg–1 K–1

(D) Thermal conductivity (IV) Jm–1K–1s–1

Choose the correct answer from the options given below :
(A) (A)–(III), (B)–(I), (C)–(II), (D)–(IV)
(B) (A)–(IV), (B)–(III), (C)–(II), (D)–(I)
(C) (A)–(III), (B)–(IV), (C)–(I), (D)–(II)
(D) (A)–(II), (B)–(III), (C)–(I), (D)–(IV)

20) Consider a circular loop that is uniformly charged and has a radius . Find the position along
the positive z–axis of the cartesian coordinate system where the electric field is maximum if the ring
was assumed to be placed in xy–plane at the origin :

(A)
(B)

(C) a
(D) 0

SECTION-II

1) A wheel of radius 0.2 m rotates freely about its center when a string that is
wrapped over its rim is pulled by force of 10 N as shown in figure. The established torque produces
an angular acceleration of 2 rad/s2. Moment of inertia of the wheel is ________ kg m2.
(Acceleration due to gravity = 10 m/s2)

2) The internal energy of air in 4 m × 4 m × 3 m sized room at 1 atmospheric pressure will be ___ ×
106 J.
(Consider air as diatomic molecule)

3) A ray of light suffers minimum deviation when incident on a prism having angle of the prism equal
to 60°. The refractive index of the prism material is . The angle of incidence (in degrees) is _____.

4) The length of a light string is 1.4 m when the tension on it is 5 N. If the tension increases to 7 N,
the length of the string is 1.56 m. The original length of the string is _____ m.

5) A satellite of mass 1000 kg is launched to revolve around the earth in an orbit at a height of 270
km from the earth's surface. Kinetic energy of the satellite in this orbit is ________ × 1010 J.
(Mass of earth = 6 × 1024 kg, Radius of earth = 6.4 × 106 m, Gravitational constant = 6.67 × 10–11
Nm2 kg–2)

PART-2 : CHEMISTRY

SECTION-I

1) When a concentrated solution of sulphanilic acid and 1-naphthylamine is treated with nitrous acid
(273 K) and acidified with acetic acid, the mass (g) of 0.1 mole of product formed is :
(Given molar mass in g mol–1 H : 1, C : 12, N : 14, O : 16, S : 32)

(A) 343
(B) 330
(C) 33
(D) 66

2) The d-orbital electronic configuration of the complex among [Co(en)3]3+, [CoF6]3–, [Mn(H2O)6]2+ and
[Zn(H2O)6]2+ that has the highest CFSE is :

(A)

(B)

(C)

(D)

3) Given below are two statements :

Statement (I) : Neopentane forms only one monosubstituted derivative.
Statement (II) : Melting point of neopentane is higher than n-pentane
In the light of the above statements, choose the most appropriate answer from the options given
below :

(A) Statement I is correct but Statement II is incorrect

(B) Both Statement I and Statement II are correct
(C) Both Statement I and Statement II are incorrect
(D) Statement I is incorrect but Statement II is correct

4) Which among the following molecules is (a) involved in sp3d hybridization, (b) has different bond
lengths and (c) has lone pair of electrons on the central atom ?

(A) PF5
(B) XeF4
(C) SF4
(D) XeF2

5) Formation of Na4[Fe(CN)5NOS], a purple coloured complex formed by addition of sodium

nitroprusside in sodium carbonate extract of salt indicates the presence of :

(A) Sodium ion

(B) Sulphate ion
(C) Sulphide ion
(D) Sulphite ion

6) In 3, 3-dimethylhex-1-ene-4-yne, there are ____ sp3, ______ sp2 and ______ sp hybridised carbon
atoms respectively :

(A) 4, 2, 2
(B) 3, 3, 2
(C) 2, 4, 2
(D) 2, 2, 4
7) Which of the following statements are true ?
(A) The subsidiary quantum number ℓ describes the shape of the orbital occupied by the electron.

(B) is the boundary surface diagram of the 2px orbital.

(C) The + and – signs in the wave function of the 2px orbital refer to charge.
(D) The wave function of 2px orbital is zero everywhere in the xy plane.

(A) (B) and (D) only

(B) (A), (B) and (C) only
(C) (C) and (D) only
(D) (A) and (B) only

8) The type of hybridization and the magnetic property of [MnCl6]3– are :

(A) d2sp3, paramagnetic with four unpaired electrons

(B) sp3d2, paramagnetic with four unpaired electrons
(C) d2sp3, paramagnetic with two unpaired electrons
(D) sp3d2, paramagnetic with two unpaired electrons

9) Consider the following reactions. From these reactions which reaction will give carboxylic acid as
a major product ?

(A)

(B)

(C)

(D)

(E)
Choose the correct answer from the options given below :

(A) A and D only

(B) A, B and E only
(C) B, C and E only
(D) B and E only

10) Electronic configuration of four elements A, B, C and D are given below :

(A) 1s22s22p3 (B) 1s22s22p4
(C) 1s22s22p5 (D) 1s22s22p2
Which of the following is the correct order of increasing electronegativity (Pauling's scale) ?

(A) A < D < B < C

(B) A < C < B < D
(C) A < B < C < D
(D) D < A < B < C

11) Match List-I with List-II

List-I List-II
(Purification technique) (Mixture of organic compounds)

(A) Distillation (simple) (I) Diesel + Petrol

(B) Fractional distillation (II) Aniline + Water

Distillation under reduced

(C) (III) Chloroform + Aniline
pressure

(D) Steam distillation (IV) Glycerol + Spent-lye

Choose the correct answer from the options given below :
(A) (A)-(II), (B)-(III), (C)-(IV), (D)-(I)
(B) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
(C) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
(D) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)

12) 'x' g of NaCl is added to water in a beaker with a lid. The temperature of the system is raised
from 1°C to 25°C. Which out of the following plots, is best suited for the change in the molarity (M)
of the solution with respect to temperature ?[Consider the solubility of NaCl remains unchanged
over the temperature range]

(A)

(B)

(C)
(D)

13) Arrange the following in order of magnitude of work done by the system / on the system at
constant temperature :
(a) |wreversible| for expansion in infinite stage.
(b) |wirreversible| for expansion in single stage.
(c) |wreversible| for compression in infinite stage.
(d) |wirreversible| for compression in single stage.
Choose the correct answer from the options given below :

(A) a > b > c > d

(B) d > c = a > b
(C) c = a > d > b
(D) a > c > b > d

14) Reactant A converts to product D through the given mechanism (with the net evolution of heat) :
A → B slow ; ΔH = +ve
B → C fast ; ΔH = –ve
C → D fast ; ΔH = –ve
Which of the following represents the above reaction mechanism ?

(A)

(B)

(C)
(D)

15) The nature of oxide (TeO2) and hydride (TeH2) formed by Te, respectively are :

(A) Oxidising and acidic

(B) Reducing and basic
(C) Reducing and acidic
(D) Oxidising and basic

16) Match List-I with List-II

List-I List-II
(Reaction) (Name of reaction)

(A) (I) Lucas reaction

(B) (II) Finkelstein reaction

(C) (III) Fittig reaction

(D) (IV) Gatterman reaction

Choose the correct answer from the options given below :

(A) (A)-(III), (B)-(II), (C)-(IV), (D)-(I)
(B) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
(C) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
(D) (A)-(IV), (B)-(I), (C)-(II), (D)-(III)

17) Consider the following chemical equilibrium of the gas phase reaction at a constant temperature
:
A(g)⇌ B(g) + C(g)
If p being the total pressure, Kp is the pressure equilibrium constant and α is the degree of
dissociation, then which of the following is true at equilibrium ?

(A) If p value is extremely high compared to Kp, α ≈ 1

(B) When p increases α decreases
(C) If Kp value is extremely high compared to p, α becomes much less than unity
(D) When p increases α increases

18) Which of the following graphs correctly represents the variation of thermodynamic properties of
Haber's process ?
(A)

(B)

(C)

(D)

19) A tetrapeptide "x" on complete hydrolysis produced glycine (Gly), alanine (Ala), valine (Val),
leucine (Leu) in equimolar proportion each. The number of tetrapeptides (sequences) possible
involving each of these amino acids is

(A) 16
(B) 32
(C) 8
(D) 24

20) In Dumas' method for estimation of nitrogen, 0.5 gram of an organic compound gave 60 mL of
nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of
nitrogen in the compound (Aqueous tension at 300 K = 15 mm Hg) is

(A) 1.257
(B) 20.87
(C) 18.67
(D) 12.57

SECTION-II

1) For the reaction A → B the following graph was obtained. The time required (in seconds) for the
concentration of A to reduce to 2.5 g L–1 (if the initial concentration of A was 50 g L–1) is _______.
(Nearest integer)
Given : log 2 = 0.3010

2) 0.2 % (w/v) solution of NaOH is measured to have resistivity 870.0 mΩ m. The molar conductivity
of the solution will be _______×102 mS dm2 mol–1.
(Nearest integer)

3)
Consider the above sequence of reactions. 151 g of 2-bromopentane is made to react. Yield of major
product P is 80% whereas Q is 100%.
Mass of product Q obtained is ________g.
(Given molar mass in g mol–1 H: 1, C : 12, O : 16, Br : 80)

4) When 1 g each of compounds AB and AB2 are dissolved in 15 g of water separately, they increased
the boiling point of water by 2.7 K and 1.5 K respectively. The atomic mass of A (in amu)
is_______×10–1(Nearest integer)
(Given : Molal boiling point elevation constant is 0.5 K kg mol–1)

5) The spin-only magnetic moment value of Mn+‑ ion formed among Ni, Zn, Mn and Cu that has the
least enthalpy of atomisation is_____. (in nearest integer)
Here n is equal to the number of diamagnetic complexes among K2 [NiCl4], [Zn (H2O)6] Cl2,
K3[Mn(CN)6] and [Cu(PPh3)3I]

PART-3 : MATHEMATICS

SECTION-I

1) If the image of the point P(1, 0, 3) in the line joining the points A(4, 7, 1) and B(3, 5, 3) is Q(α, β,
γ), then α + β + γ is equal to

(A)
(B)

(C) 18
(D) 13

2) Let ƒ : [1, ∞) → [2, ∞) be a differentiable function, If for all x ≥ 1,

then the value of ƒ(3) is :

(A) 18
(B) 32
(C) 22
(D) 26

3) The number of terms of an A.P. is even; the sum of all the odd terms is 24, the sum of all the even

terms is 30 and the last term exceeds the first by . Then the number of terms which are integers
in the A.P. is :

(A) 4
(B) 10
(C) 6
(D) 8

4) Let A = {1, 2, 3,...., 10} and R be a relation on A such that R = {(a, b) : a = 2b + 1}. Let (a1, a2),
(a2, a3), (a3, a4), ...., (ak, ak+1) be a sequence of k elements of R such that the second entry of an
ordered pair is equal to the first entry of the next ordered pair. Then the largest integer k, for which
such a sequence exists, is equal to :

(A) 6
(B) 7
(C) 5
(D) 8

5) If the length of the minor axis of an ellipse is equal to one fourth of the distance between the foci,
then the eccentricity of the ellipse is :

(A)

(B)

(C)

(D)
6) The line L1 is parallel to the vector and passes through the point (7, 6, 2) and the
line L2 is parallel to the vector and passes through the point (5, 3, 4). The shortest
distance between the lines L1 and L2 is :

(A)

(B)

(C)

(D)

7) Let (a, b) be the point of intersection of the curve x2 = 2y and the straight line y –2x –6 = 0 in

the second quadrant. Then the integral dx is equal to :

(A) 24
(B) 27
(C) 18
(D) 21

8) If the system of equation

2x + λy + 3z = 5
3x + 2y – z = 7
4x + 5y + μz = 9
has infinitely many solutions, then (λ2 + μ2) is equal to :

(A) 22
(B) 18
(C) 26
(D) 30

9) If then the number of solutions of is

equal to

(A) 6
(B) 8
(C) 10
(D) 7

10) Given three indentical bags each containing 10 balls, whose colours are as follows :
A person chooses a bag at random and takes out a ball. If the ball is Red, the probability that it is
from bag I is p and if the balls is Green, the probability that it is from bag III is q, then the value of

is :

(A) 6
(B) 9
(C) 7
(D) 8

11) If the mean and the variance of 6, 4, a, 8, b, 12, 10, 13 are 9 and 9.25 respectively, then a + b +
ab is equal to :

(A) 105
(B) 103
(C) 100
(D) 106

12) If the domain of the function is (a, b), then (1 + a)2 + b2 is

equal to :

(A) 26
(B) 29
(C) 25
(D) 30

13) dx – 3 loge is equal to :

(A) 2 + + loge

(B) 2 – – loge

(C) 2 + – loge

(D) 2 – + loge

14) If is finite, then (a+b) is equal to :

(A)

(B) 0

(C)

(D) –1

15) If . , then α is equal to :

(A) 15
(B) 11
(C) 24
(D) 20

16) The number of ways, in which the letters A, B, C, D, E can be placed in the 8 boxes of the figure
below so that no row remains empty and at most one letter can be placed in a box, is :

(A) 5880
(B) 960
(C) 840
(D) 5760

17) Let the point P of the focal chord PQ of the parabola y2 = 16x be (1, –4). If the focus of the
parabola divides the chord PQ in the ratio m : n, gcd(m, n) = 1, then m2 + n2 is equal to :

(A) 17
(B) 10
(C) 37
(D) 26

18) Let , and a vector be such

that and . If , then is equal to :

(A) 18
(B) 12
(C) 9
(D) 15

19) Let the area of the triangle formed by a straight Line L : x + by + c = 0 with co-ordinate axes be
48 square units. If the perpendicular drawn from the origin to the line L makes an angle of 45° with
the positive x-axis, then the value of b2+c2 is :

(A) 90
(B) 93
(C) 97
(D) 83

20) Let A be a 3 × 3 real matrix such that A2(A – 2I) – 4(A – I) = O, where I and O are the identity and
null matrices, respectively. If A5 = αA2 + βA + γI, where α, β and γ are real constants, then α + β + γ
is equal to:

(A) 12
(B) 20
(C) 76
(D) 4

SECTION-II

1) Let y = y(x) be the solution of the differential equation +2y sec2 x = 2sec2x + 3tan x.sec2 x such

that y(0) = . Then is equal to __________.

2) If the sum of the first 10 terms of the series is , where

gcd(m, n) = 1, then m + n is equal to ________.

3) If y = cos , then (x – y)2 + 3y2 is equal to __________.

4) Let A(4, –2), B(1, 1) and C(9, –3) be the vertices of a triangle ABC. Then the maximum area of the
parallelogram AFDE, formed with vertices D, E and F on the sides BC, CA and AB of the triangle
ABC respectively, is __________.

5) If the set of all a ∈ R – {1}, for which the roots of the equation (1 – a)x2 + 2(a – 3)x + 9 = 0 are
positive is (–∞, –α] ∪[β, γ), then 2α + β + γ is equal to _________.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D A B A D A B D B C C C B A D B B B D C

SECTION-II

Q. 21 22 23 24 25
A. 1 12 45 1 3

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A B C C A D B D D D B B A A B B A D D

SECTION-II

Q. 46 47 48 49 50
A. 43 23 184 25 0

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B B A C A A A C A C B A B A D D A D C A

SECTION-II

Q. 71 72 73 74 75
A. 21 441 3 3 7
 SOLUTIONS

PART-1 : PHYSICS

1) A : Since polar dielectrics are randomly oriental .

R : If is absent, polar dielectric remain polar & are randomly oriented.

2) Voltage sensitivity =

Ratio

3) Diameter is given as R.
∴ Radius = R/2

4)
Ui = 2 × 4pR2T
Uf = 4pr2T = 4pR2T22/3
∴ Heat lost =

5) Magnetic field does not work

∴ Speed will not charge, so De-Broglie wavelength remains same.

6)

So y = A cos (kx – ωt)

7)

Q = AT
I=A
μ0 = MLT–2 A–2
P = Qx µ0y Iz = [AT]x [MLT–2A–2]y [A]z
MLT–1 = MyLyTx–2y A–2y+z+x
Now; y = 1
x – 2y = –1
– 2y + z = 0
∴x=y=z=1

8)

9)
Using ΔV = E (Δd)
V = E (10)

10) Q = ΔU + W = 0 ⇒ –ΔU = W
WD = –nCvΔT ⇒ |WD| = nCvΔT ∝ T2 – T1
∴ B & E [Only possibility]

11) & z = 3 for Li+2 and n = 1

∴x=3

12)
EB = BEreactant – BEproduct
= 1.1 × 2 + 1.1 × 2 – 7 × 4 = –23.6 MeV
= Q = 23.6 MeV

13)
14)

Using

15)

Displacement = 2r
Distance = 2πr + πr = 3πr

16)
T1 = mgcos30°
T2 = mgsin30°

17) This will happen when

18)

19)
 20)

21)
FR = Iα

= 1 kg–m2

22) To find the internal energy of gas in the room.

23) , since A = 60° ∴ δm = 30°

δm = 2i – A [as i = e]
⇒ i = 45°

24)

∴ ℓ0 = 1m

25)

= 3×1010 J

PART-2 : CHEMISTRY
26)

0.1 mole of red-azo dye (Molar Mass = 327 gm/mol) will have 32.7 gm mass. Nearly 33 gm.

27)

In [Co(en)3]+3 S.F.L. is present and hence highest value of CFSE

In rest all complexes WFL is present hence CFSE will be low.
[Co(en)3]+3 ⇒ Co+3 and en (SFL)
Co+3 ⇒ [Ar]3d6

28) Both Statement-I and Statement-II are correct.

29)
XeF4 :- sp3d2 Hybridisation

30)

31)
4-sp3, 2-sp2, 2-sp

32) (A) Azimuthal quantum number (ℓ) indicates the shape of orbital occupied by the electron

(B)
(C) The + and – sign in the wave function of 2px orbital refer to the sign (Phase) of the wave
function , not the charge
(D) The wave function of 2px orbital will be zero in yz plane (Nodal plane).

33) [MnCl6]3– contains Mn+3

Mn+3 :- [Ar]3d4
Ligand ⇒ Cl– (WFL)
 Hybridisation = sp3d2
4 unpaired electrons

34) (A)
Under mild condition amide is formed because this reaction is typically slow if further more
heat will supplied then it gets convert in to –COOH.

(B)

(C)

(D)

(E)

35) N :- 1s2 2s2 2p3 (Electronegativity = 3)

O :- 1s2 2s2 2p4 (Electronegativity = 3.5)
F :- 1s2 2s2 2p5 (Electronegativity = 4)
C :- 1s2 2s2 2p2 (Electronegativity = 2.55)
Correct order = C > B > A > D

36)

List-II
List-I (Purification
(Mixture of organic
technique)
compounds)

(A) Distillation (simple) (III) Chloroform + Aniline

Fractional
(B) (I) Diesel + Petrol
distillation

Distillation under
(C) (IV) Glycerol + Spent-lye
reduced pressure

(D) Steam distillation (II) Aniline + Water

37)

Molarity =
Hence
1°C 4°C 25°C

38) For isothermal process

|Wreversible|expansion = |Wreversible|compression

= – nRT ln
|Wirreversible|expansion < |Wirreversible|compression
d>c=a>b
|Wirreversible|expansion = – Pext (Vf – Vi)

(single step irreversible)

Graphical representation
We can compare work by area of PV graph.
 39) A→B Slow
ΔH = +ve
B→C Fast
ΔH = –ve
C→D
ΔH = –ve

40)

TeO2 is oxidizing in nature because it can be reduced from +4 oxidation state to lower
oxidation state.
TeH2 due to less bond dissociation energy easily breaks and hence acidic in nature.

41)

List-I List-II
(Reaction) (Name of reaction)

(A) (III) Fittig reaction

(B) (IV) Gatterman reaction

(C) (II) Finkelstein reaction

(D) (I) Lucas reaction

42) A(g) B(g) + C(g)

t=0 a 0 0
t = t a (1 – α) aα aα
a moles of A(g) taken initially and at time
Now moles fraction of A(g), B(g) and C(g) are

Now if P is total pressure then partial pressure of A(g), B(g) and C(g) are
As KP is only function of temperature.
So as P α

43) N2(g) + 3H2(g) → 2NH3

ΔH° = –ve
ΔS° = –ve
(As gaseous moles decreases).

(1) As temperature increases , decreases

(2) ΔG° = –RT ln Keq

R ln Keq = –
(on increasing temperature in exothermic reaction Keq decreases)
ΔH° and ΔS° are almost constant with temperature.

44)

The number of tetrapeptides (sequences)

possible involving each of these amino acids (glycine, alanine, valine, leucine) ; It has three (3)
peptides linkage the number of permutations in which they can be arranged
=4×3×2×1
= 24

45) Pressure of N2 gas = (715 – 15)

= 700 mmHg

= 2.24 × 10–3 mol

Mass of N2 = 2.24 × 10–3 × 28g
= 0.06272 g

%N2 =

46)

Allen Ans. (BONUS)

NTA Ans. (43)
As it is difficult to predict order using data provided in graph.
For specific time interval 0 - 5 sec, 5 – 10 sec and 10 – 15 sec. order comes to be zero, but
graph is not a straight line. Assuming 1st order kinetics
Time required to reduce to 2.5 g/L

= 43.3 sec.

47)

Given : Concentration of NaOH = 0.2% (w/v)

∴ 0.2 g of NaOH in 100 ml of solution.

Molarity of NaOH solution = × 1000

M
Given resistivity of solution = 870 m ohm m
= 870 × 10–3 ohm m
= 870 × 10–3 × 10 ohm dm
= 870 × 10–2 ohm dm
= 8.7 ohm dm
Now conductivity

ohm–1 dm–1
Now molar conductivity of solution is

= 2.29 S dm2 mol–1

3 2 –1
2.29 × 10 m S dm mol
= 22.9 × 102 m S dm2 mol–1
= 23 × 102 m S dm2 mol–1

48)
Molecular mass of Q = 230g mol–1
Mass of Q = 0.8 × 230
= 184 g

49)
 For AB
ΔTb = 2.7 K
2.7 = 1 × 0.5 × m

Let molar mass of AB = x.

So
x = 12.34
For AB2
ΔTb = 1.5 K
1.5 = 1 × 0.5 × m
m=3
Let molar mass of AB2 = y

So × 1000 = 3

y = 22.22
Now let a and b be atomic masses of A and B respectively, then
A + b = 12.34 …. (i)
A + 2b = 22.22 …. (ii)
B = 22.22 – 12.34 = 9.88
Now a = 12.34 – 9.88 = 2.46
= 24.6 × 10–1 = 25 × 10–1

50)

K2[NiCl4] ⇒ sp3 , Paramagnetic

[Zn(H2O)6]Cl2 ⇒ sp3d2, Diamagnetic
K3[Mn(CN)6] ⇒ d2sp3, Paramagnetic
[Cu(PPh3)3I] ⇒ sp3, Diamagnetic
Hence the value of n is 2
Least value of enthalpy of atomisation among Ni, Zn, Mn and Cu is of Zn
Zn+2 :- [Ar]3d10
μ=0

PART-3 : MATHEMATICS

51) P(1, 0, 3)
A(4, 7, 1), B(3, 5, 3)

Line AB ⇒
Let foot of perpendicular of P on AB be
R ≡ (λ + 3, 2λ + 5, –2λ + 3)
⇒ (λ + 3 – 1) (1) + (2λ + 5 – 0) (2) + (–2λ + 3 – 3)
(–2) = 0
⇒ λ + 2 + 4λ + 10 + 4λ = 0
52)
⇒ 10f(x) = 5f(x) + 5x f ′ (x) – 5x4
⇒ f(x) + x4 = x f ′ (x)

Put x = 1 in given equation

⇒ 0 = 5f(1) – 1 – 9 ⇒ f(1) = 2

⇒ f(3) = 32

53)

a2 + a4 + ... + an = 30 ....(1)
a1 + a3 + ... + an – 1 = 24 ....(2)
(1) – (2)
(a2 – a1) + (a4 – a3) ... (an – an – 1) = 6

⇒ d = 6 ⇒ nd = 12

an – a1 = (n – 1)d =

⇒ nd – d = ⇒ 12 – =d

⇒d= ,n=8
Sum of odd terms =

A.P. ⇒
no. of integer terms = 4

54)

a = 2b + 1
2b = a – 1
R = {(3, 1), (5, 2), ..., (99, 49)}
Let (2m + 1, m), (2λ – 1, λ) are such ordered pairs.
According to the condition
m = 2λ – 1 ⇒ m = odd number
⇒ 1st element of ordered pair (a, b)
a = 2(2λ – 1) + 1 = 4λ – 1
Hence a ∈ {3, 7, ..., 99}
⇒ λ ∈ {1, 2, ..., 25}
⇒ set of sequence

2nd element of each ordered pair =

For maximum number of ordered pairs in such sequence

or 2 ; 1 ≤ λ ≤ 25
λ = 2 or λ = 3.2r – 2
r–1

Case-I : λ = 2r – 1
λ = 2, 22, 23, 24
r = 2, 3, 4, 5
Hence maximum value of r is 5 when λ = 16
Case-II : λ = 3.2r – 2
λ = 3, 6, 12, 24
r = 2, 3, 4, 5
Hence maximum value of r is 5 when λ = 24

55)
56)

Distance between skew lines

57)

x2 = 2y & y = 2x + 6
x2 = 4x + 12

x2 – 4x – 12 = 0 ⇒
∴ (6, 18) & (–2, 2)
Here (6, 18) Rejected because (a, b) lies in 2nd quadrant
∴ a = –2 & b = 2

∴I=

∴
2I = 48

58)
⇒ 2(2μ + 5) + λ (–4 –3 μ) + 3 (7) = 0
⇒ 4μ –3λμ –4λ + 31 = 0 ......(1)

⇒ 2(–17) + λ (1) + 5 (7) = 0

⇒ λ = –1
from equation (1)
4μ + 3μ + 4 + 31 = 0 ⇒
∴

59)

cosecθ = 2 or

∴ sinθ = or

∴ sinθ = has 3 solutions & also sinθ = has 3 solutions in

60)

p=P = =

q= = =

∴ + =7

61)

∵ mean = 9
∴ 53 + a + b = 72
⇒ a + b = 19

∵ σ2 = and + σ2 =

⇒ 81 + =
⇒ 648 + 74 = 529 + a2 + b2
⇒ a2 + b2 = 193
∵ a + b = 19 ⇒ a2 + b2 + 2ab = 361
⇒ 2ab = 168
⇒ ab = 84
∴ a + b + ab = 103

62) x + |x| > 0 ⇒ x ∈ (0, ∞) ....(1)

& 10 + 3x – x2 > 0
⇒ x2 – 3x – 10 < 0
⇒ x ∈ (–2, 5) ....(2)
from (1) & (2) x ∈ (0, 5)
∴a=0&b=5
∴ (1 + a2) + b2 = 1 + 25 = 26

63) 4 – 3ln

= – ln 3

=2

– – ln3

=2 – ln3

= 2 + 3 ln 3 – ln 3 – – ln (1 + )–
=2– – ln(1+ )

64) = finite

L=

∴ 1 + a – b = 0 and 2 + 8a = 0 ⇒ a = –
b=a+1
= +1=

∴a+b= + =

65)

∴ α = 20

66)
= Total – [(All in R1 and R3) + (All in R2 and R3) + (All in R1 and R2)]

= 5760

67) y2 = 16x ; a = 4 focus S ≡ (4, 0)

2at1 = –4
⇒ 2(4)t1 = –4

⇒ t1 =
∵ t1t2 = –1
⇒ t2 = 2
∴ = (16, 16)
Let, S divides PQ internally in λ : 1 ratio

∴ m2 + n2 = 1 + 16 = 17

68) ,

⇒
⇒

∴
= –2 – 12 – 1 = –15

69)

∴ area of triangle =

∵ –c =
⇒ b = 1 ∴ c2 = 96
∴ b2 + c2 = 97

70)

A3 – 2A2 – 4A + 4I = 0
A3 = 2A2 + 4A – 4I
A4 = 2A3 + 4A2 – 4A
= 2 (2A2 + 4A – 4I) + 4A2 – 4A
A4 = 8A2 + 4A – 8I
A5 = 8A3 + 4A2 – 8A
= 8(2A2 + 4A – 4I) + 4A2 – 8A
A5 = 20A2 + 24A – 32I
∴ α = 20, β = 24, γ = –32
∴ α + β + γ = 12

71)
= e2tanx
Solution of diff. eq.

x = 0, y =
c=1

Then

72)

_____________

m + n = 441
73)

3(4 – x2) = x2 + 16y2 – 8xy

12 – 3x2 = x2 + 16y2 – 8xy
4x2 + 16y2 – 8xy = 12
x2 + 4y2 – 2xy = 3
x2 + y2 – 2xy – 3y2 = 3
(x – y)2 + 3y2 = 3

74) Area of ΔABC =

= 6 square units

Maximum area of AFDE = = 3 sq. units

75) Both the roots are positive

D≥0
4(a – 3)2 – 4×9(1 – a) ≥ 0
a2 – 6a + 9 – 9 + 9a ≥ 0
a2 + 3a ≥ 0
a(a + 3) ≥ 0
a ∈ (–∞, –3] ∪ [0, ∞) ……(i)

a ∈ (–∞, 1) ∪ (3, ∞) ……..(ii)

f(0) = 9 > 0
Equation (i) ∩ (ii)
a ∈ (–∞, –3] ∪ [0, 1)
2α + β + γ – 6 + 0 + 1 = 7