0% found this document useful (0 votes)
4 views37 pages

Solution

The document contains a series of physics and chemistry problems covering topics such as electric dipoles, thermodynamics, wave properties, and molecular structures. Each section presents multiple-choice questions that require calculations or conceptual understanding of scientific principles. The problems are designed for assessment in a structured academic setting.

Uploaded by

kartikagarwaliit
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
4 views37 pages

Solution

The document contains a series of physics and chemistry problems covering topics such as electric dipoles, thermodynamics, wave properties, and molecular structures. Each section presents multiple-choice questions that require calculations or conceptual understanding of scientific principles. The problems are designed for assessment in a structured academic setting.

Uploaded by

kartikagarwaliit
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

16-03-2025

1001CJA101021240050 JA

PART-1 : PHYSICS

SECTION-I (i)

1) An electric dipole is formed by two charges +q and –q located in xy-plane at (0, 2) mm and (0, –2)
mm, respectively, as shown in the figure. The electric potential at point P(100, 100) mm due to the
dipole is V0. The charges +q and –q are then moved to the points (–1, 0) mm and (1, 0) mm,
respectively. What is the value of electric potential at P due to the new dipole ?

(A)

(B)

(C)

(D)

2) Density is expressed in terms of three derived quantities, namely, the gravitational constant G,
Planck's constant h and the speed of light c, as ρ = cα hβ Gγ. Which of the following is the correct
option?

(A) α = 5, β = –1, γ = –2
(B) α = –5, β = –1, γ = –2
(C) α = 5, β = –1, γ = 2
(D) α = –5, β = 1, γ = –2
3) A particle of mass m is moving in the xy-plane such that its velocity at a point (x, y) is given as
where α is a non-zero constant. What is the torque acting on the particle about the
origin ?

(A)
(B) 2mαxy
mαxy
(C)

–2mαxy
(D)

4) An ideal gas is in thermodynamic equilibrium. The number of degrees of freedom of a molecule of


the gas is n. The internal energy of one mole of the gas is Un and the speed of sound in the gas is vn.
At a fixed temperature and pressure, which of the following is the correct option ?

(A) v3 < v6 and U3 > U6


(B) v5 > v3 and U3 > U5
(C) v5 > v7 and U5 < U7
(D) v6 < v7 and U6 < U7

SECTION-I (ii)

1) A monochromatic light wave is incident normally on a thin glass slab of thickness d, as shown in
the figure. The refractive index of the slab increases linearly from n1 to n2 over the height h. Which
of the following statement(s) is (are) true about the light wave emerging out of the slab?

(A)
It will deflect up by an angle

(B)
It will deflect up by an angle
(C) It will not deflect.
(D) The deflection angle depends only on (n2 – n1) and not on the individual values of n1 and n2.

2) An spherical shell of mass M, inner radius a and outer radius b is placed on a horizontal surface
with coefficient of friction μ, as shown in the figure. At some time, an impulse is applied at a
height h above the center of the shell. If h = hm then the shell rolls without slipping along the x-axis.
Which of the following statement(s) is(are) correct ?

(A) For µ ≠ 0 and a → 0, hm = b/2


(B) For μ ≠ 0 and a → b, hm = 2b/3
(C) For h = hm the initial angular velocity is inversely proportional to on the outer radius b.
(D) For μ = 0 and h = 0, the shell always slides without rolling.

3) The magnetic field associated with an electromagnetic wave propagating in a dielectric medium is

given by . Which of the following option(s) is(are)


correct? [Given: The speed of light in vacuum, c = 3 × 108 ms–1]

(A)
Ex = – 15sin

(B)
Ey = –15sin
The wave is polarized in the xy-plane with electric field at an angle of 45° with respect to the
(C)
positive x-axis.
(D) The refractive index of the medium is 2.

SECTION-II (i)

Common Content for Question No. 1 to 2


S1 and S2 are two identical sound sources of frequency 536 Hz. The source S1 is located at O and S2
moves clockwise with a uniform speed 4 ms–1 on a circular path of radius R around O, as shown in

the figure. There are three points P, Q and R such that P and R are opposite at a distance of from
O while Q is equidistant from them. A sound detector is placed at point P. The source S1 can move

along direction OP. [Given: The speed of sound in air is 324 ms−1]

1) When only S2 is emitting sound and it is at Q, the frequency of sound measured by the detector in
Hz is __________.
2) Consider both sources emitting sound. When S2 is above R and S1 approaches the detector with a
speed 4 ms–1, the beat frequency measured by the detector is ____Hz.

Common Content for Question No. 3 to 4

A cylindrical furnace has height (H) and diameter (D) both 1 m. It is maintained at temperature 360
K. The air gets heated inside the furnace at constant pressure Pa and its temperature becomes T =
360 K. The hot air with density ฀ rises up a vertical chimney of diameter d = 0.1 m and height h = 9
m above the furnace and exits the chimney (see the figure). As a result, atmospheric air of density ρa
= 1.2 kg m–3, pressure Pa and temperature Ta = 300 K enters the furnace. Assume air as an ideal gas,
neglect the variations in ρ and T inside the chimney and the furnace. Also ignore the viscous effects.
Assume that just outside the furnace at the ground level pressure Pa is atmospheric. [Given: The
acceleration due to gravity g = 10 ms–2 and π = 3.14]

3) Considering the air flow to be streamline, the steady mass flow rate of air exiting the chimney is
_______gm s–1.

4) When the chimney is closed using a cap at the top, a pressure difference ΔP develops between the
top and the bottom surfaces of the cap. If the changes in the temperature and density of the hot air,
due to the stoppage of air flow, are negligible then the value of ΔP is ______ Nm−2.

SECTION-II (ii)

1) A thin circular coin of mass 5 gm and radius 4/3 cm is initially in a horizontal xy-plane. The coin is

tossed vertically up (+฀ direction) by applying an impulse of at a distance 1 cm


from its center. The coin spins about its diameter and moves along the +฀ direction. By the time the
coin reaches back to its initial position, it completes ฀ rotations. The value of n is :- [Given: The
acceleration due to gravity g = 10 ms–2]

2) A rectangular conducting loop of length 4 cm and width 2 cm is in the xy-plane, as shown in the

figure. It is being moved away from a thin and long conducting wire along the direction
with a constant speed v. The wire is carrying a steady current I = 10 A in the positive x-direction. A
current of 10 μA flows through the loop when it is at a distance d = 8 cm from the wire. If the
resistance of the loop is 0.1 Ω, then the value of ν is __________ ms–1. [Given: The permeability of free

space μ = 4π × 10–7 NA–2]

3) A string of length 1 m and mass x × 10–5 kg is under tension of 5N. When the string vibrates, two
successive harmonics are found to occur at frequencies 750 Hz and 1000 Hz. The value of x is
_______.

4) An incompressible liquid is kept in a container having a weightless piston with a hole. A capillary
tube of inner radius 0.3 mm is dipped vertically into the liquid through the airtight piston hole, as
shown in the figure. The air in the container is isothermally compressed from its original volume ฀

to with the movable piston. Considering air as an ideal gas, the height (h) of the liquid
column in the capillary above the liquid level in cm is_______.
[Given: Surface tension of the liquid is 0.075 Nm−1, atmospheric pressure is 105 Nm−2, acceleration
due to gravity (g) is 10 ms−2, density of the liquid is 103 kgm−3 and contact angle of capillary surface

with the liquid is zero]

5) In a radioactive decay process, the activity is defined as , where N(t) is the number of
radioactive nuclei at time t. Two radioactive sources, S1 and S2 have same activity at time t = 0. At a
later time, the activities of S1 and S2 are A1 and A2, respectively. Half life of S1 is 300 sec and half life
of S2 is 150 sec. At t = 600 sec, the ratio A1 /A2 is __________.

6) Two mole of an ideal monoatomic gas undergoes two different cyclic processes I and II, as shown
in the P–V diagrams below. In cycle I, processes a, b, c and d are isobaric, isothermal, isobaric and
isochoric, respectively. In cycle II, processes a′, b′, c′ and d′ are isothermal, isochoric, isobaric and
isochoric, respectively. The total heat exchange during cycle I is H1 and that during cycle II is H2.

The ratio is _______.

PART-2 : CHEMISTRY

SECTION-I (i)

1) The correct molecular orbital diagram for O2 molecule (if sp mixing is operative) in the ground
state is

(A)
(B)

(C)

(D)

2) Consider the following statements related to colloids.


(I) Lyophobic colloids can not be coagulated.
(II) For gel, both the dispersed phase and the dispersion medium are liquid.
(III) Micelles can not be formed below Kraft temperature.
(IV) Tyndall effect can be observed from a colloidal solution with dispersed phase having the
different refractive index as that of the dispersion medium.
The option with the correct set of statements is

(A) (I) and (II)


(B) (II) and (III)
(C) (III) and (IV)
(D) (II) and (IV)

3) In the following reactions, W, X, Y, and Z are the major products.

The incorrect statement about W, X, Y, and Z is

(A) W has six carbons and it undergoes Haloform reaction.


(B) X undergoes Kolbe’s electrolysis to give an eight-carbon product.
(C) Y has six carbons and it undergoes Cannizzaro reaction.
(D) Z is a secondary amine with six carbons.

4) A disaccharide X cannot be oxidised by Fehling solution. The acid hydrolysis of X leads to a


laevorotatory solution. The disaccharide X is

(A)

(B)

(C)
(D)

SECTION-I (ii)

1) The complex(es), which can exhibit any type of isomerism shown by [Co(en)3]Cl3 , is(are) [en =
H2NCH2CH2NH2] and Gly = NH2–CH2–COO– ]

(A) [Pt(en)(SCN)2]
(B) [Zn(gly)2]
(C) [Pt(NH3)2Cl4]
+
(D) [Cr(en)2(H2O)(SO4)]

2) Atoms of metals x, y, and z form face-centred cubic (fcc) unit cell of edge length Lx, body-centred
cubic (bcc) unit cell of edge length Ly, and simple cubic unit cell of edge length Lz, respectively.

If and then the correct statement (s) is (are)


[Given : Mx, My, and Mz are molar masses of metals x, y, and z, respectively.
rx, ry, and rz are atomic radii of metals x, y, and z, respectively.]

(A) C.N. of x > y > z


(B) Lx > Ly
(C) Density of y < density of z
(D) Density of x < Density of y

3) In the following reactions, P, Q, R, and S are the major products.

The correct statement (s) about P, Q, R, and S is (are)

(A) Compounds P and S are the same.


(B) P, Q, R and S are dicarboxylic acid.
(C) Compounds Q and R are the same.
(D) R does not undergo aldol condensation and S does not undergo Cannizzaro reaction.

SECTION-II (i)

Common Content for Question No. 1 to 2


"PARAGRAPH I" The enthalpy versus temperature plot for phases α and β at 1 bar pressure is given

HT is enthalpy of phases at temperatures T. The transition


temperature for α to β phase change is 600 K and CP,β – CP,α = 1 J mol K . Assume (CP,β – CP,α) is
–1 –1

independent of temperature in the range of 200 to 700 K. CP,α and CP,β are heat capacities of α and β
phases, respectively.

1) The value of enthalpy change, Hβ – Hα (in J mol–1), at 300 K is __.

2) The value of entropy change, |Sβ – Sα| (in J mol–1 K–1), at 300 K is __.
[Use : ln 2 = 0.69
Given : Sβ – Sα = 0 at 0 K]

Common Content for Question No. 3 to 4


"PARAGRAPH II" A trinitro compound, 1, 3,5 tris-(4-nitrophenyl) benzene, on complete reaction with
an excess of Fe/HCl gives major product, which on treatment with an excess of NaNO2/HCl at 0°C
provides P as the product. P, upon treatment with excess of H2O at room temperature, gives the
product Q. Bromination of Q in aqueous medium then treatment with Zn/Δ furnishes the product R.
The compound P upon treatment with an excess of aniline under mild acidic conditions gives the
product S.

3) The number of heteroatoms present in one molecule of R is _____.


[Use: Molar mass (in g mol–1): H = 1, C = 12, N = 14, O = 16, Br = 80, Cl = 35.5
Atoms other than C and H are considered as heteroatoms]

4) The total number of nitrogen atoms present in one molecule of S is _____. [Use: Molar mass in g
mol–1]: H = 1, C = 12, N = 14, O = 16, Br = 80, Cl = 35.5

SECTION-II (ii)

1) H2S (3 moles) reacts completely with acidified aqueous potassium dichromate solution. In
this reaction, the number of moles of water produced is x, and the number of moles of electrons
involved is y. The value of (x + y) is ____.

2) Among [I3]–, [SiO4]4– , SO2Cl2, XeF2, SF4, ClF3, Fe(CO)5, XeO2F2, [PtCl4]2–, XeF4, and , the total
number of species having sp3d hybridised central atom is ______.

3) Consider the following molecules : Br3O8, CrO5, , H5P3O10 , Na2S5 , H2S4O6, H2S5O6, and C3O2 ,
Mn2(CO)10
Count the number of atoms existing in their zero oxidation state in each molecule. Their sum is____.

4) For He+, a transition takes place from the orbit of radius 26.45 pm to the orbit of radius 105.8
pm. The change in wavelength associated with e– in transition is ______ pm.
(Round off your answer to nearest integer)
[Use : π = 3, Bohr radius, a = 52.9 pm]

5) 50 mL of 0.2 molal urea solution (density = 1.012 g mL–1 at 300 K) is mixed with 500 mL of a
solution containing 0.06 g of urea. Both the solutions were prepared in the same solvent. Then
(ΔTb × 100) is ______ .
[Use : Molar mass of urea = 60 g mol–1; gas constant, R = 62 L Torr K–1 mol–1 ; Assume, ΔmixH = 0,
ΔmixV= 0, Kb = 0.5 K kg mol–1]
ΔTb = elevation in boiling point of final solution.

6) The reaction of 4-methyloct-1-ene (P, 2.52 g) with HBr in the presence of (C6H5CO)2O2 gives two
isomeric bromides in a 9 : 1 ratio, with combined yield of 50%. Of these, the entire amount of the
primary alkyl bromide was reacted with an appropriate amount of diethylamine followed by
treatment with eq. K2CO3 to given a non-ionic product S in 100% yield. The mass (in mg) of S
obtained is _______ .
[Use molar mass (in g mol–1) : H = 1, C = 12, N = 14, Br = 80]

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let be a differentiable function such that and 3

. Let e denote the base of the natural logarithm. Then

(A) f(x) = 3 has 2 real solution

(B)
has 2 real solution

(C)
Range of f(x) is
(D) f(e) = 4e2/3

2) Consider an experiment of tossing a coin repeatedly until the outcomes of two consecutive tosses

are same. If the probability of a random toss resulting in head is , then the probability that the
experiment

(A)
Ends with head given that it starts with tail =

(B)
Ends with head given that it starts with head =

(C)
Ends with head given that it starts with tail =

(D)
Ends with head given that it starts with head =

3) Let {1, 2, 3}, be the 3 × 3 matrix such that aij = 1 if is divisible by i,


otherwise aij = 0. Then which of the following statements is (are) true ?

(A) M is invertible

(B)
There exists a nonzero column matrix such that

(C) 0
3
The set {X ∈ : MX = 0} is singleton where =
(D) The matrix (M – 2I) is invertible, where I is the 3 × 3 identity matrix

4) For let tan–1 (x) . Then the minimum value of the function f : → defined by

is

(A) –1

(B)

(C) 0
(D) 1

SECTION-I (ii)

1) Let f : (0,1) → be the function defined as , where [x]


denotes the greatest integer less than or equal to x. Then which of the following statements is(are)
true?
(A) The function f is discontinuous exactly at one point in (0,1)
(B) There is exactly one point in (0,1) at which the function f is continuous but NOT differentiable

(C)
The function f is differentiable in
Function f is differentible in
(D)

2) Let S be the set of all twice differentiable functions f from to such that for all x ∈
(–1,1). For f ∈ S, let Xf be the number of points x ∈ (–1,1) for which f(x) = ℓn(x + 1). Then which of
the following statements is(are) true?

(A) There exists a function f ∈ S such that Xf = 3


(B) For every function f ∈ S , we have Xf ≤ 2
(C) There exists a function f ∈ S such that Xf = 2
(D) There does NOT exist any function f in S such that Xf = 1

3) Let the position vectors of the points P,Q,R and S be

and , respectively. Then which of the following statements is true?

(A) The points P,Q,R and S are coplanar

(B)
is the position vector of a point which divides PR internally in the ratio 5 : 4

(C)
is the position vector of a point which divides PR externally in the ratio 5 : 4
(D) The square of the magnitude of the vector is 99

SECTION-II (i)

Common Content for Question No. 1 to 2

Consider on obtuse angled triangle ABC in which the difference between the largest and the

smallest angle is and whose sides are in arithmetic progression. Suppose that the vertices of this
triangle lie on a circle of radius 1.

1) If area of triangle is Δ. Then 64Δ2 =

2) Then the inradius of the triangle ABC is

Common Content for Question No. 3 to 4


Consider the 6 × 6 square in the figure. Let A1,A2,…,A49 be the points of intersections (dots in the
picture) in some order. We say that Ai and Aj are friends if they are adjacent along a row or along a

column. Assume that each point Ai has an equal chance of being chosen.

3) Let pi be the probability that a randomly chosen point has i many friends, i = 0,1,2,3,4. Let X be a
random variable such that for i = 0,1,2,3,4, the probability P(X = i)= pi. Then the value of 7E(X) is

4) Two distinct points are chosen randomly out of the points A1,A2,…,A49. Let p be the probability that
they are not friends but have a friend in common . Then the value of 21p is

SECTION-II (ii)

1) For x ∈ , let y(x) be a solution of the differential equation

such that let


f : (0,π) →

f(x) =
f(1) = 2
Then the maximum value of the function f(x) is-

2) Let X be the set of all five digit numbers formed using 01122333. For example, 33320 is in X while
02233 and 22233 are not in X . Suppose that each element of X has an equal chance of being chosen.
Let p be the conditional probability that an element chosen at random is a multiple of 20 given that
it is a multiple of 3. Then the value of 61p is equal to

3) Let A1, A2, A3, ........, A16 be the vertices of a regular hexadecagon that lie on a circle of radius 2.
Let P be a point on the circle and let PAi denote the distance between the points P and Ai for i =
1,2,....,16. If P varies over the circle, then the maximum value of the product PA1 PA3.PA5 ⋅ ⋅ ⋅ ⋅ ⋅ PA15,
is

4) Let . Then number of invertible matrix in R is

5) Let C1 be the circle of radius 1 with center at the origin. Let C2 be the circle of radius r with
center at the point A = (4,1) , where 1 < r < 3. Two distinct common tangents PQ and ST of C1 and
C2 are drawn. The tangent PQ touches C1 at P and C2 at Q. The tangent ST touches C1 at S and C2 at
T. Mid points of the line segments PQ and ST are joined to form a line which meets the x-axis at a
point B. If AB = , then the value of r2 is

6) For any y ∈ let cot–1( y) ∈ (π,2π) and tan–1 (y) ∈ . Then the number of solutions of the

equation for 0 < | y | < 3, is equal to


ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. D A A C

SECTION-I (ii)

Q. 5 6 7
A. B,D B,C,D B,C,D

SECTION-II (i)

Q. 8 9 10 11
A. 540.00 6.70 60.80 to 60.81 30.00

SECTION-II (ii)

Q. 12 13 14 15 16 17
A. 45 10 2 15 4 2

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. A C C D

SECTION-I (ii)

Q. 22 23 24
A. B,D A,C A,B,C,D

SECTION-II (i)

Q. 25 26 27 28
A. 100.00 0.02 or 0.03 6.00 9.00

SECTION-II (ii)

Q. 29 30 31 32 33 34
A. 13 6 11 159 1 1791

PART-3 : MATHEMATICS
SECTION-I (i)

Q. 35 36 37 38
A. D A B C

SECTION-I (ii)

Q. 39 40 41
A. A,B,C B,C A,B,D

SECTION-II (i)

Q. 42 43 44 45
A. 63.00 0.24 to 0.26 23.99 to 24.01 2.53 to 2.54

SECTION-II (ii)

Q. 46 47 48 49 50 51
A. 2 3 512 1110 2 2
SOLUTIONS

PART-1 : PHYSICS

1) =

2)

ML–3 = (LT–1)α(ML2T–1)β(M–1L3T–2)γ
0 = –α – β – 2γ
1=β–γ
–3 = α + 2β + 3γ
γ=–2
β = –1
α=5

3)

= mα[x2 – y2]

4)
∴ A and B are wrong.

⇒ more 'f', less 'v'

5)
n1d + ℓ = n2 d
=

6)
J0 = mv .......(1)
J0hm = Icω ........(2)
v = ωR ........(3)

⇒ hm =

(A) If a = 0 IC = &R=b ∴ hm =

(B) If a = b IC = mb2 & R = b ∴ hm =

(C) v = ⇒ω=
(D) Force is acting on COM ∴ No rotation.

7)

C= = 1.5 × 108

8)
=

9)

fP from S2 = 536

fP from S1 =
Δf = 6.7 Hz.

10)

⇒ 1.2 × 300 = ρ(360) ∴ ρ = 1

Between A & B

= .......(1)

........(2)
Between B & C

.....(3)
from (1) & (2) :

⇒P + =P+


= 2 × 1.2 × 10 × 10 – 2 × 10 × 9
= 240 – 180 = 60 ∴ V =
Ans. 60.80 to 60.81

11)

P = constant
⇒ ρaTa = ρT
1.2 × 300 = ρ × 360
ρ = 1 kg/m3
ΔP = ρag (h + H) – ρgh
= 1.2 × 10 × 10 –1 × 10 × 9
= 120 – 90 = 30 N/m2

12)
J = mv ......(1)
Jr = Icω ........(2)

JC = ........(3)

........(4)
θ = 2πN = ωt.......(5) ∴ N = 45
13)
R = 0.1Ω
ε = (B1 – B2)bvy

i=

∴ vy = 6 = ⇒ v = 10 m/s

14)

.......(1)

.......(2)

∴P=3

⇒ 1000 = ∴x=2

15)

= 5 cm +

16) A1 =

A2 =

17) ΔU = 0

PART-2 : CHEMISTRY

20)
21) Sucrose Glucose + Fructose
Specific rotation + 52.5° –92° (mixture of products is laevorotatory)
Sucrose No reaction
ABC ⇒ reducing sugars, will get oxidized by Fehling solution.

23)

Element X Y Z

Packing FCC BCC Primitive


Edge Lx Ly Lz

Relation between edge length and


Lz = 2rz
radius

C.N. 12 8 6

Now, ry = rx & rz = ry = rx ⇒ rz = 4rx

So, Lx = 2 rx, Ly = rx, Lz = 8rx

Lx = 2 rx, Ly = rx, Lz = 8rx


So Ly > Lz > Lx

Density , ,

Now, 3Mx = or Mx × 2 = My

24)
25) As the phase transition temperature is 600 K
ΔH600K = 400 J
So ΔH600 – ΔH300 = ΔCP (T2 – T1)
ΔH600 – ΔH300 = 1 × 300
ΔH300 = ΔH600 – 300 = 400 – 300 = 100 Joule/mole.

26)

(ΔS)600 K = (ΔS)300 K + (ΔCP)r ln


(ΔS)300 K = – 0.69 = – 0.024

28) Common solution for [Link]. 16 and 17


Number of N-atom in S = 9

29)

Cr2O72– + 3H2S + 8H+ → 3s + 2Cr+3 + 7H2O


x=7
y=6
31) Br3O8

Number of atoms with zero oxidation state = 0

Number of atom with zero oxidation state = 0


H2S4O6

Number of atoms with zero oxidation state = 2


H2S5O6

Number of atoms where zero oxidation state = 3


C3O2
(0)
O=C=C=C=O
Number of atoms with zero oxidation state = 1
Na2S5

Number of atoms where zero oxidation state = 3


H5P3O10

Number of atoms where zero oxidation state = 0


Mn2(CO)10
Number of Mn with zero oxidation state = 2

32) For single electron system

r = 52.9 × pm
Given Z = 2 for He+
r2 = 105.8 pm

So 105.8 = 52.9 ×
n2 = 2
r1 = 26.45

So 26.45 = 52.9 ×
n1 = 1
So transition is from 1 to 2.

= 2π × (52.9 – 26.45) = 158.7

33) Weight of 50 ml 0.2 molal urea = V × d = 50 × 1.012 = 50.6 gm


Given 0.2 molal implies
1000 gm solvent has 0.2 moles urea
So weight of solution = 1000 + 0.2 × 60 = 1012 gm.

So wt. of urea in 50.6 gm solution = = 0.6 gm


Total urea = 0.6 + 0.06 = 0.66 gm
Total volume = 550 ml

ΔTb = Kb.m = 0.5 × = 10–2


34)

PART-3 : MATHEMATICS

35)

Diff. wr.t 'x'


3f(x) = f(x) + xf'(x) – x2

y = x2lnx + cx2


36)
Req. prob = P(HH or HTHH or HTHTHH or …….)
+ P(THH or THTHH or THTHTHH or ….)

37)

|M| = –1 + 1 = 0 ⇒ M is singular so non-invertible

(B)

and a2 + a3 = 0 infinite solutions exists [B] is correct.


Option (D)

|M – 2I| = 0 ⇒ [D] is wrong

Option (C) :

MX = 0 ⇒
x+y+z=0
x+z=0
y=0
∴ Infinite solution
[C] is correct

38)

For x < 0,
For x ≥ 0,
⇒ xtan–1x ≥ 0 ∀ x ∈ R

And

Hence minimum value is

39)

f(x) is discontinuous at only

f(x) is non differentible at and

40) S = Set of all twice differentiable functions f : R → R

in (–1, 1)
Graph ‘f’ is Concave upward.
Number of solutions of f(x) = x → xf

(1) (2) (3)


⇒ Graph of y = f(x) can intersect graph of y = x at atmost two points ⇒ 0 ≤ xf ≤ 2
Aliter

Let ϕ(x) = f(x) – ℓn(x + 1)


ϕ"(x) > 0
∴ ϕ'(x) = 0 has atmost 1 root in x ∈ (–1, 1)
∴ ϕ(x) = 0 has atmost 2 roots in x ∈ (–1, 1)
∴ xf ≤ 2

41)
so [B] is correct.
option –D

= (9 + 36 + 9) (4 + 1 + 1) – (6 + 6 + 3)2
= 54 × 6 – (15)2
= 324 – 225
= 99

42) Distance between


INcentre and circumcentre
is

n – d = 2 sinα …(1)

n + d = 2 sin
⇒ n + d = 2 cosα ….(2)

…(3)
⇒ 2 cos2α = sinα + cosα
⇒ 2(cosα – sinα) = 1

43)

From equation in above Ques.


(from (2))

44)

Pi = Probability that randomly


selected points has friends
P0 = 0 (0 friends)
P1 = 0 (exactly 1 friends)

P2 = (exactly 2 friends)

(exactly 3 friends)

(exactly 4 friends)

Mean = E(x) =

45) Total number of ways of selecting 2 persons = 49C2

Number of ways in which 2 friends the selected

No. of points Mutual Friends


4 3
8 4
12 5
4 6
12 7
9 8

46)

y = xsinx(c – x2)
f(x) = x(c – x2)
f(1) = 2 ⇒ c = 3
f(x) = 3x – x3

47)

No. of elements in X which are multiple of 3


are formed using
1,2,3,3,3 or
1,2,3,3,0
11220 or
11223
Total = 122
No. of element in X which are
multiple of 20 = 3 + 3 = 6

48)

z8 – 28 = (z – 2)(z – α)(z – α2)…(z – α7)


Put z = 2eiθ
28(ei8θ – 1) = (2eiθ – 2)(2eiθ – a)…..(2eiθ – a7)
Take mod
28|ei8θ – 1| = PA1 PA3 PA5… PA15
28|2sin4θ| = PA1 PA3 PA5… PA15
(PA1 PA3 PA5… PA15)max = 512

49)

Case I : ad = bc = 0

Total ways = 11 × 11 = 121


Case II : ad = bc ≠ 0
(i) a = b = c = d
5
C1
(ii) ad = bc
No. of ways = 60
Total = 5 + 60 = 65
|R| = 0 for total = 65 + 121 = 186
|R| ≠ 0 for 1296 – 186 = 1110

50)

Let C2 (x – 4)2 + (y – 1)2 = r2


radical axis 8x + 2y –17 = 1 – r2
8x + 2y = 18 – r2

A(4,1)
AB =

r2 = 2

51) Case-I : y ∈ (–3,0)

(∵ y ∈ (–3,0))
Case-I : y ∈ (0,3)

or (rejected)

You might also like