22-01-2026

1001CJM220126MRG JM

PART-1 : MATHEMATICS

SECTION-I

1) Let and . Let the projection of the vector on

the diagonal of the parallelogram ABCD be of length one unit. If α, β, where α > β, be the roots
of the equation λ2x2 – 6λx + 5 = 0, then 2α – β is equal to

(A) 1
(B) 4
(C) 3
(D) 6

2) Let the relation R on the set M = {1, 2, 3,.......16} be given by R = {(x, y) : 4y = 5x – 3, x, y ∈ M}.
Then the minimum number of elements required to be added in R, in order to make the relation
symmetric, is equal to

(A) 1
(B) 2
(C) 4
(D) 3

3) Let the line x = –1 divide the area of the region in the ratio m : n, gcd
(m, n) = 1. Then m + n is equal to

(A) 25
(B) 28
(C) 26
(D) 27

4) Two distinct numbers a and b are selected at random from 1, 2, 3,......, 50. The probability, that
their product ab is divisible by 3, is

(A)

(B)

(C)

(D)
5) Let f(x) = x2025 – x2000, x ∈ [0, 1] and the minimum value of the function f(x) in the interval [0, 1] be
(80)80 (n)–81. Then n is equal to

(A) –81
(B) –40
(C) –41
(D) –80

6) Let P(α, β, γ) be the point on the line at a distance from the point (1, –1,

0) and nearer to the origin. Then the shortest distance, between the lines and

, is equal to

(A)

(B)

(C)

(D)

7) If a random variable x has the probability distribution

x 0 1 2 3 4 5 6 7

p(x) 0 2k k 3k 2k2 2k k2+k 7k2

then P(3 < x ≤ 6) is equal to
(A) 0.34
(B) 0.22
(C) 0.64
(D) 0.33

8) The number of distinct real solutions of the equation x|x + 4| + 3|x + 2| + 10 = 0 is

(A) 3
(B) 1
(C) 0
(D) 2

9) Let ƒ : [1, ∞) → be a differentiable function. If for all x ≥ 1, then the

value of f(2) – f(3) is

(A) –4
(B) –3
(C) 4
(D) 3

10) If the line αx + 2y = 1, where α ∈ , does not meet the hyperbola x2 – 9y2 = 9, then a possible
value of α is :

(A) 0.6
(B) 0.8
(C) 0.5
(D) 0.7

11) If the image of the point P (1, 2, a) in the line is Q(5, b, c), then a2 + b2 + c2
is equal to

(A) 293
(B) 264
(C) 298
(D) 283

12) Let the set of all values of r, for which the circles (x + 1)2 + (y + 4)2 = r2 and x2 + y2 – 4x – 2y – 4
= 0 intersect at two distinct points be the interval (α, β). Then αβ is equal to

(A) 25
(B) 20
(C) 21
(D) 24

13) If , then the determinant of the matrix (A2025 – 3A2024 + A2023) is

(A) 28
(B) 12
(C) 24
(D) 16

14) If the domain of the function f(x) = is (–∞, α] ᑌ [β, γ) – {δ}, then
6(α + β + γ + δ) is equal to

(A) 70
(B) 66
(C) 67
(D) 68
15) The value of , where [•] denotes the greatest integer function, is

(A)

(B)

(C)

(D)

16) The coefficient of x48 in (1 + x) + 2 (1 + x)2 + 3 (1 + x)3 + .... + 100 (1 + x)100 is equal to :

100 100
(A) 100. C49 – C50
100
(B) C50 + 101C49
100 100
(C) 100. C49 – C48
101 100
(D) 100. C49 – C50

17) If the chord joining the points P1(x1, y1) and P2(x2, y2) on the parabola y2 = 12x subtends a right
angle at the vertex of the parabola, then x1x2 – y1y2 is equal to

(A) 288
(B) 280
(C) 284
(D) 292

18) The number of solutions of tan–14x + tan–16x = where is equal to

(A) 3
(B) 0
(C) 1
(D) 2

19) Let the solution curve of the differential equation xdy – ydx = dx, x > 0, y(1) = 0, be y
= y(x). Then y(3) is equal to

(A) 4
(B) 6
(C) 1
(D) 2

20) If the sum of the first four terms of an A.P. is 6 and the sum of its first six terms is 4, then the
sum of its first twelve terms is
(A) –20
(B) –24
(C) –26
(D) –22

SECTION-II

1) Let and , . If (7 – 7α + 9β)20 + (9 + 7α – 7β)20 + (–7 + 9α + 7β)20

20 10
+ (14 + 7α + 7β) = m , then m is ________.

2) Let A be a 3 × 3 matrix such that A + AT = O. If and

α β γ
det(adj(2adj (A + I))) = (2) .(3) .(11) , α, β, γ are non-negative integers, then α + β + γ is equal to
______.

3) If , where pi and
qi are positive integers with gcd(pi, qi) = 1 for i = 1, 2, 3, 4 and C is the constant of integration, then

is equal to _______.

4) If , where α, β ∈ , then α + β is equal to _______.

5) Let ABC be a triangle. Consider four points p1, p2, p3, p4 on the side AB, five points p5, p6, p7, p8, p9
on the side BC and four points p10, p11, p12, p13 on the side AC. None of these points is a vertex of the
triangle ABC. Then the total number of pentagons, that can be formed by taking all the vertices from
the points p1, p2, .... p13 , is ________.

PART-2 : PHYSICS

SECTION-I

1) A solid sphere of mass 5 kg and radius 10 cm is kept in contact with another solid sphere of mass
10 kg and radius 20 cm. The moment of inertia of this pair of spheres about the tangent passing
through the point of contact is_________kg.m2.

(A) 0.36
(B) 0.72
(C) 0.18
(D) 0.63

2) 7.9 MeV α-particle scatters from a target material of atomic number 79. From the given data the
estimated diameter of nuclei of the target material is (approximately)________m.

(A) 5.76 × 10–14

(B) 1.44 × 10–13
(C) 2.88 × 10–14
(D) 1.69 × 10–12

3) Six point charges are kept 60° apart from each other on the circumference of a circle of radius R
as shown in figure. The net electric field at the centre of the circle is ________. (∈o is permittivity of

free space)

(A)

(B)

(C)

(D)

4) XPQY is a vertical smooth long loop having a total resistance R where PX is parallel to QY and
separation between them is ℓ. A constant magnetic field B perpendicular to the plane of the loop
exists in the entire space. A rod CD of length L (L > ℓ) and mass m is made to slide down from rest
under the gravity as shown in figure. The terminal speed acquired by the rod is_______m/s.
(g = acceleration due to gravity)

(A)

(B)

(C)

(D)

5) The escape velocity from a spherical planet A is 10 km/s. The escape velocity from another planet
B whose density and radius are 10% of those of planet A, is______m/s.

(A) 1000
(B)
(C)
(D)

6) A meter bridge with two resistances R1 and R2 as shown in figure was balanced (null point) at 40
cm from the point P. The null point changed to 50 cm from the point P, when 16Ω resistance is
connected in parallel to R2. The values of resistances R1 and R2 are______.

(A)

(B)

(C)

(D)

7) A projectile is thrown upward at an angle 60° with the horizontal. The speed of the projectile is 20
m/s when its direction of motion is 45° with the horizontal. The initial speed of the projectile is _____
m/s.

(A)
(B) 40
(C)
(D)

8) Given below are two statements :

Statement I : Pressure of fluid is exerted only on a solid surface in contact as the fluid-pressure
does not exist everywhere in a still fluid.
Statement II: Excess potential energy of the molecules on the surface of a liquid, when compared
to interior, results in surface tension.
In the light of the above statements, choose the correct answer from the options given below.

(A) Statement I is true but Statement II is false

(B) Both Statement I and Statement II are false
(C) Both Statement I and Statement II are true
(D) Statement I is false but Statement II is true

9) Find the correct combination of A, B, C and D inputs which can cause the LED to glow.

(A) 0100
(B) 0011
(C) 1000
(D) 1101

10) Net gravitational force at the centre of a square is found to be F1 when four particles having
mass M, 2M, 3M and 4M are placed at the four corners of the square as shown in figure and it is F2

when the positions of 3M and 4M are interchanged. The ratio is . The value of α is _____.

(A) 2
(B) 3
(C) 1
(D)

11) The minimum frequency of photon required to break a particle of mass 15.348 amu into 4α
particles is ____ kHz. [mass of He nucleus = 4.002 amu, 1 amu = 1.66 × 10–27 kg, h = 6.6 × 10–34 J.s
and c = 3 × 108 m/s]

(A) 9 × 1019
(B) 9 × 1020
(C) 14.94 × 1020
(D) 14.94 × 1019

12) A cylindrical tube AB of length ℓ, closed at both ends contains an ideal gas of 1 mol having
molecular weight M. The tube is rotated in a horizontal plane with constant angular velocity ω about
an axis perpendicular to AB and passing through the edge at end A, as shown in the figure. If PA and
PB are the pressures at A and B respectively, then (Consider the temperature is same at all points in

the tube)

2 2
(A) PB = PA exp (Mω ℓ / 2RT)
(B) PB = PA
2 2
(C) PB = PA exp (Mω ℓ /3RT)
2 2
(D) PB = PA exp (Mω ℓ /RT)

13) Rods x and y of equal dimensions but of different materials are joined as shown in figure.
Temperatures of end points A and F are maintained at 100 °C and 40 °C respectively. Given the
thermal conductivity of rod x is three times of that of rod y, the temperature at junction points B and

E are (close to) :

(A) 89 °C and 73 °C respectively

(B) 80 °C and 60 °C respectively
(C) 80 °C and 70 °C respectively
(D) 60 °C and 45 °C respectively

14) A thin convex lens of focal length 5 cm and a thin concave lens of focal length 4 cm are
combined together (without any gap) and this combination has magnification m1 when an object is
placed
10 cm before the convex lens. Keeping the positions of convex lens and object undisturbed a gap of 1
cm is introduced between the lenses by moving the concave lens away, which lead to a change in
magnification of total lens system to m2. The value of is ______.

(A)

(B)

(C)

(D)

15) Consider an equilateral prism (refractive index ). A ray of light is incident on its one surface at
a certain angle i. If the emergent ray is found to graze along the other surface then the angle of
refraction at the incident surface is close to ____.

(A) 15°
(B) 20°
(C) 40°
(D) 30°

16) The volume of an ideal gas increases 8 times and temperature becomes (1/4)th of initial
temperature during a reversible change. If there is no exchange of heat in this process (ΔQ = 0) then
identify the gas from the following options (Assuming the gases given in the options are ideal gases)
:

(A) CO2
(B) O2
(C) NH3
(D) He

17) Electric field in a region is given by , where A = 10 V/m2 and B = 5 V/m2. If the
electric potential at a point (10, 20) is 500 V, then the electric potential at origin is ______ V.

(A) 1000
(B) 500
(C) 2000
(D) 0

18) A simple pendulum has a bob with mass m and charge q. The pendulum string has negligible
mass. When a uniform and horizontal electric field is applied, the tension in the string changes.
The final tension in the string, when pendulum attains an equilibrium position is _____.
(g : acceleration due to gravity)

(A) mg – qE
(B) mg + qE

(C)
(D)

19) Match the LIST-I with LIST-II.

List-I List-II

A. Spring constant I. ML2T–2K–1

0
B. Thermal conductivity II. ML T–2

C. Boltzmann constant III. ML2T–3A–2

D. Inductive reactance IV. MLT–3K–1

Choose the correct answer from the options given below :
(A) A-II, B-I, C-IV, D-III
(B) A-I, B-IV, C-II, D-III
(C) A-III, B-II, C-IV, D-I
(D) A-II, B-IV, C-I, D-III

20) Three identical coils C1, C2 and C3 are closely placed such that they share a common axis. C2 is
exactly midway. C1 carries current I in anti-clockwise direction while C3 carries current I in
clockwise direction. An induced current flows through C2 will be in clockwise direction when

(A) C1 and C3 move with equal speeds away from C2

(B) C1 moves towards C2 and C3 moves away from C2
(C) C1 moves away from C2 and C3 moves towards C2
(D) C1 and C3 move with equal speeds towards C2

SECTION-II

1) Two loudspeakers (L1 and L2) are placed with a separation of 10 m, as shown in figure. Both
speakers are fed with an audio input signal of same frequency with constant volume. A voice
recorder, initially at point A, at equidistance to both loud speakers, is moved by 25 m along the line
AB while monitoring the audio signal. The measured signal was found to undergo 10 cycles of
minima and maxima during the movement. The frequency of the input signal is _____ Hz.

(Speed of sound in air is 324 m/s and = 2.23)

2)

The electric field of a plane electromagnetic wave, travelling in an unknown non-magnetic medium is
given by,
Ey = 20 sin (3 × 106x – 4.5 × 1014t) V/m
(where x, t and other values have S.I. units). The dielectric constant of the medium is ____.
(speed of light in free space is 3 × 108 m/s)

3) A parallel beam of light travelling in air (refractive index 1.0) is incident on a convex spherical
glass surface of radius of curvature 50 cm. Refractive index of glass is 1.5. The rays converge to a
point at a distance x cm from the centre of the curvature of the spherical surface. The value of x is
____ cm.

4) A circular disc has radius R1 and thickness T1. Another circular disc made of the same material

has radius R2 and thickness T2. If the moment of inertia of both discs are same and then

. The value of α is ____.

5) Inductance of a coil with 104 turns is 10 mH and it is connected to a dc source of 10 V with

internal resistance of 10Ω. The energy density in the inductor when the current reaches of its

0
maximum value is J/m3. The value of α is ___. (μ = 4π × 10–7 Tm/A).

PART-3 : CHEMISTRY

SECTION-I

1)

Consider the transition metal ions Mn3+, Cr3+, Fe3+ and Co3+ and all form low spin octahedral
complexes. The correct decreasing order of unpaired electrons in their respective d-orbitals of the
complexes is

(A) Cr3+ > Fe3+ > Co3+ > Mn3+

(B) Mn3+ > Fe3+ > Co3+ > Cr3+
(C) Fe3+ > Co3+ > Mn3+ > Cr3+
(D) Cr3+ > Mn3+ > Fe3+ > Co3+

2) The formal changes on the atoms marked as (1) to (4) in the Lewis representation of HNO3
molecule respectively are

(A) +1, 0, 0, –1
(B) 0, –1, 0, +1
(C) 0, +1, 0, –1
(D) 0, 0, –1, +1

3) Given below are two statements :

Statement I : Phenol on treatment with CHCl3/aq. KOH under refluxing condition, followed by
acidification produces p-hydroxy benzladehyde as the major product and o-hydroxy benzaldehyde as
the minor product.
Statement II : The mixture of p-hydroxybenzaldehyde and o-hydroxybenzaldehyde can be easily
separated through steam distillation.
In the light of the above statements, choose the correct answer from the options given below :

(A) Both Statement I and Statement II are false

(B) Statement I is true but Statement II is false
(C) Both Statement I and Statement II are true
(D) Statement I is false but Statement II is true

4) The energy required by electrons, present in the first Bohr orbit of hydrogen atom to be excited to
second Bohr orbit is ________ J mol–1.
Given : RH = 2.18 × 10–11 ergs.

(A) 1.635 × 10–18

(B) 9.835 × 105
(C) 9.835 × 1012
(D) 1.635 × 10–11

5) A ‘p’-block element (E) and hydrogen form a binary cation (EHx)+, while EH3 on treatment with
K2HgI4 in alkaline medium gives a precipitate of basic mercury(II)amido-iodine. Given below are first
ionisation enthalpy values (kJ mol–1) for first element each from group 13, 14, 15 and 16. Identify the
correct first ionisation enthalpy value for element E.

(A) 1312
(B) 1086
(C) 1402
(D) 801

6) In the reaction,
2Al(s) + 6HCl(aq) → 2Al3+(aq) + 6Cl–(aq) + 3H2(g)

(A) 11.2 L H2(g) at STP is produced for every mole of HCl consumed.
(B) 67.2 L H2(g) at STP is produced for every mole of Al that reacts.
(C) 12 L HCl(aq) is consumed for every 6L H2(g) produced.
33.6 L H2(g) is produced regardless of temperature and pressure for every mole of Al that
(D)
reacts.

7) Consider a solution of CO2(g) dissolved in water in a closed container. Which one of the following
plots correctly represents variation of log (partial pressure of CO2 in vapour phase above water) [y-
axis] with log (mole fraction of CO2 in water) [x-axis] at 25°C ?

(A)

(B)

(C)

(D)

8) A first row transition metal (M) does not liberate H2 gas from dilute HCl. 1 mol of aqueous
solution of MSO4 is treated with excess of aqueous KCN and then H2S(g) is passed through the
solution. The amount of MS (metal sulphide) formed from the above reaction is _______ mol.
(A) 2
(B) 1
(C) 3
(D) 0

9) The correct order of reactivity of CH3Br in methanol with the following nucleophiles is F–, I–,
C2H5O– and C6H5O–

– – – –
(A) I > C6H5O > F > C2H5O
– – – –
(B) I > C2H5O > C6H5O > F
– – – –
(C) I > C2H5O > F > C6H5O
– – – –
(D) I > F > C6H5O > C2H5O

10) Match the List-I with List-II

List-II
List-I
Magnitude in
Thermodynamic Process
kJ
3 3
A. Work done in reversible, isothermal expansion of 2 mol of ideal gas from 2 dm to 20 dm at 300 K. I. 4

Work done in irreversible isothermal expansion of 1 mol ideal gas from 1 m3 to 3 m3 at 300 K against A constant
B. II. 11.5
pressure of 3kPa.

Change in internal energy for adiabatic expansion of a 1 mol ideal gas with change of temperature = 320 K
C. III. 6
and .

D. IV. 7
Change in enthalpy at constant pressure of 1 mole ideal gas with change of temperature = 337 K and .

Choose the correct answer from the option given below :

(A) A-III, B-II, C-IV, D-I
(B) A-II, B-III, C-I, D-IV
(C) A-I, B-II, C-III, D-IV
(D) A-II, B-I, C-III, D-IV

11) Given below are two statements :

Statement I : Benzene is nitrated to give nitrobenzene, which on further treatment with CH3COCl /

AlCl3 will give

Statement II : NO2 group is a m-directing, and deactivating group.
In the light of the above statements, choose the most appropriate answer from the options given
below.

(A) Statement I is correct but Statement II is incorrect.

(B) Both Statement I and Statement II are correct.
(C) Statement I is incorrect but Statement II is correct.
(D) Both Statement I and Statement II is are incorrect.

12) A → products (First order reaction).

Three sets of experiment were performed for a reaction under similar experimental conditions.
Run 1 ⇒ 100 mL of 10 M solution of reactant A
Run 2 ⇒ 200 mL of 10 M solution of reactant A
Run 3 ⇒ 100 mL of 10 M solution of reactant A+ 100 mL of H2O added.
The correct variation of rate of reaction is

(A) Run 1 = Run 2 = Run 3

(B) Run 3 < Run 1 = Run 2
(C) Run 3 < Run 1 < Run 2
(D) Run 1 < Run 2 < Run 3

13) Match the LIST-I with LIST-II.

List-II
List-I Name of Reaction
Reagents involving carbonyl
compound

A. NH2– NH2, KOH I. Tollen’s Test

Clemmensen
B. Ag(NH3)2OH II.
Reduction

Aq. CuSO4, Sodium

Wolff-Kishner
C. Potassium tartarate, III.
Reduction
KOH

D. Zn – Hg, HCl IV. Fehling’s Test

Choose the correct answer from the options given below :
(A) A-III, B-I, C-IV, D-II
(B) A-II, B-I, C-IV, D-III
(C) A-IV, B-III, C-II, D-I
(D) A-III, B-IV, C-I, D-II

14) Given below are two statements :

Statement I : The halogen that makes longest bond with hydrogen in HX, has the smallest covalent
radius in its group.
Statement II : A group 15 element’s hydride EH3 has the lowest boiling point among corresponding
hydrides of other group 15 elements. The maximum covalency of that element E is 4.
In the light of the above statements, choose the correct answer from the options given below.

(A) Both Statement I and Statement II are true.

(B) Statement I is false but Statement II is true.
(C) Both Statement I and Statement II are false.
(D) Statement I is true but Statement II is false.

15) Given below are two statements :

Statement I : Sucrose is dextrorotatory. However sucrose upon hydrolysis gives a solution having
mixture of products. This solution shows laevorotation.
Statement II : Hydrolysis of sucrose gives glucose and fructose. Since the laevorotation of glucose
is more than the dextrorotation of fructose the resulting solution becomes laevorotatory.
In the light of the above statements, choose the correct answer from the options given below.

(A) Statement I is false but Statement II is true.

(B) Both Statement I and Statement II are false.
(C) Both Statement I and Statement II are true.
(D) Statement I is true but Statement II is false.

16) ‘A’ is a neutral organic compound (M. F : C8H9ON ). On treatment with aqueous Br2/HO(–), ‘A’
forms a compound ‘B’ which is soluble in dilute acid. ‘B’ on treatment with aqueous
NaNO2/HCl(0–5°C) produces a compound ‘C’ which on treatment with CuCN/NaCN produces ‘D’
Hydrolysis of ‘D’ produces ‘E’ which is also obtainable from the hydrolysis of ‘A’. ‘E’ on treatment
with acidified KMnO4 produces ‘F’. ‘F’ contains two different types of hydrogen atoms. The structure
of ‘A’ is

(A)

(B)

(C)

(D)

17) The correct order of the rate of reaction of the following reactants with nucleophile by SN1
mechanism is :
(Given : Structure I and II are rigid)

(A) IV < III < II < I

(B) III < I < II < IV
(C) II < I< III < IV
(D) I < II < III < IV

18) Two p-block elements X and Y form fluroides of the type EF3. The fluoride compound XF3 is a
Lewis acid and YF3 is a Lewis base. The hybridization of the central atoms of XF3 and YF3
respectively are

(A) Both sp3

(B) sp2 and sp3
(C) sp3 and sp2
(D) Both sp2

19) As compared with chlorocyclohexane, which of the following statements correctly apply to
chlorobenzene ?
A. The magnitude of negative charge is more on chlorine atoms
B. The C – Cl bond has partial double bond character
C. C – Cl bond is less polar
D. C – Cl bond is longer due to repulsion between delocalised electrons of the aromatic ring and lone
pairs of electrons of chlorine.
E. The C–Cl bond is formed using sp2 hybridised orbital of carbon.
Choose the correct answer from the options given below :

(A) A, C and E only

(B) B, C and D only
(C) A, D and E only
(D) B, C and E only

20) Given below are two statements :

Statement I : The Henry’s law constant KH is constant with respect to variations in solution’s
concentration over the range for which the solutions is ideally dilute.
Statement II : KH does not differ for the same solute in different solvents.
In the light of the above statements, choose the correct answer from the options.

(A) Statement I is false but Statement II is true.

(B) Statement I is true but Statement II is false.
(C) Both Statement I and Statement II are true.
(D) Both Statement I and Statement II are false.

SECTION-II
1) The cycloalkene (X) on bromination consumes one mole of bromine per mole of (X) and gives the
product (Y) in which C : Br ratio is 3 : 1. The percentage of bromine in the product (Y) is _______ %.
(Nearest integer)
(Given : Molar mass in g mol–1 H : 1, C : 12, O : 16, Br : 80 )

2) Consider the following electrochemical cell at 298 K

If the reaction quotient at a given time is 106, then the cell EMF (Ecell) is _______× 10–1V (Nearest
integer).

Given the standard half-cell reduction potential as and

3) The temperature at which the rate constants of the given below two gaseous reactions become
equal is ___ K. (Nearest integer)

[Given : ℓn 10 = 2.303]

4) Sodium fusion extract of an organic compound (Y) with CHCl3 and chlorine water gives violet
color to the CHCl3 layer. 0.15g of (Y) gave 0.12 g of the silver halide precipitate in Carius method.
Percentage of halogen in the compound (Y) is ___________. (Nearest integer) (Given : molar mass g
mol–1 C : 12, H : 1, Cl : 35.5, Br : 80, I : 127)

5) Dissociation of a gas A2 takes place according to the following chemical reactions. At equilibrium,
the total pressure is 1 bar at 300K.
A2(g) ⇌ 2A(g)
The standard Gibbs energy of formation of the involved substances has been provided below:

–1
Substance ΔGt°/kJ mol

A2 –100.00

A –50.832
The degree of dissociation of A2(g) is given by (x × 10–2)1/2 where x = _________.
(Nearest integer)
[Given : R = 8 J mol–1 K–1, log 2 = 0.3010, log 3 = 0.48]
Assume degree of dissociation is not negligible.
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C B D B A B D B D B C A D A C D A C A D

SECTION-II

Q. 21 22 23 24 25
A. 49 18 16 4 660

PART-2 : PHYSICS

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D A B D C C D D D A D A A B A D C C D B

SECTION-II

Q. 46 47 48 49 50
A. 600 4 100 16 20

PART-3 : CHEMISTRY

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C D B C A C D B B C B A C D C C B D B

SECTION-II

Q. 71 72 73 74 75
A. 66 4 1303 43 33
 SOLUTIONS

PART-1 : MATHEMATICS

1)

=1⇒3+6+λ–5=

⇒ λ2 + 8λ + 16 = λ2 – 10λ + 70

⇒λ= =3

∴ Quadratic : 9x2 – 18x + 5 = 0 ⇒ x =

∴ 2α – β = =3

2)

R = {(3, 3), (7, 8), (11, 13)} to make it symmetric (8, 7), (13, 11) must be added.

3)

∴ m + n = 20 + 7
= 27

4)

Req. probability = 1– (product not divisible by 3)

Multiple of 3 = 16
Not multiple of 3 = 34

5) f(x) = x2025 – x2000

f'(x) = 0 ⇒ x = = α(say)

∴ f(0) = 0, f(1) = 0, f(α) = = 8080.(–81)–81

6)

Let P(2λ +1, –3λ –1, λ)

Then 4λ2 + 9λ2 + λ2 = 16·14 ⇒ λ = ± 4 ⇒ –4 (nearer to origin)
∴ P(–7, 11, –4)

∴ Shortest distance =

7)
⇒ 9k + 10k2 = 1

⇒ 10k2 + 9k – 1 = 0 ⇒
P(3 < x ≤ 6) = 3k + 3k2

8) Case-I x < – 4

x2 + 7x – 4 = 0

or
Reject Accept
Case-II – 4 ≤ x < –2
x(x + 4) + 3 + 10 = 0
2
x +x+4=0
D < 0 No solution
Case III x ≥ – 1
x (x + 4) + 3 (x + 2) + 10 = 0
x2 + 7x + 16 = 0
D < 0 No solution
⇒ No. of solution = 1.

9) = 3x f(x) + x3 – 4
Diff. both side
6f(x) = 3x f '(x) + 3f(x) + 3x2
3f(x) = 3x f '(x) + 3x2

⇒ f(x) = –x2 + Cx
at x = 1, y = 1⇒ C = 2
f(x) = – x2 + 2x
f(2) – f(3) = 3

10)
Put this in equation of hyperbola

∴ x2 – 9 =9
2 2
(4–9α )x + 18αx – 45 = 0
∵ line does not intersect hyperbola
∴D<0

Here

11)

Point satisfies the line

⇒ b = 8 …(1) & c + a = 18 …(2)
Now PQ ⊥ L
⇒ (4i + (b–2)j + (c – a)k) · (3i + 2j – 2k) = 0
⇒ 12 + 2 (b – 2) – 2 (c – a) = 0
⇒ 6 + (b – 2) – (c – a) = 0
⇒b–c+a+4=0
⇒8–c+a+4=0
⇒ c + a = 12 … (3)
From (2) & (3)
c = 15 & a = 3
So a2 + b2 + c2 = 9 + 64 + 225 = 298

12) (x – 2)2 + (y – 1)2 = 32 & (x + 1)2 + (y + 4)2 = r2

|r1 – r2| < c1c2 < r1 + r2

&

i.e.

i.e.

= 34 – 9
= 25

13)
|A2025 – 3A2024 + A2023 |

= 160 – 144 = 16

14) & 10 – x > 0, 10 – x ≠ 1

& x < 10 & x ≠ 9

(5 – x) – (2x + 3)2 ≤ 0 & x < 10 & 4x ≠ 9
2

(x + 8) (3x – 2) ≥ 0 & x < 10 & x ≠ 9

⇒ (α + β + γ + δ) = 6
= 70

15)

16)

Let 1 + x = r
∴ S = 1.r + 2.r2 + 3.r3 + ……+ 100r100 ……. (1) (AGP)
rS = 1.r2 + 2.r3 + ..…+ 99r100 + 100r101 ….... (2)
(1) – (2) gives

∴ coefficient x48 in S

= –coefficient of x48 in .

Coefficient of x48 in

17) &
t1t2 = –4
x1x2 = 9(t1t2)2, y1y2 = 36t1t2
x1x2 – y1y2 = 9(16) – 36(–4)
= 144 + 144
= 288

18)
Only 1 solution in

19)

⇒ ℓn = ℓn x + ℓn k = ℓn kx

0+1=k

⇒y+ = x2

y+ =9
y=4

20) Sum of first 4 term S4 = 6

….. (1)
Sum of first 6 terms S6 = 4

….. (2)
eq. (2) – eq. (1)

21) + + (14 + 7(ω + ω2))20

= (49)10
Hence, M = 49
22) A and A
det. (adj.(2 adj (A + I)) = |2 adj (A + I)|2 = 64 |adj (A + I)|2
= 64 |A+I|4

Let A = ⇒

∴ |A+I| = = = 44

23)

Put tan x = t

⇒ p1 = 2, p2 = 6, p3 = 6, p4 = 2 & q1 = 9, q2 = 5, q3 =1, q4 = 3

24) Use sin(A + B) sin (A + B) = sin2A – sin2B

cos (A + B) cos (A – B) = cos2A – sin2B

α=3;β=1
So, (α + β) = 4

25) Case 1 :
2 from AB, 2 from BC, 1 from AC

= 6 · 10 · 4 = 240
Case 2 :
2 from AB, 1 from BC, 2 from AC
 = 6 · 5 · 6 = 180
Case 3 :
1 from AB, 2 from BC, 2 from AC

= 4 · 10 · 6 = 240

PART-2 : PHYSICS

26)

I = 63 × 10–2 kg m2
I = 0.63 kg m2

27) By mechanical energy conservation

(Me)i = (Me)f
PEi + KEi = PEf + KEf

0 + 7.9 × 106 × 1.6 × 10–19 =

= 2.88 × 10–14 m
For diameter ⇒ D = 2r = 5.76 × 10–14 m

28) Let
29)

at equilibrium (or for terminal velocity)

30)
31)

…. (1)

…. (2)

R2 = 8Ω
By equation (1)

32)

u cos 60° =

33)
According to pascal's law pressure at any point in liquid at rest is same in all direction.
It exist at every point in the liquid not just at boundaries. So statement (1) is false.
For interior molecule net cohesive forces are zero statement (2) is correct.

34)

LED will glow in forward biasing :

P higher potential – 1
Q lower potential – 0

35) Initial configuration

New configuration

∴α=2

36) hν = (4 × 4.002 – 15.348) × 1.66 × 10–27 × (3 × 108)2

37)
A[(P + dP) – P] = (dm) (ω2x)

dP =
also [PM = ρRT]

dP = ω2xdx

PB =

38) Let

… (1)

… (2)

… (3)
using (1) and (2)
120 = 1100 – 11TA
TB = 89°C
using (1) and (3)
TE = 73°C

39) Correct Answer is (B)

40) Equilateral prism.

A = 60°

μSinr2 =[Link] =1
Sinr2 =
r2 = 45°
∴ r1 = A – r2 = 15°

41) PVγ = constant

TVγ–1 = constant

TVγ–1 =
4 = 8(γ–1)
22 = 23γ–3
2 = 3(γ – 1)

Gas is a monoatomic gas

Answer is He.

42)
Vat (10, 20) = 500 V

43)

44)

(A) F = Kx
[MLT–2] = [K][L]
0
[K] = ML T–2
(B) Thermal conductivity

[K1] = MLT–3 K–1

(C) Boltzman constant

(D) Inductive reactance

= ML2T–3A–2

45)
Magnetic field through the coil is

Find the direction according to Lenz's law

If coil move away then magnetic field decreases & vice versa
Correct Ans. (2)

46)
Point B will 10th maxima
Δx = L2B – L1B
L1B =
L2B =
Δx = 50 – 44.6 = 5.4 m
Δx = nλ
5.4 = 10 × λ
λ = 0.54 m
V = fλ
47)

n=2

48)

V = 150 cm
x → measure from center
x=V–R
= 150 – 50 = 100 cm

49)

I1 = I2

50) L = 10 × 10–3 H
N = 104

(max current)

B = µ0nI
L = µ0n2πR2l
PART-3 : CHEMISTRY

51) Co3+ → 3d6 ⇒ , unpaired electron = 0

Fe3+ → 3d5 ⇒ , unpaired electron = 1

Cr3+ → 3d3 ⇒ , unpaired electron = 3

Mn3+ → 3d4 ⇒ , unpaired electron = 2

52) Consider the structure of HNO3

1 :- 0
2 :- (+1)
3 :- 0
4 :- (–1)

Formal charge = valence e’s – non bonding e’s –

53)
(can be separated by steam distillation)

54)

= 1.635 × 10–18 Joule/atom

= 1.635 × 10–18 × 6.02 × 1023 Joule/mole
= 9.835 × 105 Joule/mole

55) Element E is N, the species is , among B, C, N and O, N has highest first ionization
energy.

56) 2Al (s) + 6HCl (aq) → 2Al3+ (aq) + 6Cl– (aq) + 3H2(g)
Mole of H2 produced
= 2 × mole of HCl used

= × mole of Al used

57)

From Henry's law :

P(g) = KH.X(g)
logP(g) = logKH + logX(g)

58)

no sulphide ppt

59) Order of nucleophilicity :

IΘ > C2H5OΘ > PhOΘ > FΘ

60) Option (A)

= –11.5 kJ

Option (B)
W = –Pext[V2 –V1]
= –3[3–1]
= –6 kJ
Option (C)
ΔU = nCVΔT

= 3.99
Option (D)
ΔH = nCPΔT

= 7 kJ
61) Nitrobenzene does not give Fridel-Craft acylation since it is highly deactivated ring.

62)

For Ist order reaction

Rate = k[A] with decrease in concentration of A, rate of reaction decreases.

63) Theoretical (NCERT Based)

64) HF < HCl < HBr < HI (bond length order)

F < Cl < Br < I (radius order)
PH3 < AsH3 < NH3 < SbH3 < BiH3 (Boiling point order)
Maximum possible covalency of phosphorous is 6

65)

D– Glucose + D fructose
[α]D-sucrose = +66.5°, [α]D-Glucose = +52.5°, [α]D-Fructose = –92.4°
⇒ Sucrose is dextrorotatory and hydrolysed product is laevorotatory.

66)

67) Rate of SN1 ∝ Stability of C⊕ formed

(I) and (II) are unstable due to Bredt's rule, (I) has more +I effect.
(II) < (I) < (III) < (IV)

68) XF3 = BF3 ; sp2

YF3 = NF3 ; sp3

69)

Chlorocylohexane is more polar due to –I effect of –Cl,

Whereas chlorobenzene has –I > +M, so it is less polar & also has partial double bond
character.

70) KH depends on the nature of gas and solvent.

71) C6H10 C6H10Br2

Molecular mass of C6H10Br2 is :
12 × 6 + 10 + 160
72 + 10 + 160 = 242

% of Br =
% of Br = 66.11 % ≈ 66%

72)
= + 0.46 V
Applying Nernst equation :-

Ecell = 4 × 10–1
x=4

73)

T = 1302.64 K
T ≈ 1303 K

74) Iodine gives violet colour

% of I =

% of I = 43.23 % ≈ 43%

75) –1.664 × 103 = –8.3 × 300 lnKP

lnKP = 0.693
KP = 2

= (33.33 × 10–2)1/2