Solution
Solution
1001CJA101021240050 JA
PART-1 : PHYSICS
SECTION-I (i)
1) An electric dipole is formed by two charges +q and –q located in xy-plane at (0, 2) mm and (0, –2)
mm, respectively, as shown in the figure. The electric potential at point P(100, 100) mm due to the
dipole is V0. The charges +q and –q are then moved to the points (–1, 0) mm and (1, 0) mm,
respectively. What is the value of electric potential at P due to the new dipole ?
(A)
(B)
(C)
(D)
2) Density is expressed in terms of three derived quantities, namely, the gravitational constant G,
Planck's constant h and the speed of light c, as ρ = cα hβ Gγ. Which of the following is the correct
option?
(A) α = 5, β = –1, γ = –2
(B) α = –5, β = –1, γ = –2
(C) α = 5, β = –1, γ = 2
(D) α = –5, β = 1, γ = –2
3) A particle of mass m is moving in the xy-plane such that its velocity at a point (x, y) is given as
where α is a non-zero constant. What is the torque acting on the particle about the
origin ?
(A)
(B) 2mαxy
mαxy
(C)
–2mαxy
(D)
SECTION-I (ii)
1) A monochromatic light wave is incident normally on a thin glass slab of thickness d, as shown in
the figure. The refractive index of the slab increases linearly from n1 to n2 over the height h. Which
of the following statement(s) is (are) true about the light wave emerging out of the slab?
(A)
It will deflect up by an angle
(B)
It will deflect up by an angle
(C) It will not deflect.
(D) The deflection angle depends only on (n2 – n1) and not on the individual values of n1 and n2.
2) An spherical shell of mass M, inner radius a and outer radius b is placed on a horizontal surface
with coefficient of friction μ, as shown in the figure. At some time, an impulse is applied at a
height h above the center of the shell. If h = hm then the shell rolls without slipping along the x-axis.
Which of the following statement(s) is(are) correct ?
3) The magnetic field associated with an electromagnetic wave propagating in a dielectric medium is
(A)
Ex = – 15sin
(B)
Ey = –15sin
The wave is polarized in the xy-plane with electric field at an angle of 45° with respect to the
(C)
positive x-axis.
(D) The refractive index of the medium is 2.
SECTION-II (i)
the figure. There are three points P, Q and R such that P and R are opposite at a distance of from
O while Q is equidistant from them. A sound detector is placed at point P. The source S1 can move
along direction OP. [Given: The speed of sound in air is 324 ms−1]
1) When only S2 is emitting sound and it is at Q, the frequency of sound measured by the detector in
Hz is __________.
2) Consider both sources emitting sound. When S2 is above R and S1 approaches the detector with a
speed 4 ms–1, the beat frequency measured by the detector is ____Hz.
A cylindrical furnace has height (H) and diameter (D) both 1 m. It is maintained at temperature 360
K. The air gets heated inside the furnace at constant pressure Pa and its temperature becomes T =
360 K. The hot air with density rises up a vertical chimney of diameter d = 0.1 m and height h = 9
m above the furnace and exits the chimney (see the figure). As a result, atmospheric air of density ρa
= 1.2 kg m–3, pressure Pa and temperature Ta = 300 K enters the furnace. Assume air as an ideal gas,
neglect the variations in ρ and T inside the chimney and the furnace. Also ignore the viscous effects.
Assume that just outside the furnace at the ground level pressure Pa is atmospheric. [Given: The
acceleration due to gravity g = 10 ms–2 and π = 3.14]
3) Considering the air flow to be streamline, the steady mass flow rate of air exiting the chimney is
_______gm s–1.
4) When the chimney is closed using a cap at the top, a pressure difference ΔP develops between the
top and the bottom surfaces of the cap. If the changes in the temperature and density of the hot air,
due to the stoppage of air flow, are negligible then the value of ΔP is ______ Nm−2.
SECTION-II (ii)
1) A thin circular coin of mass 5 gm and radius 4/3 cm is initially in a horizontal xy-plane. The coin is
2) A rectangular conducting loop of length 4 cm and width 2 cm is in the xy-plane, as shown in the
figure. It is being moved away from a thin and long conducting wire along the direction
with a constant speed v. The wire is carrying a steady current I = 10 A in the positive x-direction. A
current of 10 μA flows through the loop when it is at a distance d = 8 cm from the wire. If the
resistance of the loop is 0.1 Ω, then the value of ν is __________ ms–1. [Given: The permeability of free
3) A string of length 1 m and mass x × 10–5 kg is under tension of 5N. When the string vibrates, two
successive harmonics are found to occur at frequencies 750 Hz and 1000 Hz. The value of x is
_______.
4) An incompressible liquid is kept in a container having a weightless piston with a hole. A capillary
tube of inner radius 0.3 mm is dipped vertically into the liquid through the airtight piston hole, as
shown in the figure. The air in the container is isothermally compressed from its original volume
to with the movable piston. Considering air as an ideal gas, the height (h) of the liquid
column in the capillary above the liquid level in cm is_______.
[Given: Surface tension of the liquid is 0.075 Nm−1, atmospheric pressure is 105 Nm−2, acceleration
due to gravity (g) is 10 ms−2, density of the liquid is 103 kgm−3 and contact angle of capillary surface
5) In a radioactive decay process, the activity is defined as , where N(t) is the number of
radioactive nuclei at time t. Two radioactive sources, S1 and S2 have same activity at time t = 0. At a
later time, the activities of S1 and S2 are A1 and A2, respectively. Half life of S1 is 300 sec and half life
of S2 is 150 sec. At t = 600 sec, the ratio A1 /A2 is __________.
6) Two mole of an ideal monoatomic gas undergoes two different cyclic processes I and II, as shown
in the P–V diagrams below. In cycle I, processes a, b, c and d are isobaric, isothermal, isobaric and
isochoric, respectively. In cycle II, processes a′, b′, c′ and d′ are isothermal, isochoric, isobaric and
isochoric, respectively. The total heat exchange during cycle I is H1 and that during cycle II is H2.
PART-2 : CHEMISTRY
SECTION-I (i)
1) The correct molecular orbital diagram for O2 molecule (if sp mixing is operative) in the ground
state is
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
SECTION-I (ii)
1) The complex(es), which can exhibit any type of isomerism shown by [Co(en)3]Cl3 , is(are) [en =
H2NCH2CH2NH2] and Gly = NH2–CH2–COO– ]
(A) [Pt(en)(SCN)2]
(B) [Zn(gly)2]
(C) [Pt(NH3)2Cl4]
+
(D) [Cr(en)2(H2O)(SO4)]
2) Atoms of metals x, y, and z form face-centred cubic (fcc) unit cell of edge length Lx, body-centred
cubic (bcc) unit cell of edge length Ly, and simple cubic unit cell of edge length Lz, respectively.
SECTION-II (i)
independent of temperature in the range of 200 to 700 K. CP,α and CP,β are heat capacities of α and β
phases, respectively.
2) The value of entropy change, |Sβ – Sα| (in J mol–1 K–1), at 300 K is __.
[Use : ln 2 = 0.69
Given : Sβ – Sα = 0 at 0 K]
4) The total number of nitrogen atoms present in one molecule of S is _____. [Use: Molar mass in g
mol–1]: H = 1, C = 12, N = 14, O = 16, Br = 80, Cl = 35.5
SECTION-II (ii)
1) H2S (3 moles) reacts completely with acidified aqueous potassium dichromate solution. In
this reaction, the number of moles of water produced is x, and the number of moles of electrons
involved is y. The value of (x + y) is ____.
2) Among [I3]–, [SiO4]4– , SO2Cl2, XeF2, SF4, ClF3, Fe(CO)5, XeO2F2, [PtCl4]2–, XeF4, and , the total
number of species having sp3d hybridised central atom is ______.
3) Consider the following molecules : Br3O8, CrO5, , H5P3O10 , Na2S5 , H2S4O6, H2S5O6, and C3O2 ,
Mn2(CO)10
Count the number of atoms existing in their zero oxidation state in each molecule. Their sum is____.
4) For He+, a transition takes place from the orbit of radius 26.45 pm to the orbit of radius 105.8
pm. The change in wavelength associated with e– in transition is ______ pm.
(Round off your answer to nearest integer)
[Use : π = 3, Bohr radius, a = 52.9 pm]
5) 50 mL of 0.2 molal urea solution (density = 1.012 g mL–1 at 300 K) is mixed with 500 mL of a
solution containing 0.06 g of urea. Both the solutions were prepared in the same solvent. Then
(ΔTb × 100) is ______ .
[Use : Molar mass of urea = 60 g mol–1; gas constant, R = 62 L Torr K–1 mol–1 ; Assume, ΔmixH = 0,
ΔmixV= 0, Kb = 0.5 K kg mol–1]
ΔTb = elevation in boiling point of final solution.
6) The reaction of 4-methyloct-1-ene (P, 2.52 g) with HBr in the presence of (C6H5CO)2O2 gives two
isomeric bromides in a 9 : 1 ratio, with combined yield of 50%. Of these, the entire amount of the
primary alkyl bromide was reacted with an appropriate amount of diethylamine followed by
treatment with eq. K2CO3 to given a non-ionic product S in 100% yield. The mass (in mg) of S
obtained is _______ .
[Use molar mass (in g mol–1) : H = 1, C = 12, N = 14, Br = 80]
PART-3 : MATHEMATICS
SECTION-I (i)
(B)
has 2 real solution
(C)
Range of f(x) is
(D) f(e) = 4e2/3
2) Consider an experiment of tossing a coin repeatedly until the outcomes of two consecutive tosses
are same. If the probability of a random toss resulting in head is , then the probability that the
experiment
(A)
Ends with head given that it starts with tail =
(B)
Ends with head given that it starts with head =
(C)
Ends with head given that it starts with tail =
(D)
Ends with head given that it starts with head =
(A) M is invertible
(B)
There exists a nonzero column matrix such that
(C) 0
3
The set {X ∈ : MX = 0} is singleton where =
(D) The matrix (M – 2I) is invertible, where I is the 3 × 3 identity matrix
4) For let tan–1 (x) . Then the minimum value of the function f : → defined by
is
(A) –1
(B)
(C) 0
(D) 1
SECTION-I (ii)
(C)
The function f is differentiable in
Function f is differentible in
(D)
2) Let S be the set of all twice differentiable functions f from to such that for all x ∈
(–1,1). For f ∈ S, let Xf be the number of points x ∈ (–1,1) for which f(x) = ℓn(x + 1). Then which of
the following statements is(are) true?
(B)
is the position vector of a point which divides PR internally in the ratio 5 : 4
(C)
is the position vector of a point which divides PR externally in the ratio 5 : 4
(D) The square of the magnitude of the vector is 99
SECTION-II (i)
Consider on obtuse angled triangle ABC in which the difference between the largest and the
smallest angle is and whose sides are in arithmetic progression. Suppose that the vertices of this
triangle lie on a circle of radius 1.
column. Assume that each point Ai has an equal chance of being chosen.
3) Let pi be the probability that a randomly chosen point has i many friends, i = 0,1,2,3,4. Let X be a
random variable such that for i = 0,1,2,3,4, the probability P(X = i)= pi. Then the value of 7E(X) is
4) Two distinct points are chosen randomly out of the points A1,A2,…,A49. Let p be the probability that
they are not friends but have a friend in common . Then the value of 21p is
SECTION-II (ii)
f(x) =
f(1) = 2
Then the maximum value of the function f(x) is-
2) Let X be the set of all five digit numbers formed using 01122333. For example, 33320 is in X while
02233 and 22233 are not in X . Suppose that each element of X has an equal chance of being chosen.
Let p be the conditional probability that an element chosen at random is a multiple of 20 given that
it is a multiple of 3. Then the value of 61p is equal to
3) Let A1, A2, A3, ........, A16 be the vertices of a regular hexadecagon that lie on a circle of radius 2.
Let P be a point on the circle and let PAi denote the distance between the points P and Ai for i =
1,2,....,16. If P varies over the circle, then the maximum value of the product PA1 PA3.PA5 ⋅ ⋅ ⋅ ⋅ ⋅ PA15,
is
5) Let C1 be the circle of radius 1 with center at the origin. Let C2 be the circle of radius r with
center at the point A = (4,1) , where 1 < r < 3. Two distinct common tangents PQ and ST of C1 and
C2 are drawn. The tangent PQ touches C1 at P and C2 at Q. The tangent ST touches C1 at S and C2 at
T. Mid points of the line segments PQ and ST are joined to form a line which meets the x-axis at a
point B. If AB = , then the value of r2 is
6) For any y ∈ let cot–1( y) ∈ (π,2π) and tan–1 (y) ∈ . Then the number of solutions of the
PART-1 : PHYSICS
SECTION-I (i)
Q. 1 2 3 4
A. D A A C
SECTION-I (ii)
Q. 5 6 7
A. B,D B,C,D B,C,D
SECTION-II (i)
Q. 8 9 10 11
A. 540.00 6.70 60.80 to 60.81 30.00
SECTION-II (ii)
Q. 12 13 14 15 16 17
A. 45 10 2 15 4 2
PART-2 : CHEMISTRY
SECTION-I (i)
Q. 18 19 20 21
A. A C C D
SECTION-I (ii)
Q. 22 23 24
A. B,D A,C A,B,C,D
SECTION-II (i)
Q. 25 26 27 28
A. 100.00 0.02 or 0.03 6.00 9.00
SECTION-II (ii)
Q. 29 30 31 32 33 34
A. 13 6 11 159 1 1791
PART-3 : MATHEMATICS
SECTION-I (i)
Q. 35 36 37 38
A. D A B C
SECTION-I (ii)
Q. 39 40 41
A. A,B,C B,C A,B,D
SECTION-II (i)
Q. 42 43 44 45
A. 63.00 0.24 to 0.26 23.99 to 24.01 2.53 to 2.54
SECTION-II (ii)
Q. 46 47 48 49 50 51
A. 2 3 512 1110 2 2
SOLUTIONS
PART-1 : PHYSICS
1) =
2)
ML–3 = (LT–1)α(ML2T–1)β(M–1L3T–2)γ
0 = –α – β – 2γ
1=β–γ
–3 = α + 2β + 3γ
γ=–2
β = –1
α=5
3)
= mα[x2 – y2]
4)
∴ A and B are wrong.
5)
n1d + ℓ = n2 d
=
6)
J0 = mv .......(1)
J0hm = Icω ........(2)
v = ωR ........(3)
⇒ hm =
(A) If a = 0 IC = &R=b ∴ hm =
(C) v = ⇒ω=
(D) Force is acting on COM ∴ No rotation.
7)
C= = 1.5 × 108
8)
=
9)
fP from S2 = 536
fP from S1 =
Δf = 6.7 Hz.
10)
Between A & B
= .......(1)
........(2)
Between B & C
.....(3)
from (1) & (2) :
⇒P + =P+
⇒
= 2 × 1.2 × 10 × 10 – 2 × 10 × 9
= 240 – 180 = 60 ∴ V =
Ans. 60.80 to 60.81
11)
P = constant
⇒ ρaTa = ρT
1.2 × 300 = ρ × 360
ρ = 1 kg/m3
ΔP = ρag (h + H) – ρgh
= 1.2 × 10 × 10 –1 × 10 × 9
= 120 – 90 = 30 N/m2
12)
J = mv ......(1)
Jr = Icω ........(2)
JC = ........(3)
........(4)
θ = 2πN = ωt.......(5) ∴ N = 45
13)
R = 0.1Ω
ε = (B1 – B2)bvy
i=
∴ vy = 6 = ⇒ v = 10 m/s
14)
.......(1)
.......(2)
∴P=3
⇒ 1000 = ∴x=2
15)
⇒
= 5 cm +
16) A1 =
A2 =
17) ΔU = 0
PART-2 : CHEMISTRY
20)
21) Sucrose Glucose + Fructose
Specific rotation + 52.5° –92° (mixture of products is laevorotatory)
Sucrose No reaction
ABC ⇒ reducing sugars, will get oxidized by Fehling solution.
23)
Element X Y Z
C.N. 12 8 6
Density , ,
Now, 3Mx = or Mx × 2 = My
24)
25) As the phase transition temperature is 600 K
ΔH600K = 400 J
So ΔH600 – ΔH300 = ΔCP (T2 – T1)
ΔH600 – ΔH300 = 1 × 300
ΔH300 = ΔH600 – 300 = 400 – 300 = 100 Joule/mole.
26)
29)
r = 52.9 × pm
Given Z = 2 for He+
r2 = 105.8 pm
So 105.8 = 52.9 ×
n2 = 2
r1 = 26.45
So 26.45 = 52.9 ×
n1 = 1
So transition is from 1 to 2.
PART-3 : MATHEMATICS
35)
y = x2lnx + cx2
∴
36)
Req. prob = P(HH or HTHH or HTHTHH or …….)
+ P(THH or THTHH or THTHTHH or ….)
37)
(B)
Option (C) :
MX = 0 ⇒
x+y+z=0
x+z=0
y=0
∴ Infinite solution
[C] is correct
38)
For x < 0,
For x ≥ 0,
⇒ xtan–1x ≥ 0 ∀ x ∈ R
And
39)
in (–1, 1)
Graph ‘f’ is Concave upward.
Number of solutions of f(x) = x → xf
41)
so [B] is correct.
option –D
= (9 + 36 + 9) (4 + 1 + 1) – (6 + 6 + 3)2
= 54 × 6 – (15)2
= 324 – 225
= 99
n – d = 2 sinα …(1)
n + d = 2 sin
⇒ n + d = 2 cosα ….(2)
…(3)
⇒ 2 cos2α = sinα + cosα
⇒ 2(cosα – sinα) = 1
43)
44)
P2 = (exactly 2 friends)
(exactly 3 friends)
(exactly 4 friends)
Mean = E(x) =
46)
y = xsinx(c – x2)
f(x) = x(c – x2)
f(1) = 2 ⇒ c = 3
f(x) = 3x – x3
47)
48)
49)
Case I : ad = bc = 0
50)
A(4,1)
AB =
r2 = 2
(∵ y ∈ (–3,0))
Case-I : y ∈ (0,3)
or (rejected)