Revision
Topic-: Solution
Marks: - 30 Class: - 12th Time:-60 min
1. A 10% solution (by mass) of sucrose in water has freezing point of 269.15 K. Calculate the freezing
point of 10% glucose in water, if freezing point of pure water is 273.15 K.
Given : Molar mass of sucrose = 342 g mol-1 and Molar mass of glucose = 180 g mol-1
2. Calculate the boiling point of solution when 4 g of MgSO 4 (M = 120 g mol-1) was dissolved in 100 g
of water assuming MgSO4 undergoes complete ionisation. (Kb for water = 0.52 K kg mol-1)
3. Calculate the mass of NaCI (molar mas = 58.5 g mol -1) to be dissolved in 37.2 g of water to lower
the freezing point by 2o C, assuming that NaCI undergoes completes dissociation. (K f for water =
1.86 K kg mol-1+)
4. 45 g of ethylene glycol (C2H6O2) is mixed with 600 g of water . Calculate
(i) the freezing point depression and
(ii) the freezing point of the solution.
(Given, Kf of water = 1.86 K kg mol-1)
5. A 5% solution (by mass) of cane sugar (M.W 342) is isotonic with 0.877% solution of substance X.
Find the molecular weight of X.
6. 3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 K.
Calculate the van’t Hoff factor and predict the nature of solute (associated or dissociated).
(Given : Molar mass of benzoic acid = 122 g mol-1m )
7. A solution is prepared by dissolving 10 g of non-volatile solute in 200 g of water, It has a vapour
pressure of 31.84 mm of Hg at 308 K. Calculate the molar mass of the solute.
(Vapour pressure of pure water at 308 K = 32 mm Hg)
8. Calculate the boiling point elevation elevation for a solution prepared by adding 10 g of CaCI 2 to
200 g of water.
(Kb for water = 0.52 K kg mol-1, molar mass of CaCI2 = 111 g mol-1).
9. Some ethylene glycol, HOCH2CH2OH, is added to your car’s cooling system along with 5 kg of water.
If the freezing point of water-glycol solution. is –15.0oC, what is the boiling point of the solution?
(Kb = 0.52 K kg mol-1 and Kf = 1.86 K kg mol-1 for water)
10. Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10-2 g of K2SO4 in 2L of
water at 25oC, assuming that it is completely dissociated.
(R = 0.0821 L atm K-1 mol, molar mass of K2SO4 = 174 g mol-1).
11. 1.00 g of a non-electrolyte solute when dissolved in 50 g of benzene lowered the freezing point of
benzene by 0.40 K. Find the molar mass of the solute. (Kf for benzene = 5.12 K kg mol-1)
12. A 5% solution (by mass) of cane-sugar in water has freezing point of 271 K. Calculate the freezing
point of 5% solution (by mass of ) glucose in water of the freezing point of pure water is 273.15 K.
[Molecular masses glucose C6H12O6]
13. At 25oC, the saturated vapour pressure of water is 3.165 k Pa (23.75 mm Hg). Find the saturated
vapour pressure of a 5% aqueous solution of urea (carbamide) at the same temperature, (molar
mass of urea = 60.05 g mol-1).
14. 15.0 g of unknown molecular material is dissolved in 450 g of water. The resulting solution freezes
at – 0.34oC. What is the molar of the material
(Kf for water = 1.86 K kg mol-1).
15. A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500 g of water.
The solution has a boiling point of 100.42 oC, what mass of glycerol was dissolved to make this
solution?
16. Calculate the freezing point of an aqueous solution containing 10.50 g of MgBr 2 in 200 g of water
(molar mass of MgBr2 = 184 g, Kf for water is 1.86 K kg mol-1)
17. Calculate the boiling point of a solution prepared by adding 15.00 g of NaCI to 250.0 g of water. (K b
for water = 0.512 K kg mol-1, molar mass of NaCI = 58.44 g mol-1).
18. What would be the molar mass of compound if 6.21 of it dissolved in 24.0 g of chloroform form a
solution that has a boiling point of 68.04 oC. The boiling point of pure chloroform is 61.7 oC and the
boiling point elevation constant, Kb for chloroform is 3.63oC/mol.
19. A solution prepared by dissolving 8.95 mg of a gene fragment in 35.0 mL of water has an osmotic
pressure of 0.335 torr at 25oC. Assuming the gene fragments is non-electrolyte, determine its molar
mass.
20. A. 0.561 m solution of unknown electrolyte depresses the freezing point of water by 2.93 oC. What
is van’t Hoff factor for this electrolyte? The freezing point depression constant (K f) for water is
1.86oC kg mol-1.
21. Phenol associates in benzene to a certain extent to form a dimer. A solution containing 20 g of
phenol in 1.0 kg of benzene has its freezing point lowered by 0.69 K. Calculate the fraction of
phenol that has dimerised
(Given, Kf for benzene = 5.1 Kmol-1)