INTRODUCTION
TO SEPARATION
PROCESSES
ENGR. JOSE NICKO C. RODRIGUEZ
SEPARATION PROCESS
It is defined as those operations which transform a
mixture of substances into two or more products
which differ from each other in composition.
GOAL: PURIFY SOLUTION OR SUBSTANCE
WHY DO WE
NEED TO PURIFY
A SUBSTANCE?
WHY SEPARATION IS
DIFFICULT TO OCCUR?
The creation of a mixture of chemical species from the
separate species is a spontaneous process that requires
no energy input. The inverse process, separation of a
chemical mixture into pure components, is not a
spontaneous process and thus requires energy.
SELECTION - Feed Conditions
- Product Conditions
OF FEASIBLE - Property Differences
SEPARATION - Characteristics of
Separation Operation
PROCESS - Economics
SPLIT FRACTION AND
SPLIT RATIO
EXERCISE
For the process below, compute the split fraction and the split
ratio for the iC5H12 and nC5H12
SEPARATION FACTOR OR
POWER
EXERCISE
A feed, 𝐹, of 100 𝑘𝑚𝑜𝑙/ℎ of air conditioning 21 𝑚𝑜𝑙% 𝑂2 and 79 𝑚𝑜𝑙%
𝑁2 is to be partially separated by a membrane unit according to each
of four sets of specifications. Compute the amounts, in 𝑘𝑚𝑜𝑙/ℎ, and
compositions, in 𝑚𝑜𝑙%, of the two products (retentate, 𝑅, and
permeate, 𝑃). The membrane is more permeable to 𝑂2.
Case 1: 50% recovery of 𝑂2 to the permeate and 87.5% recovery of 𝑁2 to the
retentate.
Case 2: 50% recovery of 𝑂2 to the permeate and 50 𝑚𝑜𝑙% purity of 𝑂2 in the
permeate.
Case 3: 85 𝑚𝑜𝑙% purity of 𝑁2 in the retentate and 50 𝑚𝑜𝑙% purity of 𝑂2 in the
permeate.
Case 4: 85 𝑚𝑜𝑙% purity of 𝑁2 in the retentate and a split ratio of 𝑂2 in the
permeate to the retentate equal to 1.1.