1 What is the oxidation number of S in Na2S2O3?

A –4
B –2
C +2
D +4

Your answer [1]

2 Which of the following is not a redox reaction?

A CH4(g) + 2O2(g) → CO2(g) + 2H2O(l)

B NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l)
C 2KClO3(s) → 2KCl(s) + 3O2(g)
D Fe(s) + H2SO4(aq) → FeSO4(aq) + H2(g)

Your answer [1]

3 Which compound has molecules with a trigonal planar shape?

A BeCl2
B BCl3
C NCl3
D PCl3

Your answer [1]

4 Which equation describes the second ionisation energy of magnesium?

A Mg(g) → Mg2+(g) + 2e–

B Mg(s) → Mg2+(g) + 2e–
C Mg+(g) → Mg2+(g) + e–
D Mg2+(g) + e– → Mg+(g)

Your answer [1]

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 5 Which molecule is polar?

A H2S
B CO2
C CCl4
D C2F4

Your answer [1]

6 Which statement is not a sustainability benefit of an industrial process using a catalyst?

A Lower temperatures can be used.

B The position of equilibrium moves towards the products.
C The reaction takes place in less time.
D There is reduced energy demand.

Your answer [1]

7 The burette readings from a titration are shown below.

Initial reading / cm3 4.95

3
Final reading / cm 23.10

The burette used has an uncertainty of 0.05 cm3 for each reading.

What is the percentage uncertainty of the resulting titre?

A 0.22%
B 0.28%
C 0.44%
D 0.55%

Your answer [1]

8 How many p electrons does an atom of chlorine have?

A 5
B 7
C 11
D 17

Your answer [1]

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 9 What is the number of hydrogen atoms in 6.8 g NH3?

A 2.408 × 1023
B 3.612 × 1023
C 7.224 × 1023
D 1.806 × 1024

Your answer [1]

10 Which reaction to extract iron (Fe) has the highest atom economy?

A 2Al + Fe2O3 → 2Fe + Al2O3

B FeO + CO → Fe + CO2
C Fe2O3 + 3CO → 2Fe + 3CO2
D 2Fe2O3 + 3C → 4Fe + 3CO2

Your answer [1]

11 Phosphorus is burnt in oxygen to produce a mixture of oxides.

Which oxide has the closest to 50% by mass of phosphorus?

A PO2
B P2O3
C P2O5
D P4O9

Your answer [1]

12 Which row shows the atomic structure of 25Mg2+?

Protons Neutrons Electrons

A 10 12 13
B 10 15 12
C 12 13 10
D 12 13 14

Your answer [1]

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 13 A nitrogen oxide contains 36.84% of nitrogen by mass.

What is the empirical formula of the nitrogen oxide?

A NO
B NO2
C N2O
D N2O3

Your answer [1]

14 Carbon monoxide reacts with oxygen to form carbon dioxide:

2CO(g) + O2(g) → 2CO2(g)

Which volumes of CO(g) and O2(g) produce the largest volume of CO2(g)?

All gas volumes are measured at RTP.

A 1.00 dm3 CO and 4.00 dm3 O2

B 2.00 dm3 CO and 3.00 dm3 O2
C 3.00 dm3 CO and 2.00 dm3 O2
D 4.00 dm3 CO and 1.00 dm3 O2

Your answer [1]

15 Which reaction produces a product with linear molecules?

A 2B + 3F2 →
B C + O2 →
C 2H2 + O2 →
D N2 + 3H2 →

Your answer [1]

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 16 Which statement about the periodic table is not correct?

A Elements in the same group have similar chemical properties.

B The elements are ordered by increasing atomic mass.
C The elements are ordered by increasing atomic number.
D There is a repeating trend of physical and chemical properties across the periods.

Your answer [1]

17 Group 2 compounds can be used in agriculture to neutralise acid soils and in medicine to treat indigestion.

Which Group 2 compound is not suitable for either use?

A Mg(OH)2
B MgSO4
C CaCO3
D CaO

Your answer [1]

18 Which reaction does not show disproportionation of chlorine?

A MnO2 + 4HCl → MnCl2 + Cl2 + 2H2O

B Cl2 + H2O → HCl + HClO
C 2ClO2 + 2NaOH → NaClO2 + NaClO3 + H2O
D 2NaOH + Cl2 → NaCl + NaClO + H2O

Your answer [1]

19 An unknown compound is tested to identify whether it contains sulfate, carbonate or halide ions.

What is the correct sequence of tests required?

A carbonate, halide, sulfate

B carbonate, sulfate, halide
C halide, carbonate, sulfate
D sulfate, carbonate, halide

Your answer [1]

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 20 A mixture of gases is heated in a closed container. The reaction rate increases.

Which statement explains why the rate increases?

A More molecules have an energy greater than the activation energy.

B The activation energy decreases.
C The activation energy increases.
D The concentration of the gases increases.

Your answer [1]

21 Which diagram shows a p-orbital?

Your answer [1]

22 Magnesium nitrate, Mg(NO3)2, decomposes when heated:

Mg(NO3)2(s) → MgO(s) + 2NO2(g) + ½O2(g)

0.00250 mol of Mg(NO3)2 is decomposed.

What is the volume of gas produced, measured at RTP?

A 30 cm3
B 60 cm3
C 120 cm3
D 150 cm3

Your answer [1]

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 23 Zinc reacts with aqueous silver nitrate, as shown in the equation:

Zn(s) + 2AgNO3(aq) → 2Ag(s) + Zn(NO3)2(aq)

0.10 g of zinc is added to 15 cm3 of 0.25 mol dm–3 aqueous silver nitrate.

What is the mass of silver metal that would be formed?

A 0.16 g
B 0.20 g
C 0.33 g
D 0.40 g

Your answer [1]

24 15.00 cm3 of 18.0 mol dm–3 concentrated hydrochloric acid is diluted with water to prepare 250 cm3 of dilute
hydrochloric acid.

What is the concentration, in mol dm–3, of the dilute hydrochloric acid?

A 0.0675
B 0.270
C 0.300
D 1.08

Your answer [1]

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 25 The Boltzmann distribution showing the activation energy, Ea, for an uncatalysed reaction is shown below.

What is the difference for the catalysed reaction?

A The activation energy shifts to the left.

B The activation energy shifts to the right.
C The curve flattens.
D The curve shifts to the right.

Your answer [1]

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 26 A student measures how the OH– concentration changes over time for a reaction.

The student plots the graph below.

What is the rate of reaction, in mol dm–3 s–1, at 200s?

A 2.2 × 10–4
B 2.8 × 10–4
C 1.8 × 10–3
D 4.4 × 10–2

Your answer [1]

27 Which statement explains the trend in boiling points down the halogens group?

A Covalent bonds become stronger.

B Induced dipole–dipole interactions (London forces) become stronger.
C Ionic bonds become stronger.
D Permanent dipole–dipole interactions become stronger.

Your answer [1]

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 28 A hydrocarbon contains 85.71% carbon by mass.

What is the empirical formula of the hydrocarbon?

A CH
B CH2
C CH4
D C2H4

Your answer [1]

29 Hydrogen can be prepared industrially by the reaction of methane with steam.

The equation is shown below.

CH4(g) + 2H2O(g) → 4H2(g) + CO2(g)

What is the atom economy of hydrogen for this process?

A 3.8%
B 4.3%
C 15.4%
D 17.4%

Your answer [1]

30 How many p-orbitals are occupied by electrons in a sulfur atom?

A 2
B 4
C 6
D 10

Your answer [1]

31 Which substance has the lowest oxidation number for sulfur?

A Na2SO4
B S8
C SF2
D SO2

Your answer [1]

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 32 Successive ionisation energies, in kJ mol–1, of an element in Period 3 of the periodic table are shown below.

1st 2nd 3rd 4th 5th 6th 7th 8th 9th

578 1817 2745 11578 14831 18378 23296 27460 31862

What is the formula of the oxide of the Period 3 element?

A Na2O
B MgO
C Al2O3
D SiO2

Your answer [1]

33 How many oxygen atoms are in 120.2 g of SiO2?

A 3.01 × 1023
B 1.20 × 1024
C 2.41 × 1024
D 3.61 × 1024

Your answer [1]

34 What is the meaning of the term electronegativity?

A The ability of an atom to attract the electrons in a covalent bond.

B The ability of an atom to gain an electron.
C The electrostatic attraction between a negative ion and a positive ion.
D The size of the charge on a negative ion.

Your answer [1]

35 Which compound is an alkali?

A CH3COOH
B CH3OH
C HNO3
D NH3

Your answer [1]

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 36 What is the number of paired orbitals in a sulfur atom?

A 4
B 6
C 7
D 8

Your answer [1]

37 Which element has the lowest melting point?

A S
B P
C Cl
D Ar

Your answer [1]

38 The first four ionisation energies of a Period 3 element X are shown in the table.

Ionisation energy/kJ mol–1

1st 2nd 3rd 4th
738 1451 7733 10 541

Element X is reacted with chlorine.

What is the formula of the chloride formed?

A XCl
B XCl2
C XCl3
D XCl4

Your answer [1]

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 39 A sample of lead(II) sulfate (M = 303.3 g mol–1) is decomposed by heat, as shown in the equation below.

2PbSO4(s) → 2PbSO3(s) + O2(g)

The reaction forms 2.40 g of O2(g).

What is the mass of lead(II) sulfate that has been heated? Assume a 100% yield.

A 22.7g
B 30.3g
C 45.5g
D 60.7g

Your answer [1]

40 Which volume of 18.0 mol dm–3 hydrochloric acid should be diluted to 250.0 cm3 to prepare a 0.450 mol dm–3
solution of hydrochloric acid?

A 4.50 cm3
B 6.25 cm3
C 10.0 cm3
D 32.4 cm3

Your answer [1]

41 What is the number of ions in 4.00 mol of magnesium chloride, MgCl2?

A 1.81 × 1024
B 2.41 × 1024
C 4.82 × 1024
D 7.22 × 1024

Your answer [1]

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 42 What is the correct explanation for the trend in the boiling points of chlorine, bromine, and iodine down the
group?

A Bond enthalpy increases.

B Chemical reactivity decreases.
C Electronegativity decreases.
D London forces increase.

Your answer [1]

43 Complete combustion of an alkane forms 30 cm3 of carbon dioxide and 40 cm3 of water vapour, under the same
conditions of temperature and pressure.

Which alkane has undergone complete combustion?

A butane
B ethane
C heptane
D propane

Your answer [1]

44 Which substance has a giant covalent lattice structure in its solid state?

A potassium
B silicon
C sodium chloride
D water

Your answer [1]

45 Which sequence has elements in order of increasing first ionisation energy?

A Na < Mg < Al
B Mg < Al < Si
C Al < Si < P
D Si < P < S

Your answer [1]

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 46 Which element has atoms with the largest number of unpaired p-electrons?

A aluminium
B oxygen
C chlorine
D phosphorus

Your answer [1]

47 The Boltzmann distributions below show a gas at two different temperatures.

Which Boltzmann distribution shows the dotted curve at a higher temperature?

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 D

Your answer [1]

48 Which compound contains the smallest bond angle?

A bromoethane
B ethanol
C ethane
D ethene

Your answer [1]

49 Which compound has the highest boiling point?

A ethanol
B heptane
C sodium chloride
D water

Your answer [1]

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 50 Pauling electronegativity values for the halogens F to I and some elements in period 2 of the periodic table are
shown below.

B C N O F
2.04 2.55 3.04 3.44 3.98
Cl
3.16
Br
2.96
I
2.66

Which bond has the correct polarity?

Your answer [1]

51 Which compound releases hydroxide ions when it dissolves in water?

A CH3COOH
B HNO3
C H2SO4
D NH3

Your answer [1]

52 Which alkane is 82.8% carbon by mass?

A CH4
B C2H6
C C4H10
D C8H18

Your answer [1]

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 53 Which gas sample has the greatest mass at RTP?

A 50 cm3 of Ar(g)
B 100 cm3 of O2(g)
C 150 cm3 of N2(g)
D 200 cm3 of Ne(g)

Your answer [1]

54 A student mixes 250.0 cm3 of 0.100 mol dm–3 KOH with 750.0 cm3 of 0.100 mol dm–3 Ca(OH)2. What is the OH–
concentration, in mol dm–3, in the resulting mixture?

A 0.0250
B 0.100
C 0.150
D 0.175

Your answer [1]

55 After delivering a solution from a pipette, a droplet remains in the tip of the pipette.

How should a student ensure that the pipette delivers the volume of solution stated on the pipette?

A Fill the pipette just above the graduation line to compensate for the volume of the droplet that remains in
the tip.
B Leave the droplet in the tip.
C Shake the pipette to force out the droplet left in the tip.
D Use a pipette filler to force the droplet out of the tip.

Your answer [1]

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 56
A student reacts 24.24 g of 2-bromobutane in the reaction below.

CH3CH2CHBrCH3 + NaOH → CH3CH2CHOHCH3 + NaBr

M r = 136.9 M r = 74.0

The reaction produces 4.81 g of CH3CH2CHOHCH3.

What is the percentage yield of CH3CH2CHOHCH3?

A 10.7%
B 19.8%
C 36.7%
D 54.1%

Your answer [1]

57 Which statement explains why ice is less dense than water?

A Hydrogen bonds are stronger in ice than in water.

B Hydrogen bonds hold H2O molecules apart in ice.
C Ice is a solid but water is a liquid.
D Ice contains hydrogen bonds, but water does not contain hydrogen bonds.

Your answer [1]

58 Some Group 2 compounds can be used to neutralise acid soils and to treat acid indigestion.

Which Group 2 compound would not be suitable for either use?

A BaSO4
B CaCO3
C Ca(OH)2
D Mg(OH)2

Your answer [1]

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 59 Which p-block element contains atoms with one unpaired electron?

A Al
B Si
C P
D S

Your answer [1]

60
The equation for a redox reaction is shown below.

2HClO3 + 2HCl → 2ClO2 + Cl 2 + 2H2O

Which statement is correct?

A Cl is both oxidised and reduced.

B Cl is oxidised and O is reduced.
C O is both oxidised and reduced.
D O is oxidised and Cl is reduced.

Your answer [1]

61 Potassium ferrate(VI) contains two potassium ions for every ferrate(VI) ion.

What is the formula of the ferrate(VI) ion?

A FeO3 2–
B FeO4 2–
C FeO5 2–
D FeO6 2–

Your answer [1]

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 62
The unbalanced equation for the reaction of copper with concentrated nitric acid is shown below.
.........Cu + .........HNO3 → .........Cu(NO3)2 + .........NO2 + .........H2O

What is the number of moles of HNO3 that react with 1 mole of Cu?

A 2
B 3
C 4
D 6

Your answer [1]

63
2.0 dm3 of Cl2 gas reacts with 2.0 dm3 of Cl F3 gas to form 6.0 dm3 of a gaseous compound.
The reaction has 100% atom economy and all volumes are measured at the same temperature and pressure.

What is the molecular formula of the compound formed?

A Cl F
B Cl2F3
C Cl3F2
D Cl3F3

Your answer [1]

64 Which sample contains the greatest number of molecules?

A 1 g of methanol, CH3OH
B 2 g of nitrogen dioxide, NO2
C 3 g of phosphorus, P4
D 4 g of iodine, I2

Your answer [1]

65 Which substance contains polar molecules?

A C2H4
B CO2
C NCl3
D SF6

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 Your answer [1]

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 66 What is the formula of silver carbonate?

A AgCO3
B Ag(CO3)2
C Ag2CO3
D Ag3CO3

Your answer [1]

67 What is the main reason for the increase in reaction rate with increasing temperature?

A The activation energy decreases.

B The activation energy increases.

C More molecules have an energy greater than the activation energy.

D The molecules collide more frequently.

Your answer [1]

68 0.24 g of an element, X, is reacted with 0.0100 mol Cl2 to form a chloride with the formula XCl2.
What is element X?

A carbon

B magnesium

C molybdenum

D titanium

Your answer [1]

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 69 A phosphate(V) ion has the formula PO43–.

What is the formula for copper(I) phosphate(V)?

A Cu(PO4)5

B Cu5PO4

C Cu(PO4)3

D Cu3PO4

Your answer [1]

70 Which reaction shows chlorine only being oxidised?

A Cl2 + H2O → HCl + HClO
B 2ClO2 + 2NaOH → NaClO2 + NaClO3 + H2O
C 4KClO3 → 3KClO4 + KCl
D MnO2 + 4HCl → MnCl2 + Cl2 + 2H2O

Your answer [1]

71 Which chemical process is the most sustainable in terms of the atom economy of the organic product?

A CO2 + 3H2 → CH3OH + H2O

B CH3CH2OH + NaCl + H2SO4 → CH3CH2Cl + NaHSO4 + H2O

C CH3CH2Br + NaOH → CH3CH2OH + NaBr

D CH3CH2CH2CH2OH → CH3CH2CH=CH2 + H2O

Your answer [1]

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 72 8.0 dm3 of NO is mixed with 6.0 dm3 of O2 at room temperature and pressure (RTP).
The reaction below takes place until one of the reactants is used up.

2NO(g) + O2(g) → 2NO2(g)

What is the volume of the mixture at RTP after the reaction has taken place?

A 8.0 dm3

B 10.0 dm3

C 12.0 dm3

D 14.0 dm3

Your answer [1]

73 What is the volume of 0.0100 mol of N2 at 350 °C and 200 kPa?

A 145 cm3

B 259 cm3

C 145 dm3

D 259 dm3

Your answer [1]

74 Which statement about the periodic table is not correct?

A The elements are arranged in groups with similar chemical properties.

B The elements are arranged in periods with repeating trends in properties

C The elements are arranged in order of increasing atomic number.

D The elements in the halogen group increase in reactivity down the group.

Your answer [1]

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 75 Which molecule contains the largest bond angle?

A C2H4

B H2O

C NH3

D CH4

Your answer [1]

76 What is the percentage composition by mass of nitrogen in (NH4)2CO3?

A 14.58%

B 17.95%

C 29.17%

D 37.50%

Your answer [1]

77 1 mol of a compound reacts with 8 mol O2 for complete combustion.

What is the formula of the compound?

A C4H8

B C4H9OH

C C5H11OH

D C5H12

Your answer [1]

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 78 The first five successive ionisation energies of an element Y are shown below.

1st 2nd 3rd 4th 5th

496 4563 6913 9544 13352

What is the formula of a chloride of Y?

A YCl

B YCl2

C YCl3

D YCl4

Your answer [1]

79 Which element has induced dipole–dipole interactions (London forces) in its solid lattice?

A boron

B magnesium

C silicon

D sulfur

Your answer [1]

80 What determines the order of elements in the Periodic Table?

A first ionisation energy

B number of electrons in the outer shell

C number of protons in the nucleus

D relative atomic mass

Your answer [1]

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 81 The electron configuration of element X is: 1s22s22p63s23p4

What is the formula of a compound formed when sodium reacts with element X?

A NaX

B NaX2

C Na2X

D Na2X3

Your answer [1]

82 What is the number of oxygen atoms in 88.0 g of CO2?

A 3.01 × 1023

B 1.20 × 1024

C 2.41 × 1024

D 4.82 × 1024

Your answer [1]

83 A compound has the composition by mass:

H, 5.00%; N, 35.00%; O, 60.00%.

Which compound has this composition?

A HNO3

B NH4NO3

C HNO2

D NH2OH

Your answer [1]

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 84 Sodium reacts with water as shown below.

2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g)

Which mass of sodium reacts with water to produce 960 cm3 of hydrogen gas at RTP?

A 0.46 g

B 0.92 g

C 1.84 g

D 3.68 g

Your answer [1]

85 Which equation does not represent a neutralisation reaction?

A Zn + 2HCl → ZnCl2 + H2

B 2NH3 + H2SO4 → (NH4)2SO4

C Na2CO3 + 2CH3COOH → 2CH3COONa + CO2 + H2O

D CuO + 2HNO3 → Cu(NO3)2 + H2O

Your answer [1]

86 What is the oxidation number of Fe in K2FeO4?

A +4

B +5

C +6

D +7

Your answer [1]

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 87 Which reaction shows oxidation of sulfur?

A 2HBr + H2SO4 → SO2 + 2H2O + Br2

B SO2 + 2NaOH → Na2SO3 + H2O

C 8HI + H2SO4 → 4I2 + H2S + 4H2O

D H2S + Cl2 → 2HCl + S

Your answer [1]

88 Samples of four hydrocarbons are completely burnt under the same conditions of temperature and pressure.

Which sample produces the greatest volume of CO2?

A 0.4 mol C2H6

B 0.3 mol C3H8
C 0.2 mol C4H10
D 0.1 mol C5H12

Your answer [1]

89 Which reaction produces the smallest atom economy of BaCl2?

A BaCl2•2H2O → BaCl2 + 2H2O

B BaO + 2HCl → BaCl2 + H2O
C BaCO3 + 2HCl → BaCl2 + CO2 + H2O
D Ba + 2HCl → BaCl2 + H2

Your answer [1]

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 90 The burette readings from a titration are shown below.

Final reading / cm3 24.95

3
Initial reading / cm 5.00

The burette used has an uncertainty of ±0.05 cm3 in each reading.

What is the percentage uncertainty of the resulting titre?

A 0.20%
B 0.25%
C 0.45%
D 0.50%

Your answer [1]

91 Which element has atoms with the greatest number of singly occupied orbitals?

A C
B Cl
C Ca
D Ga

Your answer [1]

92 Which compound has polar molecules?

A OCl2
B BCl3
C CCl4
D SCl6

Your answer [1]

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 93 Which element has the highest melting point?

A silicon
B phosphorus
C sulfur
D chlorine

Your answer [1]

94 What is the best explanation for the trend in boiling points down the halogens group?

A The covalent bonds become stronger.

B The hydrogen bonds become stronger.
C The permanent dipole–dipole interactions become stronger.
D The induced dipole–dipole interactions (London forces) increase.

Your answer [1]

95 Which silver compound is insoluble in concentrated NH3(aq)?

A AgNO3
B AgCl
C AgBr
D AgI

Your answer [1]

96 Which ion has a different number of electrons from the other three ions?
A Ga3+
B Cl−
C S2−
D Ca2+

Your answer [1]

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 97 An organic compound has the composition by mass:
C, 53.33 %; H, 11.11%; O, 35.56%.
What is the empirical formula of the organic compound?
A C4H8O2
B C4H10O2
C C2H4O
D C2H5O

Your answer [1]

END OF QUESTION PAPER

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