09-11-2025

0999DJA161153250003 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Two blocks of masses 1 kg and 2 kg are connected by a metal wire going over a smooth pulley.

The breaking stress of metal is . What should be the minimum radius of wire used,
if it should not be broken? (g = 10ms–2 )

(A) 0.5 mm
(B) 1 mm
(C) 1.5 mm
(D) 2 mm

2) Two rods of length ℓ1 and ℓ2 are made of materials whose coefficient of linear expansion are α1
and α2. If difference between two lengths is independent of temperature, then :–

(A)

(B)

(C)

(D)

3) The temperature of equal masses of three different liquids x,y and z are 10ºC, 20ºC and 30ºC
respectively. The temperature of mixture when x is mixed with y is 16ºC and that when y is mixed
with z is 26ºC. The temperature of mixture when x and z are mixed will be :-

(A) 28.32º C
(B) 25.62º C
(C) 23.84ºC
(D) 20.28ºC

4) Two rods of identical dimensions (Area = A, length ℓ each) are kept as shown in figure. One end
of both the rods is kept at 100° C & another end at 0°C. The rods have different thermal conductivity

given by K1 = and K2 = where x is the distance from the end having 100°C
temperature & K0 is a +ve constant. Find the rate of heat flow through this combination in
steady state :-

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) Two bodies A and B have thermal emissivities of 0.01 and 0.81 respectively. The outer surface
areas of the two bodies are the same. The two bodies radiate energy at the same rate. The
wavelength λB, corresponding to the maximum spectral radiancy in the radiation from B, is shifted
from the wavelength corresponding to the maximum spectral radiancy in the radiation from A by
1.00 μm. If the temperature of A is 5802 K,

(A) the temperature of B is 1934 K

(B) λB =1.5 μm
(C) the temperature of B is 11604 K
(D) the temperature of B is 2901 K

2) The temperature of an isotropic cubical solid of length ℓ0, density ρ0 and coefficient of linear
expansion α is increased by 20°C. Then at higher temperature, to a good approximation :–

(A) Length is ℓ0 (1 + 20α)

2
(B) Total surface area is ℓ0 (1 + 40α)
3
(C) Total volume is ℓ0 (1 + 60α)

(D)
Density is

3)

The wires A and B shown in the figure are made of the same material, and have radii rA and rB
respectively. The block between them has a mass m. When the force F is mg/3, one of the wires
breaks :–
(A) A will break before B if rA = rB
(B) A will break before B if rA < 2rB
(C) Either A or B may break if rA = 2rB
(D) The lengths of A and B must be known to predict which wire will break

4) The figure-2, figure-3, figure-4 and figure-5 represents the graphs of the source voltage V, resistor
voltage VR, inductor voltage VL and capacitor voltage VC as a function of time t of the series circuit

with impedance 500Ω as shown in the figure-1 . Choose correct option(s).

(A) R = 400 Ω, C = 0.5 μF and L = 50 mH

(B) R = 300 Ω, C = 0.5 μF and L = 60 mH
(C) V10 = 30V
(D) I = 0.1A cos (10000 t) Amp and current lag the source voltage

SECTION-I (iii)

Common Content for Question No. 1 to 2

The circuit consists of a capacitor connected in parallel to a resistor R with a coil of inductance L in
series with them. The power source could be an AC or a constant voltage DC source. When AC

source is applied then XL = XC = R.

1) If an AC source is applied across the input terminal, then :-

(A)
The peak value of current through AC source will be .

(B)
The peak value of current through AC source will be .

(C)
The peak current across capacitor will be

(D)
The peak current across capacitor will be

2) If a constant DC source of voltage ξ0 is applied across the input terminal with a switch, then :-

(A) Just after the switch is closed the initial current through the voltage source will be zero.

(B)
Just after the switch is closed the initial current through the voltage source will be .
(C) The current through the voltage source long time after the switch is closed will be zero.

(D)
The current through the voltage source long time after the switch is closed will be .

Common Content for Question No. 3 to 4

The figure shows a radiant energy spectrum graph for a black body at a temperature T.

3) Choose the correct statement(s).

(A) The radiant energy is not equally distributed among all the possible wavelengths.
(B) For a particular wavelength the spectral intensity is maximum.
The area under the curve is equal to the total rate at which heat is radiated by the body at that
(C)
temperature.
(D) None of these.

4) If the temperature of the body is raised to a higher temperature T', then choose the correct
statement(s),
(A) The intensity of radiation for every wavelength increases.
(B) The maximum intensity occurs at a shorter wavelength.
(C) The area under the graph increases.
(D) The area under the graph is proportional to the fourth power of temperature.

SECTION-I (iv)

1) An alternating current circuit is shown in figure. In each branch the values of resistances and
corresponding reactance are shown. Match the elements of List-I with List-II and select the correct

option.

List-I List-II

(P) i1 (1) 10 SI Unit

(Q) i2 (2) 20 SI Unit

(R) i3 (3) 3200 SI Unit

(S) Total power of circuit (4) 1000 SI Unit

(A) P → 2;Q → 1;R → 1;S → 3
(B) P → 2;Q → 1;R → 3;S → 1
(C) P → 1;Q → 2;R → 3;S → 1
(D) P → 2;Q → 3;R → 1;S → 1

2) A sample ‘A’ of liquid water and a sample B of ice of equal mass are kept in 2 nearby containers
so that they can exchange heat with each other but are thermally insulated from the surroundings.
The graphs in List-II show the sketch of temperature T of samples versus time t. Match with
appropriate description in List-I.

List-I List-II

Equilibrium temperature is
(P) (1)
above melting point of ice.
 At least some of water
(Q) (2)
freezes.

(R) At least some of ice melts. (3)

Equilibrium temperature is
(S) below freezing point of (4)
water.

(A) P → 2;Q → 1,3;R → 3,4;S → 3

(B) P → 1;Q → 2;R → 3;S → 4
(C) P → 3;Q → 2;R → 4;S → 1
(D) P → 4;Q → 3;R → 2;S → 1

SECTION-III

1) A block is hung by means of two identical wires having cross section area A (1 mm2) as shown in
the diagram. If temperature is lowered by ΔT (10°C), find the mass (in kg) to be added to hanging
mass such that junction remains at initial position. Given that co-efficient of linear expansion α = 2 ×

10–5 /°C and Young's modulus Y = 5 × 1011 N/m2 for the wire. If your answer is N fill value of .

2) A liquid A is kept flowing through a tube while it is cooled by water surrounding the tube. The
temperature of the incoming liquid A is 60°C and that of the outgoing liquid A is 30°C. The capacity
of the cooler tank is 60 liter and the water in it is completely changed in every hour. The initial
temperature of the cooling water is 10°C and it is 20°C when it is changed. What is the amount of

the liquid (in kg) that goes through the tube in one hour? If your answer is N, fill value of . (Take
: Specific heat capacity of water Swater = 4200 J/kg-K, Sliquid A = 140 J/kg-K, density of water = 1000
kg/m3)
3) Three alternating voltage sources V1 = 3sinωt volt, V2 = 5sin(ωt +ϕ1) volt and V3 = 5 sin(ωt – ϕ2)

volt connected across a resistance as shown in the figure (where ϕ1 and ϕ2 corresponds to
30° and 127° respectively). Find the peak current (in Amp) through the resistor.

4) A solid has a volume v0 when external pressure is p0. Bulk modulus of the material is B. Now the
pressure is increased to p. The additional energy per unit volume now stored in the material is

. Find z.

SECTION-IV

1) Entries in column-I consists of diagrams of thermal conductors. The type of conductor and
direction of heat flows are listed below. Entries in column-II consists of the magnitude of rate of heat
flow belonging to any of the entries in column-I. If temperature difference in all the cases is (T1 – T2),
then match column.

Column-I Column-II

(A) (P) 6πk0 R(T1 – T2)

Thick cylindrical shell, flow along axis

(B) (Q)

Thick spherical shell, radial flow

 (C) (R) πk0 R(T1 – T2)

Thick cylindrical shell, radial flow

(D) (S)

solid cylinder, flow along axis, variable k as k = k0(1 + x/(3R))

(T) 4πk0 R(T1 – T2)

2)

In the circuit shown in figure, switch remains closed for long time. It is opened at time t = 0. Match
the following two columns at t = (ln 2) second.

Column-I Column-II

(A) Potential differences across inductor (P) 9V

(B) Potential difference across 3Ω resistance (Q) 4.5 V

(C) Potential difference across 6Ω resistance (R) 6V

(D) Potential difference between points b and c (S) 3V

(T) None of these

PART-2 : CHEMISTRY

SECTION-I (i)

1) The potential energy of the electron present in the ground state of Li2+ ion is represented by :
(r = Radius of ground state)
(A)

(B)

(C)

(D)

2) Which of the following electron shown highest energy :-

(A)

(B)

(C)

(D)

3) Which of the following statements is not correct?

(A) A colloidal solution is a heterogeneous two-phase system.

(B) Silver sol in water is an example of lyophilic solution.
(C) Metal hydroxides in water are examples of lyophobic solution.
(D) Liquid-liquid colloidal solution is not a stable svstem.

4) The acidic solution of a salt produces blue colour with KI starch solution. The reaction indicates
the presence of :

(A) Sulphite
(B) Bromide
(C) Nitrite
(D) Chloride

SECTION-I (ii)

1) ; This is the equation representing an orbital. Which of

the following is/are correct ?

(A) This equation is of 3s orbital

(B) Radial probability curve touches r-axis at three finite points
(C) Above equation can be used to deduce n & quantum numbers.
(D) Probability density curve shows four maximas
2) Regarding the radial probability distribution vs r plot which of the following is/are
correct?

(A) The number of maxima is (n–ℓ)

(B) The number of nodal points is (n– ℓ –1)
(C) The radius at which the radial probability density reaches to maxima is 3s > 3p > 3d
(D) The number of angular nodes is ℓ.

3) The carbonate of which of the following cation is soluble in water ?

(A) Na+
(B) K+
+
(C) NH4
+
(D) Ca2

4) Na2SO4 and Na2S can be distinguished from each other by using :

(A) dilute H2SO4

(B) acidified KMnO4 solution
(C) sodium nitroprusside solution
(D) cadmium acetate solution

SECTION-I (iii)

Common Content for Question No. 1 to 2

A sample of H–atoms contains all atoms in ground state. If the atoms are irradiated by photon of x
eV, the atoms get excited to a particular enegy level. When these atoms de–excites, they emit the
radiations of six different photon energies.

1) What is the value of x ?

(A) 12.75
(B) 13.6
(C) 10.2
(D) 3.4

2) What is the orbit number for the excited state ?

(A) 6
(B) 3
(C) 4
(D) 2

Common Content for Question No. 3 to 4

An aqueous solution of a mixture of two inorganic salts, when treated with dilute HCl, gave a
precipitate (P) and a filtrate (Q). The precipitate P was found to dissolve in hot water. The filtrate (Q)
remained unchanged, when treated with H2S in a dilute mineral acid medium. However, it gave a
precipitate (R) with H2S in an ammoniacal medium. The precipitate R gave a coloured solution (S),
when treated with H2O2 in an aqueous NaOH medium.

3) The coloured solution S contains

(A) Fe2(SO4)3
(B) CuSO4
(C) ZnSO4
(D) Na2CrO4

4) The precipitate P contains

(A) Pb2+
(B)
(C) Ag+
(D) Hg2+

SECTION-I (iv)

1) Match the list -

List-I List-II

(P) Angular probability is independent of θ & ϕ (1) 5d

(Q) (2) 5p

(R) Two maxima in 4πr2R2 vs r graph. (3) 4s

(S) (4) 3p

(A) P → 3;Q → 4;R → 1;S → 2

(B) P → 3;Q → 4;R → 2;S → 1
(C) P → 3;Q → 1;R → 4;S → 2
(D) P → 2;Q → 3;R → 4;S → 1

2) Borax Bead test is carried out when the original mixture is coloured. It is done with the help of a
clean platinum wire on which a small loop is made at the end. When borax is heated on platinum
wire loop a transparent glass like bead is obtained. The hot bead is brought in contact with salt till it
reacts with fused borax and colour is imparted to the bead. Bead colour is noted.

List-I List-II

(P) Blue Green (1) Mn2+

(Q) Yellow (2) Cr3+

(R) Green (3) Fe3+

(S) Violet (4) Cu2+

(A) P → 1;Q → 3;R → 2;S → 4
(B) P → 4;Q → 3;R → 2;S → 1
(C) P → 4;Q → 1;R → 3;S → 2
(D) P → 1;Q → 4;R → 3;S → 3

SECTION-III

1) Photon having energy equivalent to the binding energy of 4th state of He+ atom is used to eject an
electron from the metal surface of work function 1.4 eV. If electrons are further accelerated through
the potential difference of 4V then the minimum value of De–broglie wavelength associated with the
electron is (in Å)

2)

A 50 watt bulb emits monochromatic red light of wavelength of 795 nm. The number of photons
emitted per second by the bulb is x × 1020. The value of x is _________.
[Given : h = 6.63 × 10–34 Js and c = 3.0 × 108 ms–1]

3) Concentrated sulphuric acid is added followed by heating of each of the following test tubes
labelled (i) to (v).

(i) (ii) (iii) (iv) (v)

How many statement(s) is/are correct about these observations ?
(a) Evolution of reddish brown gas takes place in (ii).
(b) Evolution of reddish brown gas takes place in (iii) tube and blue solution forms.
(c) Evolution of neutral colourless gas takes place in (iv) tube.
(d) Evolution of yellowish green gas takes place in (v) tube and colourless solution forms.
(e) Formation of black mass in (i) tube.

4) 1 gm of charcoal having surface area 3.01 × 102 m2 is mixed in 100 ml of 0.5 M acetic acid
solution; after few time concentrations of solution becomes 0.4 M. The surface area occupied by one
molecule of acetic acid is y × 10–20 m2. Then y is
 SECTION-IV

1)

Column-I Column-II

Electron moving in 2nd Radius of orbit in which moving

(A) (P)
orbit in He+ ion electron is is 0.529 Å

Electron moving in 3rd Total energy of electron

(B) (Q)
orbit in H-atom is (–)13.6 × 9eV

Velocity of electron is
Electron moving in 1st
(C) (R)
orbit in Li+2 ion
m/sec

De-broglie wavelength of
Electron moving in 2nd
(D) (S)
orbit is Be+3 ion
electron is Å

Potential energy of electron is (–)

(T)
27.2 × 9 eV.

2) Match the column -

Column-I Column-II
(Element) (Correct characteristics)
2–
(A) Ba (P) cation in solution produces brick red ppt. with CrO4
2–
(B) Pb (Q) cation in solution produces yellow ppt. with CrO4

(C) Ag (R) corresponding salt produces apple green colour in the flame test

(D) Ca (S) corresponding salt produces brick red colour in the flame test
2–
(T) cation in solution produces no ppt. with CrO4 ion

PART-3 : MATHEMATICS

SECTION-I (i)

1) The total number of positive integral solutions of 15 < x1 + x2 + x3 ≤ 20 is equal to:

(A) 685
(B) 785
(C) 1125
(D) None of these

2) Total number of 5 digit numbers having all different digits and divisible by 4 that can be formed
using the digits 1,2,3,6,8,9 is equal to -
(A) 192
(B) 32
(C) 1152
(D) 384

3) If total number of ways in which 9 distinct books can be distributed among 3 students such that

each receives atleast one book and no two of them get the same number of books is k then is
equal to

(A) 3
(B) 6
(C) 12
(D) 18

4) If and let
then is

(A) 1
(B) 2
(C) 3
(D) 4

SECTION-I (ii)

1) Which of the following is/are true

(A)
(B)
(C)

(D)

2) Let Tr denote the rth term in the expansion of [2x + (1/4x)]n (x ∈ R, n ∈ N). If the ratio T3 : T2 = 7 : 1
and sum of the binomial coefficients of second and third terms is 36, then

(A) n = 7
(B) n = 8

(C)

(D)

3) If W is the total number of words formed by using all the letters of the word 'TANGENT' such that
Both 'T' are always together and both 'N' are separated, then -
(A) Exponent of 2 in W is 4.
(B) Number of divisors of W are 20
(C) Number of even divisors of W are 4.
(D) Number of cyphers at the end of W are 1

4) If are non zero, non coplaner vectors such that ;

then which of the following can be true

(A)

(B)

(C)
Volume of tetrahedron with coterminous edges is

(D)
Volume of tetrahedron with coterminous edges is

SECTION-I (iii)

Common Content for Question No. 1 to 2

All the letters of the word MULTIPLE are arranged in all possible ways. Answer the following
questions.

1) The number of arrangements in which the order of the vowels does not change is :

(A) 3330
(B) 3320
(C) 3340
(D) 3360

2) The number of arrangements in which the each vowel's position is not disturbed is :

(A) 60
(B) 260
(C) 160
(D) 330

Common Content for Question No. 3 to 4

Let are non zero vectors such that . Also &
and .

3) is not equal to -

(A) 3
(B) 5
(C) 6
(D)

4) is equal to -

(A) 1
(B) 9
(C) 4
(D) 25

SECTION-I (iv)

1)

List-I List-II

The coefficient of x–9 in the expansion of

(P) (1) 1512
is

The term independent of x in the expansion

(Q) (2) 476
of is

The coefficient of x10 in the expansion of (1 +

(R) (3) 512
x2 – x3)8 is

The coefficient of x4 in the expansion of (3x +

(S) (4) 4320
1)7 (1 – 2x + 3x2) is
(A) P → 3;Q → 4;R → 2;S → 1
(B) P → 2;Q → 3;R → 4;S → 1
(C) P → 1;Q → 3;R → 2;S → 4
(D) P → 3;Q → 4;R → 1;S → 2

2) Let v1 = 2 + + , v2 = 4 + 2 – 2 , v3 = p + q + r then match the following List :

List-I List-II

(P) For p = 4, q = 2, r = 2, vectors and are (1) Non coplanar

(Q) For p = 1, q = 2, r = 2, vector and are (2) Collinear

(R) (3) Linearly independent

For p = 1, q = , r = vectors , and are

(S) For p = 2, q = –1, r = 1 vectors , and are (4) Linearly dependent

(A) P → 1;Q → 2;R → 1;S → 3

(B) P → 1;Q → 4;R → 4;S → 1,3
(C) P → 2,4;Q → 3;R → 4;S → 1,3
(D) P → 2,4;Q → 3;R → 2;S → 2,4

SECTION-III

1) The value of is :

2) If the number of terms in the expansion of is 17, where n ∈ I+, find n.

3) 6 lecturers A,B,C,D,E,F want to deliver lecture in a particular batch (one by one), such that A
wants to take class before B and B wants to take class before C (not necessarily consecutive), if total

number of ways are , then n is equal to (where n ∈ N)

4) If the letters of the word "MASTER" are written in all possible ways and then arranged as in a
dictionary, then the rank of the word "MASTER" is 2n + 1, the value of n is

SECTION-IV

1)

Column–I Column–II

The number of lines formed from 10 points of which no three points are collinear
(A) (P) 30
except 4 points which are collinear is

The maximum number of points of intersection of 10 distinct straight lines in a

(B) (Q) 40
plane is

(C) The maximum number of points of intersection of 6 distinct circles in a plane is (R) 53

The maximum number of points of intersection of 3 distinct lines and 5 distinct

(D) (S) 45
circles in a plane is

(T) 60

2) Consider vectors , and .

Column-I Column-II

A vector perpendicular to the vector and

(A) (P)
coplanar with and , is

A vector perpendicular to and the vector

(B) (Q)
in (A), is

(C) A vector perpendicular to & , is (R)

(D) A vector perpendicular to and + , is (S)

(T)
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B B C A

SECTION-I (ii)

Q. 5 6 7 8
A. A,B A,C,D A,B,C B,C,D

SECTION-I (iii)

Q. 9 10 11 12
A. A,C A,D A,B A,B,C,D

SECTION-I (iv)

Q. 13 14
A. A A

SECTION-III

Q. 15 16 17 18
A. 4 4 3 6

SECTION-IV

Q. 19 20
A. A->R,B->P,C->S,D->Q A->T,B->Q,C->P,D->P

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 21 22 23 24
A. D B B C

SECTION-I (ii)

Q. 25 26 27 28
A. A,B,C A,C,D A,B,C A,B,C,D

SECTION-I (iii)

Q. 29 30 31 32
A. A C D A
 SECTION-I (iv)

Q. 33 34
A. C B

SECTION-III

Q. 35 36 37 38
A. 5 2 4 5

SECTION-IV

Q. 39 40
A. A->S,B->R,C->QT,D->P A->QR,B->Q,C->P,D->ST

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 41 42 43 44
A. A A B C

SECTION-I (ii)

Q. 45 46 47 48
A. A,B,D B,D A,B,D A,B,D

SECTION-I (iii)

Q. 49 50 51 52
A. D A A,C,D C

SECTION-I (iv)

Q. 53 54
A. A C

SECTION-III

Q. 55 56 57 58
A. 1 8 3 8

SECTION-IV

Q. 59 60
A. A->Q,B->S,C->P,D->R A->R,B->S,C->P,D->Q
 SOLUTIONS

PART-1 : PHYSICS

1) Here T – g = a ----------(1)
2g – T = 2a ----------(2)

⇒ 2g – T = 2 (T – g)

For minimum radius r :- = Stress

⇒r=

⇒r= =

2) Δℓ1 = Δℓ2
ℓ1 α1ΔT = ℓ2 α2ΔT

3) X Y Z
m1 = m m2 = m m3 = m
T1 = 10°C T2 = 20°C T3 = 30°C
s1 s2 s3
when x & y are mixed,
m1s1T + m2s2T2 = (m1s1 + m2s2)Tf1
s1 × 10 + s2 ×20 = (s1 + s2) × 16

.....(ii)
when x & z are mixex
m1s1T1 + m3s3T3 = (m1s1 + m3s3)Tf

Tf = 23.84°C
Ans (3)
4)

k=

5)

eA = 0.01, eB = 0.81
Area = same for both

= same for both

σeAATA4 = σeBATB4

⇒
also
λBTB = λATA
λB × 1934 = (λA – 1)5802
λB = 3λB – 3
2λB = 3
⇒ λB = 1.5 µm

6)

Length
= ℓ0 (1 + 20α)
Area
A = A0 (1 + βΔΤ) = 6ℓ02 (1 + 40α)
Volume
V = V0 (1 + γΔΤ) = ℓ03 (1 + 3αΔΤ) = ℓ03 (1 + 60α)
Density

p=

7)

Wire having more stress will break first as compared to other.

if rA = 2rB, then
Stress in wire A = stress in wire B
8)
VC = 20 sin ωt ⇒ XCI0 = 20
VR = 30 cos ωt ⇒ RI0 = 30
VL = –60 sin ωt ⇒ XLI0 = 60

⇒ XC = 200 Ω

, XL = 600 Ω

9)

(A)

Since xL = xC = R

(C)

10)

(A) Inductor will not allow any correct to flow initially

(D) At t → ∞. Inductor as short circuit & no current flows through charge

11)

Conceptual

12)

Conceptual

13) Conceptual

14)

In the graph between T v/s t, lines with zero slope represents phase change.

15)

Change in tension = ΔT
∴ 2 ΔT sin 37° = Δmg

ΔT =

Δl =
But Δl = LαΔθ

∴ = LαΔθ
⇒ Δm = α Δθ × A × Y × 2 sin 37°

∵ g= = 12

16)

By conservation of heat energy

mA SA ΔTA = mwSwΔTw

mA =
17)

v1 = 3 sinωt; v2 = 5 sin(ωt +ϕ1); v3 = 5sin (ωt –ϕ2)

18) For any small change of pressure dp, there will be a change of volume dV and .
In this change, work is done on the system and the energy stored in the material is

In the change mentioned in the question, the total work done is

The change in volume is negligible and volume can be treated as constant.

Extra energy stored per unit volume is

19)
Thick cylindrical shell along the axis:
A = π(2R)2 – R2 = 3πR2
Length: L = 3R

∴
Thick spherical shell, radial flow:

∴
Thick cylindrical shell radial flow:
 ∴

∴
Solid along the axis:
A = π(2R)2 – R2 = 3πR2
Length: L = 3R

20)

Conceptual

PART-2 : CHEMISTRY

21)

22) e– (n + ℓ)
3,2,1,+½ 5
4,2,–1,+½ 6
4,1,0,–½ 5
5,0,0,+½ 5

23)

(B) Silver sol in water is an example of lyophobic solution.

24) 2NO2– + 3I– + 4CH3COOH

→ I3– + 2NO + 4CH3COO– + 2H2O
Starch + I3– → Blue (starch iodine adsorption complex)

25)
According to equation, l = 0, it has 2 roots, so this equation is for 3s orbital. radial part of
equation gives n and quantum numbers.

26)

Probability distribution Function =

The number of maxima = n – ℓ
The number of radial nodes = n – ℓ – 1
The number of Angular Node = ℓ
Total number of nodes = (n –1)

27) Carbonates of alkali metals and ammonium are soluble in water. All other carbonates are
insoluble in water.

28) (A) Na2S + H+ H2S + 2Na+. ; Na2SO4 gives no reaction with H2SO4.
(B) 2MnO4– (pink solution) + 5H2S + 6H+ 2Mn2+ (colourless) + 5S ↓ + 8H2O.
No colour change is observed with Na2SO4.
(C) S2– + [Fe(CN)5NO]2– [Fe(CN)5NOS]4– (purple or violet colouration).
No colour change is observed with Na2SO4.
(D) S2– + Cd2+ CdS ↓ (yellow).
Na2SO4 forms CdSO4 which is water soluble.

29) ΔE = E4 – E1 = –0.85 – (–13.6)eV

= 12.75 eV

30) It is n = 4 to n = 1, de–excitation.

31) Acc. to the options given the cation present in filtrate Q may be Fe+2 or Cu+2 or Zn+2 or Cr+3
because Q remains unchanged with H2S in dil. mineral acid medium but gives ppt with alk.
H2S, the cation can not be Cu+2
Hence

Among these three ppt. only Cr(OH)3 gives coloured solution with H2O2 in alk. Medium
i.e.

Note :
(i) Zn+2 can not produce any coloured solution due to d10 configuration
(ii) FeS may be oxidised by H2O2 in basic medium into Fe3+ and and Fe3+ must give
raddish brown ppt of Fe(OH)3, not coloured solution.

32)
ppt. (P) is PbCl2 because it is insoluble in cold water but soluble in hot water.

33) (P) For s-orbital angular probability is independent of θ and ϕ.

(Q) Radial nodes = 2
Radial nodes = n – ℓ – 1
For 5d ⇒ 5 – 2 – 1 = 2
For 5p ⇒ 5 – 1 – 1 = 3
For 4s ⇒ 4 – 0 – 1 = 3
For 3p ⇒ 3 – 1 – 1 = 1
(R) Number of maxima in 4πr2R2 v/s r graph = n – ℓ

34) Colour of the bead Ion

2+
1. Blue green Cu
2. Yellow Fe3+
3. Green Cr3+
4. Violet Mn2+

35)

Total energy = = = 3.4 eV

Now K.E. = 3.4 – 1.4 = 2 eV
Now, Total energy = 2 + 4 = 6 eV i.e. potential = 6 V

For electron, λ = so λ = 5 Å.

36)

P = 50 W
λ = 795 nm
n = x1020

37) (i) C12H22O11 12C (black) + 11H2O

(ii) 2NaBr + 2H2SO4 Na2SO4 + SO2 + Br2 ↑ (reddish brown) + 2H2O
(iii) 2Cu(NO3)2 + 2H2SO4 2CuSO4 (blue solution) + 4NO2 ↑ (reddish brown) + O2 + 2H2O
(iv) K4[Fe(CN)6] + 6H2SO4 + 6H2O 2K2SO4 + FeSO4 + 3(NH4)2SO4 + 6CO ↑(neutral and
colourless)
CO burns with blue flame.
(v) KCl + H2SO4 KHSO4 + HCl ↑ (colourless)

38)

Number of moles adsorbed = × 0.5 – × 0.4 = 0.01

Number of molecules adsorbed = 0.01 × 6 × 10 = 6 × 1021
23

Surface area occupied =

39) (A) (S)

(B) (R)
(C) (Q) T.E. = –13.6 × 9 eV
(T) P.E. = –27.2 × 9 eV.
(D) (P) R = 0.529
Alternating
(A) n = 2, z = 2

= 0.529 × 2

TE
so K.E. = 13.6 ev

&

so A → S
(B) z = 1, n = 3

so
hence B → R
(C) n = 1, z = 3

K.E. = 13.6 × 9 so
 so C → Q,T
(D) z = 4, n = 2

K.E. = 13.6 × 4 ev so
hence D → P

40) (A) Ba → BaCrO4 (yellow ppt)

Ba → flame test (apple green)
(B) Pb → PbCrO4 (yellow ppt)
(C) Ag → Ag2CrO4 (brick red ppt)
(D) Ca → CaCrO4 soluble
Ca → flame test (brick red)

PART-3 : MATHEMATICS

41)

15 < x1 + x2 + x3 ≤ 20
⇒ x1 + x2 + x3 = 16 + r, r = 0, 1, 2, 3, 4
Now, the number of positive integral solutions of x1 + x2 + x3 = 16 + r is 13+r+3–1C13+r, i.e.,
15+r
C13+r = 15+rC2.
Thus, the total number of solutions is

= 685

42) A number is divisible by four, if the last two digit are divisible by four. In this case last two
digits can be 12, 16, 28, 32, 36, 68, 92, 96
∴ Total number of such numbers
= 8(4C3.3!)
= 192

43) Grouping
9 → 6, 2, 1
9 → 5, 3, 1
9 → 4, 3, 2

so
=
(9 × 4 × 7 + 9 × 8 × 7 + 9 × 4 × 7 × 5 ) × 6
= 2016 × 6

44) Using cross product of three vectors

Let

...(1)
similarly :

...(2)

And :
...(3)
Adding (1) (2) and (3)

n n n n n n
45) C0 Cn–1 + C1 Cn–2 + ... + Cn–1 C0
= 2nCn–1 = 2nCn+1
(nC0)2 + (nC1)2 + ... + (nCn)2 = 2nCn

46)

This implies

⇒ ... (1)
Also nC1 + nC2 = 36
⇒ n2 + n – 72 = 0
(n + 9) (n – 8) = 0
n=8
Putting the value n = 8 in equation (1), we have

⇒
Therefore

47) Total number of words

= 240

48)

(A)

(B)

(C)

49) The order of vowels does not change means, first u occurs, then i and then e must occur.

The total number of arrangements is (since there are two l) In each of these arrangements,
vowels may occur in 3! ways. Therefore the number of arrangements in which u, i, e occurs in
this order is :

50) Keeping u, i, e in their respective places, the number of arrangements is

51)

also

52)
also

53) (P)
so 18 – 3r = –9 ∴ 3r = 27 ⇒r=9

so T10 = T9 + 1 = 9C9 = 512x–9

so cofficient of x–9 is 512

(Q)
6 – 2r = 0 ⇒ r = 3
T4 = T3 + 1 = 6C3 . 23 . 33 = 20 × 8 × 29 = 4320
(R) (1 + x2 – x3)8 = [(1 + x2) – x3]
= 8C0(1 + x2)8 + 8C1(1 + x2)7 (– x3) + 8C2(1 + x2)6(–x3)2 + 8C3(1 + x2)5 + (–x3)3 + ... so
coefficient of x10 = 8C5 + 8C2 × 6C2 = 56 + 28 × 15 = 56 + 420 = 476
(S) coefficient of x4 in (3x + 1)7 (1 – 2x + 3x2)
= 7C3 .34 – 7C4 . 33(2) + 7C5 32 . 3 = 35 × 81 – 35 × 54 + 21 × 27 = 1532

54) (P) For p = 4, q = 2, r = 2

= , ,

⇒ are collinear and linearly dependent.

(Q) For p = 1, q = 2, r = 2
,
for any real λ
so are linearly independent.

(R) For p = 1, q = , r =

So are linearly dependent.

(S) For p = 2, q = –1, r = 1
⇒
 so , , are linearly independent or non-coplanar.

55)

0
= [2nC – 2nC1 101 + 2nC2 102 – 2nC3 103 +.....+ 2nC2n 102n]

= (1 – 10)2n = = =1

56) We have

=
= a0 + a1x + a2x2 + a3x3 +......+ a2nx2n
Clearly number of terms = |2n + 1|
Thus, |2n + 1| = 17
⇒n=8
hence, the value of n is 8.

57) Order at A,B,C is one

6
C3.3! = ∴n=3

58) "MASTER"
Rank of master is 257 = 256 + 1 = 28 + 1
⇒ n=8

59) (A) 10C2 – 4C2 + 1 = 40

(B) Maximum number of points = 10C2 = 45
(C) Maximum number of points of intersection of 6 circles = 6C2 . 2 = 30
(D) Required points = 3C2 + 5C2.2 + 3C1.5C1.2
= 3 + 20 + 30 = 53

60) (A) Vector coplanner with a & b

is
which is ⊥ to if
(B) Let required vector is
then 2x – y + z = 0 ........(i)
x+y=0 ........(ii)
by (i) & (ii) x = 0, y = z
(C)
(D)