Quizrr Chapter-Wise Test for JEE Advanced - 2025

By: C I P H Ξ R

Q.1

Density of some aq. solution ( 60% by wt.) is lowered upto 1.2gm/cc by addition of water. If initial density was
1.6gm/cc then new approximate percentage by wt. will be (Take density of water = 1gm/cc)
(A) 45%
(B) 39%
(C) 27%
(D) 19%

Q.2

At 20∘ C and 1.00 atm partial pressure of hydrogen, 18 mL of hydrogen measured at STP, dissolves in 1 L of
water. If water at 20∘ C is exposed to a gaseous mixture having a total pressure of 1400 Torr (excluding the vapour
pressure of water) and containing 68.5%H2 by volume, what volume of H2 , measured at STP, will dissolve in 1L
​ ​

of water ?

(A) 18 mL
(B) 12 mL
(C) 23 mL
(D) 121 mL

Q.3

The elements A and B form compounds having molecular formulae AB2 and AB4 , when dissolved in 20 g of
​ ​

C6 H6 . lg AB2 lowers the freezing point by 2.3 K whereas 1.0 g of AB4 lowers it by 1.3 K. The molal
​ ​ ​ ​

depression constant for benzene is 5.1 K kg mol−1 . The atomic masses of A and B are, respectively -

(A) A = 26, B = 42.64

(B) A = 31.72, B = 47.02
(C) A = 13.11, B = 24.25
(D) A = 19.17, B = 3.01

Q.4

π1 , π2 , π3 and π4 are the osmotic pressure of 5% (mass / volume ) aqueous solution of each of urea , fructose ,
​ ​ ​ ​

sucrose and KCN (α = 1) respectively at certain temperature The correct order of their magnitudes is

(A) π1 > π4 > π2 > π3

​ ​ ​ ​

(B) π1 < π4 < π2 < π3

​ ​ ​ ​ @IITJEE_Advanced
(C) π4 > π1 > π2 > π3
​ ​ ​ ​

(D) π4 > π1 > π3 > π2

​ ​ ​ ​

Q.5

A mixture of chlorobenzene and water (which are virtually immiscible) boils at 90.3∘ C at an external pressure of
740.2 mm. The vapour pressure of pure water at 90.3∘ C is 530.1 mm. What is the percent weight of
chlorobenzene in the distillate ?

(A) 20.21
(B) 37.19
(C) 28.74
(D) 71.26

Q.6

Pure water freezes at 273 K and 1bar. The addition of 34.5 g of ethanol to 500 g of water changes the freezing
−1
point of the solution. Use the freezing point depression constant of water as 2 K kg mol . The figures shown
below represent plots of vapour pressure (V.P.) versus temperature (T). [Molecular weight of ethanol is 46 g mol−1
]
Among the following, the option representing change in the freezing point is

(A)

(B)

(C)

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(D)

Q.7

A gaseous mixture of helium and oxygen is found to have a density of 0.5 gdm−3 at 25∘ C and 0.662 atm. What
is the percentage by mass of helium in this mixture?
(Given: R = 0.08 L atm mol−1 K−1 , 5960
331 = 18) ​

(A) 11.11
(B) 14.23
(C) 23.18
(D) 18.13

Q.8

The vapour pressure of a pure liquid A is 70 mm of Hg at 300 K. It forms an ideal solution with an another
liquid B. The mole fraction of B in the solution is 0.2 and total pressure of the solution is 84 mL of Hg at 300 K.
The vapour pressure of pure liquid B at 300 K would be -

(A) 140 mm of Hg
(B) 70 mm of Hg
(C) 35 mm of Hg
(D) 280 mm of Hg

Q.9

Mark out the correct statement (s) -

(A) For a binary solution AB, if FA−B ​ > FA−A and FB−B , there is negative deviation from ideality or Rault's
​ ​

law.
(B) If FA−B ​ = FA−A and FB−B , binary solution AB formation is not spontaneous as ΔHmixing = 0.
​ ​ ​

(C) If FA−B ​ < FA−A and FB−B , ΔHmixing > 0 and solution formation is spontaneous.
​ ​ ​

(D) There is deviation from Raoult's law in every case if ΔHmixing ​ =0



Q.10

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The total vapour pressure of a binary solution is given by p = (110xA + 125xB ) mmHg, where xA and xB
​ ​ ​ ​

are the mole fractions of components A and B , respectively. It suggests that -

(A) the vapour pressure of solution (nA ​ = nB ) is less than the pure B component.
​

(B) the vapour pressure of solution (nA ​ = nB ) is more than that of pure component A
​

(C) the vapour pressure of pure A component is 110 mmHg and that of pure B is 125 mmHg.
(D) the vapour pressure of pure A and B are 125 mmHg and 110 mmHg, respectively.

Q.11

Two liquids A and B form an ideal solution. The solution has a vapour pressure of 700 torr at 80∘ C. It is distilled till
2/3rd of the solution is collected as condensate. The composition of the condensate is x′A = 0.75 and that of the
​

residue is x′′ A = 0.30. If the vapour pressure of the residue at 80∘ C is 600 torr, which of the following is/are true
​

(A) The composition of the original liquid was xA ​ = 0.6

(B) The composition of the original liquid was xA ​ = 0.4
2500
(C) P∘A = ​

3 Torr
​

(D) P∘B = 500 Torr

​

Q.12

Paragraph:
The total vapour pressure of a binary solution is given by p = (110xA + 125xB ) mmHg where xA and xB
​ ​ ​ ​

are the mole fractions of components A and B , respectively.

Question:
The vapour pressure of pure liquid component A is -

(A) 135

(B) 110

(C) 125

(D) 15

Q.13

Paragraph:
The total vapour pressure of a binary solution is given by p = (110xA + 125xB ) mmHg where xA and xB
​ ​ ​ ​

are the mole fractions of components A and B , respectively.

Question:
The mole fraction of A in the solution is 0.3. The mole fraction of B in the vapour phase, yB , is -​

(A) 0.36
(B) 0.73
(C) 0.27
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(D) 0.46

Q.14

Paragraph:
The total vapour pressure of a binary solution is given by p = (110xA + 125xB ) mmHg where xA and xB
​ ​ ​ ​

are the mole fractions of components A and B , respectively.

Question:
For the equimolar solution of A and B , which of the following is a correct statement?

(A) p > pA ∘ ​

(B) p < p∘A ​

(C) p = pA ∘
​

(D) None of these

Q.15

Paragraph:
An ideal solution of two volatile liquids A(ℓ)& B(ℓ) is vaporized by raising the piston slowly at constant
temperature. Initially in liquid mixture mole % of A was 60% at 1 atm. Vapour pressures of pure liquids A \& B
are 100 and 400 mm Hg respectively.

Question:
What is mole fraction of A in solution at when vapour pressure of solution is 0.5 atm ?

(A) 2/3
(B) 3/5
(C) 1/15
(D) 4/15

Q.16

Paragraph:
An ideal solution of two volatile liquids A(ℓ)& B(ℓ) is vaporized by raising the piston slowly at constant
temperature. Initially in liquid mixture mole % of A was 60% at 1 atm. Vapour pressures of pure liquids A \& B

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are 100 and 400 mm Hg respectively.

Question:
What is vapour pressure of solution when last drop of liquid mixture is left?

(A) 1/7
(B) 2/3
(C) 6/7
(D) 1/3

Q.17

Paragraph:
An ideal solution of two volatile liquids A(ℓ)& B(ℓ) is vaporized by raising the piston slowly at constant
temperature. Initially in liquid mixture mole % of A was 60% at 1 atm. Vapour pressures of pure liquids A \& B
are 100 and 400 mm Hg respectively.

Question:
As piston is lifted which of options is correct -

(A) Mole fraction of A in liquid solution decreases

(B) Mole fraction of B in liquid solution increases

(C) Mole fraction of A in vapour phase decreases

(D) None of these

Q.18

Match the column:

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(A) A-p,q,s; B-p,r ; C- p ; D-p,q,s;

(B) A-p,q; B-r ; C- p,q,s ; D-p,q,s;

(C) A-p,q,s; B-p,r ; C- p,q,r,s ; D-p,q,s;

(D) A-r,s; B-p,r ; C- p ; D-p,q,s;

Q.19

An aqueous solution of an acid is so weak that it can be assumed to be practically un-ionised when boiled at
100.4∘ C, 25 mL of this solution was neutralised by 38.5 mL of 1 N solution of NaOH. Choose the basicity of
the acid if Kb for water is 0.52 K mol−1 kg.
​

Q.20

A certain mass of a substance when dissolved in 100 gC6 H6 , lowers the freezing point by 1.28∘ C. The same mass
​ ​

of solute dissolved in 100 g water lowers the freezing point by 1.40∘ C. If the substance has normal molecular
weight in benzene and is completely ionised in water, how many ions does it dissociate in water?
[Kf (H2 O) = 1.86 K mol−1 kg and Kf (C6 H6 ) = 5.12 K mol−1 kg]
​ ​ ​ ​ ​

Answers & Solutions

Q.1 Answer:
27%
Solution:

mass of 1 litre of solution = 1600gms.

mass of solute = 960gm
Let V litre of water is added.
new vol = (1 + V) litre = (1 + v)1000cc
new mass = 1600 + V(1000)gms
1.2 = 1600+1000 V
(1+V)1000
= 1.6+V
1+V
​ ​

1.6 + V = 1.2 + 1.2 V

0.2 V = 0.4
V = 2 litre
960×100
new wt. % = 1600+2000 = 27% approx ​

Q.2 Answer:
23 mL
Solution:
V2 p2
According to Henry's law, = ​

V1 ​
​

p1
​

​
​

V 1.26
2
or 18 mL = or V2 = 23 mL
​

1.00
​ ​ ​

Q.3 Answer:
@IITJEE_Advanced
A = 26, B = 42.64
Solution:

Suppose atomic masses of A and B are x and y, respectively.

Molar mass of AB2 = x + 2y ​

1
lg AB2 = x+2y mol ​ ​

Molar mass of AB4 = x + 4y ​

1
lg AB4 = x+4y mol ​ ​

m (AB2 ) = 1/(x+2y)20 × 1000 =

​ ​
50
x+2y
​

ΔTf = Kf × m ​ ​
​

50
2.3 = 5.1 × x+2y ​

or x + 2y = 110.87
Similarly, for the 2nd case
x + 4y = 196.15
(2)
Solving eqs. (1) and (2), we get, x = 25.59, y = 42.64

Q.4 Answer:
π4 > π1 > π2 > π3
​ ​ ​ ​

Solution:

Calculate molarity for each solution

(P W
V ) × 10
molarity of urea solutioon =
​

GM W
5 × 10
= = 0.83
60
​

(P W
V
) × 10
Molarity of fructose solution =
​

GM W
5 × 10
​ ​

​ ​

= = 0.27
180
​

(P W
V
) × 10
Molarity of sucrose solution =
​

GM W
5 × 10
=. = 0.14
342
​

Q.5 Answer:
71.26
Solution:

At boiling point P′M ​ = 740.2 mm

P′H2 O = 530.1 mm
​
​

∴ P′chlorobenzene = 740.2 ​
− 530.1 ​

= 210.1 mm
Also, P′ = PM × mole fraction
​

@IITJEE_Advanced
 530.1 = 740.2× mole fraction of H2 O ​

∴ mole fraction of H2 O = 0.716 ​

∴ mole fraction of C6 H5 Cl = 0.284 ​ ​

w H2 O /18 wH2 O /112.5

Let a g2 O and b g chlorobenzene be present in distillate or = 0.716....(i) and =
​ ​

wCB WH O ​

wCB WH O ​

2 2
112.5 + 18 112.5 + 18
​ ​

​ ​ ​ ​

​ ​ ​ ​

0.284.
By eq. (i)/(ii)
a
or 18 × 112.5
​

b
= 0.716
0.284
​ ​

or ba = 12.89
​

31.5
= 0.403 ​

Let total distillate be 100 g

∴ a + b = 100 … . (iv)
By eqs. (iii) and (iv)
b = 71.27%
a = 28.73%
​

Q.6 Answer:

Solution:

W2 × 1000
ΔTf = iKf [ ]
​

M2 × W 1
​ ​ ​

​ ​

34.5 × 1000
= 1 × 2[ ]
46 × 500
​

​ ​

=3K
273(K) − Tf = 3(K) ​

⇒ Tf = 270 K
​

Also, with decrease in temperature, V.P. decreases.

∴ Graph (B) is correct.

Q.7 Answer:
11.11
Solution:

Let the mean molar mass of the mixture be = M.

From ideal gas law,
we know that, PM = dRT
Where, d = density of the gas mixture @IITJEE_Advanced
 ∴ 0.662 × M = 0.5 × 0.08 × 298
⇒ M = 18 g
​

Let the mole fraction of He in the mixture be a.

So, XHeHe ​ = a, XO2 = (1 − a)
​

Average molar mass

M = a × MHe + (1 − a)MO2​

​
​

⇒ 18 = a × 4 + (1 − a)32
14
⇒a= = 0.5
​

28
​

∴ 1 − a = 0.5
mass of helium
% by mass of He = × 100
Total mass of gases
​

0.5 × 4
= × 100 ​

0.5 × 4 + 0.5 × 32
​

= 11.11%

Q.8 Answer:
140 mm of Hg
Solution:

pT = 84 mm, p∘A = 70 mm, XA = 0.8, XB = 0.2

​ ​ ​ ​

pT = 84 mm, p∘A = 70
​ ​

∘ pT − p∘A × XA
pB =
​ ​ ​
​ ​

XB
​ ​

Q.9 Answer:
For a binary solution AB, if FA−B ​ > FA−A and FB−B , there is negative deviation from ideality or Rault's law.
​ ​

Solution:

Stronger resultant molecular attraction emerges

⇒ vapour pressure less ⇒ negative deviation.
Weaker resultant force ⇒ positive deviation.
Solution formation is spontaneous even in those cases where ΔH = 0 or ΔH = + ve, because entropy
changes, ΔS is always +ve.

Q.10 Answer:
the vapour pressure of solution (nA ​ = nB ) is less than the pure B component.
​

Solution:

@IITJEE_Advanced
 p = 110xA + 125xB ​ ​

nA = nB ​ ​

1
∴ xA = xB =
​ ​

2
​ ​ ​

1 1
p = 110 × + 125 × = 117.5 mmHg
2 2
​ ​

When B is pure xB = 1 and xA = 0 ​ ​

pB ∘ = 125 mmHg
​

Hence, p < p∘B , 1 st statement

​

When A is pure xA = 1, xB = 0 ​ ​

pA ∘ = 110 ​

Hence, p > pA ∘ , 2nd statement.

​

Q.11 Answer:
The composition of the original liquid was xA ​
= 0.6
Solution:

x′′A P∘A + x′′B P∘B = 0.30P∘A + 0.70P∘B = 600 ……… .(2) If moles of A and B initially are x and y
​ ​ ​ ​ ​ ​

then

xA P∘A + xB P∘B = 700

​ ​ ​ ​

x′′A P∘A + x′′B P∘B = 0.30P∘A + 0.70P∘B = 600

​

​ ​ ​ ​ ​ ​

x = 0.75 × 32 (x + y) + 0.30 × 31 (x + y) and xA = x+y

​
x
or xB = x+y
x
​ ​ ​ ​ ​

Solving gives xA = 0.6, xB = 0.4, P∘A = 2500

​

3
torr and P∘B = 500 torr
​ ​ ​ ​

Q.12 Answer:
110
Solution:

(i) Pure liquid component A, xA = 1 and xB = 0 ​ ​

Thus, p = 110 × 1 + 125 × 0 = 110

Similarly, for pure B, xB = 1; xA = 0, pB ∘ = 125​ ​ ​

(ii) xA = 0.3 (given), then xA = 0.7

​ ​

p = pA ∘ xA + pB ∘ (1 − xA ) = 110 × 0.3 + 12.5 × 0.7 = 120.5

​ ​ ​

yA = 33
@IITJEE_Advanced
​
 px x
33 pxB xB 87.5
yA = Ap A = 120.5 = 0.27 and yB = = = 0.73
​ ​ ​ ​

p 120.5
​ ​ ​ ​ ​ ​

(iii) p∘A = 110, p∘B = 125

​ ​

p = p∘A xA + p∘B xB = 120.5

​ ​ ​ ​

pA ∘ < p < pB ∘
​ ​

(15)(C), (16)(C), (17)(C)

(i) 100XA + 400 (1 − XA ) = 380 ⇒ 20 = 300XA
​ ​ ​

Q.13 Answer:
0.73
Solution:

(i) Pure liquid component A, xA = 1 and xB = 0 ​ ​

Thus, p = 110 × 1 + 125 × 0 = 110

Similarly, for pure B, xB = 1; xA = 0, pB ∘ = 125 ​ ​ ​

(ii) xA = 0.3 (given), then xA = 0.7

​ ​

p = pA ∘ xA + pB ∘ (1 − xA ) = 110 × 0.3 + 12.5 × 0.7 = 120.5

​ ​ ​

yA = 33
​

px x
33 pxB xB 87.5
yA = Ap A = 120.5 = 0.27 and yB = = = 0.73
​ ​ ​ ​

​ ​ ​ ​

p ​

120.5 ​

(iii) p∘A = 110, p∘B = 125

​ ​

p = p∘A xA + p∘B xB = 120.5

​ ​ ​ ​

pA ∘ < p < pB ∘
​ ​

(15)(C), (16)(C), (17)(C)

(i) 100XA + 400 (1 − XA ) = 380 ⇒ 20 = 300XA
​ ​ ​

Q.14 Answer:
p > pA ∘ ​

Solution:

(i) Pure liquid component A, xA = 1 and xB = 0 ​ ​

Thus, p = 110 × 1 + 125 × 0 = 110

Similarly, for pure B, xB = 1; xA = 0, pB ∘ = 125 ​ ​ ​

(ii) xA = 0.3 (given), then xA = 0.7

​ ​

p = pA ∘ xA + pB ∘ (1 − xA ) = 110 × 0.3 + 12.5 × 0.7 = 120.5

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​ ​ ​
 yA = 33
​

33px x pxB xB 87.5

yA = Ap A = 120.5 = 0.27 and yB = = = 0.73
​ ​ ​ ​

p 120.5
​ ​ ​ ​ ​ ​

(iii) p∘A = 110, p∘B = 125

​ ​

p = p∘A xA + p∘B xB = 120.5

​ ​ ​ ​

pA ∘ < p < pB ∘
​ ​

Q.15 Answer:
1/15
Solution:

(i) 100XA ​
+ 400 (1 − XA ) = 380 ⇒ 20 = 300XA
​ ​

1
XA =
15
​ ​

Q.16 Answer:
6/7
Solution:

(i) 100XA ​ + 400 (1 − XA ) = 380 ⇒ 20 = 300XA

​ ​

1
XA =
15
​ ​

Q.17 Answer:
Mole fraction of A in vapour phase decreases
Solution:

(i) 100XA ​ + 400 (1 − XA ) = 380 ⇒ 20 = 300XA

​ ​

1
XA =
15
​ ​

Q.18 Answer:
A-p,q,s; B-p,r ; C- p ; D-p,q,s;
Solution:

((A)-pqs, (B) - pr, (C) - p, (D) - pqs)

(A) C2 H5 OH − H2 O non-ideal solution +ve deviation.
​ ​ ​

(B) H2 O − HNO3 non-ideal solution -ve deviation.

​ ​
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 (C) CH3 OH − CH3 CH2 OH ideal solution.
​ ​ ​

(D) CCl4 ​ − CH3 OH non-ideal solution +ve deviation.

​

Q.19 Answer:
—
Solution:

Meq. of acid in 25 mL = 38.5 × 1

∴ Meq. of acid in 1000 mL = 38.5×1×1000
25
= 1540 ​

1540
∴ Normality of acid = 1000 = 1.54 ​

∴ Molarity of acid = 1.54

n
(where, n is basicity of acid) ​

ΔT 0.4
Also, molality = K = 0.52 = molarity (given) ​ ​

f
0.4 1.54
​

∴ =
0.52 n
​ ​

∴n=2
Thus, the acid is dibasic.

Q.20 Answer:
—
Solution:

In benzene, ΔTf
= Kf m ​ ​

1.28 = 5.12 × m
∴ m = 0.25
​

In H2 O, ionization takes place,

​

∴ ΔTf = iKf m
​ ​

1.40 = i × 1.86 × 0.25 ​

∴i=3

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