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Subject Test No. Chapter No 7
Chemistry Part-I
Time Allowed: 1 ½ Hrs
Maximum Marks: 25
Objective
Question: 1 Encircle the Correct answer. 5
(i) Calori is equal to:
a. 0.418J b. 41.84J c. 4.184J d. 418.4J
(ii) For a given process the heat changes at constant pressure and at constant volume
are related to each other as:
a. b. c. d.
(iii) Spontaneous reactions are:
a. Reversible b. Irreversible c. Not Irreversible d. None
(iv) At constant volume is equal to:
a. b. c. d.
(v) Most of the reactions which give stable products are:
a. Exothermic b. Endothermic c. Isothermal d. None of these
Question: 2 Write Short answers of the following (Any Six) 2X6 = 12
I. What is system and state function?
II. What is the physical significance of equation ?
III. State why in a case of liquids and solids?
IV. State first law of thermo dynamics and give its mathematical form.
V. The total energy of a system is the sum of translational, rotational and vibrational motions justify it.
VI. Define (enthalpy of reaction). Can it be negative? How?
VII. How do we determine the in the laboratory for food, fuel etc?
VIII. Comment that enthalpy of neutralization is merely the heat of formation of one mole of liquid water.
Subjective (Any one)
Question: 1
a) State “Hess’s Law of constant Heat Summation” and explain with one example. (03)
b) Prove that (03)
c) Is it true that and have the same values for the reactions. Taking place in the solution
state? Explain it? (02)
Question: 2
a) How does Born-Haber cycle help to calculate the lattice energy of Nacl? (04)
b) What are Spontaneous and non-spontaneous processes? Give examples. (2+2)