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Subject Test No. Chapter No 9
Chemistry Part-I Solutions
Time Allowed: 1 ½ Hrs
Maximum Marks: 35
Objective
Question: 1 Encircle the Correct answer.
5
(i) Molarity of pure water is:
A. 1 B. 18 C. 55.5 D. 6
(ii) A solution of glucose is 10% w/v. The volume in which 1g mole of its dissolved will be:
A. B. C. D.
(iii) Azeotropic mixture can be separated into pure components by:
A. Distillation B. Fractional distillation C. Vacuum distillation D. None
(iv) The molal boiling point constant is the ratio of the elevation in boiling point to:
A. Molarity B. Molality
C. Mole fraction of solvent D. Mole fraction of solule
(v) The number of moles of a solute per kg of solvent is called
A. Molality B. Molarity C. Mole fraction D. Normality
Question: 2 Write Short answers of the following (Any five) 2X5 =
10
I. The concentration in terms of molality is independent of temperature but molarity depends upon
temperature. Why?
II. Shows discontinuous solubility curve, when plotted against temperature. Why?
III. What is conjugate solution?
IV. Colligative properties are obeyed when solutions are dilute. Why?
V. Explain why give acidic solution when put in water?
VI. Molar solution in concentrated than a molal solution why?
VII. Define Azeotropic mixture.
VIII. Heat of solution of substances is measured at infinite dilution. Why?
Subjective (Any Two) 10x2=20
Question: 1
a) State and explain Raoult’s Law in three different forms. (
)
b) Non-Ideal solutions do not obey the Raoult’s Law. Why? (
)
c) Relative lowering of vapour pressure is independent of a temperature. Why? (
)
Question: 2
a) What are Colligative properties? Explain elevation of B.P?
(04)
b) The freezing point of pure camphor is . Find the freezing point of a solution
containing
2.0g of a non-volatile compound having molecular 140, in 40g of camphor.
(04)
c) Beckmann’s thermometer is used to note the depression in freezing point. Justify that.
(02)
Question: 3
a) Define molarity and molality. Differentiate between hydration and hydrolysis giving examples.
(06)
b) Freezing points of solutions are depressed when non-volatile solutions are present in volatile
solvents. Justify it. Plot a graph to elaborate your answer. (04)