Solution 3
Solution 3
9610ZJA801443240004 JA
PART-1 : PHYSICS
SECTION-I (i)
1) In the pulley system shown the movable pulleys A, B and C have mass m each, D and E are fixed
(A)
the tension throughout the string is the same and equals .
(B) pulleys A and B have acceleration each in downward direction and pulley C has acceleration
in upward direction.
(C)
pulleys A, B and C all have acceleration in downward direction.
(D) None of these
2) In the diagram, BAC is a rigid fixed rough wire and angle BAC is 60°. P and Q are two identical
rings of mass m connected by a light elastic string of natural length 2α and force constant . P
and Q are in equilibrium when PA = AQ = 3α. The least coefficient of friction between the ring and
the wire is μ . The value of μ + is
(A) 2
(B) 3
(C) 4
(D) 7
3) A man can swim with a certain speed, in still water to cross a river to a point directly opposite to
the starting point in time t0. When the river flows, he crosses the river directly along the same path
in a time t1. If ‘d’ be the river width, Then the velocity of water current is :
(A)
(B)
(C)
(D)
4) A particle is projected from a point O on the horizontal surface OA with speed u and angle of
projection θ. It just grazes the plane BC which makes an angle α with the horizontal. The time taken
(A)
(B)
(C)
(D)
5) Assertion A : If A, B, C, D are four points on a semi-circular arc with centre at ‘O’ such that
= = , then + + = + +
Reason R : Polygon law of vector addition yields + + + =
SECTION-I (ii)
(B)
(C)
(D)
2) Initially two particles A and B are present at (0, 0) and (d, 0) respectively. They start moving with
speed and . If R is magnitude of relative separation between them and T0 be the
time when separation between them is minimum, then
(A)
(B)
3) A projectile is projected as shown in figure. A proper light arrangement makes a shadow on the
wall as well as on the floor. Which of the following graphs is correct?
(A)
(B)
(C)
(D)
4) An open elevator is ascending with zero acceleration and speed 10 m/s. A ball is thrown vertically
up by a boy (boy is in elevator) when he is at a height 10 m from the ground, the velocity of
projection is 30 m/s with respect to elevator. Choose correct option(s) assuming height of the boy
very small : (g = 10 m/s2)
5) A cart of mass 0.5 kg is placed on a smooth surface and is connected by a string to a block of
mass 0.2 kg. At the initial moment the cart moves to the left along a horizontal plane at a speed of 7
(A)
The acceleration of the cart is towards right.
(B) The cart comes to momentary rest after 2.5 s.
(C) The distance travelled by the cart in the first 5s is 17.5 m.
(D) The velocity of the cart after 5s will be same as initial velocity.
6) A painter is applying force himself to raise him and the box with an acceleration of 5 m/s2 by a
massless rope and pulley arrangement as shown in figure. Mass of painter is 100 kg and that of box
7)
The four pairs of force vectors are given, which pairs of force vectors cannot be added to give a
resultant vector of magnitude 10 N?
(A) 2N, 13 N
(B) 5N, 16 N
(C) 7N, 8N
(D) 100N, 105 N
8) Sometimes it is convenient to construct a system of units so that all quantities can be expressed in
terms of only one physical quantity. In one such system, dimensions of different quantities are given
in terms of a quantity X as follows: [position] = [Xα ]; [speed] = [Xβ]; [acceleration] = [Xp]; [linear
momentum] = [Xq]; [force] = [Xr]. Then -
(A) α + p = 2β
(B) p + q – r = β
(C) p – q + r = α
(D) p + q + r = β
SECTION-III
1) A ferry is moving due east and encounters a southwest wind (Wind coming from south west and
going towards north east) of speed 10 m/s as shown. The experienced ferry captain wishes to
minimize the effects of the wind on the passengers who are on the outdoor decks. At what speed (in
m/s) should he proceed?
2)
In a new system of units mass, acceleration & frequency are taken as fundamental units. If unit of
mass is 100 g, unit of acceleration is 2 m/s2 and unit of frequency is 4 sec–1, in this new system of
units, then the value of 10 J in this new system is K × 100. Fill K in OMR Sheet.
3) If d is the depth to which a bullet of kinetic energy K can penetrate into a human body of modulus
of elasticity E, then using the method of dimension establish a relation between d, K and E. If K =
cdxEy, where c is a dimensionless constant, fill x + y in OMR sheet. Modulus of elasticity =
4)
Three forces (shown in figure) act on a body simultaneously. What will be magnitude (in newton) of
smallest additional force to make net force along North direction.
5) A 12 kg bar is pressed between two blocks, the coefficient of friction between the blocks and the
bar is µ = 0.3. If force F pressing the blocks is 50 N. Minimum force required to keep the block at
rest is F1 and force required to move block with constant velocity is F2. Fill value of . (g =
10 m/s2)
PART-2 : CHEMISTRY
SECTION-I (i)
1) One quantum is absorbed per gaseous molecule of Br2 for converting into Br atoms. If light
absorbed has wavelength 5000 Å, then the bond energy of Br2 is about.....KJ/mol (1 eV/particle = 96
KJ/mol).
(A) 119
(B) 238
(C) 357
(D) 476
(B)
(C)
4) In which of the following arrangements the order is NOT according to the property indicated
against it ?
(A) Al3+ < Mg2+ < Na+ < F– – increasing ionic size
(B) B < C < N < O - increasing first ionization enthalpy
(C) I < Br < F < Cl - increasing electron gain enthalpy (with negative sign)
(D) Li < Na < K < Rb - increasing metallic radius
5)
280 mL of sulphur vapour (Sx) at 1 atm, 273 K weighs 1.6 gm. Determine the molecular formula of
sulphur vapour?
(A) S
(B) S4
(C) S6
(D) S8
SECTION-I (ii)
3) Which of the following species have integral bond order, gerade type HOMO and paramagnetic
nature.
(A)
(B)
(C) O2
(D)
4)
For diatomic molecules, the correct statement(s) about the molecular orbitals formed by the overlap
of two 2pz orbitals is(are)
The difference in angular momentum associated with the electron present in consecutive orbits
(A)
of H-atom is (n–1) .
Energy difference between energy levels will be changed if, P.E. at infinity assigned value other
(B)
than zero.
(C) Frequency of spectral line in a H-atom is in the order of (2 → 1) < (3 → 1) < (4 → 1).
(D) On moving away from the nucleus, kinetic energy of electron decreases.
(A) Over a boundary surface, value of probability density | |2 is constant for an orbital.
(B) Probability of finding an electron is 100 % in an orbital
(C) Number of angular nodes are (n – –1)
(D) For 1s orbital, the probability density is maximum at the nucleus.
7) A quantity of 0.22 g of a gas occupies a volume of 112 ml at pressure of 1 atm and temperature of
273 K. The gas may be
8) Regarding the radial probability distribution vs r plot which of the following is/are
correct?
1) 1gm of dry green algae absorbs 5 moles of CO2 per hour by photo synthesis. If fixed carbon atoms
were all stored in the form of starch (C6H12O6)n after photo synthesis then calculate time required (
in sec.) to double the weight of algae.
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.
2) 45 g of gaseous mixture of NO2 & N2O gas occupy 22.7 litre at S.T.P. Find the mole % of NO2 in
the gaseous mixture.
[Report your answer as sum of digits till you get single digit, excluding decimal places]
3) In a sample of H–atom containing 1 mole H–atoms, electrons in 30% of H–atoms are in 1st excited
state and remaining are in 2nd excited state and ground state. If the total energy emitted when all
electrons return to ground state is 642.24 kJ. Then find % of electrons in 2nd excited state.
[Energy level in H–atom = E1 = –13.6eV, E2 = –3.4eV, E3 = –1.5eV, 1eV/species = 96 kJ/mole]
(Report your answer in sum of digits if answer is 32 mark your answer 3 + 2 = 5)
4) When a metal is exposed with light of wavelength λ, the maximum kinetic energy of electron
produced was found to be 2 eV. When the same metal was exposed with light of wavelength λ/2 , the
maximum kinetic energy of electron produced was 6 eV. What is the value of work function of metal
in eV.
5) If the number of 3c-2e bond and 2c-2e bond present in Be2(CH3)4 are 'X' and 'Y' respectively. Give
the value of (X + Y)
[Report your answer as sum of digits till you get single digit, excluding decimal places]
PART-3 : MATHEMATICS
SECTION-I (i)
(A) 0
(B) n
(C) 2n
(D) n2
is equal to
(A)
(B)
(C)
(D)
3)
(A) log34
(B) 1 – log34
(C) 1 – log43
(D) log43
(A)
(B)
(C) [1, 2]
(D) (-2, 2)
(A) 2
(B)
(C)
(D) 4
SECTION-I (ii)
1) If A, B be any two sets, then (A ∪ B)' is equal to __________ (Here U is universal set).
(A) a > 0
(B) b > 0
(C) c > 0
(D) b2 < 4ac
(A) Sum of absolute values of real solution(s) of given equation is a prime number
(B) equation has more than two real solutions
(C)
(D)
(where α, β ∈ S and α > β)
6) Let a1, a2, a3, .......be an arithmetic progression with a1 = 7 and common difference 8. Let T1, T2,
T3,....be such that T1 = 3 and Tn+1 – Tn = an for . Then, which of the following is/are TRUE?
(A)
(B)
(C)
(D)
7) If a, b, c are in H.P., then
(A)
are in H.P.
(B)
(C)
are in G.P.
(D)
are in H.P.
8) If are the roots of ax2 – 4x + 1 = 0 and β, δ are the roots of bx2 – 6x + 1 = 0 and
are in H.P. then which of the following is correct ?
(A)
(B)
(C) b = 8
(D) a = 3
SECTION-III
4) Find the number(s) of integer value of 'a' for which the equation 4x2 – 2x + a = 0 has two root's lie
in the interval (–1, 1).
PART-1 : PHYSICS
SECTION-I (i)
Q. 1 2 3 4 5
A. B A B C D
SECTION-I (ii)
Q. 6 7 8 9 10 11 12 13
A. A,D A,B B,D A,B,C,D A,B,C A,C A,B A,B
SECTION-III
Q. 14 15 16 17 18
A. 6 4 4 6 6
PART-2 : CHEMISTRY
SECTION-I (i)
Q. 19 20 21 22 23
A. B B C B B
SECTION-I (ii)
Q. 24 25 26 27 28 29 30 31
A. A,B,C B,D B,C A,D C,D A,D B,C,D A,C,D
SECTION-III
Q. 32 33 34 35 36
A. 6 5 3 2 7
PART-3 : MATHEMATICS
SECTION-I (i)
Q. 37 38 39 40 41
A. D C B A A
SECTION-I (ii)
Q. 42 43 44 45 46 47 48 49
A. A,B,D A,B B,C A,C,D A,B,C,D A,C,D A,B,C,D A,B,C,D
SECTION-III
Q. 50 51 52 53 54
A. 6 3 7 2 4
SOLUTIONS
PART-1 : PHYSICS
1)
Take downward as positive direction.
The total length of the thread is a constant.
Starting from centre of A and going to centre of B we have
(xB – xA) + xB + 2xA + xC + (xC – xB) = constant ⇒ xB + xA + 2xC = constant
⇒
⇒ aB + aA + 2aC = 0 ........(i)
Applying cause-effect equations we get
mg – 2T = maC (For C) .......(ii)
mg + T – 2T = maB (For B)
⇒ mg – T = maB ........(iii)
mg + T – 2T = maA (For A)
Þ mg – T = maA ........(iv)
From (3) and (4), aA = aB so (1) gives
⇒ aA = aB = –aC
Adding (3) and (4), we get
2mg – 2T = 2maA
Subtract (2) from (6), we get
mg = 2maA – maC
⇒ mg = 2maA + maA
{∵ aA = – aC}
⇒ mg = 2maA
⇒ aA =
So, aA = aB = ; Downwards
aC = Upwards
Also we get T by putting value of aA in (4) i.e.
2)
mgsin60° – f – kx cos60° = 0
= µN
3)
0
t =
t1 =
vr = vbr sin θ
vr =
4)
u cos θ · sin α = (u sin θ – gt ) cos α
(θ = 2α)
5) Polygon law is applicable in both but the equation given in the reason is not useful in
explaining the assertion.
6)
(D)
7)
tan θ =
0
T =
9)
hmax = hi = ff = 10 +
h = 90 m
40 t – × 10 × t2 = 10 × t ⇒ t = 6s.
(D) with respect to elevator Vball = 30 m/s downward
∴ Vball with respect to ground = 30 – 10 = 20 m/s
10) (A)
(B)
t = 2.5 sec.
(D)
11)
13)
Given L = xα ……(A)
LT–1 = xβ ……(B)
LT–2 = xp ……(C)
MLT–1 = xq ……(D)
MLT–2 = xr ……(5)
⇒ T = xα –β
From (C)
⇒ α + p = 2β (A)
From (D)
M = xq–β
From (5) ⇒ xq = xr xα–β
⇒ α + r – q = β ……(6)
Replacing value 'α' in equation (6) from (A)
2β – p + r – q = β
⇒ p+q–r=β (B)
Replacing value of 'β' in equation (6) from (A)
2α + 2r – 2q = α + p
α = p + 2q – 2r
Answer is (A,B)
14)
n2 = 10
= 10 × 10 × × 16
n2 = 400
17)
To have resultant along north, force towards west should be cancelled.
⇒ = =6
PART-2 : CHEMISTRY
19)
Bond energy
20)
R(r) =
Let's compare with standard from.
R(r) = (constant) [polynomial in σ]σ × e–kσ
Degree of polynomial = n– – 1 = 1
Also : = 1(p) : n = 3
So orbital is, 3p : one radial node.
Angular node = = 1
3px, 3py or 3pz
Can be to total only by knowing angular function
21)
has lowest bond order 0.5, hence it has highest bond length.
22)
Nitrogen has half filled stable configuration, ns2np3. So, ionization enthalpy of nitrogen is greater
than oxygen. Across the period with increasing effective nuclear charge and decreasing atomic size
the ionization energies increases but down the group decreases due to increasing atomic radii. So,
the correct of increasing the first ionization enthalpy is B < C < O < N. (Ionisation energy in kJ mol–1
B = 801; C = 1086 ; O = 1314 ; N = 1402).
24)
First ΔegH of any element is endothermic for group-2, group-18 & Nitrogen
25)
Element B Al Ga In Tl
I.E (kJ/mol) 801 577 579 558 589
26)
27)
28) (A) Angular momentum =
29)
(A) Fact
(B) Probability of finding an electron is upto 90% to 95% in an orbital
(C) No. of angular nodes are
(D) For 1s. is maximum at nucleus
30)
Moles of gas =
31)
32)
t= sec.
Sum of digits = 2 + 4 = 6
x=
34)
If x mole % of e– are in 2nd excited state then no. of moles of e– in 2nd excited state =
Energy emitted by all e– in returning from n = 3 → n = 1
⇒
Energy emitted by all e– in returning from n = 2 → n = 1
642.24 =
642.24 = 11.616 x + 293.76
x = 30
=3+0=3
35)
2= ........(i)
6= ........(ii)
Solving : ϕ = 2eV Ans.
36)
X=2
Y = 14
X + Y = 16
1+6=7
PART-3 : MATHEMATICS
37)
n2
38)
39)
+ 5 = 12.3x
3x = t (t > 0)
2
12t – 5t – 3 = 0
12t2 – 9t + 4t – 3 = 0
(3t + 1) (4t – 3) = 0
x = 1 – log3 4
Ans. (B)
41)
Let , then
⇒
⇒ a=1
⇒ x=2
42)
(A ∪ B)' = (1)
(A) A' = (1), (4)
B' = (1), (2)
(B) U – (A ∪ B) = (1)
(C) A – B = (2), B – A = (4)
((A – B) ∪ (B – A))' = (1), (3)
(D) A' = (1), (4)
A ∪ (U – B) = (1)
43)
44)
45)
Given equation is x2 = 4 − 3x x = 1, −4
46)
a3 + b3 = (a + b)3 ⇒ a = 0 or b = 0 or a + b =0
log10x + 2 = 0
log10x – 1 = 0
x = 10–2
x = 10
2log10x + 1 = 0
x = 10–1/2
47) an = 8n – 1
Tn+1 – Tn = 8n –1
T2 – T1 = 8 × 1 –1
T3 – T2 = 8 × 2 –1
T4 – T3 = 8 × 3 – 1
.
.
Tn+1 – T1 = 4n(n+1) – n
Tn+1 = 4n2+3n+3
48)
are in A.P.
are in A.P.
also
Lastly,
are in G.P.
49)
Hence and
Substituting the values of roots in the respective equations gives b = 8 and a = 3.
50)
4y + 5x = xy
xy – 5x – 4y = 0
(x – 4) (y – 5) = 20
Now 20 can be split in following ways
1 × 20 ⇒ (x, y) = (5, 25)
20 × 1 ⇒ (x, y) = (24, 6)
4 × 5 ⇒ (x, y) = (8, 10)
5 × 4 ⇒ (x, y) = (9, 9)
10 × 2 ⇒ (x, y) = (14, 7)
2 × 10 ⇒ (x, y) = (6, 15)
Hence, total number of possible ordered pair of positive integer (x, y) is 6.
51)
52)
x2(y – 1) + x(y – 1) + y – 2 = 0
Case-1 : When y ≠ 1
as x ∈ R ⇒ D ≥ 0
(y – 1)2 – 4(y – 1)(y – 2) ≥ 0
y2 + 1 – 2y – 4(y2 – 3y + 2) ≥ 0
–3y2 + 10y – 7 ≥ 0
3y2 – 10y + 7 ≤ 0
(y – 1)(3y – 7) ≤ 0
Case-2 : When y = 1
0+0+1–2=0
–1 = 0 (Not possible)
53)
54)
Required