CHEMISTRY

26. Which of the following contains the highest 36. Which of the following contains the least number
number of molecules - of molecules ?
(1) 2.8 g of CO (2) 3.2 g of CH4 (1) 4.4 g CO2 (2) 3.4 g NH3
(3) 1.7 g of NH3 (4) 3.2 g of SO2 (3) 1.6 g CH4 (4) 3.2 g SO2

27. 5.6 L of oxygen at NTP is equivalent to – 37. The number of molecule in 4.25 g of NH3 is -
23 23
(1) 1 mole (2) 1/2 mole (1) 1.505 × 10 (2) 3.01 × 10
23
(3) 1/4 mole (4) 1/8 mole (3) 6.02 × 10 (4) None of these

28. A gas is found to have the formula (CO)x. It's VD 38. Vapour density of ammonia is 8.5, then 85 g of
is 70 the value of x must be:- NH3 at NTP will occupy.
(1) 7 (2) 4 (3) 5 (4) 6 (1) 22.4 L (2) 112 L
(3) 224 L (4) 1120 L
29.
23
If 32 g of O2 contains 6.022 × 10 molecules at
39. CaCO3 is 90% pure. Volume of CO2 collected at
NTP then 32 g of S, under the same conditions,
will contain:- STP when 10 g of CaCO3 is decomposed is -
23
(1) 6.022 × 10 S
21
(2) 3.011 × 10 S (1) 2.016 litres (2) 1.008 litres
23
(3) 1 × 10 S
23
(4) 12.044 × 10 S (3) 10.08 litres (4) 20.16 litres

30. 4.4 g of an unknown gas occupies 2.24 L of 40. How many mole of magnesium phosphate,
volume at STP. The gas may be :- Mg3(PO4)2 will contain 0.25 mole of oxygen atoms?
–2
(1) N2O (2) CO (1) 2.5 × 10
(3) CO2 (4) 1 & 3 both (2) 0.02
–2
(3) 3.125 × 10
31. 500 mL of a gaseous hydrocarbon when burnt in (4) 1.25 × 10
–2

excess of O2 gave 2.5 L of CO2 and 3.0 L of

41. Perecentage composition of an organic compound
water vapours under same conditions. Molecular
is as follows :
formula of the hydrocarbon is -
C=10.06, H=0.84 , Cl=89.10
(1) C4H8 (2) C4H10
Which of the following corresponds to its
(3) C5H10 (4) C5H12
molecular formula if the vapour density is 60.0
32. 1 L of a hydrocarbon weighs as much as one (1) CH2 Cl2 (2) CHCl3
litre of CO2 Under similar conditions. Then the
(3) CH3Cl (4) None
molecular formula of the hydrocarbon is -
(1) C3H8 (2) C2H6 42. The ratio of masses of oxygen and nitrogen in a
particular gaseous mixture is 1 : 4. The ratio of
(3) C2H4 (4) C3H6
number of their molecule is
33. 0.01 mole of iodoform (CHI3) reacts with Ag to (1) 1 : 8 (2) 3 : 16
produce a gas whose volume at NTP is (3) 1 : 4 (4) 7 : 32

2CHI3 + 6Ag → C2H2 + 6Ag I(s) 43. 23 g sodium metal reacts with water. Calculate the
(a) volume of H2 liberated at NTP (b) moles of H2
(1) 224 mL (2) 112 mL
liberated (c) weight of H2 liberated.
(3) 336 mL (4) None of these
2Na + 2H2O → 2NaOH + H2
34. The volume of a gas in discharge tube is (1) 22.4 L, 1 mol, 2g
–7
1.12 × 10 mL at STP. Then the number of
(2) 11.2 L, 1/2 mol, 1g
molecule of gas in the tube is -
(1) 3.01 × 10
4
(2) 3.01 × 10
15 (3) 44.8 L, 2 mol, 4g
12 16
(3) 3.01 × 10 (4) 3.01 × 10 (4) None of the above

35. Vapour density of gas is 11.2, volume occupied 44. Which of the following is a compound
by 2.4 g of this at STP will be - (1) graphite (2) steel
(1) 11.2 L (2) 2.24 L (3) cement (4) marble
(3) 22.4 L (4) 2.4 L
45. A mixture of 2.3 g formic acid and 4.5 g oxalic acid 48. The volume occupied by 1.8 g of water vapour
is treated with conc. H2SO4. The evolved gaseous at 374 °C and 1 bar pressure will be :-
–1 –1
mixture is passed through KOH pellets. Weight [Use R = 0.083 bar L K mol ]
(in g) of the remaining product at STP will be (1) 96.66 L (2) 55.87 L
(i) HCOOH 
H 2SO 4
→ CO + H2O (3) 3.10 L (4) 5.37 L
Formic acid (H2O absorbed by H2SO4) 49. Which one of the following has maximum number
(ii) H2C2O4 → CO + CO2 + H2O
H 2SO 4
of atoms?
Oxalic acid (H2O absorbed by H2SO4) (1) 1g of Li(s) [Atomic mass of Li = 7]
(iii) CO2 is absorbed by KOH (2) 1g of Ag(s) [Atomic mass of Ag = 108]
(1) 1.4 (2) 3.0 (3) 2.8 (4) 4.4 (3) 1g of Mg(s) [Atomic mass of Mg = 24]
(4) 1g of O2(g) [Atomic mass of O = 16]
46. In which case the number of molecules of water is
50. One mole of carbon atom weighs 12 g, the
maximum?
number of atoms in it is equal to, (Mass of
(1) 18 mL of water –23
carbon – 12 is 1.9926 × 10 g)
(2) 0.18 g of water (1) 1.2 × 10
23
(2) 6.022 × 10
22

(3) 0.00224 L of water vapours at 1 atm and (3) 12 × 10

22
(4) 6.022 × 10
23

273 K
–3
(4) 10 mol of water

47. The number of moles of hydrogen molecules

required to produce 20 moles of ammonia
through Haber's process is :-
(1) 10 (2) 20 (3) 30 (4) 40