Scribd
Upload
6 views28 pages

Organic RXN

The document appears to discuss various chemical reactions and processes involving organic compounds, including methods of preparation and reactivity. It mentions specific reagents, reaction conditions, and the implications of certain chemicals on health and the environment. Additionally, it touches on the historical context of some compounds and their regulatory status.

Uploaded by

raghavishukla242
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
6 views28 pages

Organic RXN

The document appears to discuss various chemical reactions and processes involving organic compounds, including methods of preparation and reactivity. It mentions specific reagents, reaction conditions, and the implications of certain chemicals on health and the environment. Additionally, it touches on the historical context of some compounds and their regulatory status.

Uploaded by

raghavishukla242
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
MOA (ANE | aaa Cat-ee | C=¢-¢ ‘- leyytt we | : | ce | OF chee fetrytidene ] ee | Vinyl sy Allyl Chloves GBenayte chloride T > Be >@ CE Che > Cu ser ul Nethed x Prepration @ From Mohol # (Best method an Yeshol eosity Qwailable) a) CHC -OK +H Be SMB + Ho [fie ncn be # Grove Process Negi Be (ust) ° [us Tat] ROH + Hy Zot : tu core, Ray. TAR Ho 7] Zale seq? Ke ool Ue eyn: ans ze 7 °&2° Alcohol « ~ PPR-GH ie We A243" ng Shy . x Reactivity S HX HI PHB, HOLS Hp only fe Ram ROH 32> a2>7° Ron +HYX 0) R-OH +NaBr + Hys0y R~Br + NaHSa, + Ko a Row Red P Lx R-X + Hy Pos Exact f [o> esr] dues srt (a) Bron +p . a . oe ae SR-X + Hs PO; Row 4 eke. R-h + HO + Pot, BROW = Sot, ——+ R-@ + 50, + HU Pheftugl ow = Pls Oe oi [Ron +sou, Meda, QR +s, tHe] Sse oe a it give trust (Inversion) e ; reno) fos panxl double ; Mote method not aphicabls, An Arug ralllele A pheno. pad double: wei ©) Hewgn ciel HCH, Oa, | HSomauc = mono & pelynaloatkaay [hic beStposte pum Cmpouy A. CN OG ML CH, oh CM, tH, EX ie 5 bow veld J LOle Ch \ Cig tO AL. Cee nee ee ha tHe, +a | Shy + @ pikenes Lorne HET _ «HK + x —_» \ 7 [x qoo 6" fo Markon’ how ral a FTN 5 pee tate, Prove onnle cf Ae HY ~ CHU act + _, uv S m * Cech, + concn —T oe r, (riage) Cainer) &) with (hy = City iene St CHC (Red otane 7) tap ect a ee pra) vic dittanide Oy Dts. ae : / Nu +r Cts Ses Km ” ON Ol Ete TR “cae iS Grd -H + HH ee TkKM TRAM lane ee pas mod chy Ne= a? cH + By. w Wy e * eras Teo. \ Q)EX ita Reroride Ch, = CHL Hop Peers cy ey cut, ~R, fo Fallos Anti markonikoy /xhowsh /Poromdt fel mr goes w core H ofm] He AHI don't follow /his~ © Halogen on cheng o Fiesta X 4 No T eset Rag eNaX LOT nae) feo 365, Br (Report 3} oa oSWart2 2 Hb TYE ——— cl, P+ er Ry : ee iy 4 85 #597 [905 4.6 Hot / ab fge “OO Car ae © Yo (arboxylic Acad L Hunsdick er K~E-0H fare Ro Br + 8 thy ‘tz: RK Peormde —OH op eo |e A fa : 6-hebstu urn ™ p tebe hovslons a “OO «n _ FP ° . _t . ay @) +N, +8F, Fe malin RAS Ahher x : L * (Oem f sen WS J Ret : : - fe U, br. (ux + p Us + (y+ ee LS p. & v coos (0-0-NERT J ee GRE: © +H,O , 0, =e oe “A ana (loud . Boam a0 “ec — ep Mdas 7 Hydrocrbor froperk 4 ost F a (da TOP. ome ors orprm? oe Grok gon 0 Rb > RO PRH-E ? if sie eet ot Lo J] or & « [psoe aT wae EW pnsihy s RL 7K te Re > RF Lp boos = i tds, ak Saub' hy + pheakkoe wy 03 Atos alle! Ved OY gt . Sf Pisa na ‘ AN FTA NCE e eo Nucleophihe arbste Aches RV aN HR - nog _ Reagent Nacleoph rs Nadi HO WoO Wo NaOR? or Nol r NM, NI RN, ann, Renn Rea “KON Cent Ay CN Ayre Ne K NO, O=nN-0 Ay No, Ay -S-n=0 Rico Ay R’coo” > LAH H a 5 fe Cet 27Gb & nw “Yams deny Nacleoph & fey Qolable a a Woy RCE WRVAILO e-RND, Pye) SMD *E re tty (2 rude) 2 Ge Cloth teveciecy” svily aio I8 54° RDP KBr HR Ce > RF. er NN NaN io 1 Pode! (Obl VIX Rell ROR? ) Ne RS RN, nr? aAne’e? RecN RNC RO gN-O RIND, Hono BN ric=w® 5 NO > B= n-0, \ Wame Dicoher ' Mex pothes Aibyl wel « ra - 3° Aasiet Nel Troniinde Nieyk Nitrile lire A} Rar Rc OOR Bier x ie wy Hy obo coh * . wee At enw VO Ha Sex Te Donee. Tae leoahy group < oan sone 3 Ce Ae eee ae y2, Joa) we Reacrivity | gavin’ / 8 Ce SN) & [A-X9 401: —» on. fi ee eee a aCe tae a> RT > RO, > Row 60-767. Taverston + Faroe Race misty ) OH foam J OQ ep) OP Sedu) A lu)c-o + Ry > ef es 4) DR, [Rirakion of Casual Pa oot ( Reactiuy 5 d Z den ; [he ue © ~ deny x r % 44 Oe NE, atuck] o >t& 28> Now eae t nove) : x Benoyre fehs ‘ eo wt NH, OT NS ry € = > Cin Product Polar Profie , “protic i [rte support Hy corer Wa. | nae | % , SD, M0, RON of iy DME, Bmsoy : Re | CHAN, DEEL] | : senee oe Limination Ra? ef, elimination = [oehy clehetegusti | aa i Ly B ~ elimination Katt SC See pel 2 Soroy 9 bao evo, CSP, fr cher —cy, en, HE KOH, f fa Ch, A= CH. & 4 Les n= o1en, “ek (Satz yate) lactaan) -aoncopt @ ery — Gf — CH, Oh, Lacou , Ch, He ~¢, ; = Satagatt coe 5 “4 pe Miaor + low o> bedkiee gy wall Pe H from [HOFf man Product) 52 Hoff mon py oltre les Wade! B @ Eee Helton fase, © Ey elemnation CH, % no os > Cty~ C~ Br Chae 4 ay LO j ay) cs q : J cu, a eDehalogenation § Oh CH Za, Ch, = OL + Pale 1 t D cee # ble froph PMc SebdSt bath RAs oO rtolo en ation sf a, Mb fell, C . (Sy meoe D@ Writra Hon » x & HNO, ( oe Ao, Co core LOL cy of New @suf 5 a gior DSulphonation (Sy tenn, ¢ ee ay Sot a (ey 2 SS : sou @ Fredel ol! Ru yor Ale leben t” w@ ra Ae cnyca fila, a oe EG the a Ba &. Sy GP + (O01, atay men, & ip ReeW phe rane Nbuut 2 2 RX + 2Na + Rx —eyerher “RRR 4 2a a ayer he Fig: RX + 2am exp, ogy ee . Rt anex ne 2 Eathing PRX # 2M + Phy eg ee | “Gi grent fe Aeseenl PRB Hg EEL Rh Gy ons ne seen gmy muse | FRMGX + HO» Ry +My lon ve Org Shor = Reagent «at frie Rot Aga 2 Rx! gas. Bon +X cme ee hits NoNiy : es ae es — Ehovactin like Heohelt Kor] 4, deprotorotion > cy cacy MMs Gy, c= Chat ee ng Chloride # harms human CNS, re to Lew buel Sepaival Hevea Vision MEK tue oD tren, Nousta, Nunb , bn aie con tach * Intense kurnit. redatta Gin cornes! 3m ; (OOp Pm > ditalave febyue , heacla che Produchion Of freon Releicont R22 < eager 7 a / 5 we erat to bony Red ene tiers xe Pevelop sores we, bul eet 4 ain jn Preince of qf light che Cade ra fi Chlocide PPhognegene 7 CHC Storeol in dente Mp2 eee “ 2COCL, + 2H Prot phos + Cl; 4 o —s aw rena tee (dee Helier © Antise pire cartier (fibers nw objectieneble seth td) Tetra chlore methane (Cy) eranh Propellant fer ALros0) cara . = exposure liver catboen Bei vin ayn these oy Chlorate Corben eat, nousen, ae * Phanmacernbol merufartwrig ~ gourd sehen leak aie coon tes ee ee 2 feet peat veptn or Sop “He exbageibe Ae Se aRe ugh dagen © Freon Shin concer , Bye Sifpox, chiar [bemmen fem > Freon 12 (Ce FJ . > 4 DDT eens By suc, & - e i di chro -trichlore ethene “om pints gin, A, a, a by AT > DRI ompound pro dacher |B tear ata ° MeN toxic, bmeactuc, sipble, \ > as “Ta sec Huds« iS Non covociye, easily iepuifdbe, \is ediesasa copula ou Shika free quecttat ciate Re natore ja Reine FTO OH QT in shatorcphure thal upsek ozone anne co USA te 1973. ae Aiko - ketones ee 5 on names ® 0 Feo comm cK, cm Fen HEHE — CIQErfO oe Moe aihg hecbtddyts COT Ree pHeesne in Held Arr Prepration ® adation of Mlcohel ) ey [0], R-cho Rs © Re 3° Alora Cree Stray a Tima et 2) Deludeo aeration ef Ache! core nd chy sng Ve -F. “SS | 3) Hydration, 9f Atkyne oe cr) A y2 cH fascia A 300°C (673K) Sct aie ax [x Not shows by ~ Atcohor | es — Hag Se gots D ozo0e ysis of Rirenes. ; & eo BN ON LE : Noe 3 at ELE anes Nese a FNez oe 4 2n0. ‘ ian i £25 A n eit bre E ae Meneggdhide 7 * free of Kelone “J (all below) - / hey! ad (acid chloride ) | Rosenmund Reduction] J e Fa [Ba soggy SMMC Renu R- BL a PaleasecS R=tHo 8 Picto ot FF (Gailey) te oe nt Xylene or * de go, or" 6) Nitrile or Ester (Reduction) 0) RCN WDibal -H Sone) Hao ———-r R-CHO [oaey Aen. 8). ° - Ssebaty alumay ccm» byYR~ Cop? > 3 PRE SOR nT Bek we Hes — i * R~CHEcHH ¢ ~ CRC piel H HCN Mwai R-Ote(U~UH, Ho | D Steplan’s Re acten RCN + SO, +H, heh. RCHo D Etand‘s Reaction 7 Gronyl_chto Chloride or" eat Panes n Sau ae chtomae APS ne < FL sychtomic oxide + Jers-E-e-€ - cH ) NAN el / oO + 60, +(cK,c0) 0 Gratis roy Acetic Prhyesidle ™~ cHo 8) Gatier man kook TO) Co He, \ cio SF Pinky ALC At > ') Chlorination Ga oy _U hw) cr-Oe) wer aichovinonan™ et ex KOH, CS) CHO. + By G& bw he Shoo : ea, Kon, cooH “Prep Aketone ieee ty . toy ) Real | chloric, 2R-MgX + GUC, ——+R, Ue + 2g) didkiaeodaaco dialli! nium cod thie oR c~e Pe ho Rcd + 2@-c-R + Ga, oO 2 Nibile © ° RCN + gr myer HOM’, R_ dy, t 2) Frieda Galt Aoylation S 9 I oO} + —c- An r oO Ae/e—c-a tld Me yt. K~> Physical Properties Meohols > > hes ae Molar May oy se Xe of Gt ‘eee ketch sobebhity Maker May & “bona —— me Boiling Poin) f aa + Choon’ ¢ rep ercies Nucleo philit Addilron Ra? 7 t. + Ne ee Oe 20 SO GO os = ogo" b Tolermediale, [he yde 7 Ketone] oer il Nyt [HCHO > Ch, 0, > yoneney > MMH Ea s-HO D> Gus -—cho >fen)c-o fen =o > lend G) RA” Codigor Bisulphate : 4 =—_ Se ee e < OH an Ne PSGNE ‘ Ove Gee Noy De Rha Bele el cme R On wn Cerystetiney OE + pay HBS Le 1 ©) Re” Mecho y R 7 " oR” Brew RrOn dues, Rom a wn’ hos =a ORCH + Ho 4 Ww Soai oe wR i + Creriace tat] [Acetoa fae daltons c= + HO-Gy ( 5 “ ‘- sy Ha, R Me 4 eo 28 Re bn, Beep phe etn, | pate ae clic Acetas” a7 cyow reo. ce as 4 a 4 a7 dome d) oe & doravitives: igi tc cHO + N- - Ket " S HyNWZO oo E og, 8 Cage neha) Se Gigative Ee _ 9 ay NH (Ammo Lionel =| NHR (Ione) Ses NR fsaeitba] | rateel Iesing, 3 Hon | NK: ox [iysexylarine} Se = nH [oxime 7] 2 ¥ NH, NH-NH, [Hydtezine ] Ne = No hy [uyaeasene ] J : -un-& 0 Ppigtecig] > dex 09-1 LS fegliperve] ay e 5 —RA- cH NH, NH ~ nb -NA, he cone 2 J (Set extarite] 1 Nae “a sc bazone, an HN my aegerag | | Pescrw By Sen Biggio [2,U~dnitrophenylnyataie] et “if 2 Recdur fon v4 orl a on LAL, oF Beg, 1 or yr Pali” — CN '© ) Wolf K'schner Reduction | fio Gy Nihon Xp eo Sh wienh Noy 1 A. arty \ | ral “ oo c Aumee we HHO | 7 eH at / 9 : cH! Red P frit Br —Ul, Bel? fut, Ch -Oh—en, FB) Oxrdaton [aidehyde oxidise cvly fron Keone 7 a) Rx" sth follen's Reagen Gg on [wis], 04 or 9,0 fo Stuer Mmitnor teat) Poombnicas Silve Aitrare ketone do ROT give R-v1o Tele Reagent » RCoQ~ + Matd pes tek y Blot ppt) ~ = 4 SYR vite Feb bs an Ny feagett [ftbin soins, 09. Geopper Sulphave | R- CH —Febttieg so” - 97 GIB SIE Btossiom Tat * Reoo™ + &,0 | Fiews soy, CRoehelle ott] cnn Flees Ganadaed a tal ¢ : : ) Oxtdtron of Kelone * Cppote’s tute) ieee - =n, £6 Loy, -R? ome Hao . © = 28 R- Oh, Sof P BROOK GR Rc, “coon > + RID COOH coe (i &) Koloform Tear. ate 3 £ NOX i 4 ~O-CH, ~e Ws + _ - a % Bion pict ® CHONa* My Xz [ G, 8,7] 4 4. Ms cM, ee Na OK? ny 5 Se eH » Nee + UG o% an tn SMe i foc defeckO Todeform fest with sodium nypotodide ts. ured ; _— > of co: or crewed) ar. which wake GCO ge ™ os 4 yee yd ne dus hudnoge, - x Shade gue aarboagl gr. 1) Ador’ conden sation . (sieagttrcishasmrD ond) Uy) Reacts on 2c), GiLWSO ¥ CH eH CH CHO Ay Hj —cH=ScHecHa CH Hs 7 ° 3 -Mydro ny Butorat i ilo! coasting ne C el] a rel 2 cycoc, si Nasi CMs i uy 3 or bao), cH & nye cH, on ; (Retor ] ") Cross Afdal condensation Wie seotsenl [gr CHycH Ne pee 7 bCHO + che CHO —NOOH Sto weor [* on on Bie §-€ -e~ cto Up yila's 2s as + ane ei] oo + Dew ow 9 2g oe - on ' r st 2, ©) 4 oe Comet a He OY GoGSr 1 SD Gnnizzaro ke? (ne & =H) (s) Wlee> Fee 4 aycrio tes Kove fe H-coona +0407 [RATS Fot mad delay Potasyum Semete — methanel Hoge ws Ste BO fs «Neon (s) Cress. Conni 22 ano Cae H-CHO + Ay O>-cno PUCH 0 ahoeys getontl red 7 Proce geactias ger ondsedy # ton eet SY, Cee | ae - Ff, —» iC0O- + LO con P a . 5 e R-c7 ——lan -¢ : Nowe: R- Coon + rg lon )x Wn Ter On", Wa”. RCCOH R~ Conn, “ean zarnllt 3) Alay! Benzene y on [eseuse CH, 501. ics Hy ee a= a oe tls _Keily /od” erst: go _ (oy wa” cor } rx v ae yu) Aydecips af ester. cr, FOG Ms + Heon eo Ci -e-On 4 Caior [Asse Hydrolssis gi ong toon 2 Neou yen, ‘ GUE OOM Cry C= ONn C4 Fon, get + Cats Of “ciao 5) heyh Holids @4 An luydade oe pb R-csonw — HW. fi fodthonds &@lon_, p-coom — 4 coon, ge HHO 9 9 Ps -€-0-¢-R? 2 AC -0-2-R? _ HOM gp coon + RCO. 6) Dida fH 9f Nt cohol O) 3 ee He May Kit,07 (Ter R-on FRenes t Ur Oy in aud Physicat feoper ty © less than Yatom ‘C' Clowrley + Unpies 7 Mere IH, Pleo f phen + Er tke 1 od Curlers Coon > C1Ofe ron] tipto totem 'c Hows Delon | © bese Inlermoloaian “Orem ANrorey — Com cat 4) NetdPy 2R- COOH 4 2K — Rec. Chany 22 C08 Recor + Woot ne coe e? + 1,0 RCO Re HCO, — 4 @ _coonn 4 Ho +a, R-Coo HW Wx - aa R~coe- | pros eZ] | Bkeeteo nerar ° | : 4 > R-c8, & ryt CR tren yy ritmo, 4 orMereltet &" » = ES ea aatl or phenigl in — | y ewep lr / “\\ . Sty Zw . ey Laren Ce 2 \ b iS OH HO or) ec Al Ethaneic acie ® Esten/fcation Ethanere Anhydiids R-COOH + Ron == R-cooR? + H,0 eee ©) KCOOK + PRs ——»5 RECOM + POR, + Hee m SR- COOH FP BROOK + Wy POs R-coon + FOU, > Reo + Sat + HOT Peeled D. & gsle Ammonia. 2 -coOH + Nt = coo t ‘ ° " oH NT SO Reon 4 H,O armonivn Mea Acetoamete & “ey £ Ei) COMM” CACO ph | 2 Speer” eeeon oe . Co Ny _ ecm ran Bact pty ca “Oy 2 ere fn ala so, Se SS Phthalic? * = ) Zqvetuiy Cort Dies Pata o) Reducer R-coort Su Hite fee or Bare a WD the mt———* — R-CH, Ong [ sitar” OF My nether © iF dom don’ cedoeg ee MiroX 5) pecorborybtien naar, i SES kt he, CO, 1C) Kolbe’s ele ctrolys ec 3) Substihoion * 5 Helo gen’ ation © Hell - Uthand— aliaskey fo" R-ci, ~ Ceon an fst id! Ff CB en [" ae i> es 2) Bing Subst fesh’on ¢ oa coon | | cs con anh | a [Fe8e, se core Hy $0, aa : . Common /Tue0C AN { o CO Gorm | Se Glechot x? Prepeator | os A) Alenes HT oy . Bci=G Gra Hign asoaeat ae ery «9 fate ‘narhon' kev. Hon doy menawy hom - Demenrculy hin + Open =e, DIF M06) 0h Hr YolONe), Me CH = San - Cleastinen tetrehadeal Hyco Be log 22" Gece a ow on | @ repatin on ws G Ore i Resorcino| oH 099 Ss deste @ On Mpfepuiene| ae a qaine! : 2) Hydroboca tion -Oxiclahian Cy cHe cH, 4 10, JOH” 8 THE [Ark meron ey rat, ay eon itis BOg-01,-cy or 1S Haden ea SPRkohol obtiree { { CH GSE rien 0g Gi) NaBH, oe “aj OHHH G04), eal 4) Realuchin of Mlehiyde Chefone ee ss R-E-y _B:A Rho RAS HAN 0 H [a : e ua, 7 R-C_p kA R-cu-R Ab eit on ROOM cany Redue COOH g, ester) &-CooH Shope. R-cH Stow A: LAL, : ; 7 QrpPnsive) a ; or us - e u. Therefore Recopn o" . R coon Taegan? ROOn + eo Coonverted 4. tne) f S) Grignard Reasgeoy : Catal jadi bn / Jf + OR Hee rr ; Adduech Metharak py oho! [ Aldehyde 3 | 0°? al Ketone 4 32, Tr f | \ [ge~> Phono ! f { Hobe D Heloornes oe BH CY ttn. CI © 623k, 2 Benzene Sulphoore Gerg [71 Ma80u +503) x oO ) Ofer ] — 3 Ren Piezonlun COt | wn, a | f ho. Wie O) _Noter OB 6 Aniline NS +) Cummens No oy cu b-0-0-4 ou 6 * t Oo a, 3} oe cH Come My : Cummene Cammene 5 Cees vevitl Hyd opero nds wot BPrayatet | eel? : atop 1. Mas BP: ° x BP [oe > RRROR, A! Branching & : aching Chemicel. _ Nucleophile => RSet” 3 RZO= Electophile = Reci-Ont + Wh ——+ R-cH, Se Be t Oy 7 On! —s br -¢ => Reidity ? Rx ily meted: ) 2ROM + 2Ne ——* 20 -o-1e 4 1 2ne » moe on, ¢ °) 1 Ot f on, Iw tne of om wat, FAL HE LS any bald bronafed hod Bary a feuteiot Me weaken acid hoy co BO jo a WO eg, Q ee hag 1 en On rod > pave i * Mkoriden ore M00 Nee besay Phonsl Mor Rou | R n ‘ R=OH > Ra soy >(0)-C-0n 7 duc OW, give © puicn ty 1 4° ae Cresol < Phen a . (0 & Om ndau > t eeepes | hai, > Eslerif cation T : ; 2 _ HK /R- OM + COOH — Ne /R-@ —'C-0R? FLO Trrcnee on 4 . 2 : p cone. Ho, Reon + ie, )o oe R-C=OR? , orn, Toe 2 DOG pevertte. RO + RCo Prine, R~b oR? + HO. Tegra Le NYuvtn Rex Reon + RHX Rx eno, [fe MSS nearebig Lucas Tents Reagent tt p20 2° Alevbel” Shows Yury Proms le ROR Me Reo yo fhe shane tome, Feed wii Ron ge a led agen SR-OH + PX, 9 ge 4 hy Pee R-On 4 PK, t Ao x + Hx. + POX, s R-on + sow, ~~ R-a 4+ soale nce f 3) De Ny dechn bE WSO, HyPOy, , anydroun Zine Grlorite, Aeamins (ether, be Reagents © FSOy 5 hy : its Us ~¢-¢- wt, 2 GHOK ee Lh. 30y Order ware 7 3°> 2! a eo) cn BS bP 4, fr F 2) we ou Se Ch ~CH= tH, + Uo # fee oy 20k Hy Poy | oe —%y +hLo ¢ 358 d poe : fron aaa : 7 ehydvo yon ~ : i) Orydation ee ol eb 7 yié-o-H —* F=0 RCHLOW bl. g- Ee eee Mildo-h = PCC 4 CrOz ,PDC j E strong OB KMnOy 3 On, Or 5 GO 1%? > Wer On At BY with Ge ‘ pecn,-on RONDO i S73 K R-c~ w? @ , p-o-#? on 5734 5 on ( en — 2° — on & ee es eA Fre aK, \ 4 Oy p enor. Rot i » 2) Frectrophib. ermmehe subd tachion 4 4 Maton : ; sete : ou @) Dil. Hag oy of on © -Nrivophend! eNO dy : eC conc. “tno, "6, 4 ncmemHINe, | re no, ert ie 10 ff Ser “O--H0 aa Trlramtuls 0 104 ; ss Irtem mejeostor (Picrie avd ) « Steom volafhQ BG) Helogenotion a ee ee ce SHR: 5'lbw fens. _ 38 Be _ 2, Ses bee ae ere _- 3Mb- s 2 Bromise a0 Her ) Br [ive preupriede [ cle Reo Renzoguunene (dikelone) = Glourlew 2 Beil at BFK 2Solstal tepaid ~ Longe quantity by’ H > ay se Hert by hyd i Ethanol )2) Brera on | Gy Hy, O, + HO Swetalts G4,0,-4H,,0, | Zy mage CoH, SE a neon +260, at 337K jn cor Cat ida) nee 9 RE By ree Tah leed thten i? "8 doth. noaareebic) Te ale act inks fernuntotin mith. , efter! pared , Veoyirh < bridges to ethanvic add => destrey Heafe~ Lommentiak Maho! mad? Win BE by adeltg Ay t0y ie 2 bnacturcatlon (or (oleae) 4 Pyridine Gage DI yee for al ea { Tupac + OM; | on: Bnisole | oe Pravetole | fh Prapration “CUOGn.# Alyy other GF )Delyarahin, _i1,60y eee Hupbat vie SM CA, = Ut, ont & P pliohel © cH “Tt a CR BOOS" Chon < K Aipte (vs ge ¥, $04 SD sh OGM ILSN, px? ee Willio, 10° Son Mo: col yp theres > np, Iebaralary method tye both gymetrick unyymat7e\ R-X + R— Spry > RO-R +naX KS (om)e-Gns + By W-o ne" | Aron” + kwyeg, | —* (4-0-clo + Nebr * R-ONe con bn 1,2 oe 30 bet | on “ One | oO Noon + Na oO A> Pra Aico Pro pertiey 8 (BPE Ether 3 Aton. ® Alcano! |Sobwoirty + l o¥ me Od Mleahe/ Etter just phe Hayho) dd y We nich San H 4 Chonitoat Ropandien oe Least tages BIE) Fanttioval yoo ca a R-0- RP > px iz. Rx + R=0y RON +HXK ~~ SAK + 70 8 on OP FNS SY ax [ Te LO Bowes ef PEI a) Swehen ou ~ & . SC Her, cy . 3g2 (Otinse J HNO,” + Oo) AO, 2-Ni boanical e = (Miner) ik) Friedl Gof Feiedal Croft Aiylaction z a ery ce ~ oye. Bally rt. 4 4 (onnory a (testis) Oo major es oc, 2] ~ _ Ants « ACL a an a ee coon, | Beece’) er ~ Pilea | M1 2 pretnory eerophenone (airor) Gn) Re F Ree ae eget soi tate Ls eg, 6 On cy cr, AO yes, W804 on i P [MINE cs chan Jur ac kanamine Strwchowe op | cS Ai kanaming Comm a; Alklamine —“] for «® ( R-NH~ Qs p & - vt . | R. er ue allyl atenomnn a) 9 NN-dimethyl metnamins oo mH Ws (oy i ‘ Zz UNH, CLC =e, eh = AdyLoming . i C- toluidine NSN -Lmefhayl ns? ore ee | pegsucion of 81% Compounds NO, M A 3) 2! or H AierPt Nit e ‘ > * OF” threo . + Hee Nr reek Prefered beer fF COL, Seemast oO ae hybuigseo te mabkeHCg 9 heh Puy, inthiote Ran 7 [8 Huo Jot 523% 5 sealed Tate Fp S { ea" x || a 2 > a 4 7 fet L RyN"X + NoOH ———+ R-NH, +O + Ra XH (steny Base) w Dis advantage However Order of Reactivity RE > KBr PRO ERE 23> Reduction A Noire, oa Ae diy WoO Weld mix ture amine a) Al Ay SOU, 2° db. ate awe + RN, 5 mape ve Amoronia a excess ester R-CH, —NM [eens & Amine Seve . ¢ Prep of Beniea One ‘C' more “hag seating amine Ps ¢ ~ CH, > CH, ~ NY, ex ket, 9” cn. a ee * Promaht peimany omic fan NOT ke i Hstf man Bromamrde degradation au” : 3 - Be: 10 > 2? pd Am Grow i? rm move H Ee a Abe Spler molec 608° fe fo Chincical Keach or Sree A O bare Mate oe Miphadic Amick > Prmoria 7 bene Ary GP bese & gry emt aE 3. Fane eos ea, bastely| * tela go Ame i [edto™ « apa yates HIN EY us Row, 7B @ >) Ag, laten as Gils nod oO 5 ‘ypueling » CH Nec nee body Cli, CO ane bg, N- Phanyl cthenom ce or Reetanilids + U4 Co lance pee Ot, Cooper Bonzamine ~ Benzoylation Ce" wil! ts Coca) cnn + ohr Cow —fitioling 7 TD Schatten ~* CHNH-d 6 yy +Ha Y ions Batina N-Octy benzamible J Ran mn 4) Coby lamin watlion Lor Asoryanide Test . c R-NH, + CHC, + Sion —2_| chloroform + fee + 3K aH 7 tis fee B bor tendseeeitnn J Arne S) Rx" with Nitrou acre Clout Seth), } NaN, +HOC . 0) RNA, +HNO, “+ Rota> “ROH +A, FHC Cl 1° Anite) aw NTE oS + Nall +20,.0 z aa 1 9 3 ° Ob~ N-N=O | Commo, ony Ke ae + [c we 6) gut wits + Aye Oe c Chloride (Tet is ste pote ) Ny _ 2 He Dog Page 2H, = Gt we CMs +Hee Beh Se, é N-e they Lpenzeiccul pheramd: ey rg exgon/) bong, wbphony! ojhe D Llechqtwbc Subst tebon + Benzene Sulphony tt. chlorise (tase % supleccd by B 7, jug (i Y Brtomuinalion. NH, 7 ‘NH, : Br 2 e oS HO /a, 8 SuBr Si + Bex, Hoe, . be 2,4.6-Tribromoarttiog , on wo og preceed a Mt, if See ou, 7 oe Sy «Cy , Pyridine ayes . ) 1 Anitine N-prengtethanamicle a i Trectanilise) (majood tng) ©) Nihration + NHL Hh ne win : = NO. Tien Beclinn Ithack wit S Wes MSO OY (ce 7 ay Se ha Ha 288K No, NS Seen Priliniam an NO, | aWeh 6 mebe direetig | a“ p(s] m [a7 go -L2%7 >) Sublphe nation nee NH HSC NH, NH, O*- = G—G y ist aS ee. mead Ani finan dao gen sulphate So, H = Hyseogensulp Selphonic ass Sea s Bwkder Pon Fried a Cafe se” [plhy lation Be UCC BAI) with Waminkun chianide (ca faslys) ), hug to Hus, < charge 4 hoe ach oy strong deactuatts gr? . if 7 piazontin _ Nex” [X= 5 Be, Heo WR J Dent ataven age] fe pipnaic ante om OE Ryman sab 1 Aeonate wre Uaroniun colt sie Shble tor chort tee i ow ten. Nia wre (3) NaNO. + 2HC (LO) “yar =a? + fall + 2H0 Bonrend? *Celburers Qpey stale soled. sazonium floxobele : foergtic net dre zoniim + Solubie sh“ usoter Physical foprt Li Sie ah rom 7p de © stable ik Caled + “deccrpose eeuly > dbysiare, Are Camitod Re” + Cu UalHtl .» as (l +N 7 los tra HBr Ae Be HN 4 Sandmeyor My AeCN + Ny Newer yall nee zy goikendnn ; 1 re ral ArCl +N, +CuxX } Gateman {ta hi 3 ASB AN GX — LKE Oy And + KU 4N, LHe Ar- NI BRO 7 ) J eo / HPO +0, ApH + Ny + HsPo, + HU a Rerixne dermal e Gore0e) {| Cig CHOW + iG@ROULGHO + Ha |! fReisere | * 4 KO ae OH + Nat Ha _] Phenol \ Cehenel] AN HER, be ane Bre eee ae Ng + NBR a, EEL A . 5) Coupling RA" Oi ntne . °. Oy-N* -0) cf xe »{O>-oH ee On > em Ls ed 4 4,0 2) ema (Owners "Xow, at, (O~v= Sait Gy teas eLbow og £

You might also like