0 ratings 0% found this document useful (0 votes) 5 views 29 pages Solid State PDF
The document appears to be a fragmented and disorganized text discussing various concepts related to crystallography, including unit cells, packing efficiency, and coordination numbers. It mentions different types of voids and their significance in crystal structures, as well as various examples of atomic arrangements. Overall, the content seems to focus on the properties and characteristics of crystalline materials.
AI-enhanced title and description
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content,
claim it here .
Available Formats
Download as PDF or read online on Scribd
Go to previous items Go to next items
Save solid state pdf For Later
Jol liol State
asta 1 Sell Ubode *- ~ SO peace
2. gate
mite MAAA @ y Vol™ and ape - __«
maeteeut, shark. a
2 dre Aid a
4 uty, comsttlaent: Upaniteses tla ota 8
on. tao Weta pew “eg obeut tain 4
VS Sapa ss —— -
iat Se atie
‘ep Mildabany tn sate
im en ¢ tof samp 4
‘Wt + tt ” ihusa. fl
* se ed, eat \
ee @ 4
HH |
es a fie ‘
WY de on
tft AN not hay
i : pipet [Link]
ma pon - Parade! astiole or,
osopeend— en nce : (Capua cnet og| Ge | | |
oS cece | oe rit | | |
|| Lio 2 |
oo cate Ie i array
si) |
| rod dt |
arity | ays Nees t kibelee | || |
7 | ab Lagererrg| | nr i Bae | wag) ree
, | ] lf r
S1] ep) rst | Nach sh ees || | | pote
ial ae Sees |
S| senerG Atos stag vy “werahge) ape; Bice nh
~} i | spn ners
j | Daprzemeve peed) RY
| Tenany3 oe there) | 4 bot | Frey beh
rola wle en ey eet ere eetall
~atYfla Lats pc Lattiee / 3-D Lathite t=
ie ea pape Ph see rene in pate .
ee “in
Unik Cell: = St da the -emallect portion
the while eae i Har entine Lattite a
int dig. iy
“Unde “eell a el y_edlge
aybse
Saha ania unit collet fe w« PY
bho. -pabal b4 wh @ be,ta Mh
aan nan nr eraeeehenvaa
~
«
~
é
-tate ingonad_=4 -
_ Fed Dia "+ & axe a1
*TMAL ane 8 Commend in Cube and | cermin ai
COM mow _ tn _ 8 Wwbe. _ >
Sy t8_tomtans in its pwn cube is Ve,
»
Tike hau 6 ipa F gee tonya.
Sp-2- Les_tentaibution_in it own Cube is Yo
»o Angle fas 120 pt Gee edie le costa fo
+ Gs "nb sibadiens in ittoum ube is Vey
sel ae me
> Gus dnd sgl Sh semi at .
sins pO feof ise
Xx Cian
ya me tmtrr > dates
vid
d
ocLupies
XY,
Lind ioletudes wale
Quy molecular _formular
9 a
oe eee Pepe Lge ce
cons
Yr edges centre op KE 22 Y
A
Trey Triste.
Gus, a
A ali is pont B t : 4 Ave ad
tone pes 10-4 ty a 4 Jackie
cate btl Bd aces ane minsi ” contre ©
Yoon fe {mal fo ee «
- 2 “qe 2
l $l
ae Ld
«
dy ene —+
~ Ag BoC 5
, A _ oe
Ac oec © BI. dees [xe e
ee .
mead
oa solid is Ay OB Fey mrt
aocFe 1h ee
wcugt boy tt wnt * Lircl mpl. fe poy told p — =
RB pla -3
tn-7]
Ophir
B> 3-1
fale *
A> [1-2
8
>£
As Bie os
irk: Ser: 11%; 9 A Bagle
ae 2 i 2 comme
= &
8
>oPReRr Rr RFR E_— th L Unit eld p— —
O Wriwistiae / simple Cubie Unit cell —
Koddite Voint’ + ot! corners Y tuebe
Z = ne :) be Portela in dnit Coll
«Bx ID
g
- Zep —
Coordination Wo. + ne- Tcasat mnelyboun, partic
ote Around _a saceip c! particle fn crystal
(atttee Afa CN.” nl - “ -
CN: Of S06: = 6_*
—o 7
212 a
=
— ps) 7
- — =
a ve Ce (clistowme = fa) *
~ — ~ {2 eee =
_ —__Tetol cube atten aid -
~ A — A tube shan tommen-——_
“[el) aah he. :
meanest tui 2 iu = & [stone °Sae)
lena Cond AR, - 5
ot _ Sa 22H is __j
- © - , :
- oe escllenseto5 :
Packing gin Vel. fs bu ates .
PE. = Z Xam x4 a, oes .
. a Tans Be OSH ou 52:4 %,
i uvid space = 0 (1m), 2 4F.6Y
density = way, Si 2 2x Min
as
-- em he@
Lattin Doimt .- Bodie
22 84 4+ j - tomo 2 mee
Yeuching cond” -
— B a-2A xX
Ba. on,
z
CN con, of ¢prnen atom in tle untd cell = 1.
A ce Oho is Shared in 8 cubes
WH & ON, Cormmr atom = 9
We ON ely in Afom <3
= 8 Xx Bins amt cell a elistsnts fea face)
21 :
212 [Me thanedl by 2 Cubes
Pez zy SRn
a2
= > 3
= LX 3%? ax tar
~ [ay or ER
Ts SHA? 3
. 353
cbbseesad
R
. 7 = 0:68 or 6827
-[J-Bx
(1 B®) peo = 32%“EL
Gy +
t thwdee net tout each oun
~ CN unrb- to “Wwrwnor adem = 8430 212
2
CN. Wart: fee tomtrud atom =I2- _ -
t
CH temo + 8 on cote)
Khas id 12 dittanee "= a 8 m) _
mepntak-npphbam, 6 Colintanee =
me es Ce " )
! —
i)"TTT VPP wPeegCeeCe eer KTVITIIIF ICL IFFY
qrened 2s uses 43 Hy NS ‘
dlentity. = 2.40 i
‘ { FX Nn
118 | es
s oH a —
2 Voiol = (= Jive = 264%
Be
on) -
20 ae -
ex Ct. —_
z e__[Pa_= 4n_
= SG XM =A A >
fy = -
i A= ROU AVY =
221 ERXAAN
Qe ah
Bx bor = 1A
lol
Density = 4X Rai
'
'
|
|
Closed Parked; 4
0000 yO
[Link] Parked Lin 2D =
ok
O- SH Osu), 7 OM ot @ 4
in_L-D ic __
veel
aA ),
6
‘ogee
oS
fem
Hex
“ Pent nat
ABAB ~ ~ t
in 3D I- ype
S. tlased Paging —
1 Bt ly mut ~~ _
SCC|
LISS
hah
| |
=|
3D (year,
pe
Fig jon PN
eevvvewsy
“im marti Layer. -
Y amp -
type vt - _lt
2 Naat
Abe / ta
aaaaa
@aaa
“se pepevrveneagaevvvervvwrrrwrere
|
|
+eanaegaguegeace@ecetr(
4
}
a is box)
| cores Unik cetk oad Cn (oa)
————
Pe. 2 ZAKS
— yet Umit_cell -
2 6x 4 xp ——,
fT rn +
ae@oeaetean hao atm.
7 It in Frcangiles 6fe vate dighnudly —
> Henee rH ON. iw 4
Pog” berahural Void in Fete. i
In Fi Ome COMA oom, + andre ato
permed at “at dttnaludnal vail od ab ate
fot Pa ty
oer etc Petra araiaaa
o=
“dliasyonnad. in tube hence
Voids in Fee _
% Hun Coordinktes 1" A (% 9% 0)
ok
face comma tom 8 (4 , 0, %)
0H AD
_ vail 7 (Spt ——
dinkawnn OP =
a
Anion at comms ——_
Catlomunak Voi dy _
Qetabed al Voids s-
Un vortant gate biw 6 tewelri cy
Ribas sida - 9 1 tit
Fe q Odtahadaal oe in-Fec_
rye = weer wrrcecewertrtervrvdedly teuctnn A edge costar —
~ Me Gf ttindsal veld in fee= p+ lex
— _ _ 2 epee
angele grt
~ lt
Neo «of akems ‘in Jee unit cell = N=4
Nog, ep octmbudral Avicle SN =H
ourhing Cond” + p -
VIVID
Quu Akow, Aa tai lewd, Fee, atom @ ts +n
“at ettalednral I void, atom) C iw tnt at 257% om
“‘ttaducdrel void» Find. sub hu MP
Atom A» FCC 4 AXg eI Xe
- - 8
-
Ys
=U atten:
Atom B > Octahedrel Void = Yoho s
Akoya tC — 856 Y Terrabedrel Void- as xg2
_ ATO
= 2 atoms PIC
AuByC, = ArBal
nenaeannvaand
|
|
|
ai
f
‘
\
t
i
iy
=i!
3 !
:
belle about ; sp itl a
SISSL IIS
» - ~
Y
bY - _
+e = _2-b - _
Reg of a ar jel -
7 ) ONS E AN ¢0.295 —
~ . ahs Oe -
CoNe = Y —— UebAmhedyl 2
~~ ~ ~
© Letrahurabt Anion = F-c¢ -
» YA. = Gi aw -O _
wy Cation > Jetrrkrelratuoiol
+ Ar tA Ba
w a
» Yas ture > [Ba —@
2/\ Ware + YA 2
UA. nem
= Ar ay B
s Ae & ;
* ft. Bo -1= B-f
Pe Ap ZzQe sneeseensenmnenemeneiesset
“t* fet nakadrsl Vi
tL as 22 At Zz
oe roa
quent
$ 2, sq
~ DAL tI a J
omy
R
“oe Pi yi Ht Ae £0132
aa VAM atmadmanra
ane oe eee aanaPllrlvadral veld ob. 0:6: OMB
2Az= a ~Q ak get. 2
Pare aer
et rity Ba QO or bee
2N4+ + - BH 2 1732
Ojos tas a
a ae 213971
\ $ 20-13%
Y cent oclabedrsl Void at BCC C-N-=8
S a “01138 < fs a a ;
S_ if Ae a
Soon. f— Motel — Rane Enample
yo 4 {ys 9 ABS fs C058 B20,
wa —Jetrakednal Doth ZnS, Si0,,
S i 5 J CaF
yO , LA 4
wi ee Pits
Ya Ottahednal a B34 Cae (ora. Nath, wg
» keh
my Ft 8 _ Octabednab in, <1 seh
5 ~
pe Joie ¢. -
° at i da atl 4 i / -
> + ec a
* - pias > Dedabudrad ff
no unit cell there xe eae aniwna 4 tations
% Nay tly = 4 Natl, 4
2
> There are fe Units in a unibedl- te, z24
: foomula.ala aaae
|
|
almla mliaid a @
|
|
a
P— Ue Ee me i
|
= WE ase | de ml,
_ cabo) —__—_ - i
Pe. = ZZ 7
4 Lalickes ay “liz Nay ky, fe.
Drides § "ulphiolia of, Ukaline ead metal -
evite nm & +
Sphakestt mye 2 e Ripe be. Foe,
“Fatt = wat athewmnake “Tet Netds
a lel oo »
50 of “elnaludnal VadVetta dd
»
>
»—
r "E+ 3 5 [ moi be
Pe GEE At egyation 21
» Cation = 0-84).
~— Bits Bees aos Cath, Cu Bry Col.
»
'
Fluorite Jype Ca taht Ea
de ig ifn cer, tg am
amon 2? THV
x Thow_one 4 codiens 6, 8 arions in “ene _urntt cell.
CayFe = 4CaFy
Want ans “pple unt im a unit cell
A= UXM
Nara?~— Dhin, BY rea ina wk coll
[No.4 /Dsy_3¢ 4NaJB/) 2 —
= '
Thao roby wie pt Lees 2 yy
a= 4xM
—_Na xa
coken = 4
pono
____®
_ -
-
7
a° =
1M xf a2 (es) =
= Ss - - a
2 “y CAL — -
5+ Sallr _ = —a
Bak,’ Ball,
eee pe «Nao - _*
CoP Vine Fee —4
tation TH -_ 4
anion: &
= cond” re we > a
pes 8% tx ann xA\o0
: Gaga 200 | a(az)ar] —
_ a -
= fear)
Pe. = 15°63 7% Murion = Ty
a bation eics iDenes
(SCL type t lita =
om is aa
Ware t
uni wll yee aan V -
sia fovea ue in unit cell 2=]
Na xa?
oe
{
verre
y ON at =
rns AL Cae “
a Vourhi uaa" Bart RA- = [Ba
» - So At tae = fae
¥ Pe. = 1x ERR EERE ERA Yoo
— 2 4Rae ce K je
: a
; + ee OF J
»
aor n lattices wr dislocation
— fn “Da Vai
1. Mikaotion in solid
8+ Ayentoue in temp,
— .
eck in CAystalr :
aie in dowel t ofa an dilsed due by
'
'gti Dyed
On pital, eyes — a
Pirin dap now - Slaiekevmatn. Sale
Selottl Metal, d . Metal inne
afl oe Coteus inva Tap {>
Okaltaiomebay at ‘ dipet —T
Schottky De ine tryetads vit et hdeln
\- 4 CN. fs
Q Di ein ip timo
ST Natl, Cot
2 8 Ktry A
chi doje phased de
val
tlio, dient tn enya ry Meat
@ exansrosvoFFiciaL Oousew © EXAMSROAD oO EXAMSROAD—Fawadkel Tapa “ teund im _dabfels im vokielh.
ON. 44 Lor, |
ear mee ge
hte AR fol pl “a Fanelli
Res Sm tp
at nov cortieyy)
feaues i ne Se
- wltes of dati > :
Restle
+ Solid Rematns electri Newaal
“* Denafhy Aemalnssames ~
WE is Kens ,ee rte
«
€
«
-@«
*
atl, ti 3
ie N wredeal hinted in_ tno abroogphere @
at Heat gt fe ft i
=
a
@
=
¢
a clerk eb.
Oi ea ——
Forbenzenben,
Scoloy
In0 a + VaOn +1EO 7-\~- TPT erty
E Founsl in tanmsthion
ae bo Deft L
an a peat
Stade ‘lal Geb
tHerkniratl neutral
wtos Daichacine, Stake “wa
eget
“aoe ital of tower. frisdaltan
maintoi. the
M ekoul ion.
42 i — ps, Se
Feo — Fe.430. z VES
Oo: o7 Fe’ leaves Site
i Fe** jon
toss Me Te
24 2 KO: 07 = 0-14 Fenn
boo "0-07. Fe?” i qr =
hh fe?" 2 O-l¥ ax 170
0-93
‘h Pet = 190— pep her”
feet 7% -
fet 28 0:93 -%
3x + 2(0:93~ %A)- 2=0
XH 20-14Oil