(1001CJA102122066) Test Pattern

CLASSROOM CONTACT PROGRAMME JEE (Advanced)

FULL SYLLABUS
(Academic Session : 2022 - 2023)
22-04-2023

JEE(Main + Advanced) : ENTHUSIAST & LEADER COURSE (SCORE ADVANCED)

ANSWER KEY PAPER-2
PART-1 : PHYSICS
Q. 1 2 3 4 5 6
SECTION-I
A. B,C A,B,C,D A,C A,B,C A,C A,C
Q. 1 2 3 4 5 6
SECTION-II
A. 8.00 4.68 5.00 4.20 2.25 20.00
Q. 1 2 3 4 5 6
SECTION-III
A. 3 6 6 4 3 1

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6
SECTION-I
A. B,C,D A,B A,C B,D B,C A,B,C
Q. 1 2 3 4 5 6
SECTION-II
A. 32.93 to 33.00 51.20 14.00 3.47 or 3.48 1.40 12.00
Q. 1 2 3 4 5 6
SECTION-III
A. 5 4 9 2 5 2

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6
SECTION-I
A. A,C A,B,C,D B,C A,B,C A,B,C A,D
Q. 1 2 3 4 5 6
SECTION-II
A. 0.08 0.75 1.60 1.33 0.83 0.66 or 0.67
Q. 1 2 3 4 5 6
SECTION-III
A. 1 7 0 2 0 9

HINT – SHEET
PART-1 : PHYSICS q1 =
C1
×Q
C1 + C2
SECTION-I Qε 1
q1 =
1. Ans ( B,C ) ε1 + ε2
Qε 2
q2 =
ε1 + ε2
Qε 1
q ε 1 +ε 2
ΔV = 1 =
C1 2 πε1 ba
b−a
Q(b − a)
ΔV =
2π(ε1 + ε2 )ba
as potential difference is same Using Gauss Law
q1 q2 q q2
∴ = E 1 × 2 π r2 = 1 ; E 2 × 2 π r2 =
C1 C2 ε1 ε2
2πε1 ba q1
C1 = , C2 = 2πε2 ab E1 =
(b − a) b−a ε 1 2 π r2
q q Q (b − a) Q
ΔV = 1 = 2 = E1 = = E2
C1 C2 2π (ε1 + ε2 ) ab (ε1 + ε2 )2πr2
q1 + q2 = Q

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2. Ans ( A,B,C,D ) 5. Ans ( A,C )

For loop 1 ϕ1 = 0.2 × e−2t

d ϕ1
E1 = − | = 0.2 (−2) e−2t | = −0.4 vot
dt t=0 t=0

⇒ 0.4 V in Anticlockwise
Phaser diagram of given circuit d
E2 = − (0.2 × 2t) = 0.4 in clockwise direction
3. Ans ( A,C ) dt
Now in loop 1

0.4 – I1 – 3 (I1 + I2 ) = 0

⇒ 0.4 = 4I1 + 3I2 .... (1)

in loop 2
0.4 – 0.3 = 3 (I1 + I2 ) + 2I2
0.1 = 3I1 + 5I2 .... (2)
1. T – mg = ma
a by 3 × (1) – 4 × (2)
2. Mg sin θ − T − f = M
2
MR2
3. (f − T ) R = .∝
2
a
4. =R∝
2
4. Ans ( A,B,C )
0.8 8
dQ = (4m)s (–dT1) = (2m) (2s) dT2) ⇒ I2 = = A
11 110
1 8
− 5 (− 110 )
On solving we get 0.1 − 5I2 10
now I1 = =
3 3
1 40
Temperature of point P remains constant 10
+ 110
I1 =
3

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6. Ans ( A,C ) PART-1 : PHYSICS
Velocity of particle after time ‘t’ is given by SECTION-II

v = gt 1. Ans ( 8.00 )
Distance travelled in time ‘t’ is given by Change in momentum of 1 particle = 2 Mv0 cos θ
1 2
S= gt
2
No. of particle striking per second per unit length
Now, we know that
→ →
V I/M = −m2 V O/M = (nv) Rdθ cosθ
→
Here, V O/M = gt π /2 π /2

f= ∫ (nv R cos θ)dθ[2mv cos θ] cos θ = 4nmvR ∫ cos3 θ dθ 2

π
− /2 0

π /2

4nmv2 R
= ∫ (cos 3θ + 3 cos θ) dθ
4
0
π
8nmv2 R
/2
sin 3θ 2 ∣
= nmv R [ + 3 sin θ] ∣ =
3 ∣
0
3

Also, 2. Ans ( 4.68 )

f −f 2f dN
m= =
f gt2
= = q − λN (q = 108 nuclei/sec)
f−u −f + ( − )
f+ gt2 dt
2 2

V1 = Velocity of image N t
dN dN
2 ⇒ = dt ⇒ ∫ = ∫ dt
2f q − λN q − λN
= −( ) . gt 0 0
f + gt2
4f 2 gt 1 q − λN
= 2
(– ve sign indicates that image ⇒− ℓn ( ) =t
(f + gt2 ) λ q
will move upward)
t1/2 q
For maximum speed of image ⇒t= . ℓn ( )
ℓn2 q−A
dv1
=0
dt ℓn2
f ( ∵λ= ) and A = λN
⇒ t=√ t1/2
3g
3√
vmax = 3fg t1/2 108 t1/2 10
4 = . ℓn = . ℓn ( )
ℓn2 (
8
10 − 7.5 × 10 7
) ℓn2 10 − 7.5

= 2t1/2 = 4.68 minute

1001CJA102122066 HS-3/12
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3. Ans ( 5.00 ) 5. Ans ( 2.25 )
Sol. r = tan 53∘ W = 2 ω0 =
2
h
4 √
LC
r=h
3 L
and liner XL = WL = 2 √ ;
C

1 1 L
XC = = √
WC 2 C

P = VI cos ϕ

V 2R
P= 2
R2 + (XL − XC )

Energy supplied
Flux through slant surface of cone containing
πR√LCV 2
shaded section E = PT =
q q R2 + 2.25 ( CL )
[1 − cos 53∘ ] − [1 − cos 37∘ ]
2ε0 2ε0
q 4 3 q 1 q 6. Ans ( 20.00 )
= [ − ]= =
2ε0 5 5 2ε0 5 10ε0
M2 r
q
⋅ h r1 =
10ε0 2 M1 + M2
ϕthrough shaded section =
2π 4h/3
3q M1 r
ϕ= =5 r2 =
160πε0 M1 + M2
4. Ans ( 4.20 )
P itch 0.75 GM1 M2
LC = = = M 2 ω 2 r2
50 r 2
no. of circular divisions
= 0.015 mm
GM1
Negative zero error : ω=√
r2 r2
20 divisions × LC
2 π √ r2 r2 2 π √ r3
⇒ 20 × 0.015 = (–0.3) T= =
√ GM1 √ G(M1 + M2 )
When metal is put
Measured valve = 3.75 mm + 10 divisions × LC
= 3.75mm + 10 × 0.015
= 3.90 mm 2
3√ T
r= G(M1 + M2 )( )
TV = MV – (zero error) 2π

= 3.9 – (–0.3) = 4.20 mm

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PART-1 : PHYSICS 3. Ans ( 6 )
SECTION-III
1ℓ = 103(cc)3
1ℓ = 10–3 m3
1. Ans ( 3 ) 1000
Rate of water flowing = ℓ/ min
7
= 1 m3 / min {ρ = 1000 kg/m3 }
7
Rate of water flow = 1000 kg/ min
76
Power of source = P × 10 watt/sec
Let for a 60 sec power supply
Energy of source = P × 106 × 60
using energy conservation
P × 106 × 60
= 1000 × 1 × 4200 (60) + 1000 × 1 × 2268 × 103
7 7
i0 = 0.5 A 42 × 6 2268
P × 60 = + = 36 + 324
7 7
When; S2 is closed; P × 60 = 360
P=6
di 4. Ans ( 4 )
−L − 4i + 4 = 0
dt E0 h2 n2
di rn = , where μ is the reduced mass
−2 − 4i0 + 4 = 0 πμe2 z
dt 1
⇒ rα
di μ
−2 + 4 × 0.5 + 4 = 0 [∵ i0 = –0.5A] μ z 2 e4
dt Also ionisation energy E =
di 8 ε h2 n2
2

=3 0

dt ⇒ E αμ
For H-atom, μ = me and for positronium,
2. Ans ( 6 ) μ = me /2
rE0
At half power frequencies, ⇒ =4
r0 E
5. Ans ( 3 )
Z = R 2 ⇒ |XL − XC | = R
√ Using mirror formula,
1 1 2 xi xc
+ = , we have x0 =
2 xi x 0 xc 2xi − xc
1 1 2L
( ωL − ) = R 2 ⇒ ω2 L 2 + − = R2 Also,
ωC ω2 C 2 C xc xc
− xi
yi 2 2 xc − 2xi
=m= xc
= xc
=
4 2 2 2 2L y0 − xo xc
ω L C −ω ( + R2 ) C 2 + 1 = 0 2 2
C yi . xc
⇒ y0 =
xc − 2xi
The product of roots is Now,
yi . xc xi . xc
y0 = mx0 + C ⇒ = m. +C
xc − 2xi 2xi − xc
1 1 ⇒ −yi xc = +mxi . xc + 2xi . c − cxc
ω ω
2 2
= = ω1 ω2 = =ω 2

1 2
L2 C 2 LC
0
2C ′ 2C
⇒ yi = −xi [m + ] + C ⇒ m = − [m + ]
xc xc
⇒ ω0 = √ ω1 ω2 = 60 rad/s ⇒ ω0 /10 =6 Now, ⇒ m = − 4 , C = 5, xc = −50
5
4 2×5
⇒ m′ = − [− + ] =1
5 −50

1001CJA102122066 HS-5/12
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6. Ans ( 1 ) PART-2 : CHEMISTRY
at any time t SECTION-I

1. Ans ( B,C,D )
ωA = ωB = ω/R

v t = ωB x
BN is having graphite structure.
u
vt = x BH3 (g) → B(g) + 3H(g), ΔHr = 1119 0

R
1119
BEB−H = = 373
vb = u 3
B2 H6 (g) → 2B(g) + 6H(g); ΔHr = 2402 0

dx 2402 − 373 × 4
√ Vt + Vr = u
2 2
Vr = BE3c−2e− = = 455 kJ/mol
dt bond
2
2 2
u 2 dx 2 2. Ans ( A,B )
( ) x + ( ) = u
R dt ‘R’ is least acidic.
2
dx 2 x2
( ) = u [1 − ]
dt R2
R t
dx
∫ = u ∫ dt
x2
0
√ 1− 0
R2
R
x
R[sin−1 ] = ut
R 0

22
28 × 7
= ut
2

t = 11 sec.

10 + x = 11
In option (D) :
x=1

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3. Ans ( A,C ) 6. Ans ( A,B,C )
(A) is correct because K = Ae−Ea /RT
dK KE
T1 V γ
1
−1
= T2 V γ
2
−1

dT
=
RT 2
T 1 dK Ea
T1 = T, T2 = ⇒ ⇒σ
2 K dT RT 2
1.25 × 106
V1 = V and V2 = 5.66 V Ea = σRT 2 = RT 2
T 3
T 1.25 × 106 R
T V γ−1 = (5.66 V )γ−1 Ea ⇒
2 T
2 = (5.66)γ – 1 (A)
1.25 × 106 × 2
T = 250 = ( ) = 104 Cal/mol = 10 K cal/mol
Taking logarithm on both the sides we get 250
(B)
log 2 = (γ – 1) (log 5.66) 1.25 × 106 × 2
T = 2000K = = 1.25 × 103 Cal/mol
0.3010 = (γ – 1) (0.7528) 2000
⇒ 1.25K Cal/mol
1
γ – 1 = 0.3998 (C) dK α 2
dT T
γ = 1.3998 1.25 × 106
(D) dK = σK = ×K
dT (2000)3
γ = 1.4
= 0.156 × 10–3K
CP
= γ = 1.4 PART-2 : CHEMISTRY
CV
So the gas is diatomic. SECTION-II

(C) is correct because work done 1. Ans ( 32.93 to 33.00 )

P 2 V2 − P 1 V1
W= = 1.25 P V
γ−1
4. Ans ( B,D )
BBr3 is having high lewis acid nature.
P4O10 has 6 POP bonds.
ClOF3 & XeO2F2 are isostructural.
% of R–2–bromopentane
5. Ans ( B,C ) 4 × 82 65.86
⇒ × 100 = = 32.93
Phenol does not give NaHCO3 test. 6 + (4 × 82) + (2 × 82) 2

2. Ans ( 51.20 )
is more acidic than (PNH3 )2
Reaction Quotient QP = 3
at 1 hour
(PH2 ) (PN2 )
(200)2
due to ortho–effect. QP = = 100
3
(50)(2)

ΔG = −19.56 kJ/mol
–19.56 × 1000 = (–4.2 × 1000) – (300)ΔS
ΔS = 51.2 JK–1.
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3. Ans ( 14.00 ) 2. Ans ( 4 )
In CrO , number of Cr-O bonds = 4
2− (i), (ii), (iii), (vii) are the correct combinations
4

Magnetite Fe3O4
In Cr2 O , number of Cr-O bonds = 8
2−

Gibbsite Al(OH)3
In CrO2Cl2, number of Cr-O bonds = 2
Copper pyrite CuFeS2
4. Ans ( 3.47 or 3.48 ) Galena PbS
PCl5 and PBr5 both exist in ionic form in solid
Cerussite PbCO3
state, both give H3PO4 and HX on hydrolysis. Lunar caustic AgNO3
Bromine is liberated from NaBr on reaction with Dolomite MgCO3.CaCO3

conc H2SO4 (this is not possible with NaCl). 3. Ans ( 9 )

Theory based.
Hence, a = 5, b = 3, c = 4 and atomic weight of
4. Ans ( 2 )
Bromine is 80 amu. Hence 80/23 value is 3.48.
At constant volume
PART-2 : CHEMISTRY
N = number of gas molecules
SECTION-III

1. Ans ( 5 ) σ = collision area (depends on molecular size only)

Cell becomes 8RT

uavg = average velocity of gas molecules = √

πM
∥
∣ ∥ ∣
Hence correct statements are (i) and (vii).
+ +
P t, H 2∣
∣
H ∥ HK ∣
∣ P t, H2
Ka .C1 ∥ w
(1 atm) ∣ √
∣ (1 atm)
∥
√ Kb .C2 6. Ans ( 2 )
RT [H + ]left cell 1, 3, are correct.
ECell =0− log
nF [H + ]right cell
(Ka C1 )1/2
= −0.0625log10
−1/2
(Kb. C2 ) . Kw
−5
√
10 × 10−5 × 0.1 × 0.1
= −0.0625 log
10−14

= –0.0625 × 8

ECell = –5 × 10–1

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PART-3 : MATHEMATICS 3. Ans ( B,C )
→a . →r 10
SECTION-I given =
→
|a | √3

1. Ans ( A,C )
3
⇒ x + y + z = 10, x,y,z ∈ N
[ x2 ]
I=∫ dx ....(1) total number of positions = 9C2 = 36
2
1
[ (x − 4) ] + [x2 ]
2
(A) Number of natural solutions of
3
[ (4 − x) ]

I=∫ dx ....(2) x + y + z = 7 is 6C2 = 15

2
1
[x2 ] + [(4 − x) ]
(B) 6 × 6 = 36
By Adding (1) & (2)
3
[ x2 ] + [(x − 4)2 ] (C) ∵ 1800 = 23 × 32 × 52
∴ 2I = ∫ dx = 2 ⇒ I = 1
[ (x − 4)2 ] + [x2 ]
number of divisors = (3 + 1) (2 + 1) (2 + 1) = 36
1
Also, (D) Number of cyphers in 120! = exponent of 5 in
2 1 2 2

∫ ([x] − [
x
]) dx = ∫ [x] dx + ∫ [x] dx − ∫ [
x
] dx
(120)!
2 2
0 0 1 0 120 120 120
=[ ] + [ ] + [ ] = 28
1 2 2
5 25 125
= ∫ 0. dx + ∫ 1. dx − ∫ 0. dx (where [.] greatest integer function)
0 1 0
=0+1–0=1 4. Ans ( A,B,C )
2. Ans ( A,B,C,D ) f (0 − h) = lim 3−h = 3∘ = 1
h→0
Given equation
1
∫ dy = ∫ ex (ℓn x + x
) dx ⇒ y = e . ℓnx + c
x
∵ the curve passes through (1, 0)
∴ 0 = exℓn1 + c ⇒c=0

y = exℓnx ⇒ ƒ(x) = ex.ℓnx

(A) ƒ(x) > 0 ∀ x ∈ (1, ∞)
(B) ∫ e−x . ex ℓn x dx = ∫ ℓnx dx = x ℓn x − x + c f(0 + h) = λ
ex . ℓ n x e1+h ( ℓn (1 + h))
(C) x→1
lim = lim =e f(x) is a continuous function and λ = 1
x−1 h→0 h
(Put x = 1 + h) Range of f(x) is (0, ∞)
1 1
(D) x→1
lim 1 + ex ℓnx
( = lim 1 + e1+h ℓn (1 + h)
h→0
)
x−1 ( )
1+h−1
f(x) = 1 has one solution
∞
= 1 form (Put x = 1 + h)
f(x) = |f(x)| is always possible
lim 1
(1+e
1+h ℓn(1+h)−1 )

=e h→0 h

e1+h ℓn(1+h)
because f(x) > 0 for all x ∈ R
lim e
= eh→0 h
=e

1001CJA102122066 HS-9/12
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5. Ans ( A,B,C ) 2. Ans ( 0.75 )
2
ƒ(x) (x – 2) = x – 5x + 6 ∴ 'ƒ' is continuous E : Rose bush has withered.
A : Gardner did not water the rose bush
2
P (A) =
3
1
B : Gardner watered the rose bush P (B) =
3
E 3 E 1
P( ) = ;P ( ) =
A 4 B 2
P (A) . P ( E )
A A 3
P( ) = = = 0.75
E E E
P (A) . P ( ) + P (B) . P ( ) 4
A B

3. Ans ( 1.60 )
x2 − 5x + 6 (x − 3) (x − 2)
f (x) = = = x − 3,
x−2 (x − 2)
for x ≠ 2

6. Ans ( A,D )
f' (x) = −e−ax ax2 + ( ( a2 − 2) x + ab − a)
∵ ƒ(–2) = ƒ(1) = 0
( a2 − 2 ) ab − a
⇒− = −1 & = −2
a a
⇒ a = 2 & b = –1
f ′ (x) = –e–2x (2x2 + 2x – 4)
f ′ (x) = –2e–2x (x2 + x – 2) 1
V = (Area of Base) × Height
f ″ (x) = 2e–2x(2x2 – 5) 3
f ″ (–2) = 6e4 > 0 ×d
f ″ (1) = –6e–2 < 0 d=
18
=
6
units.
PART-3 : MATHEMATICS √ 126 √ 14
4. Ans ( 1.33 )
SECTION-II
e3x − 2ex
I= ∫ (f (x) − 2g (x)) dx = ∫ dx
1. Ans ( 0.08 ) e4x + 8e2x + 4
2
− x2 Let ex = t
e − cos x 2
k = lim 1−
x→0 x2 4 t2 1 −1 ex + 2e−x
x4 x2 x4
I=∫ dt = tan ( ) +c
( 1−
x
+ −. . . .) − (1 − + −. . .) t2 + 8 + 4 2 2
2 8 2 4! t2
= lim
x→0 x4
1 1 1 1 −1 ex + 2e−x
k= − = Hence, h (x) =tan (
8 24 12 2 2
)

1 −1 3
h (0) = tan ( )
2 2
∴ a = 2, b = 3, c = 2.

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5. Ans ( 0.83 ) PART-3 : MATHEMATICS
RHS = 2y2 – 8y + 21 = 2(y – 2)2 + 13 ≥ 13 SECTION-III

LHS = 12sinx + 5cosx ≤ 13 1. Ans ( 1 )

Let S1 = α + β + γ and S2 = αβ + βγ + γα &
∴ RHS = LHS S3 = αβγ
⇒ 12sinx + 5cosx = 2y2 – 8y + 21 = 13 ∴ S1 = 6 & (α + 1) (β + 1) (γ + 1) = 33
⇒ S3 + S1 + S2 = 32
Now 2(y – 2)2 + 13 = 13 ⇒ S2 + S3 = 26 ...(1)
⇒ y=2 Also, α3 + β3 + γ3 = 87
⇒ S1(S12 – 3S2) + 3S3 = 87
Similarly 12sinx + 5cosx = 13
⇒ 216– 18S2 + S3 = 87
12 5 ⇒ 18S2 – 3S3 = 129
⇒ sin x + cos x = 1
13 13
5 ⇒ 6S2 – S3 = 43 ...(2)
or sin(x + tan−1 ) = 1
12 Adding (1) & (2)
x 69
For least positive value of ⇒ 7S2 = 69 ⇒ S2 =
y 7
π − tan−1 5 113
x 2 12 1 −1 5 & S3 =
∴ = = cot ( ) 7
y 2 2 12 1 1 1 S 69
∴ + + = 2 =
6. Ans ( 0.66 or 0.67 ) α β γ S3 113
x − √3 y 2. Ans ( 7 )
Line AB = =r
cos 60 ∘
sin 60∘ 13
|zn | =
2n
r r√ 3
x = √3 + , y= ∴ zn lies in part S ⇒ |zn| < 1
2 2
⇒ n≥4
r r √3 2
∴ Point (√ 3+ , ) lies on 2y = 2x + 3
zn also lies in IVth quadrant
2 2

3r2 ∴ minimum value of n is 7

∴ = 2 √3 + r + 3
2 n = 4 then lie in Ist Quad
n = 5 then lie in IInd Quad
⇒ 3r2 – 2r – ( 6 + 4 √3 ) = 0
n = 6 then lie in IIIrd Quad
PA and –PB are roots 3. Ans ( 0 )
→c = →a × →c + →a × →b ...... (i)
2
∴ PA – PB = ⇒ →a . →c = 0 ...(ii)
3
6 + 4 √3 Also →a × →c = →a × (→a × →c ) + →a × (→a × →b)
P A. P B =
3
{Taking cross with →a }
→c − →a × →b = −→a 2→c + (→a . →b) →a − →a 2→b

( 1 + →a 2 ) →c + →b × →a + (→a × →b) × →a = 0

1001CJA102122066 HS-11/12
 Target : JEE (Main + Advanced) 2023/22-04-2023/Paper-2
4. Ans ( 2 )
1 1
log2 y + 2 (2x + x
) log y + 2 (2
2x
+ ) = 0
2 22x
2
1 1 1
( log y + 2x + 2x 2x
x ) + 2 (2 + 2x ) = 2 + 2x + 2
2 2 2
2
1 1
( log y + 2x + ) = − (22x + ) + 2
2x 2 2x
 
⩾0 ⩽0
–2
⇒ x = 0; y = e

5. Ans ( 0 )

As, MMT = 4I
⇒ MT = 4M–1
adjM
⇒ MT = 4( )
|M|
⇒ 2MT + adj.M = O
T
⇒ |2M + adj.M| = 0

6. Ans ( 9 )
1 n−6 1 6
P = n C6 . ( 3 3 ) . (4− 3 )
1 6 1 n−6
Q = n Cn−6 . (3 3 ) . (4− 3 )
Q n−6
∴ = 12 ⇒ (12) 3 = (12)1
P
n−6
⇒ =1⇒n=9
3

HS-12/12 1001CJA102122066