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Solutions Notes

The document discusses various concentration terms and calculations related to solutions, including mass/volume, ppm, and the effects of pressure and temperature on solubility. It also covers Henry's Law, Raoult's Law, and colligative properties such as vapor pressure lowering, boiling point elevation, and freezing point depression. Additionally, it explains osmotic pressure and its applications in determining molecular weights of solutes.

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trisha100908
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5 views33 pages

Solutions Notes

The document discusses various concentration terms and calculations related to solutions, including mass/volume, ppm, and the effects of pressure and temperature on solubility. It also covers Henry's Law, Raoult's Law, and colligative properties such as vapor pressure lowering, boiling point elevation, and freezing point depression. Additionally, it explains osmotic pressure and its applications in determining molecular weights of solutes.

Uploaded by

trisha100908
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© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF or read online on Scribd
UNIT. L: SOLUTH _— | DONCENTRATION TERMS : 1 | Mana ot component = Maal of solute x OSA | MIM) mas of col” “ wry) VOL” of SoU’ Ree |.) “1. = _VOL™ of Solute x 100 | Taek aT hee pe ———~ 4 + || Masa by volume = Mass ot Solute x 10D 4 i cCM/v) vol™ ot sel” * || parva per milion (ppm) = mass Of Soluke Xx 19° | aad OF col” | = masi%,s xX 10% . g. Hits of Sta_wnita conse &510*9 of 0, calaeiale tas “ conc” te _ppm i aC ppm = bXI0 x10" = 5.¢2 ppm 1920 x SS Le * a Motto na eee Neen geeNs ns B X= A Nyathp aroun Ry thg Xt Xe = Tene ane %i oompongnia, Mth. +X =f Volume of Solution CU) 8 Vol of sot Cm) Eaeiger aa mae of SQwent CG) Pind moss of ouatic acid read, tO prepare 2.50mi A r §-- | . Fi : ee 126 g/mok | cbtubom Of oKalic acral. Mocauie b | | \ +t | oh Mass= 2b X28P = LSTS9 Lo * 1 p6p Ars a pe a al soni ele agai nc The. marin amourt of a Solute that ca C | UKE AISSOLVES UKE a || Effect of PRESSURE & TEMPERATURE on Solubility || _Pressuce does not play much role ta the SOuubibity Ob Solids | _If dissouuoion OF 0. Sotid th a Uquid ib EXoTHERMee |____ Solubility | tenpenate f HE disrowtion of a solid tk 0 viquild iy ENDOTHERMC, solubility * tuipenanore t nore: || twin ip based on he~ théithien's prdvoiple \ A \\\ 4 \ Lueniieiia ce gy |The pantial preasune of the gas Cp) is promote ees. Rieck ph p= KX 1 © Henny! s comtant j Cnaracteussnta of Ky : | Value pf My depends upon ne notune of the ga, | Value OF Ky increases wnith increase hn tempenstwe foro parkiCWlarn gas eck CoMAcont Breas iare pe ky 4,2 T, Atmperatune fT Mole frackion v ms Sotuortity Solunitcty t ees : a of Oxygen So Pt Ww temperature, Wwe Vio highir consentrabin o Crygen tn _waker, thinly o& Ureasing sebebetity of a Un_colol wakern oa per Hewry's (ow wears ed: ol aa As the ttmsporatune tnercasey, the oluibecUby decreases Ubidin wot good for aauatic aninro lu. APPUCATIONS OF HENRY's LAW. Sopt dri or carbonated drinia Lott drink bottles ane packed at high Pip, to dissolve nore CO, Ur the rink. Stuloo. brett divert When the stuba divea dives the Soba of gares pot ae Ltn ome a O, Vr blood & RP LI a... igh _atcitudey ; _| Cimber become, weate meee uRale to tink __,_Ueanby. Tain known a4 anonia . > VAPOUR PRESSURE OF UQUIN SOWTIONS | iene pr Ke X%, pz= pe, X. Alo Satton’s (aw of pantial preauuc., Penta = Py + py aa = p52, 8 xe Sa = p's =p + ph Xe += p's +(p =p) x4. Page No. | | | COMPOSITIDN OF VAPOUR PHASE (Mole traction of vapours) yy nol ys Ss vapour mate froerion) pe _p°s. = wp munsig p°, = 41S mung _ WwW. MM = = 28.5 = 0.213) = Hee ude= 25359 Mies 8G Man BE Wao Wore MM cacy We eucas. ua.s Wertz crs 0-45 Wessel, AQ gS MMe, 25.5 0.213 0.213 + 0.44% Wy +n, 28.5) 4 N4.S gs 0.213 0.683 = 0.312 bi 2 Eri = 62.4 VogeS ye deine as — si s aS Rees AS (OURS) = 28C C5, 235 + 4 \ A. so 's und Ky _ OF Hi pe ky x % pe pox x when po = Ky aaa ROBIN Law befomer SOLVENT + OLUTE Mo! When @ wom volottle Solure is disteied Ui a coluent, the VOpoun pressure Of the Solubimn at a gion. tonip A found tp be WwWer thai the Vapmun prediune of || Ke Aline Souirewt at the Sayre tenipt Suubace 14s orcupied by both soluke. by etic Solent _molecuses Chcoping from the reduced & the Uopeun predsune U also reduredt. cue cote ai Rtas tue no. ey OT Peoear = p's XK | | WoTe:|| IN SUCH CATES THE VAPOUR PRE

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