17-09-2025

7101CJA101004250005 JM

PHYSICS

SECTION-I

1) On a particle placed at origin a variable force F = –ax (where a is a positive constant) is applied. If
U(0) = 0, the graph between potential energy of particle U(x) and x is best represented by :-

(A)

(B)

(C)

(D)

2) A block of mass 1kg is initially at rest at origin. It is acted upon by a horizontal force F = 15 – 5x3
where x is the x-coordinate of block. Coefficient of friction between block & surface is 0.5. Distance

travelled by the block till it stops again is :-

(A) 1m
(B)
(C) 2m
(D)

3) A particle of mass 0.1 kg is subjected to a force which varies with distance as shown in figure. If it
starts its journey from rest at x = 0, its velocity at x = 12 m is :

(A) 0 m/s
(B) m/s
(C) m/s
(D) 40 m/s

4) A block of mass 6kg is initially at rest. A force starts acting on the block, power delivered by the
force is shown in figure. Speed of object when its displacement is 2m is :-

(A) 4 m/s
(B) 8 m/s
(C) 2 m/s
(D) 6 m/s

5) A collar ‘B’ of mass 2 kg is constrained to move along a horizontal smooth and fixed circular track
of radius 5 m. the spring lying in the undeformed when the collar is at ‘A’. If the collar starts from
rest at ‘B’ the normal reaction exerted by the track on the collar when its passes through ‘A’ is:

(spring constant k = 200 N/m)

(A) 360 N
(B) 720 N
(C) 1440 N
(D) 2880 N
6) The power output from the motor on a 2 kg body depends on the velocity of body as P = v(5 – v).
The work done on the body for first 2 second is :- (The particle starts from rest)

(A) 25(e–1)

(B)

25
(C)

(D)
25

7) A force = N acts on a body due to which its displacement varies as . Work

done by this force in t = 0 to 2 sec is :-

(A) 23 J
(B) 32 J
(C) zero
(D) can’t be obtained.

8) A particle in a certain conservative force field has a potential energy given by . The force
exerted on it is :

(A)

(B)

(C)

(D)

9) Potential energy function along x–axis in a certain force field is given as

. For the given force field :–

(i) the points of equilibrium are x = 1, x = 2 and x = 3.
(ii) the point x = 2 is a point of unstable equilibrium.
(iii) the points x = 1 and x = 3 are points of stable equilibrium.
(iv) there exists no point of neutral equilibrium.
The correct option is :-

(A) (i), (ii), (iv)

(B) (i), (ii), (iii), (iv)
(C) (iii), (iv)
(D) (ii), (iii)
10) A bead of mass m is sliding down the fixed inclined rod without friction. It is connected to a point
P on the horizontal surface with a light spring of spring constant k. The bead is initially released
form rest and the spring is initially unstressed and vertical. The bead just stops at the bottom of the
inclined rod. Find the angle which the inclined rod makes with horizontal.

(A)

(B)

(C)

(D)

11) A uniform cable of mass 'M' and length 'L' is placed on a horizontal surface such that its
part is hanging below the edge of the surface. To lift the hanging part of the cable upto the surface,
the work done should be :

(A)

(B)

(C)

(D) nMgL

12) Power supplied to a particle of mass 2 kg varies with time as watt. Here t is time in
second. If velocity of particle at t = 0 s is v = 0 m/s. The velocity of particle at time t = 2 s will be :-

(A) 1 m/s
(B) 4 m/s
(C) 2 m/s
(D)

13) Two small rings each of mass m are connected to a block of same mass m through inextensible
light strings. Initially system is at rest as shown in figure. The system is released from position
shown. The magnitude of relative velocity of the rings with respect to each other when the string
makes an angle of = 60° with vertical. (Take : g = 10m/s2) [Friction is absent]

(A)

(B)

(C)

(D)

14) A locomotive of mass m starts moving so that its velocity varies according to the
law where k is constant and s is the distance covered. Find the total work performed by all the force
which are acting on the locomotive during the first t second after the beginning of motion :-

(A)

(B)

(C)

(D)

15) Track OABCD (as shown is figure) is smooth and fixed in vertical plane. What minimum speed
has to be given to a particle lying at point A, so that it can reach point C?

(A) 60 m/s
(B) 100 m/s
(C) 70 m/s
(D) 80 m/s
16) A particle of mass 1 kg is given a horizontal velocity of 4 m/s along a horizontal surface, with
which it has a coefficient of friction (both static and kinetic) of 0.4. The particle strikes a fixed ideal
spring of force constant 6 N/m after traveling a distance of 0.25 m. Assume acceleration due to
gravity is 10 m/s2. Find the maximum displacement of the particle from its starting point.

(A)

(B)

(C)

(D) 1.25 m

17) The potential energy of a 1 kg particle free to move along the x-axis is given by

. The total mechanical energy of the particle is 2 J. Then the maximum speed (in
m/s) is :

(A) 2

(B)

(C)

(D)

18) A block is released from rest from a height h = 5m. After travelling through the smooth curved
surface it moves on the rough horizontal surface through a length ℓ = 8 m and climbs onto the other

smooth curved surface through a height h'. If µ = 0.5, find h'.

(A) 2 m
(B) 3 m
(C) 1 m
(D) zero

19) A wedge of mass M fitted with a spring of stiffness 'k' is kept on a smooth horizontal surface. A
rod of mass m is kept on the wedge as shown in the figure. System is in equilibrium. Assuming that
all surfaces are smooth, the potential energy stored in the spring is:

(A)

(B)

(C)

(D)

20) One end of a light spring of natural length 4 m and spring constant 170 N/m is fixed on a rigid

wall and the other is fixed to a smooth ring of mass kg which can slide without friction in a vertical
rod fixed at a distance 4 m from the wall. Initially the spring makes an angle of 37° with the
horizontal as shown in figure. When the system is released from rest, find the speed of the ring when

the spring becomes horizontal.

(A) 15 m/s
(B) 10 m/s
(C) 20 m/s
(D) 25 m/s

SECTION-II

1) The potential energy for a force field is given by U(x, y) = sin (x + y). The force acting on the

particle of mass m at is

2) 2kg block is kept on 1kg block as shown. The friction between 1kg block and fixed surface is
absent and the coefficient of friction between 2kg block and 1kg block is µ = 0.1. A constant
horizontal force F = 4N is applied on 1 kg block. If the work done by the friction on 1kg block in 2s

is –xJ, then find x. (Take: g = 10 m/s2)

3) Two blocks A and B, each having a mass of 480 gm connected by a light string passing over a
smooth light pulley. The block A is attached to a spring of spring constant 60 N/m whose other end
is fixed to a support 40 cm above the horizontal surface as shown. Initially, the spring is vertical and
unstretched when the system is released to move. If the velocity of the block A at the instant it just

breaks off the surface below is then value of n. (take g = 10 m/s)

4) The ends of a spring are attached to blocks of mass 3 kg and 2 kg as shown in the figure. The 3
kg block rests on a horizontal surface and the 2 kg block which is vertically above it is in
equilibrium producing a compression of 2 mm of the spring. It is found that the 2 kg mass must be
compressed further by at least x (in mm) so that when it is released, the 3 kg block may be lifted off
the ground. Find the value of x in mm.

5) A small block slides along a path which is smooth until the block reaches the section of length L =
3m, which begins at height h = 3m on a flat incline of angle 37°, as shown in the figure. In that
section, the coefficient of kinetic friction is 0.50. The block passes through point A with a speed of
m/s. Find the speed (in m/s) of the block as it passes through point B where the friction ends.
 CHEMISTRY

SECTION-I

1)

Pick out the incorrect statement :-

(A) sp3d hybridisation involves orbital

(B) Hybridised orbital form σ-bond when overlaps with other orbitals.
(C) SF2 molecule is more polar than CS2
(D) o-nitrophenol is more volatile than p-nitrophenol.

2) Which of the given reaction is not an example of disproportionation reaction?

(A) 2H2O2 → 2H2O + O2

(B) 2NO2 + H2O → HNO3 + HNO2
- + -
(C) MnO4 + 4H + 3e → MnO2 + 2H2O
2- + -
(D) 3MnO4 + 4H → 2MnO4 + MnO2 + 2H2O

3) Which among the following molecules is (a) involved in sp3d hybridization, (b) has different bond
lengths and (c) has lone pair of electrons on the central atom ?

(A) PF5
(B) XeF4
(C) SF4
(D) XeF2

4) Which one of the following has the regular tetrahedral structure?

(Atomic nos. : B = 5, S = 16, Ni = 28, Xe = 54)

(A)
(B) SF4
(C) XeF4
 2–
(D) [Ni(CN)4]

5) Among SO2, NF3, NH3, XeF2, ClF3 and SF4, the hybridization of the molecule with non-zero dipole
moment and highest number of lone-pairs of electrons on the central atom is

(A) sp3
(B) dsp2
(C) sp3d2
(D) sp3d

6) The bond angle of NH3, NH2– and NH4+ are in the order :

– +
(A) NH2 > NH3 > NH4
+ –
(B) NH4 > NH3 > NH2
– +
(C) NH3 > NH2 > NH4
+ –
(D) NH3 > NH4 > NH2

7) Which of the following are isoelectronic and isostructural ?

(A)
(B)
(C)
(D)

8) o-Nitrophenol is less soluble in water than p- and m- nitrophenols because :

(A) o-nitrophenol is more volatile steam than those of m- and -isomers.

(B) o-nitrophenol shows intramolecular H-bonding
(C) o-nitrophenol shows intermolecular H-bonding
(D) Melting point of o-nitrophenol is lower than those of m- and p-isomers.

9) The correct statement for the reaction-

NH3 + H+ →

(A) Hybridisation state is changed

(B) Bond angle increase
(C) NH3 act as a Lewis acid
(D) Regular geometry is changed

10) The dipole moment of CCl4, CHCl3, CH4 are in order of:

(A) CHCl3 < CH4 = CCl4

(B) CCl4 < CH4 < CHCl3
(C) CH4 < CCl4 < CHCl3
(D) CH4 = CCl4 < CHCl3

11) Ionic bond formation depends on

(A) Ionisation energy

(B) Electron affinity
(C) Lattice energy
(D) All of these

12) The correct order of the O–O bond length in O2, H2O2 and O3 is :-

(A) O2 > O3 > H2O2

(B) O3 > H2O2 > O2
(C) H2O2 > O3 > O2
(D) H2O2 > O2 > O3

13) Which molecule is non polar but contains all polar bonds ?

(A) H2
(B) BF2Cl
(C) CCl4
(D) HCN

14) Solubility of Cl2 in water is due to:

(A) Dipole-Dipole interaction

(B) Dipole-induced dipole interaction
(C) Ion-dipole interaction
(D) Ion-induced dipole interaction

15) In which of the following the oxidation number of oxygen has been arranged in increasing order
:-

(A) OF2 < KO2 < BaO2 < O3

(B) BaO2 < KO2 < O3 < OF2
(C) BaO2 < O3 < OF2 < KO2
(D) KO2 < OF2 < O3 < BaO2

16) An ion is reduced to the element when it absorbs electron. The number of equivalent of
the ion is

(A) 0.1
(B) 0.0
(C) 0.001
(D) 0.0001

17) In which of the following reaction, hydrogen peroxide acts as oxidizing agent?

– –
(A) I2+H2O2+2OH → 2I +2H2O+O2
+ –
(B) HOCl+H2O2→H3O +Cl +O2
(C) PbS+4H2O2→PbSO4+4H2O
– –
(D) 2MnO4 +3H2O2→2MnO2+3O2+2H2O+2OH

18) Which ordering of compounds is according to the decreasing order of the oxidation state of
nitrogen ?

(A) HNO3, NO, NH4Cl, N2

(B) HNO3, NO, N2, NH4Cl
(C) HNO3, NH4Cl, NO, N2
(D) NO, HNO3, NH4Cl, N2

19) The oxidation number of C in CH4, CH3Cl, CH2Cl2, CHCl3 and CCl4 are respectively:

(A) +4, +2, 0, –2, –4

(B) +2, +4, 0, –4, –2
(C) –4, –2, 0, +2, +4
(D) –2, –4, 0, +4, +2

20) Oxidation number of carbon in carbon suboxide (C3O2) is :

(A)

(B)

(C) +4

(D)

SECTION-II

1) An oxide of a metal contains 40% oxygen by weight. If equivalent weight of metal is M. Find value
of M/3 ?

2) How many of the following form H-bond(s) with water :

NH3, CH4, HF, CH3OH, CH3COOH

3) Consider the following molecule

Calculate value of , here p and q are total number of dπ - pπ bonds and total number of sp3
hybridized atoms respectively in given molecule.

4) The number of species have paramagnetic nature given following:

N2, O2, B2,

5) Find the number of molecules in which hybridisation is not present, according to Drago’s rule
NH3, H2S, H2Se, PH3

MATHS

SECTION-I

1) Let , then is

(A) 1

(B)

(C) 2

(D)

2) In the interval , the value of is -

(A) 1 – tanα
(B) tanα – 1
(C) cotα – 1
(D) 1 – cotα

3) Range of values of the expression [Link] is -

(A) (–2, 2)
(B) [0, 2)
(C) [–2, 2]
(D) (0, 2)
4) is equal to -

(A) 1
(B) 2
(C) 3
(D) 4

5) Value of sin 10° + sin 20° + ...... + sin 360° is

(A) 0
(B) 1
(C)
(D) 2

6) If , then the value of is:

(A) 4
(B)
(C) 2

(D)

7) If log (tan1°. tan2°.tan 3°,........................ tan 89°) = ?

(A) 1
(B) 0
(C) – 1
(D) 2

8) cso248° – sin212° is equal to

(A)

(B)

(C)

(D)

9) The greatest value of sinxcosx is

(A) 1
(B) 2
(C)
(D)

10) Which is smaller, sin 64° or cos 64°?

(A) sin 64°

(B) cos 64°
(C) both are equal
(D) cannot be compared

11) The value of is

(A)
(B)
(C)
(D)

12) is -

(A) 0
(B) –1
(C) 1
(D) 2

13) If A = 130º and x = sinA + cosA, then -

(A) x > 0
(B) x < 0
(C) x = 0
(D) none of these

14)

(A)
(B)

(C)

(D)

15) cosec (–1110°) = ?

(A)
(B)

(C) 2
(D) – 2

16) is equal to

(A) tan x
(B) cot x
(C) sec x
(D) cosec x

17)

(1 + tan(6.9º)) (1 + tan(29.3º)) (1 + tan38.1) (1 + tan15.7º) is equal to-

(A) an irrational number

(B) a prime number
(C) a rational number lying between 1 and 5
(D) a rational number less than 4

18) If sin α + sin β = a and cos α – cos β = b, then tan is equal to

(A)

(B)

(C)
(D)

19) Maximum and minimum value of 2sin2θ – 3sinθ + 2 is -

(A)

(B)

(C)

(D)

20) =

(A) cot A
(B) tan A
(C) sin A
(D) cos A

SECTION-II

1) Exact value of sin217° + sin243° + sin273° – cos247° is

2) The value of to n terms is equal to

3) Maximum value of the expression is equal to

4) If A + B + C = π then value of is equal to

5) If sin A. cos B = 1/4 and 3 tan A = tan B, then sin (A + B) is

 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C D C C C B B B A B C C A D D B C C C

SECTION-II

Q. 21 22 23 24 25
A. 1 8 2 5 4

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A C C A D B A B B D D C C B B C C B C B

SECTION-II

Q. 46 47 48 49 50
A. 4 4.00 1 5 3

MATHS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C B B D A A B B D B B C A B D B C B D B

SECTION-II

Q. 71 72 73 74 75
A. 1 0 2 4 1
 SOLUTIONS

PHYSICS

1) F = – ⇒U=

2) Applying work energy theorem,

WF + Wf = ΔKE

⇒ x3 = 8
x = 2m

3) Area fo F-x curve = change in kinetic energy of particle

4) Area of power displacement graph

= m(v3 – u3)

5) Initial extension will be equal to 6 m.

∴ Initial energy =

Reaching A :
⇒ mv2 = 7200 J
From F.B.D. at A :

N= = 1440 N

6) P = Fv = v (5–v) ⇒ F = 5–v

m =5–v
=2

⇒ ⇒

Now W = ΔKE

7) =

= = ω= = · dt = = 4 (23 – 02) = 32 J

8)

Put

9) For equilibrium points,

F=– ⇒ x3 – 6x2 + 11x – 6 = 0 ⇒ x = 1, x = 2 and x = 3

In stable equilibrium, ⇒ x = 1 and x = 3 are stable while x = 2 is unstable.

In neutral equilibrium, and

10) Loss in gravitational P.E = gain in spring P.E

or
11) Mass of the hanging part =

hCOM =

work done W = mghCOM =

Option (2)

12)

13) Ans. (3)

vcosθ = usinθ
v= (tan60° = )
From loss in PE = Gain in KE

mg ℓ cos θ =

∴u=

∴ Relative velocity =

14)
15)

To reach at C, particle must reach at B first.

u2 = 2 × 10 × 320
u = 80 m/sec.

16)
8 = 1 + 4x + 3x2
3x2 + 4x – 7 = 0
x=1

17) KEmax. = ET = Vmin.

Given: U(x) =

∴
When U is minimum, (dU/dx) = 0
∴ x = 0, ±1

Umin. (x = ± 1) =

(KE)max. = 2 –

(KE)max. =

or

18) The forces acting on the block and N, gravity and friction.

Wf + Wf + Wgr = DK
Where WN = 0, Wf = – µmgl
and Wgr = mg (h – h') and ΔK = 0
Thus, – µmgl + mg(h – h') = 0

19)

Nsinθ = kx
Ncosθ = mg

20) = (170) (1)2 + (10) (3)

= v2

85 + 15 =
400 = v2
v = 20

21)

22) F – f = ma
4 – 2 = 1 × a1kg ⇒ a1kg = = 2 m/s2
Distance travelled by 1kg in t = 2s

Velocity of the 1kg block after t = 2sec

V = at = 2 × 2 = 4 m/s
∴ Work done by F = F.S = 4 × 4 1 = 16
ωF + ωfriction = kf – ki
ωfriction = – 8J
 23)
kx cosθ = mg

so d = 0.4 tanθ = 0.3m

24)
m1g = kx0 ........... (i)
Block m2 wil l loose contact in position (B)
If Kh = m2g .......... (ii)
Applying WET in (A) and (B)

On solving eq. (i), (ii) and (iii) ; we get

x = 5 m.m.

25)
m/s

CHEMISTRY
 26) Explain Question : In this question we have to find out incorrect statement.
Concept : This Question is based on Hybridisation
Solution : sp3d hybridisation involves dz2 orbital.
Final Answer option (1)

27)

MnO4- + 4H+ + 3e- → MnO2 + 2H2O

28)
XeF4 :- sp3d2 Hybridisation

29)
chang in 0.5 = 2

Eq. wt. =

Eq. wt =

30)

Lone pair
on the
Molecule Hybridisation Dipole Moment
central
atom
SO2 sp2 Non-zero 1
3
NF3 sp Non-zero 1
NH3 sp3 Non-zero 1
3
XeF2 sp d zero 3
3
ClF3 sp d Non-zero 2
3
SF4 sp d Non-zero 1

31)
32)

Shape - Original planar

33)

Due to intramolecular Hydrogen bonding, volatility increases and solubility decreases.

34)

NH3 + H+ → NH4+
NH3 → Sp3 (1 and 3bp)
Pyramidal (BA decreases due to )
NH4+ → Sp3 (4bp)
tetrahedral (BA = 109o48')
Bond angle increases

35)
All same bonds, μ = 0
→μ≠=0
Hence,

36) Conceptual.

37)
B.O. = 2 B.O. = 1.5 B.O. = 1

B.O.
B.L. → O2 < O3 < H2O2

38)
39)
(Non-polar )
H2O (polar)
Diploe - induced dipole interaction

40)

Explaining the Question :- We need to arrange compounds by increasing oxidation number

of oxygen.

Concept:- This question is based on oxidation number of oxygen depends on type: peroxide

(–1), superoxide , elemental (0), positive with F.

Solution :-
• In OF2, O = +2.

• In KO2 (superoxide), O = .
• In BaO2 (peroxide), O = –1
• In O3, O = 0.
Arranging –1 (BaO2) < –0.5 (KO2) < 0 (O3) < +2 (OF2).
Final Answer :- 2 BaO2 < KO2 < O3 < OF2

41) N. of moles of e- = no of equation of e- = no of equation of ions.

42)
Since, H2O2 undergoing reduction hence acting as oxidising agent.

43)

44)

Answer:- O.N of C
CH4 → x + (1)4 = 0 ⇒ x = -4
CH3Cl → x + (1)3 - 1 = 0 ⇒ x = -2
CH2Cl2 → x + (1)2 - 2 = 0 ⇒ x = 0
CHCl3 → x + 1 - 3 = 0 ⇒ x = +2
CCl4 → x - 4 = 0 ⇒ x = +4
45)

C3O2
3x + 2(–2) = 0
3x = 4

46) metal oxygen

=
E = 12

47) H-bonding with water

CH4 Does not form H-bonding

high electronegativity is required to cause enough polarisation between C – H bond and create
δ + on H
atom that is required to form H-bond N,O,F.
H – F form as ENf = 4

So 4 molecules will form H-bonding except CH4.

48)
Total number of pπ – dπ bond = 6 = p
Total number of sp3 hybridised atom = 6 = q
 49) Conceptual.

50) On the basis of Drago’s rule PH3, H2Se & H2S have no hybridization.

MATHS

51)

52)

53) y = [Link]

but cosx ≠ 0

⇒
⇒

54)
use sin2A + sin2B + sin2C = 4sinAsinBsinC

55) = sin 10 + sin 20 + sin 30 + sin 40 + .... sin 180 + sin (360 - 170) + ..... + sin (360 - 40) +
sin (360 - 30) + sin (360 - 20) + sin (360 - 10) + sin360
sin 360 - x = - sin x
here all the terms canceled out
so, sin 10 + sin 20 + sin 30 + ... + sin 360 = 0

56)

tan 195º = tan 15º =

57) log (tan1°. tan2° . tan 3°,........................ tan 89°)
⇒ log(1) = 0

58)

cos248 – sin212 = cos60 cos 36

59)

Concept : We know that maximum value of sinx is 1 and minimum value is -1

sinx [-1, 1]

Solution : The value of sinx cosx is

Now sinx cosx = (2sinx cosx)

= sin2x
Now maximum value of sinx cosx is

when sin2x maximum and sin2x

maximum when sin2x = 1

So maximum value of sinx cosx is

=
Option (D) is correct

60)

sin 64° > cos 40°

61)

62)

Let A = 38°, B = 92°, C = 50°

63) x = sin130º + cos130º = sin50º – sin40º > 0

64)

65)

180º = πC ⇒ 1110° =

∴ cosec (–1110°) = – cosec 1110° = –

[ cosec (2nπ + θ) = cosec θ].

66)

67) Use the formula

(1 + tanθ)(1 + tan(45° – θ)) = 2
=4

68) Here ,

and

Dividing, we get

69)

at
 at

70)

71) sin243° = cos247°

⇒ sin217° = cos217° = 1

72) Use sin α + sin(α + β) + sin(α + 2β) + ... + sin(α + β)

Here ,

73) = (sinx + cosx)2 ≤ 2

74)

sin 2A +sin 2B + sin 2C = 2 sin(A + B) cos (A – B) + 2 sin C cos C

= 2 sin(π – C) cos (A – B) + 2 sin C cos (π– (A + B)) = 2 sin C (cos (A – B)–cos(A + B))

= 2 sin C (2 sin A sin B) ⇒

75) = ⇒ =

Put sin A. cos B =

∴ cos A. sin B =

∴ sin(A + B) = + =1