In compliance with EC Regulations No.: 1907/2006, 830/2015 and 1272/2008 (CLP).

Date last modified: 31 January 2018 - version 5.0

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY

1.1 Product Identifier

Product Name: SOLBREAK HFP

Product Code #: 832548 (25 lt) / 832140 (210 lt)

1.2 Relevant identified uses of the substance or mixture and uses advised against

Intended Use: Industrial applications; Cleaning agent for machinery & equipment.

Uses advised against: This product is not recommended for any industrial, professional or consumer use
other than the Intended Uses above.

1.3 Details of the supplier of the safety data sheet

Company/undertaking identification

Supplier/Manufacturer:

Marichem Marigases Hellas SA

Sfaktirias 64,
185 45 Piraeus,
Greece
Tel. No.: ++30 210 4148800
Fax No.: ++30 210 4133985
[Link]

e-mail: mail@[Link]

1.4 Emergency telephone number

Tel. No.: ++30 210 4148800 (including working hours)

Emergency Information:
Inside U.S. and Canada: (800)-424-9300 (CHEMTREC)
Outside U.S. and Canada: 1-703-527-3887 (CHEMTREC)
National Emergency Centre (Greece): ++30 210 7793777

2. HAZARDS IDENTIFICATION

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2.1 Classification of the mixture

Classification under EC 1272/2008 regulation - GHS classification.

Aspiration Toxicity, Category 1

Specific target organ toxicity-single exposure, Category 3
Eye damage, Category 1
Acute Toxicity (dermal, oral, inhalation - vapor), Category 4
Skin Corrosion/Irritation, Category 2

SIGNAL WORD: DANGER

Hazard Statement(s):

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
EUH066: Repeated exposure may cause skin dryness or cracking.

2.2 Label Elements

Labelling according to Regulation (EC) No. 1272/2008.

The substance is classified and labelled according to the CLP Regulation.

Hazard Pictograms

GHS 07 GHS 08 GHS 05

SIGNAL WORD: DANGER

Hazard Statements

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
EUH066: Repeated exposure may cause skin dryness or cracking.

Precautionary Statements

Prevention
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 P261: Avoid breathing mist/vapours/spray.
P262: Do not get in eyes, on skin or on clothing.
P264: Wash face, hands and any exposed skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Use personal protective equipment as required.

Response

P310: Immediately call a POISON CENTER or doctor/physician.

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301+P330: IF SWALLOWED: Rinse mouth.
P303+P361+P352: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water.
P361: Remove/Take off immediately all contaminated clothing.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P305+P351+P338+P310: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or
doctor/physician.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P331: Do NOT induce vomiting.
P391: Collect spillage.

Storage

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

P405: Store locked up.

Disposal

P501: Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and
national regulations.

2.3 Other Hazards

Does not meet the criteria for PBT or vPvB.

Ingestion may cause irritation to mucous membranes.
Material can accumulate static charges which may cause an ignition.
May be irritating to the eyes, nose, throat and lungs.
Combustible liquid. In use, may form flammable/explosive vapour-air mixture. Electrostatic charges may
be generated during pumping. Electrostatic discharge may cause fire.

Product classification and labelling according to Directive 67/548/EEC, European Dangerous

Preparations Directive (1999/45/EC), European Regulation 648/2004 and their amendments.

Symbol: Xn

Harmful (Xn)

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R-phrases: R36/38 Irritating to eyes and skin.
R52/53 Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.

S-phrases: S2 Keep out of the reach of children.

S23 Do not breathe gas/vapor.
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
S28 After contact with skin, wash immediately with plenty of water.
S61 Avoid release to the environment. Refer to special
instructions/safety data sheets.
S62 If swallowed do not induce vomiting: seek medical advice
immediately and show this container or label.
S36/37/39 Wear suitable protective clothing, gloves and eye/face
protection.

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Chemical Composition:

Ingredients CAS Number Proportion Hazard Code(s)*

2-aminoethanol 141-43-5 1% - 5% H302; H312; H314;
H332; H335.
2-Propylheptanol 160875-66-1 1% - 5.5% H318
Ethoxylate
Hydrocarbons, C10- H304; EUH066
C13, n-alkanes,
isoalkanes, cyclics, <2% 64742-48-9 35% - 55%
aromatics
Phosphoric acid, 1310-73-2 0.5% - 2.5% H314
2-ethylhexyl ester
2-butoxyethanol 111-76-2 5.5% - 15% H319; H315; H312;
H332; H302.
Hydrocarbons, C9, 64742-95-6 1% - 5% H226; H304; H335;
aromatics H336; EUH066; H411.
Ingredients that do not
contribute in the - 8% - 15% -
classification of the
product

*
See section 16 for the full text of the Hazard Code(s) declared above.

Occupational Exposure Limits, if available, are listed in section 8.

4. FIRST AID MEASURES

4.1 Description of first aid measures

Inhalation

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Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device, or use
mouth-to-mouth resuscitation.

Skin contact
Wash contact areas with soap and water. Remove contaminated clothing. If this chemical penetrates the
clothing promptly remove the clothing and wash. Launder contaminated clothing before reuse.

Eye contact
Flush thoroughly with water. If irritation occurs, get medical assistance.

Ingestion
Seek immediate medical attention. Do not induce vomiting. Never give anything to an unconscious person.

4.2 Most important symptoms and effects, both acute and delayed
Acute health effects: drowsiness, dizziness, nausea, skin irritation.
Delayed effects: N/A.

4.3 Indication of any immediate medical attention and special treatment needed
Note to physician: If ingested, material may be aspirated into the lungs and cause chemical pneumonitis.
Treat appropriately.

5. FIRE-FIGHTING MEASURES

5.1 Extinguishing media

Appropriate extinguishing media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate extinguishing media: Straight streams of water.

5.2 Unusual fire hazards arising from the substance or mixture

Hazardous material. Fire-fighters should consider protective equipment.
Hazardous combustion products: Smoke, Fume, Incomplete combustion products, Oxides of Carbon.
Possible formation of toxic Carbon Monoxide when combustion takes place in lack of oxygen.

5.3 Fire Fighting Instructions

Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water
supply.
Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing
apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel.

6. ACCIDENTAL RELEASE MEASURES

6.1 Notification Procedure

In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations.
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6.2 Protective Measures

Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if
required, due to toxicity or flammability of the material

6.3 Spill Management

Land Spill: Stop leak if you can do so without risk. Do not touch or walk through spilled material. Large
Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Small Spills:
Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.
Recover by pumping or with a suitable absorbent

Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn
other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a
specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current
direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts
should be consulted. Note: Local regulations may prescribe or limit action to be taken .

6.4 Environmental Precautions

Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.

6.5 Reference to other sections

See Section 1 for emergency contact information.

See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Prevention of user exposure: Avoid breathing mists or vapours. Avoid contact with skin. Potentially
toxic/irritating fumes/vapour may be evolved from heated or agitated material. Use only with adequate
ventilation. Prevent small spills and leakage to avoid slip hazard.

Prevention of fire and explosion: Material can accumulate static charges which may cause an electrical
spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any
flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use
proper bonding and/or earthing procedures. However, bonding and earthing may not eliminate the hazard
from static accumulation. Consult local applicable standards for guidance. Additional references include
American Petroleum Institute 2003 (Protection against Ignitions Arising out of Static, Lightning and Stray
Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or
CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static
electricity).

Static Accumulator: This material is a static accumulator. A liquid is typically considered a non-
conductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter), and
is considered a semi-conductive, static accumulator, if its conductivity is below 10,000 pS/m. Whether a
liquid is non-conductive or semi-conductive, the precautions are the same. A number of factors, for
example: liquid temperature, presence of contaminants, anti-static additives and filtration, can greatly
influence the conductivity of a liquid.

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Precautions while moving the product:
Loading/Unloading Temperature: [Ambient]
Transport Temperature: [Ambient]
Transport Pressure: N/D

7.2 Conditions for safe storage, including any incompatibilities

Technical measures: The container choice, for example storage vessel, may effect static accumulation and
dissipation. Keep container tightly closed and in a well ventilated place. Handle containers with care. Open
slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Storage containers
should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment
should be grounded and bonded to prevent accumulation of static discharge. Keep away from direct
sunlight and other sources of ignition. Do not smoke in storage areas.

7.3. Specific end use(s):

Cleaning product for industrial use only.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components with workplace control parameters

Name of Substance: Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics

Occupational exposure limit values:

UK Workplace Exposure Limits

In the absence of occupational exposure standards for this product, it is recommended that the
following are adopted.

Material Source Type ppm mg/m3 Notation

RCP UK SIA TWA (8 h) 150 ppm 1,000 mg/m3
Dearom.
Mineral
spirits 175
- 220

Biological Exposure Index (BEI)

Biological Limit Values (BLV) have not been established for this material.

Derived No Effect Levels

(DNEL/DMEL) Table: No DNEL value has been established.

PNEC related information: Substance is a hydrocarbon with a complex, unknown or variable

composition. Conventional methods of deriving PNECs are not appropriate and it is not possible to identify
a single representative PNEC for such substances.

Name of Substance: Hydrocarbons, C9, aromatics

Occupational Exposure Limits

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 Material Source Type ppm mg/m3 Notation
1,2,4- ACGIH TWA 25 ppm
Trimethyl
benzene
EH40 WEL TWA 25 ppm 125 mg/m3
1,3,5- ACGIH TWA 25 ppm
Trimethyl
benzene
EH40 WEL TWA 25 ppm 125 mg/m3
Cumene ACGIH TWA 50 ppm
EH40 WEL TWA 25 ppm 125 mg/m3
EH40 WEL SKIN_DES Can be absorbed through
the skin
EH40 WEL STEL 50 ppm 250 mg/m3
1,2,3- ACGIH TWA 25 ppm
Trimethyl
benzene
OSHA Z1A TWA 25 ppm 125 mg/m3
Xylene, ACGIH TWA 100 ppm
Mixed
Isomers
ACGIH STEL 150 ppm
EH40 WEL SKIN_DES Can be absorbed through
the skin
EH40 WEL STEL 100 ppm 441 mg/m3
EH40 WEL TWA 50 ppm 220 mg/m3

Additional Information: Wash hands before eating, drinking, smoking and using the toilet.

Biological Exposure Index (BEI)

Material Determinant Sampling time BEI Reference

Benzene t,t-Muconic acid in Sampling time: 500 μg/g ACGIH BEL
Creatinine in urine End (2011)
of shift.

S- Sampling time: 25 μg/g ACGIH BEL

Phenylmercapturic End (2011)
acid in of shift.
Creatinine in urine

Xylene, Mixed Methylhippuric Sampling time: 1.5 g/g ACGIH BEL

Isomers acids in Creatinine End (2009)
in urine of shift.

Methylhippuric Sampling time: 650 mmol/mol UKEH40BMGV

acids in Creatinine End (2005)
in urine of shift.

Derived No Effect Levels (DNEL/DMEL) Table

Component Exposure Route Exposure Type Application Area Value

(long/short)
Hydrocarbons, Dermal long term, Worker 25 mg/kg/d
C8-C12, systemic effects
n-alkanes,
isoalkanes,
cyclics, aromatics
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(2-25%)

Inhalation long term, Worker 150 mg/m3

systemic effects

Inhalation long term, Consumer 32 mg/m3

systemic effects

Dermal long term, Consumer 11 mg/kg/d

systemic effects
Oral long term, Consumer 11 mg/kg/d
systemic effects

PNEC related information

Substance is a hydrocarbon with a complex, unknown or variable composition. Conventional methods of
deriving PNECs are not appropriate and it is not possible to identify a single representative PNEC for such
substances.

Name of Substance: 2-Propylheptanol Ethoxylate

Contains no substances with occupational exposure limit values.

Name of Substance: 2-aminoethanol

TWA value 2.5 mg/m3 ; 1 ppm (OEL (EU)) indicative

STEL value 7.6 mg/m3 ; 3 ppm (OEL (EU)) indicative
Skin Designation (OEL (EU))
The substance can be absorbed through the skin.

PNEC
Freshwater: 0.085 mg/l
Marine water: 0.0085 mg/l
Intermittent release: 0.025 mg/l
Sediment (freshwater): 0.425 mg/kg
Sediment (marine water): 0.0425 mg/kg
Soil: 0.035 mg/kg
STP: 100 mg/l

Worker:
Long-term exposure- systemic effects, dermal: 1 mg/kg
Worker:
Long-term exposure - systemic and local effects, Inhalation: 3.3 mg/m3
Consumer:
Long-term exposure- systemic effects, dermal: 0.24 mg/kg
Consumer:
Long-term exposure - systemic and local effects, Inhalation: 2 mg/m3
Consumer:
Long-term exposure- systemic effects, oral: 3.75 mg/kg

Name of Substance: Phosphoric acid, 2-ethylhexyl ester

EXPOSURE LIMITS

Derived No Effect Level (DNEL)

No information available.

Predicted No Effect Concentration (PNEC)

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No information available.
Exposure limits This product, as supplied, does not contain any hazardous materials with
occupational exposure limits established by the region specific regulatory bodies.

Name of Substance: 2-butoxyethanol

Skin Designation (OEL (EU))

The substance can be absorbed through the skin.
TWA value 98 mg/m3 ; 20 ppm (OEL (EU)) indicative
STEL value 246 mg/m3 ; 50 ppm (OEL (EU)) indicative

PNEC
freshwater: 8.8 mg/l
marine water: 0.88 mg/l
intermittent release: 9.1 mg/l
sediment (freshwater): 34.6 mg/kg
sediment (marine water): 3.46 mg/kg
soil: 3.13 mg/kg
STP: 463 mg/l
oral (secondary poisoning): 20 mg/kg

DNEL
worker:
Long-term exposure- systemic effects, dermal: 75 mg/kg
worker:
Long-term exposure- systemic effects, Inhalation: 20 ppm
consumer:
Long-term exposure- systemic effects, dermal: 38 mg/kg
consumer:
Long-term exposure- systemic effects, oral: 3.2 mg/kg
consumer:
Short-term exposure - local effects, Inhalation: 123 mg/m3
consumer:
Long-term exposure- systemic effects, Inhalation: 49 mg/m3

8.2 Exposure controls

PERSONAL PROTECTION

Eye and face protection: Wear safety glasses. Contact lenses should not be worn. Chemical goggles
and face shield should be worn where splashing is a possibility.

Skin protection: Wear solvent resistant gloves such as Viton, polyvinyl alcohol or
equivalent and solvent resistant boots, safety shower and eyewash station
should be available.

Respiratory protection: If engineering controls do not maintain airborne concentrations to a

level which is adequate to protect worker health, select respiratory
protection equipment suitable for the specific conditions of use and
meeting relevant legislation. Where air-filtering respirators are
suitable, select an appropriate combination of mask and filter. Select
a filter suitable for organic gases and vapours [boiling point >65 °C
(149 °F)] meeting EN141. Where air-filtering respirators are
unsuitable (e.g., airborne concentrations are high, risk of oxygen
deficiency, confined space) use appropriate positive pressure
breathing apparatus.
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9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

9.1.1. Appearance

Physical State: Liquid

Color: Colorless

Odor: Odorless

9.1.2. Basic data

Initial Boiling Point: <240oC

Final Boiling Point: >262oC

Flash Point: > 61oC

Autoignition Temperature: >220oC

Lower Explosion Limit (vol %): <0.6% (v/v)

Upper Explosion Limit (vol %): >5.5% (v/v)

Vapour Pressure: <0.0003 kPa at 20oC

Relative vapor density (air= 1) : <0.01

Specific Gravity (gr/cm3): 0.88 at 200C

pH: -

Pour point (at 0C) : < - 300C

Cloud Point: < - 50C

Viscosity: < 100 cSt at 150C

9.2 Other Information: No further relevant information available.

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10. STABILITY AND REACTIVITY

10.1 Chemical stability

Material is stable under normal conditions of use and storage.

10.2 Conditions to avoid

Avoid open flames, sparks, heating and high energy ignition sources.

10.3 Materials to avoid

Keep it away from strong oxidizing materials.

10.4 Hazardous Decomposition products

Material does not decompose at ambient temperatures.
Possible the formation of toxic Carbon monoxide when no proper combustion takes place.

10.5 Hazardous polymerization

Will not occur.

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

EXPOSURE LIMITS

Name of Substance: Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics

Basis for Assessment

Information given is based on product testing, and/or similar products, and/or components.

Routes of Exposure
Exposure may occur via inhalation, ingestion, skin absorption, skin or eye contact, and accidental
ingestion.

Acute Oral Toxicity

Low toxicity: LD50 >5000 mg/kg.

Acute Dermal Toxicity

Low toxicity: LD50 >5000 mg/kg.

Acute Inhalation Toxicity

Low toxicity: LC50 greater than near-saturated vapour concentration. / 4 hours, rat.

Skin Irritation
Causes mild skin irritation. Prolonged/repeated contact may cause defatting of the skin which can lead to
dermatitis.

Eye Irritation
Expected to be non-irritating to eyes.

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Respiratory Irritation
Not expected to be a respiratory irritant.

Sensitisation
Not a skin sensitiser.

Name of Substance: Hydrocarbons, C9, aromatics

Basis for Assessment: Information given is based on product testing, and/or similar products, and/or
components.
Routes of Exposure: Exposure may occur via inhalation, ingestion, skin absorption, skin or eye contact,
and accidental ingestion.
Acute Oral Toxicity: May be harmful if swallowed. LD50 >2000 - <=5000 mg/kg, Rat
Acute Dermal Toxicity: Low toxicity: LD50 >2000 mg/kg, Rabbit
Acute Inhalation Toxicity: Low toxicity: LC50 greater than near-saturated vapour concentration.
Skin corrosion/irritation: Causes mild skin irritation. Prolonged/repeated contact may cause defatting of
the skin which can lead to dermatitis.
Serious eye damage/irritation: Expected to be non-irritating to eyes.
Respiratory or skin sensitisation: Not expected to be a sensitiser.
Aspiration hazard: Aspiration into the lungs when swallowed or vomited may cause chemical
pneumonitis which can be fatal.
Germ cell mutagenicity: Not mutagenic.
Carcinogenicity: Not expected to be carcinogenic. Tumours produced in animals are not considered
relevant to humans. (Cumene)

Material Carcinogenicity Classification

Hydrocarbons, C9, GHS / CLP: No carcinogenicity classification

Aromatics

1,2,4-Trimethyl benzene GHS / CLP: No carcinogenicity classification

1,3,5-Trimethyl benzene GHS / CLP: No carcinogenicity classification
1,2,3-Trimethyl benzene GHS / CLP: No carcinogenicity classification
Cumene IARC 2B: Possibly carcinogenic to humans.
Cumene GHS / CLP: No carcinogenicity classification

Reproductive and Developmental Toxicity: Does not impair fertility. Not a developmental toxicant.
Causes foetotoxicity in animals at doses which are maternally toxic.
Specific target organ toxicity - single exposure: May cause drowsiness or dizziness. May cause
respiratory irritation.
Specific target organ toxicity - repeated exposure: Auditory system: prolonged and repeated exposures
to high concentrations have resulted in hearing loss in rats. Solvent abuse and noise interaction in the work
environment may cause hearing loss. (Xylene)
Kidney: caused kidney effects in male rats which are not considered relevant to humans.

Name of Substance: 2-Propylheptanol Ethoxylate

Acute oral toxicity: LD50: > 2,000 - 5,000 mg/kg

Species: rat
The value is estimated from tests on similar products.

Acute inhalation toxicity: LC50: > 20 mg/l

Acute dermal toxicity: LD50: > 2,000 - 5,000 mg/kg

Skin irritation: No skin irritation

Eye irritation: Risk of serious damage to eyes.

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Sensitisation: Not sensitizing.

Repeated dose toxicity: NOEL: 250 mg/kg

Germ cell mutagenicity

Genotoxicity in vitro: Negative

Genotoxicity in vivo: Negative

Target Organ Systemic Toxicant - Repeated exposure: NOEL: 250 mg/kg

Name of Substance: 2-aminoethanol

Acute toxicity

Assessment of acute toxicity:

Of moderate toxicity after short-term inhalation. Of moderate toxicity after short-term skin contact. Of
moderate toxicity after single ingestion. Inhalation-risk test (IRT): No mortality within 8 hours as shown
in animal studies. The inhalation of a highly saturated vapor-air mixture represents no acute hazard.
Experimental/calculated data:
LD50 rat (oral): 1,515 mg/kg (OECD Guideline 401)

LC50 rat (by inhalation): > 1.3 mg/l 6 h (IRT)

LD50 rabbit (dermal): 2,504 mg/kg (OECD Guideline 402)

Irritation

Assessment of irritating effects:

Damages skin and eyes. May cause severe damage to the eyes.

Experimental/calculated data:
Skin corrosion/irritation rabbit: Corrosive. (OECD Guideline 404)
Serious eye damage/irritation rabbit: Irritant. (OECD Guideline 405)
Respiratory/Skin sensitization

Assessment of sensitization:
No sensitizing effect.
Experimental/calculated data:
Guinea pig maximization test guinea pig: Non-sensitizing. (OECD Guideline 406)
Germ cell mutagenicity

Assessment of mutagenicity:
In the majority of studies performed with microorganisms and in mammalian cell culture, a mutagenic
effect was not found. A mutagenic effect was also not observed in in vivo tests.

Carcinogenicity
Assessment of carcinogenicity:
The whole of the information available provides no indication of a carcinogenic effect.

Reproductive toxicity
Assessment of reproduction toxicity:
The product has not been tested. The statement has been derived from products of a similar structure
or composition. The potential to impair fertility cannot be excluded when given at maternally toxic
doses. Because the relevance of the results to human health is unclear, further tests will be initiated.

Developmental toxicity
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Assessment of teratogenicity:
In animal studies the substance did not cause malformations.

Specific target organ toxicity (single exposure)

Assessment of STOT single:

The available information is not sufficient for evaluation.

Assessment of repeated dose toxicity:

After repeated exposure the prominent effect is local irritation. The substance may cause damage to
the upper respiratory tract even after repeated inhalation, as shown in animal studies.
Aspiration hazard
No aspiration hazard expected.

Name of Substance: Phosphoric acid, 2-ethylhexyl ester

No data available.

Name of Substance: 2-butoxyethanol

Acute toxicity

Assessment of acute toxicity:

Of moderate toxicity after short-term inhalation. Of moderate toxicity after short-term skin contact. Of
moderate toxicity after single ingestion. EU-classification.

Experimental/calculated data:
LD50 rat (oral): 1,746 mg/kg
LC50 rat (by inhalation): 2 - 20 mg/l 4 h (IRT)
LD50 guinea pig (dermal): > 2,000 mg/kg (OECD Guideline 402)

Irritation

Assessment of irritating effects:

Eye contact causes irritation. Skin contact causes irritation.
Experimental/calculated data:
Skin corrosion/irritation rabbit: Irritant. (BASF-Test)
Serious eye damage/irritation rabbit: Irritant. (OECD Guideline 405)

Respiratory/Skin sensitization.

Assessment of sensitization:
Skin sensitizing effects were not observed in animal studies.
Experimental/calculated data:
Guinea pig maximization test guinea pig: Non-sensitizing. (similar to OECD guideline 406)

Germ cell mutagenicity

Assessment of mutagenicity:
In the majority of tests performed (bacteria/microorganisms/cell cultures) a mutagenic effect was not
found. A mutagenic effect was also not observed in in-vivo assays.

Carcinogenicity
Assessment of carcinogenicity:
Indication of possible carcinogenic effect in animal tests. A clear indication of an increased risk of
cancer in humans has so far not been shown. IARC Group 3 (not classifiable as to human
carcinogenicity).

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Reproductive toxicity
Assessment of reproduction toxicity:
The results of animal studies gave no indication of a fertility impairing effect.

Developmental toxicity
Assessment of teratogenicity:
The substance did not cause malformations in animal studies; however, toxicity to development was
observed at high doses that were toxic to the parental animals. After the uptake of small doses
toxicity to development will not be expected in humans.

Specific target organ toxicity (single exposure)

Assessment of STOT single:
Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:
No substance-specific organ toxicity was observed after repeated administration to animals.
Aspiration hazard not applicable

Other relevant toxicity information

Skin resorption hazard.

HEALTH EFFECTS

Inhalation: Exposure to high concentrations of vapour or mist can cause dizziness, headache,
drowsiness, nausea, cough and unconsciousness.

Skin contact: Prolonged or repeated contact of liquid can cause dry skin and defats of skin.

Eye contact: Liquid in eyes produces pain and irritation with mild temporary damage, vapour slightly
irritating to eyes.

Ingestion: It can be aspired into lungs, which can cause Cough, Diarrhoea, Sore throat and vomiting.

12. ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL DATA

12.1 Toxicity

Name of Substance: Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics

Acute Toxicity

Fish: Practically non toxic: LL/EL/IL50 > 100 mg/l

Aquatic crustacea: Practically non toxic: LL/EL/IL50 > 100 mg/l
Algae/aquatic plants: Practically non toxic: LL/EL/IL50 > 100 mg/l
Microorganisms: Practically non toxic: LL/EL/IL50 > 100 mg/l

Chronic Toxicity

Fish: NOEC/NOEL expected to be > 0.1 - <= 1.0 mg/l (based on modeled data).
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Aquatic crustacea: NOEC/NOEL expected to be > 0.1 - <= 1.0 mg/l (based on modeled data).

Name of Substance: 2-aminoethanol

Toxicity to fish

LC50 (96 h) 349 mg/l, Cyprinus carpio (Directive 92/69/EEC, C.1, semistatic)
Nominal values (confirmed by concentration control analytics)
LC50 (96 h) 170 mg/l, Carassius auratus (APHA 1971, static)
The statement of the toxic effect relates to the analytically determined concentration. Literature data.

Aquatic invertebrates

EC50 (48 h) 65 mg/l, Daphnia magna (Directive 84/449/EEC, C.2, static)

Nominal values (confirmed by concentration control analytics).

Aquatic plants

EC50 (72 h) 2.5 mg/l (growth rate), Selenastrum capricornutum (OECD Guideline 201)
Literature data.
EC50 (72 h) 22 mg/l (growth rate), Scenedesmus subspicatus (Guideline 92/69/EEC, C.3)
Nominal values (confirmed by concentration control analytics).

Microorganisms/Effect on activated sludge

EC20 (0.5 h) > 1,000 mg/l, activated sludge, domestic (DIN EN ISO 8192-OECD 209-88/302/EEC,P.
C, aquatic)
Nominal concentration.
EC50 (16 h) 110 mg/l, Pseudomonas putida (DIN 38412 Part 8)
The details of the toxic effect relate to the nominal concentration.
EC50 (3 h) > 1,000 mg/l, activated sludge, domestic (OECD Guideline 209, aquatic).

Chronic toxicity to fish

No observed effect concentration (30 d) 1.2 mg/l, Oryzias latipes (OECD Guideline draft).

Chronic toxicity to aquatic invertebrates

No observed effect concentration (21 d), 0.85 mg/l, Daphnia magna (OECD Guideline 211)
Assessment of terrestrial toxicity: Study scientifically not justified.

Name of Substance: Hydrocarbons, C9, aromatics

Acute Toxicity
Fish: Expected to be toxic: LC/EC/IC50 > 1 - <=10 mg/l
Aquatic crustacea: Expected to be toxic: LC/EC/IC50 > 1 - <=10 mg/l
Algae/aquatic plants: Expected to be toxic: LC/EC/IC50 > 1 - <=10 mg/l
Microorganisms: Expected to be practically non toxic: LC/EC/IC50 > 100 mg/l

Chronic Toxicity
Fish: Data not available.
Aquatic crustacea: Data not available.

Name of Substance: 2-Propylheptanol Ethoxylate

Toxicity to fish

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LC50: > 10 - 100 mg/l
Exposure time: 96 h
Species: Oncorhynchus mykiss (rainbow trout)

Toxicity to daphnia and other aquatic invertebrates

EC50: > 10 - 100 mg/l

Exposure time: 48 h
Species: Daphnia magna (Water flea)

Toxicity to algae

EC50: > 10 - 100 mg/l

Exposure time: 72 h
Species: algae

Name of Substance: Phosphoric acid, 2-ethylhexyl ester

The toxicity data listed, below, is based on a similar product:

Ecotoxicity effects
The environmental impact of this product has not been fully investigated.

LC50 189 - 355 mg/L (Danio rerio; 96hrs, OECD 203A).

EC50/96hr/48hr/24hr: EC20: 56.9 mg/L (bioluminescence method; NVN 6516).

Name of Substance: 2-butoxyethanol

Toxicity to fish:
LC50 (96 h) 1,474 mg/l, Oncorhynchus mykiss (OECD Guideline 203, static)
Nominal concentration. Literature data.

Aquatic invertebrates:
EC50 (48 h) 1,550 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)
Nominal concentration. Literature data.

Aquatic plants:
EC50 (72 h) 1,840 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201, static)
Nominal concentration. Literature data.

Microorganisms/Effect on activated sludge:

Toxic limit concentration (16 h) > 700 mg/l, Pseudomonas putida (DIN 38412 Part 8, static)
Nominal concentration. Literature data.

Chronic toxicity to fish:

No observed effect concentration (21 d) > 100 mg/l, Brachydanio rerio (semistatic)
Nominal concentration. Literature data.

Chronic toxicity to aquatic invertebrates:

No observed effect concentration (21 d) 100 mg/l, Daphnia magna (OECD Guideline 211, semistatic)
Nominal concentration. Literature data.

Assessment of terrestrial toxicity:

Study scientifically not justified.

12.2 Persistence and Degradability

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Name of Substance: Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics

The substance is readily biodegradable. Oxidises rapidly by photo-chemical reactions in air.

Name of Substance: Hydrocarbons, C9, aromatics

Readily biodegradable. Oxidises rapidly by photo-chemical reactions in air.

Name of Substance: 2-Propylheptanol Ethoxylate

Degradation: Readily biodegradable. >60% BOD, 28 days, Closed Bottle Test (OECD 301D).

Name of Substance: 2-aminoethanol

Assessment biodegradation and elimination (H2O):

Readily biodegradable (according to OECD criteria).

Readily biodegradable (according to OECD criteria).

Elimination information: > 90 % DOC reduction (21 d) (OECD 301 A (new version)) (aerobic, activated
sludge, domestic)

Assessment of stability in water:

According to structural properties, hydrolysis is not expected/probable.

Name of Substance: Phosphoric acid, 2-ethylhexyl ester

Inherently biodegradable.

Name of Substance: 2-butoxyethanol

Assessment biodegradation and elimination (H2O):

Readily biodegradable (according to OECD criteria).

Elimination information:
90 % TIC of the ThIC (28 d) (OECD 301B; ISO 9439; 92/69/EEC, C.4-C) (aerobic, activated sludge)

Assessment of stability in water:

Study scientifically not justified.

12.3 Bioaccumulative potential

Name of Substance: Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics

Has the potential to bioaccumulate.

Name of Substance: Hydrocarbons, C9, aromatics

Contains components with the potential to bioaccumulate.

Name of Substance: 2-Propylheptanol Ethoxylate

Bioaccumulation: Bioaccumulation is unlikely.

Name of Substance: 2-aminoethanol

Assessment bioaccumulation potential:

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Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to
be expected.

Name of Substance: Phosphoric acid, 2-ethylhexyl ester

No data available.

Name of Substance: 2-butoxyethanol

Assessment bioaccumulation potential:

Significant accumulation in organisms is not to be expected.

12.4 Mobility in soil

Name of Substance: Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics

Floats on water. Adsorbs to soil and has low mobility.

Name of Substance: Hydrocarbons, C9, aromatics

Floats on water. Adsorbs to soil and has low mobility.

Name of Substance: 2-Propylheptanol Ethoxylate

Bioaccumulation is unlikely.

Name of Substance: 2-aminoethanol

Assessment transport between environmental compartments:

The substance will not evaporate into the atmosphere from the water surface.
Adsorption to solid soil phase is not expected.

Name of Substance: Phosphoric acid, 2-ethylhexyl ester

Mobility: Not applicable.

Biodegradability: The product is readily biodegradable
(> 60%; OECD 301B)
74% (OECD 302 B, Zahn-Wellens, 28 d)
82% (OECD 301 D, Closed bottle, 21 d)

Name of Substance: 2-butoxyethanol

Assessment transport between environmental compartments:

Volatility: The substance will not evaporate into the atmosphere from the water surface.
Adsorption in soil: Adsorption to solid soil phase is not expected. Study scientifically not justified.

12.5 Results of PBT and vPvB assessment

Name of Substance: Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics

The substance does not fulfil all screening criteria for persistence, bioaccumulation and toxicity and hence
is not considered to be PBT or vPvB.

Name of Substance: Hydrocarbons, C9, aromatics

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The substance does not fulfill all screening criteria for persistence, bioaccumulation and toxicity and hence
is not considered to be PBT or vPvB.

Name of Substance: 2-Propylheptanol Ethoxylate

This substance is not considered to be a PBT (Persistent, Bioaccumulation, Toxic).

This substance is not considered to be vPvB (very Persistent nor very Bioaccumulating).

Name of Substance: 2-aminoethanol

According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): Not fulfilling PBT
(persistent/bioaccumulative/toxic) criteria. Self classification.

According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): Not fulfilling vPvB (very persistent/very
bioaccummulative) criteria. Self classification.

Name of Substance: Phosphoric acid, 2-ethylhexyl ester

Not applicable.

Name of Substance: 2-butoxyethanol

According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The substance does not fulfil the criteria for PBT
(Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative). Self
classification.

12.6 Other adverse effects

Name of Substance: Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics

No data available.

Name of Substance: Hydrocarbons, C9, aromatics

None known.

Name of Substance: 2-Propylheptanol Ethoxylate

No data available.

Name of Substance: 2-aminoethanol

Biochemical oxygen demand (BOD) Incubation period 5 d: 800 mg/g.

Name of Substance: Phosphoric acid, 2-ethylhexyl ester

BOD/COD:
BOD/COD: 0.16
COD-value: 2.0 g O2/g
BOD5-value: 0.32 g O2/g

Name of Substance: 2-butoxyethanol

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The substance is not listed in Regulation (EC) 1005/2009 on substances that deplete the ozone
layer.

Adsorbable organically-bound halogen (AOX):

This product contains no organically-bound halogen.

DEGRADATION
Product readily biodegradable. Oxidizes rapidly by photochemical reaction in air.

BIOACCUMULATION
Product has the potential to bioaccumulate.

The product is not harmful to the marine environment as per paragraphs 1.7.4 and 1.7.5. of Resolution
MEPC. 219 (63) /Annex 24 - 2012 adoption of IMO’s MARPOL Annex V.

13. DISPOSAL CONSIDERATIONS

13.1 Waste disposal

Disposal recommendations are based on material as supplied. Disposal must be in accordance with current
applicable laws and regulations, and material characteristics at time of disposal .
Disposal recommendation: Product is suitable for burning in an enclosed controlled burner for fuel value
or disposal by supervised incineration at very high temperatures to prevent formation of undesirable
combustion products .
Regulatory Disposal Information: European Waste Code: 08 XX XX

NOTE: These codes are assigned based upon the most common uses for this material and may not reflect
contaminants resulting from actual use. Waste producers need to assess the actual process used when
generating the waste and its contaminants in order to assign the proper waste disposal code(s).

13.2 Disposal of contaminated packaging

Disposal recommendation: Empty containers may contain residue and can be dangerous. Do not attempt
to refill or clean containers without proper instructions. Empty drums should be completely drained and
safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling,
recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental
regulations.

DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

14. TRANSPORT INFORMATION

14.1 Not classified as dangerous for the transportation according to IMO, ADR/RID, US DOT and
IATA/ICAO codes.

15. REGULATORY INFORMATION

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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture.

If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

15.2 Chemical Safety Assessment

A CSA has been carried out for the raw materials in this product, from the raw materials manufacturers
(when needed to be carried out).

16. OTHER INFORMATION

16.1 Full text of Hazard Code(s) referred in Section 3

H226: Flammable liquid and vapour.

H302: Harmful if swallowed.
H304: May be fatal if swallowed and enters airways.
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
H336: May cause drowsiness or dizziness.
H411: Toxic to aquatic life with long lasting effects.
EUH066: Repeated exposure may cause skin dryness or cracking.

16.2 Abbreviations and acronyms

ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road).
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail).
IMDG: International Maritime Code for Dangerous Goods.
IATA: International Air Transport Association.
ICAO: International Civil Aviation Organization.
bw: Body weight.
Carc.: Carcinogenicity.
CAS number: Chemical Abstracts Service number.
CLP: Classification Labelling Packaging Regulation.
CSA: Chemical Safety Assessment.
CSR: Chemical Safety Report.
DNEL: Derived No Effect Level.
dw: Dry weight.
EC number: EINECS and ELINCS number.
EC: European Commission.
EC50: Half maximal effective concentration.
EINECS: European Inventory of Existing Commercial Chemical Substances.
ELINCS: European List of Notified Chemical Substances.
EmS: Emergency Schedule.
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ERC: Environmental Release Category.
ES: Exposure scenario.
food: oral feed.
GHS: Globally Harmonized System of Classification and Labelling of Chemicals.
Irrit.: Irritation.
LC50: Lethal concentration, 50 %.
LD50: Median Lethal dose.
LOAEC: Lowest Observed Adverse Effect Concentration.
LOAEL: Lowest Observed Adverse Effect Level.
MK value: Maximum Concentration value.
NCO: An international corporation that provides customer service contracting.
NOAEC: No Observed Adverse Effect Concentration.
NOAEL: No Observed Adverse Effect Level.
NOEC: No Observed Effect Concentration.
OECD: Organisation for Economic Cooperation and Development.
PBT: Persistent, Bioaccumulative and Toxic.
PNEC: Predicted No Effect Concentration.
PROC: Process category.
REACH: The Registration, Evaluation, Authorisation and Restriction of Chemicals.
Resp.: Respiratory.
Sens.: Sensitization.
STEL value: Short Term Exposure Limit value.
STOT RE: Specific target organ toxicity — repeated exposure.
STOT SE: Specific target organ toxicity — single exposure.
STOT: Specific Target Organ Toxicity.
STP: Sewage Treatment Plant.
SU: Sector of use.
Tox.: Toxicity.
TWA value: Time Weighted Average value.
vPvB: Very Persistent and Very Bioaccumulative.

16.3 Notice to reader

All information, instructions and statements contained in this Material Safety Data Sheet are compiled in
accordance with European Directives, corresponding national legislation and on the basis of information
given by our suppliers.
The information disclosed in this Material Safety Data Sheet (which supersedes all previous versions) is
believed to be correct, at the date of issue, to the best of our current knowledge and experience. It only
relates to the specific product designated herein and it may not be valid when said product is used in
combination with any other products or in any processed form, unless specified in the text. This document
aims to provide the necessary health and safety information of the product and is not to be considered a
warranty or quality specification. It is the responsibility of the recipient of this Material Safety Data Sheet
to ensure that information given here is read and understood by all who use, handle, dispose of or in any
way come in contact with the product.
Also, it is the responsibility of the user to comply with local legislation relating to safety, health,
environment and waste management. Data and information provided concerning the product are
informative, exclusively presented to the customer.

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