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Subject Test No. Chapter No 10
Chemistry Part-II 4 Alkyl Halides
Time Allowed: 1 ½ Hrs
Maximum Marks: 25
Objective
Question: 1 Encircle the Correct answer. 5
(i) Which of the following is not a Nucleophile?
a. b. c. d.
(ii) Grignard’s reagent is reactive due to:
a. The presence of halogen atom b. The presence of Mg atom
c. The polarity of Mg atom d. None of the above
(iii) Grignard’s ‘s reagent gives alkane with:
a. Water b. Ethylamine c. Ethanol d. All of them
(iv) reactions are given by:
a. Primary alkys halids b. Secondary alkys halide
c. Primary alcohols d. Secondary alcohls
(v) What is the shape of carbanion?
a. Linear b. Tetrahedral c. Planar d. Pyramidal
Question: 2 Write Short answers of the following (Any Five) 2X5 = 10
I. What are elimination reactions? Give examples of .
II. Why dry either is necessary for the preparation of Grignard’s reagent?
III. What is wurtz synthesis?
IV. Differentiate between Electrophile and Nucleophile :
V. How will you convert ethyl bromide in to ethyl nitrile?
VI. Give the mechanism for the addition of Grignard’s reagent at to give carboxylic acids.
VII. Convert ethyl alcohol in to their respective halides by using and .
Subjective
Question: 3
a) What is Grignard’s Reagent? Give its preparation and its use to prepare the following: (4)
i) Propane 2. Propanoic acid 3. 1-Propanol 4. 2-Butanol
b) Describe briefly mechanism of SN reaction. (4)
c) Write two methods for the preparation of Alkyl halide. (2)