14-05-2025

1701CJA101029240103 JA

PART-1 : PHYSICS

SECTION-I (i)

1) As shown in the figure, a particle A of mass 2m and carrying charge q is connected by a light rigid
rod of length L to another particle B of mass m and carrying charge –q. The system is placed in an
electric field . The rod can oscillate in horizontal plane. The electric force on a charge q in an
electric field is . After the system settles into equilibrium, one particle is given a small
push in the transverse direction so that the rod makes a small angle with the electric field. Find

maximum tension in the rod.

2
(A) qE + qEθ0

(B)

(C)

(D)

2) In the given circuit switch S is closed at t = 0. The current I in the figure at time t is :-

(A)

(B)
(C)

(D)

3) A cylindrical resistance is connected across battery . Cylinder has uniform free electron density,
mid part of cylinder has larger radius as shown in figure. Then graph for Vd (drift velocity) V/S

(distance across the length of the resistance) L will be :-

(A)

(B)

(C)

(D)

4) A liquid is flowing in a horizontal pipe of uniform cross section at a speed v. Two tubes A and B
are inserted into the pipe as shown. Assume the flow to remain streamline inside the pipe. The
difference in height of the liquid in two tubes is :-

(A)

(B)

(C)

(D) Information is not enough to calculate.

SECTION-I (ii)

1) When an AC source having frequency applied in series with a circuit having resistance

and inductor or capacitor then i and E as a function of time are observed to vary with
time as shown in figure and phase difference between them is 60°.

(A) Circuit has inductor in series with resistor

(B) Circuit has capacitor in series with resistor
(C) Value of L or C is (10 × 10–6) SI unit
(D) Value of L or C is (3 × 10–6) SI unit

2) A time varying magnetic field exists in the region, . ABC is a conducting triangular

loop (see figure). Then:

(A) Direction of induced current in the loop is from A to B.
(B) Direction of induced current in the loop is from B to A.
2
(C) Induced EMF in loop is B0a .
(D) Induced EMF in loop is B0a2.

3) A screw gauge (as shown in figure) having 100 equal division on circular scale and a pitch of 1
mm is used to measure the diameter of a wire of length 4.2 cm. The main scale reading is 2 mm and

45th circular division coincides with the main scale. . Choose the correct option/options :

[Before the measurement when screw is taut]

(A) Diameter of wire is 2.50 mm

(B) Diameter of wire is 2.40 mm
(C) Surface area (in cm2) of wire in appropriate significant figure is 3.2.
(D) Surface area (in cm2) of wire in appropriate significant figure is 3.168

4) The x-ray spectrum of a metallic target has been shown in figure. Given : and
[Both characteristic x-rays belong to k series ( )]. Choose the correct

option/options :

(A) wave length of x-ray is 0.286 nm

(B) wavelength of x-ray is 0.303 nm
(C) atomic number of the target atom is 21.
(D) accelerating voltage for x-rays tube is 12400 V.

5)

In the given figure if A is connected with C and B is connected with D, then

(A) Charge flows in the circuit is 12 µC.
(B) Heat produced in the circuit is 60 µJ.
(C) Charge flows in the circuit is 14 µC.
(D) Heat produced in the circuit is 490 µJ.

6) A narrow capillary tube open at both ends of radius r = 0.25 mm contains some water in it. When
the tube is held vertical, the water remains inside the tube as shown. Choose the correct

option/options. [Given : surface tension = 0.075 N/m and contact angle = 0°, ]

(A) For h = 4cm, lower meniscus is convex upwards.

(B) For h = 6 cm, lower meniscus is flat.
(C) For h = 8 cm, lower menicus is concave up.
(D) For all values of h lower meniscus is convex upward always.

SECTION-III

1) A uniform disc of radius R = 0.2 m is projected along a rough horizontal surface with initial linear
velocity v0 = 2m/s and initial angular velocty ω0 = 5 rad/sec as shown in the figure. Coefficient of
friction is µ = 0.1. The time (in second) at which it starts pure rolling is.

2) In the fusion reaction , the masses of deuteron, helium and neutron

expressed in a.m.u. are 2.015, 3.017 and 1.009 respectively. If 1 kg of deuterium undergoes
complete fusion, the amount of total energy released is a × 1013 (in Joules), find nearest integer of a.
(Given 1 a.m.u. ≡ 931.5 MeV/c2)

3) Two moles of a diatomic gas undergoes two process in succession. Starting from temperature T1,
it is first heated at constant volume until its pressure is tripled. It is further heated at constant
pressure until its volume is doubled. What is the average molar heat capacity for the whole process?
If your answer is nR, where R is universal gas constant. Round off n to nearest integer.

4) A stone of mass 0.2 kg is tied to one end of a thread of length 0.1 m whirled in a vertical circle.
When the stone is at the lowest point of circle, tension in thread is 52N, then velocity (in m/s) of the
stone will be :–

5) A hydrogen atom in excited state n reaches the ground state by emitting three photons of
frequency in ratio 5 : 72 : 243. Wavelength corresponding to one of the transitions belongs to visible
region. Find the value of ‘n’.

6) In the circuit shown in figure, calculate the current (in A)through S in the circuit when S is closed.

7) One end of a string of length L is tied to the ceiling of a lift accelerating upwards with an
acceleration 2g. The other end of the string is free. The linear mass density of the string varies
linearly from 0 to λ from bottom to top. The acceleration of the wave w.r.t. string through out string

is . Find p.

8) Suppose the potential energy between an electron and a proton at a distance r is The
velocity of

orbital motion of the electron is given as, Then find the value of (α + β).

PART-2 : CHEMISTRY

SECTION-I (i)

1) During the Hinsbergs Test, which of the following primary amines is most likely to be detected as
a secondary amine?

(A)
(B)

(C)

(D)

2)
Find the product 'X'

(A)

(B)

(C)

(D)

3) Which of the following does not liberate NO2 gas

(A)

(B)

(C)
(D)

4) Calculate change in Gibbs energy of 10 moles of ice when pressure on it is increased from 1 bar
to 101 bar isothermally at –73°C.
[Given : Density of ice at –73°C = 0.9 g mL–1]

(A) 1000 J
(B) 2000 J
(C) 76360 J
(D) 4000 J

SECTION-I (ii)

1) The compound reacts with triphenylphosphine in diethyleneglycol in an atmosphere of

CO to give , known as Vaskas compound. (Atomic number of Ir = 77)
Select correct for Vaskas compound :

(A) The IUPAC name of the complex is carbonylchloridobis (triphenylphosphine)iridium(I)

(B) The hybridization of the metal ion is sp3
(C) The magnetic moment (spin only) of the complex is zero
(D) The complex shows geometrical as well as optical isomerism

2) Which of the following is incorrect when alkali metal is allowed to react with the increased
concentrated in liq.NH3

(A) Paramagnetic character of solvated electrons gets changed

(B) Solvated electrons associate to form electron pairs
(C) Oxidising nature of the solution is increased
(D) Color of solution remain same as in dilute

3) The major product formed in the following reaction is

(A)

(B)

(C)

(D)
4)

(A)

(B)

(C)

(D)

0
5) At 25 C, for half-cell reactions :
, M is a solid metal.
Then the value of for the sparingly soluble salt MI is ?

(A) –16.13
(B) –20.22
(C) –8.05
(D) –32.26

6) Which of the following molecular orbitals has two nodal planes?

(A)

(B)

(C)

(D)

SECTION-III

1) A first order chemical reaction. is occurring at 500 K. If the same reaction is to be carried
out in presence of a catalyst, temperature of 400 K is required to be maintained in order to maintain
the same rate of reaction. If the catalyst lowers the activation energy by 30 kJ, then the value of

activation energy of the original pathway (uncatalysed reaction) is x kJ/mol, then is

0
2) A closed container of volume 0.02 m3 contains a mixture of Ne and Ar at a temperature of 27 C
and a pressure of 105N/m2. If the total mass of mixture is 28 gm. Find the mass of Neon in grams?
[Given : Atomic mass : Ne = 20, Ar = 40 and R = 25/3 J mol–1 K–1]

3) The enthalpy of fusion of ice is . The heat capacity of water is 4.214 J g–1 K–1. What is
the smallest number of ice cubes at 0° C, each containing one mole of H2O , that are needed to cool
500g of liquid water from 20oC to 0oC ?

4) How many of of the following species are aromatic

(I) (II) (III)

(IV) (V) (VI)

(VII) (VIII)

(IX) (X)

5) When mixture of and is reacted

with Br2 / OH–, how many possible amines are obtained?

6) The number of only acidic oxides among the following oxides is

CO, CO2, SiO2, PbO, PbO2, SnO, NO, N2O, N2O3, NO2, P4O6, P4O8, P4O9, P4O10

7) The number of compounds among the following compounds which give characteristic colour or

precipitate with neutral ferric chloride solution is CH3CO2Na ,

8) A reaction follows temperature - rate constant relation as

If R = 2 cal k–1 mol–1 then the value of activation energy of reaction (in kcal/mole) is :

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let C1 : x2 + y2 = 1, C2 : (x – 10)2 + y2 = 1 and C3 : x2 + y2 – 10x – 42y + 457 = 0 are three circles. A

circle C has been drawn to touch circle C1 and C2 externally & C3 internally, Now circle C1, C2 & C3
start rolling on circumference of C in anticlockwise direction with constant speed. The locus of the
centroid of triangle formed by the centres of C1, C2 & C3 as its vertices -

(A) x2 + y2 – 12x – 22y + 144 = 0

(B) x2 + y2 – 10x – 24y + 144 = 0
(C) x2 + y2 – 8x – 20y + 64 = 0
(D) x2 + y2 – 4x – 2y – 4 = 0

2) Define the function A, L, E, N as follows

A(x) = 24x
L(x) = 12x2 + 12x
E(x) = 4x3 + 12x2 + 8x
N(x) = x4 + 6x3 + 11x2 + 6x

The value of is

(A) 24
(B) 25
(C) 28
(D) 34

3) If f(x) is continuous, increasing and an odd function such that and

then the area bounded by y = f(x), x-axis in between the ordinates x = –4 and x = 4 is

(A) 23
(B) 19
(C) 20

(D)

4) The number of shortest paths from point A to D

(as shown in figure)

(A) 276
(B) 186
(C) 150
(D) 126

SECTION-I (ii)

1) Let z be complex number such that |z| = 1 then possible values of |1 – z| + |1 + z2| among the
following is/are

(A)

(B)
(C) π
(D) 4

2) Let α, β (α > β) be the roots of the equation x2 – x – 1 = 0. Define Which

among the following holds TRUE?

(A) T(2023) = T(2022) + T(2021)

(B) T(10) = 55
(C)

(D)

3)
Then

(A) Number of positive divisors of P is 4

(B) ℓn x = P x has exactly two real solutions
(C) 2018x + 2019x + 2020x = Px has exactly one real root
(D) Unit digit of PP is 1

4) Let f : [0, 1] (0, ) be an integrable function such that f(1 – x) = 1/f(x) for all x [0, 1]. The

possible value of can be

(A)

(B) π

(C)

(D) e

5) An invertible function and g is the inverse of function ƒ,

then Note : Here sgn(x) denote signum function of x.

(A) sgn(ƒ(g(x))) = 1
(B) sgn(g(ƒ(x))) = –1

(C)

(D) ƒ(x) is discontinuous at x = –1

6) Let If then which of the following statements is/are true.

(A)
where α, β, γ lies on the line of intersection of planes 3x + y + z = 5
and 2x – y + 3z = 4

(B)
= 33

(C)

has no real solution

(D)

The number of 3 3 matrix B with integer entries such that AB - BA = is 2

SECTION-III

1) Let S be the sum of smallest element of each subset of the set (Ignore
empty subset as it has no elements). Then the sum of digits of S is ____.

2) Let f(x) be a continuous function on [0, 1] such that . Then

equals _____.

3) If . Then ln (I + 1) is ____.

4) Tangents are drawn from any point on straight line y = x + 8 to the auxiliary circle of x2 + 16y2 =
16. If A and B are the points of contact of these tangent and P, Q are corresponding points of A and
B on the ellipse respectively. If locus of mid point of PQ is x2 + αy2 + βx + γy = 0 then value of (α – β
+ γ) is

5) Let S be the solid tetrahedron with boundary points (0,0,0), (2,4,0), (5,1,0),(3,2,10).

Let

and
Then is _____.

6) Let (x0, y0, z0) be the solution of equation

Then is ____.

7) Suppose are two non-collinear unit vectors such that . The value of

is ____.

8) An unbiased coin is tossed n times.

Define events E1 and E2 as follows :
E1 : event that both heads and tails are present in n-tosses.
E2 : event that coin shows up heads atmost once.
Find n such that E1 and E2 are independent events.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A D A B

SECTION-I (ii)

Q. 5 6 7 8 9 10
A. B,C B,C B,C B,C,D A,B A,B,C

SECTION-III

Q. 11 12 13 14 15 16 17 18
A. 1 9 3 5 9 2 3 9

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22
A. D C B B

SECTION-I (ii)

Q. 23 24 25 26 27 28
A. A,C C,D A A A B,D

SECTION-III

Q. 29 30 31 32 33 34 35 36
A. 6 4 7 5 3 8 4 1

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40
A. B A A B

SECTION-I (ii)

Q. 41 42 43 44 45 46
A. B,C,D A,B,C A,C,D B,D A,B,C A
 SECTION-III

Q. 47 48 49 50 51 52 53 54
A. 8 5 2 6 4 3 2 3
 SOLUTIONS

PART-1 : PHYSICS

1)

I=

I=
net = qE sin
net = I
2
for small oscillation =

Fnet toward centre

T – qE = m 2particle R [ωparticle = max ]
phase

2)

Ceq. =
τ = Req Ceq = RC

...(1)

...(2)
Solving (1) & (2)
3) i = JA
J = ne Vd
i = Ane Vd
i = constant
AVd = Constant

4) Apply Bernaulli's theorem between just below points of tubes

5)

Since current is leading voltage so, it is RC circuit

; where ϕ = 60°
Solving, C = 10 µF

6)

Flux linked with the loop

induced emf,

7)
+ve zero error = 0.05 mm
diameter of wire = 2 mm + 0.45 mm – 0.05 mm = 2.40 mm

surface area
in appropriate significant figure
surface area = 3.2 cm2

8)

So,

= 12400 V

9)

Common potential
 = 14 V
qA = C1VC = 28 µC
Δq = C1V1 – C1VC = 12 µC
Heat produced

10)

0
for h = 4 cm, P2 = P – 200

for h = 6 cm,

for h = 8 cm,

11)
Fr = macm
R Fr = Ia
I = 1/2 mR2
N = mg
Fr = µN
acm = µg
α = 2µg / R

0
v – µgt =
t = 1 sec.

12)

Mass defect in the reaction

Δm = 2 × 2.015 – 3.07 – 1.009 = 0.004 amu

Fractional mass defect =

mass defect in 1 kg

Energy released
E = mc2 = 8.9 × 1013 J

13)

ΔQ = nCV2T1 + nCP(3T1)

ΔT = 5T1

∴C=

= = 3.1 R

14)
From FBD, we have

T – mg =

52 – 2 =
v2 = 25
v = 5 m/s

15) En→m :Em→2 :E2→1 = 5 : 72 : 243

Em→2 ⇒ Transition corresponding to visible region.
 .

16)

17)

18) &

.....(i)

......(ii)

PART-2 : CHEMISTRY

19) After formation of N substituted sulphonamide

with the Hinsbergs reagent, then solubility of the salt

depends on the length of hydrophobic Rportion. A very long

chain may cause non- dissolutions and the amine may therefore appear as secondary

20) When a- haloketones are treated with alkali, ring contraction occurs ( Favorsky
rearrangement)
Mech:

21)

23) It is dsp2 hybridized due to pairing up because of strong field ligand CO. It cannot show
ionization isomerism

24) Solvated electrons gets associated

25)

26)

The products are followed by reduction ad EAS

27) , (from the given data)

28)
29)

30)
n = 0.8
Let Neon = x gm
Argon = y gm

2x + y = 32
Given x + y = 28gm
2x + 28 - x = 32
x = 4gm

0 0
31) Heat released to cool 500 g water from 20 C to 0 C

Number of moles of water (Ice) that will melt to absorb

Number of cubes of ice that will melt = 7

32) application of Huckel's rule of periphery electrons

Total no. of periphery electrons participating in aromatic character is 18
non-aromatic
- aromatic
aromatic
non-aromatic
Anti-aromatic
non-aromatic
Anti-aromatic
aromatic
aromatic

33) In Hoffmann bromide reaction, cross over products are not obtained.

34) CO2, SiO2, N2O3, NO2, P4O6,P4O8, P4O9, P4O10

 35) , CH3CO2Na,

PART-3 : MATHEMATICS

37)
Equation of C is
(x – 5)2 + (y – 12)2 = 122 ...(1)
this also touch at (5,0) centriod lie on the circle (x – 5)2 + (y – 12)2 = 52

38) Observe
A(x) = 24(xC1)
L(x) = 24(x+1C2)
E(x) = 24(x+2C3)
N(x) = 24(x+3C4)
So,

and

39)

Therfore Required Area = 23

40) Number of paths passing through M are

Number of paths through N are

150 + 126 – 90 = 186

41) Put z = eiθ and

Hence, y = |x| + |1 – 2x2|

where x =

Hence,

42)
Similarly

Hence,
So, T(n) forms fibonacchi sequence {1,1,2,3,5,......}.

= T(2023) – 1
T(10) = 55

43)
Hence, P = 2021

Let
Hence, f(x) = 2021 has no solution
If
then g(x) is strictly decreasing function
Hence, g(x) = 1 has exactly one real solution.

44) by A.M - G.M inequality

45) x = –1 is the only value in domain of ƒ

Now, verify the options

46) Correct Ans. A

Observe that
and Trace(AB) = Trace(BA). Hence D is wrong

47)

48) by substitution x = t2 The given equation

 Since f is continuing

So,

Put

49)
by letting x = y2

So,

50) a2 = 16, b2 = 1
a = 4, b = 1

let A(x1, y1) and B(x2, y2) then P, Q will be and

mid point of AB will be

mid point of PQ will be

⇒ mid point of AB will be (h, 4k)
let point S(t, t + 8) be a point on y = x + 8
AB is chord of contact of x2 + y2 = 16
⇒ xt + y(t + 8) = 16 ....(i)
AB as chord whose mid point is (h, 4k)
xh + y(4k) = h2 + 16k2 ...(ii)

⇒ and

⇒
⇒ 2h + (h2 + 16k2) = 8k
⇒ x2 + 16y2 + 2x – 8y = 0
x2 + αy2 + βx + γy = 0
⇒ α = 16, β = 2, γ = –8
⇒ α – β + γ = 16

51) Notice that α, β lies on the boundary of S, so each lies on one of the four planes. However
we can ignore the plane defined by (0,0,0), (2,4,0), (5,1,0) (as it lowest).
Let P1 be planes by (2,4,0), (5,1,0),(3,2,10)
So,
Similarly P2 be plane by points (0,0,0), (2,4,0),(3,2,10)

So,
P3 be plane by (0,0,0), (5,1,0) and (3,2,10)

So, P3 :

Using this we find pts as

and Only lowest is on tetrahedron

so,

Similarly

So,

52) Let P = xyz

3x - 4y + pz = 12
- 12x + py + 4z = 3
px + 12y - 3z = 4

53) Let angle between be θ

then

So

54)

For being independent we must have