11-01-2026

3010CJA101001250020 JM

PART-1 : PHYSICS

SECTION-I

1) Particle is undergoing circular motion on a smooth horizontal table. It is connected to spring of

negligible natural length. If particle is displaced slightly in radial direction, find time period of small
radial oscillation. [Spring constant k] (mass = m)

(A)

(B)

(C)

(D)

2) A cylindrical piston of mass M slides smoothly inside a long cylinder closed at one end, enclosing
a certain mass of gas. The cylinder is kept with mass of gas. The cylinder is kept with its axis
horizontal. If the piston is disturbed from its equilibrium position, it oscillates simple harmonically.
The period of oscillation will be :-

(h = initial length of cylinder)

(A)

(B)

(C)
(D)

3) A massless rod is pivoted at point O. A string carrying a mass m at one end is attached to the
point A on the rod. The period of small vertical oscillation of mass m around its equilibrium position

is

(A)

(B)

(C)

(D)

4) A bob of mass'm' suspended by a thread of length l undergoes simple harmonic oscillations with

time period T. If the bob is immersed in a liquid that has density times that of the bob and the
length of the thread is increased by 1/3rd of the original length, then the time period of the simple
harmonic oscillations will be :-

(A) T

(B)

(C)

(D)

5) Due to some force F1 a body oscillates with period 4/5 s. and due to other force F2 oscillates with
3/5 s. If both forces act simultaneously, the new period will be :-

(A) 0.72 s
(B) 0.64 s
(C) 0.48 s
(D) 0.36 s

6) Two masses m and are connected at the two ends of a massless rigid rod of length ℓ. The rod is
suspended by a thin wire of torsional constant k at the centre of mass of the rod-mass system(see
figure). Because of torsional constant k, the restoring torque is τ=kθ for angular displacement θ. If
the rod is rota ted by θ0 and released, the tension in it when it passes through its mean position will
be:

(A)

(B)

(C)

(D)

7) A long container has air enclosed inside at room temperature and atmospheric pressure (105 pa).
It has a volume of 20,000 cc. The area of cross section is 100 cm2 and force constant of spring
is kspring = 1000N/m. We push the right piston isothermally and slowly till it reaches the original
position of the left piston which is movable. What is the final length of air column in m. Assume that

spring is initially relaxed.

(A) 1
(B) 2
(C) 3
(D) 4

8) An ideal gas of density ρ = 0.2 kg m–3 enters a chimney of height h at the rate of α = 0.8 kgs–1 from
its lower end, and escapes through the upper end as shown in the figure. The cross-sectional area of
the lower end is A1 = 0.1 m2 and the upper end is A2 = 0.4 m2. The pressure and the temperature of
the gas at the lower end are 600 Pa and 300 K, respectively, while its temperature at the upper end
is 150 K. The chimney is heat insulated so that the gas undergoes adiabatic expansion. Take g = 10
ms–2 and the ratio of specific heats of the gas g = 2. Ignore atmospheric pressure.
 Which of the following statement(s) is(are) correct?

(A) The pressure of the gas at the upper end of the chimney is 300 Pa.
The velocity of the gas at the lower end of the chimney is 40 ms–1 and at the upper end is 20
(B)
ms–1.
(C) The height of the chimney is 590 m.
(D) The density of the gas at the upper end is 0.05 kg m–3.

9) If an object is released from rest, on the surface of a liquid of triple density as shown in fig Then
find out distance moved by object inside liquid before coming to rest

(A) 4 m
(B) 2 m
(C) 1 m

(D)
m

10) A thin uniform tube is bent into a circle of radius r in the vertical plane. Equal volumes of two
immiscible liquids, whose densities are and , fill half the circle. The angle θ between
the radius vector passing through the common interface and the vertical is:

(A)

(B)
(C)

(D)

11) A thin vertical uniform wooden rod is pivoted at the top and immersed in water as shown. The
container is slowly raised. At a certain moment, the equilibrium becomes unstable. If density of
water is 9/5 times the density of wood, then ratio of total length of rod to the submerged length of

rod, at that moment is :-

(A) 2
(B) 3
(C) 4
(D) 6

12) A bent tube of uniform cross section is mounted on a cart which is accelerating towards right
with constant acceleration 'a'. The total length of the liquid is Find the level difference

between two limbs in equilibrium (a = 2m/s2, ℓ = 10m)

(A) 2 m
(B) 4 m
(C) 6 m
(D) 12 m

13) As shown in figure, a flat water gate, height 2m and width 6m, is free to rotate about a
horizontal axis. What is the torque (in N-m) that we should exert on the gate about the axis to keep
the water gate closed? Assume that the right side is exposed to atmosphere. Fill Torque/104 in OMR

sheet.

(A) 4 × 104 Nm
(B) 12 × 104 Nm
(C) 16 × 104 Nm
(D) 8 × 104 Nm

14) During an earthquake the ground is observed to move horizontally. First it moves suddenly
cm to the right, then after 1 second it moves suddenly to the left by cm and returns to its
original position. A chandelier hang on a 4m long cord. Find the amplitude (in cm) of the chandelier
after the earthquake. Take π2 = g

(A) 4
(B) 6
(C) 8
(D) 10

15) A particle of mass m can move along x-axis of co-ordinate frame in a force field of stationary
sources. Potential energy 'U' of system varies with position x of the particle according to the
equation , where k is a positive constant. If the particle is projected from the origin with a

kinetic energy k', and its period of bounded motion is . Find the value of N?

(A) 4
(B) 6
(C) 8
(D) 10

16) At a smooth horizontal table are two identical cubes of mass m, connected by a spring of rigidity
k. The length of spring in the unstretched state is ℓ0. The right cube is linked to the load mass m at
the end. At some time the system is released and the system moves without initial velocity. Find the
maximum distance (in cm) between blocks during the motion of the system. [ℓ0 = 1 cm, m = 3 kg, k

= 1000 N/m]

(A) 1
(B) 3
(C) 5
(D) 7

17) In the given figure time period (in second) of small oscillations is (m = 1kg, k = 5 N/m)
(A) 2π
(B) 4π
(C) 6π
(D) 8π

18) The axle of a uniform cylinder with mass m and radius R is connected to a spring with spring
constant k, as shown in the Fig. A horizontal board with mass m rests on top of the cylinder, and
the board also rests on top of a frictionless support near its left [Link] system is slightly displaced
from equilibrium. There is no slipping between the cylinder and the board, or between the cylinder

and the ground. The angular frequency of the oscillatory motion is p. The value of is .

(A) 1
(B) 2
(C) 3
(D) 4

19) Three moles of an ideal diatomic gas are taken through a cyclic process ABCA as shown in the
P-T graph. During the process AB, pressure and temperature of the gas vary such that PT =
constant, if T0 = 200K then the work done on the gas in the process AB is xR (in Joule), where R is

the universal gas constant then fill value of x.

(A) 1000
(B) 1100
(C) 1200
(D) 1300
20) A wooden plank of length 1m and uniform cross section is hinged at one end to the bottom of
the tank as shown in figure. The tank is filled with water up to height of 0.5 m. The specific gravity
of the plank is 0.5. Find the angle θ (in degree) that the plank makes with the vertical in the

equilibrium position.

(A) 30°
(B) 45°
(C) 60°
(D) 90°

SECTION-II

1) A thermally isolated cylindrical closed vessel of height 8 m is kept vertically. It is divided into two
equal parts by a diathermic (perfect thermal conductor) frictionless partition of mass 8.3 kg. Thus
the partition is held initially at a distance of 4 m from the top, as shown in the schematic figure
below. Each of the two parts of the vessel contains 0.1 mole of an ideal gas at temperature 300 K.
The partition is now released and moves without any gas leaking from one part of the vessel to the
other. When equilibrium is reached, the distance of the partition from the top (in m) will be ______
(take the acceleration due to gravity = 10 ms–2 and the universal gas constant = 8.3 J mol–1K–1).

2) One mole of a diatomic gas is taken around a cyclic process shown in the figure. The process BC
is adiabatic expension and the process CA is isothermal compression. If the volume of the gas at C is

given by VC = (2)nV , then the value of n is

3) An ideal gas of 'n' moles whose pressure P is related to its volume V as (P0 and are
positive constants of appropriate dimensions). The maximum attainable temperature of this ideal gas

is . The value of k is _______.

4) A cylindrical wooden float whose base area is 4 m2 and height 1 m drifts on the water surface in
vertical position. Density of wood is 500 kg/m3 and that of water is 1000 kg/m3. What minimum work
(in kJ) must be performed to take the float out of the water?

5) A cube (density 0.5 gm/cc) of side 10 cm is floating in water kept in a cylindrical beaker of base
area 1500 cm2. When a unknown mass is kept on wooden block the level of water rises in the beaker
by 2mm. If the unknown mass is 75α (in gm) then the value of α.

PART-2 : CHEMISTRY

SECTION-I

1) Select the option having correctly named compound(s)

(I) 3,3-dimethyl-l-hydroxycyclohexane
(II) 4-ethoxy-2-methoxypentan-3-one
(III) 2-ethyl-1,1-dimethylcyclopentane
(IV) 4-amino-2-hydroxy-4-oxobutanal

(A) I, II and III

(B) III Only
(C) II and IV
(D) II only

2) Which of the following is the correct molecular formula of the third member of the homologous
series of ketone :

(A) C3H6O
(B) C2H4O
(C) C5H10O
(D) C4H8O

3)

The common name of the compounds

CH2=CH–CH2–NH2

(A) Vinyl Amine

(B) Allyl Amine
(C) Acryl Amine
(D) Divinyl Amine
4) Functional group isomer of

(A)

(B)

(C)

(D)

5) (a) (b) are :-

(A) Conformational isomer

(B) Position isomer
(C) Chain isomer
(D) Functional group isomer

6) Identify the compound which rotate the plane polarised light.

(A)

(B)

(C)

(D) CH2ClF

7) The relationship among the following pairs of isomers is:

(A) I - A,II -B,III -B,IV -D
(B) I - A,II - A,III -B,IV -D
(C) I -B,II - A,III -B,IV -D
(D) I -B,II -B,III - A,IV -B

8) Which branched chain isomer of the hydrocarbon with molecular mass 72 u gives only one isomer
of mono substituted alkyl halide ?

(A) Neohexane
(B) Tertiary butyl chloride
(C) Neopentane
(D) Isohexane

9) Highest enol content will be shown by :

(A)

(B)

(C)
(D)

10) Which of the following compounds will show geometrical isomerism.

(A)

(B)

(C)

(D)

11) Which of the following will show geometrical isomerism ?

(A)

(B)

(C)

(D)

12) One of the newman projection of

 is
Then possible pairs of X & Y are ___

(A) (Et, Me), (secbutyl, H), (Pr, H)

(B) (Et, H), (secbutyl, H), (Me, Pr)
(C) (Me, Pr), (Et,Et) (secbutyl, H)
(D) None of the above

13) Which of the following has “Z” as well as “trans” configuration :

(A)

(B)

(C)

(D)

14) The absolute configuration of [AIEEE 2008]

(A) S, S
(B) R, R
(C) R, S
(D) S, R
15) The Fischer projection of D-erythrose is shown below. D-Erythrose and its
isomers are listed as P, Q, R and S in Column-I. Choose the correct relationship of P, Q, R and S with
D-erythrose from Column-II.

Column-I Column-II

1. Diastereomer

(P)

2. Identical
(Q)

3. Enantiomer
(R)

(S)
(A) P→2, Q→3, R→2, S→2
(B) P→3, Q→1, R→1, S→2
(C) P→2, Q→1, R→1, S→3
(D) P→2, Q→3, R→3, S→1

16) Which of the following compound does not exhibit geometrical isomerism :-

(A) Cinnamic acid

(B) Maleic acid
(C) Crotonic acid
(D) Malic acid

17) 30.9 g of (+) 2-butanol was taken in a 309 mL solution and was mixed with 15.45 g of
(–)2–butanol placed in 154.5 mL and the final solution is passed through 444 mm tube. What will be
observed rotation for the final solution if specific rotation of 2-butanol is 13.5° .
(A) –1°
(B) +2°
(C) +1°
(D) –2°

18) Increasing order of stability among the three main conformations (i.e. Eclipse, Anti, Gauche)
of 2-fluoroethanol is

(A) Gauche, Eclipse, Anti

(B) Eclipse, Anti, Gauche
(C) Anti, Gauche, Eclipse
(D) Eclipse, Gauche, Anti

19) Compounds which can show geometrical isomerism :

(A)

(B)

(C)

(D)

20) The correct statements about the compounds I, II and III

(A) I and II are identical

(B) I and II are diastereomers
(C) I and III are enantiomers
(D) I and II are enantiomers

SECTION-II

1) How many of the following are cis dichlorocyclohexane.

2) X = count the number of Enantiomer
Y = count the number of Diastereomer
X+Y=

3) If p → Total of geometrical isomers in compound I

q → Total number of stable conformation of compound II
Then value of (p + q) is :

4) Number of structural isomers are formed by C4H10O is

5) C7H9N has how many isomeric forms that contain a benzene ring :-

PART-3 : MATHEMATICS

SECTION-I

1) If latus rectum of hyperbola subtends right angle at point (0, b), then square of eccentricity of the
hyperbola is equal to

(A)
(B) 2
(C)
(D)

2) The slope of a chord of the parabola y2 = 4ax which is normal at one end and which subtends a
right angle at the origin is-

(A)

(B)
(C) 2

(D)

3) Let a line ℓx – y – 2ℓ = 0 (where ℓ ∈ R – {0}) intersects the parabola y2 = 8x at points A and B.

Tangents drawn to parabola at A and B intersect at C(–2, 5), then sum of the angles CAB and CBA
is -

(A) π

(B)

(C)

(D)

4) The number of values of c such that the line y = cx + c, c ∈ R touches the curve is

(A) 0
(B) 1
(C) 2
(D) more than 2

5) If mid point of the chord intercepted on the line 9x – 4y = 13 by the ellipse is (α, β) ,
then (α + β) is
(A) 0
(B) 2
(C) 1
(D) –2

6) Equation of a minor axis of an ellipse is x + 2y = 3 and length of minor axis is , foot of directrix
is (2, 3), then which is wrong

(A) equation of ellipse is 4(2x – y – 1)2 + 2(x + 2y – 3)2 = 25

(B)
eccentricity of ellipse is
(C) length of major axis is 3

(D)
length of LR is

7) Ray y – 2 = 0 strike the parabola y2 = 4x at A and after reflection it passes through a point B on
the axis of parabola & normal at point A meet the axis of parabola at C, then which is correct

(A) A = (2, 0)
(B) B = (1, 0)
(C) B = (3, –6)
(D) C = (1, 0)

8) From a point on , two tangents are drawn to and the corresponding chord

of contact meets at point Q and R then incorrect statements.

(A) The locus of mid-point of QR is x2 + y2 = a2

(B)
The locus of mid-point of QR is

(C)
The locus of image of mid-point of QR in x-axis is

(D)
The locus of foot of perpendicular from point to QR is x2 + y2 = a2

9) If the eccentricity of the ellipse (a > b > 0, a,b 1) is and 'e' be the

eccentricity of the hyperbola , then e2 is (where logx= ℓnx)

(A)

(B) 5
(C)

(D)

10) Consider a curve C : and a line L of slope 1, which is tangent to C at point A,

then

(A) Equation of Lis y = x + 2

(B) Equation of Lis y = x + 5
(C) Equation of circle passing through origin and touches the curve C at A is x2 + y2 + x – 41y = 0
Equation of circle passing through origin and touches the curve C at A is 4x2 + 4y2 + x – 41y =
(D)
0

11) If the tangent at the point P having abscissa to the curve meets the director
circle of the circle 2x + 2y = 25 at (α, β) & (γ, δ), then numerical value of harmonic mean of β and δ
2 2

is less than

(A) 7
(B) 6
(C) 5
(D) 4

12) Let H: is a hyperbola such that its eccentricity and eccentricity of its conjugate
hyperbola are same. Let foot of the perpendicular drawn from focus of H to its one of the tangent is

. Tangents drawn at the ends of chord of length 2 unit of the circle C : x2 + y2 = a3 – 4b2 +
12 meets each other at 'P' on the transverse axis of H then.
Number of common tangent of H & C is

(A) 2
(B) 4
(C) 6
(D) 8

13) Let x1, x2, x3, x4 be non zero real numbers. Let A,B,C,D be distinct points on the parabola y2 = 4x
Suppose that F(x0, y0) is mid point of focal chord AB and lines BC and AE are parallel lines, where
A(x1, y1), B(x2, y2), C(x3,y3), D(x4, y4) and E(2, 0)
If y1y4 = 4 then the tangent at D and normal at A to the parabola meet at a point whose abscissa is-

(A)

(B) 1 + x0 – x2
(C) 1 – x0 + x2

(D)

14) A hyperbola 'H' intersects the ellipse orthogonally. The eccentricity of the hyperbola
'H' is three times the eccentricity of the ellipse. Transverse and conjugate axis of H are along x and y
axis respectively. If 2a, 2b are respectively the length of transverse axis and conjugate axis, (x1, 0) is
the focus and ℓ is length of latus rectum of H.
Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) a (1) 1

(Q) |x1| (2) 2

(R) b2 (3) 3

(S) ℓ (4) 6

(A) P - 1, Q - 2, R - 3, S - 4
(B) P - 2, Q - 1, R - 4, S - 3
(C) P - 4, Q - 3, R - 2, S - 1
(D) P - 3, Q - 4, R - 1, S - 2

15) Let ℓx + my + 1= 0 is common tangent of curves x2 = 4y, x2 + and y2 = 4ax a > 0,

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) 4ℓ2 – a (1) neither prime nor composite number

(Q) 3m2 + 3a (2) odd composite number

(3) odd prime number

(R)

(S) 2a2 + 3ℓ2 + 4m (4) even composite number

(A) P - 2, Q - 1, R - 4, S - 3
(B) P - 4, Q - 3, R - 2, S - 1
(C) P - 3, Q - 4, R - 1, S - 2
(D) P - 1, Q - 4, R - 3, S - 2

16) The equation of parabola whose vertex is at (5, 4) and focus at (3, 4) is-

(A) y2 – 8y – 8x + 40 = 0
(B) y2 – 8y + 8x – 8 = 0
(C) y2 – 8y + 8x – 24 = 0
(D) None of these

17) If one end of a focal chord AB of the parabola y2 = 8x is at , then the equation of
tangent to parabola at the other end of this chord.

(A) 2x + y – 24 = 0
(B) x – 2y + 8 = 0
(C) 2x – y – 24 = 0
(D) x + 2y + 8 = 0

18) A point P on the ellipse has the eccentric angle . The sum of the distance of P from
the two foci is :-

(A) 5
(B) 2
(C) 10
(D) 3

19) An ellipse is drawn by taking a diameter of circle (x – 2)2 + y2 = 4 as its semi minor axis and a
diameter of circle x2 + (y – 3)2 = 9 as its semi major axis if the centre of ellipse is at the origin and its
axis are coordinate axes, then the equation of the ellipse is :-

(A) 4x2 + 9y2 = 144

(B) 4x2 + 9y2 = 36
(C) 9x2 + 4y2 = 16
(D) 9x2 + 4y2 = 36

20) The equation 16x2 – 3y2 – 32x + 12y – 44 = 0 represents a hyperbola-

(A) the length of whose transverse axis is

(B) the length of whose conjugate axis is 4.
(C) whose centre is (–1,2)

(D)
whose eccentricity is

SECTION-II

1) The integral value of area of triangle formed by common tangents to parabola y2 = 8x and

hyperbola and directrix of parabola is

2) A parabola passes through two point A(1, 0) and B(–1, 0) such that directrix always touches the
x2 + y2 = 4 and if locus of focus of parabola is , then is. where [.] is G.I.F

3) Let A be any point on the ellipse x2 + 16y2 = 4 with foci S1 and S2 then the maximum value of AS1 .
AS2 is

4) From any point on line (t + 2)(x + y) = 1, tangents are drawn to ellipse 4x2 + 16y2 = 1. If
chord of contact passes through a fixed point, then number of integral values of t for which fixed
point lies inside ellipse is.

5) Tangents drawn from the point P(2,3) to the circle x2 + y2 – 8x + 6y + 1 = 0 touch the circle at
the points A and B. The circumcircle of the ΔPAB cuts the director circle of ellipse

orthogonally. Find the value of b2.

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C A A D C D A B A D B B A B C B A B C B

SECTION-II

Q. 21 22 23 24 25
A. 6 6 1 5 4

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B C B C B B B C B D B C D B C D B B D D

SECTION-II

Q. 46 47 48 49 50
A. 5 7 3 7 5

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C B B A A C B A A D A A B A C C B C A D

SECTION-II

Q. 71 72 73 74 75
A. 4 1 4 2 54
 SOLUTIONS

PART-1 : PHYSICS

1)
.....(1) equilibrium
L is angular momentum

2) at equillibrium position
pA – patm A = 0
when disturbed by x
pAh = p' A(h – x)

p' =
net force

(Fnet) = (p' – patm) A = A

= ≈ x<<h k=

=ω=

T = 2π

3) In this device, the restoring torque is constituted by spring force .

so for small

4) Explanation Question: We have to find the new time period of SHM

Concept: This question is based on calculation of time period of SHM
Solution:

When bob is immersed in liquid

mgeff = mg – Buoyant force
mgeff = mg –νσg (σ = density of liquid)

=
 and geff =
By solving

Final Answer: Option (4)

5) Under the influence of one force F1 = m and under the action of another force, F2 = m .
Under the action of both the forces F = F1 + F2
⇒ mω2y = m +

⇒ ω2 = ⇒ = +

⇒T= = = 0.48 S.

6)

Ω = ωθ0 = average velocity

T = mΩ2r1
7) Question Explanation : The question asks to find the final length of an air column after
isothermal compression by a piston connected to a spring.
Concept : Ideal Gas Law and Force Balance.
Solution :
Vi = 20000 cm3
Vf = 100 x cm3
P1V1 = P2V2 (isothermal process)

Final Answer : Option (1)

8)

g = 10 m/s2
γ=2
Gas undergoes adiabatic expansion,
p1–γ Tγ = Constant

Now
 = 0.1 kg/m3

Now ρ2A2v2 = 0.8

Now Won gas = ΔK + ΔU + (Internal energy)

P1A1Δx1 – P2A2Δx2 =

⇒
h = 360 m

9)

At maximum displacement v = 0

10)

Question Explanation: Vertical circular tube half-filled by equal volumes of two immiscible
liquids; find angle θ of the interface from vertical.

Concept: This question is based on hydrostatic pressure balance between immiscible fluids.

Solution:

Let us find the pressure at the lowest point 1 . Since the liquid has density and height h1 on
the left hand side of point 1, we have
....(1)
Since two liquid columns of height h2 and h2 and densities and are situated above point l,
on the right hand side, we have

∴ P2 = P1

Substituting
 This gives

Final Answer: The correct option is (4).

11)

Explanation Question: Ratational equilibrium at a rod dipped in liquid is to be analysed

Concept: This question is based on rotational equilibrium in fluids
Solution:

where
Balancing torque about hinge

[where θ is very small]

Final Answer
The correct option is (2)

12)
13)

14) T = 2π

Speed of chandelier is v = A1ω,

ω=

v=ω ⇒A=

A=

15)

F = K F = –K
U = –Kx U = Kx

So by concept of motion with uniform acceleration:

T= where

so T =

Hence N = 8

16) mg – T = macm
T = 2macm
mg – 2macm = macm
mg = 3macm
acm = g/3
In centre of mass frame

ω=

maximum acceleration of mass m =

= ω2x1
x1 is maximum displacement of mass m

x1 =

maximum acceleration of mass m =

= ω2 × 2
x2 is maximum displacement of mass 2m
x2 =
total displacement

x = x1 + x 2 =

= 10 × 2 × 3 = 2 mela
net separation between

then is = = 3cm

17)

T = 2π

18) f2 = map ... (1)

kx – f1 – f2 = maC ... (2)

(f1 – f2)R = ICα = ... (3)

aC + αR = aP ... (4)
aC – αR = 0 ... (5)
Solving the equations we get

, f2 = 2maC

⇒
 ⇒

19) n = 3

f=5 =
PT = C = 2nR(T2 – T1)

T0 = 200k WAB = 2 × 3 × R(200 – 400)

nR × 2TdT = CdV = –1200R
W =1200 R (on gas)

20) Free body diagram of plank ;

V – buoyant force at the centre of buoy any w is weight acting at the centre of gravity.
Rx, Ry = → hinge reactions

Length of plank inside water =

∴u= × A × ρw × g Nt

= × A × 103 × g

Taking moment about the point A :-

× A × 103 × g ×

=
cos2θ =

∴ cosθ = ± ;
∴ θ = 45° : θ > 90° will be not acceptable.
θ = 45°

21) Question Explanation:

The question asks to find the equilibrium position of a diathermic partition.

Concept:
This question is based on Force balance and ideal gas law.

Solution:
Assuming temperature remains constant at 300 K
From P1V1 = P2V2

x=2
distance = 4 + 2 = 6m
Final Answer : 6

22)

Answer : 6
23)

=0

or

k=1

verifying maxima

<0
k=1

24) Applying Newton’s law vertical direction

⇒ dSH × g = ρSh × g

⇒h=

Now when force F is applied, for minimum work a = 0 (∵ For a = 0, F is minimum)

F – mg + ρSxg = 0; F = mg – ρSxg

W= = = mg

W = mgh – = (dSH) gh –

= dSghH – =
[Here S = 4 m2, H = 1 m, d = 500 kg/m3, and ρ = 1000 kg/m3]

25) Let the cube dips further by y cm and water level rises by 2 mm.

Then equating the volumes (///

 volume = \\\ volume in figure) ⇒ volume of water raised
= volume of extra depth of wood

⇒ 100 y = (1500 – 100) = 1400 × = 280

∴ y = 2.8 cm ∴ Extra upthrust ρwater × (2.8 + 0.2) × 100 g = mg ⇒ m = 300 gm.

PART-2 : CHEMISTRY

26)

Answer (B)
(III) 2-ethyl-1-1,1-dimethylcyclopentane

27)

C5H10O

28)
Common-Name ⇒ Allyl Amine

29)

Answer :

30)

Position isomerPosition isomer

31) (2s, 3s) - 2,3-dichloro butane is Dys-Symmetric

32)
I - A,II - A,III -B,IV -D

33)
[M.W. = 72]

34)

35) Question Explanation: The question asks which of the given cyclic compounds will
exhibit geometrical (cis-trans) isomerism.

Concept: This question is based on geometrical isomerism (cis-trans or E/Z) condition

Solution:
In cyclic rings, rotation around the C–C single bonds is restricted, so substituents can
occupy different positions relative to the ring plane. Substituents must be unidentical at each
carbon.

Compound 1: A substituted cyclopentane with two identical groups (CH3) on each carbon of
the ring. Since each carbon has identical groups, no cis-trans isomerism is possible.
Compound 2: Cyclohexane derivative with two deuterium atoms (D) on one carbon and
hydrogen on another. Here, each carbon of interest does not have two different groups, so
geometrical isomerism is not possible.

Compound 3: Cyclopentane with a Cl and two CH3 groups. Two CH3 groups are at one carbon
so no geometrical isomerism.
Compound 4: Both carbons have two different groups, so the compound can exist in cis
(both bromine on same side) and trans (bromine on opposite sides) forms.
 Final Answer: Option (4)

36) Question Explanation:

Identify which of the given compounds can exhibit geometrical (cis–trans) isomerism.

Concept:
This question is based on Geometrical isomerism.

Solution:
Geometrical isomerism arises due to restricted rotation and different spatial arrangements of
substituents.
Benzene, o-Xylene and naphthalene are planar aromatic compounds and do not show cis–trans
isomerism.
Decalin exists in cis- and trans-forms due to restricted rotation at the fused ring junctions.
Final Answer: Option (2)

37) Answer (C)

(Me, Pr), (Et,Et) (secbutyl, H)

38) Question Explanation: Identifying the isomer with both Z and trans configuration.

Concept: E/Z and cis/trans Configuration in Alkenes

Solution: Z (Zusammen) means the two higher-priority groups (HPG) on the double bond
carbons are on the same side. Trans means the main chain groups are on opposite sides.

Same group opposite side, so trans.

Final Answer: Option (4)

39)

Question Explanation:
The question asks to determine the absolute configuration (R/S) of the given compound,
tartaric acid.

Concept:
This question is based on R and S configuration using the Cahn–Ingold–Prelog (CIP)
priority rules.

Solution:
To assign the R/S configuration at each chiral center (C2 and C3), the given wedge–dash
structure is first converted into an equivalent Fischer projection.

Assignment of priorities (1–4) according to CIP rules:

A. –OH: Highest priority (1) due to the oxygen atom.

B. –COOH: Priority (2), as the carbon is bonded to two oxygen atoms.

 C. –CH(OH)COOH (remaining carbon chain): Priority (3).

D. –H: Lowest priority (4).

Using these priorities, the configuration at each chiral center is determined by the direction of
the 1 → 2 → 3 sequence with the lowest priority group oriented away from the observer.

Final Answer: Option (2)

40)

Compound P It is Identical P-2

Compound Q It is Diastereomer Q-1

Compound S It is Enantiomer S-3
Ans. P-2, Q-1, R-1, S-3

41)

Malic acid

42) Answer (B) +2°

43) in 2 flouro ethanol. gauche form is more stable due to intramolecular H-bonding thus
stability order is
Eclipse < Anti < Gauche

44)

Answer :

45)

I and II are enantiomers

46) (iii, v, vi, vii, viii)

47)

48) Question Explanation: Calculate the value of p + q, where p is total geometrical isomers
 of Compound (I) and q is total stable conformations of Compound (II).

Concept: Geometrical Isomerism in Rings and Conformational Analysis of Ethane

Solution:
Compound (I): 1,4-Diethylcyclohexane.
This is a 1,4-disubstituted cyclohexane (X−C6​H10​−Y). Since the substituents are the same
(Et and Et), the isomers are the cis form and the trans form.

p = 2.

Compound (II): CH3​—CD3​ (Ethane with deuterium substitution).

A. In an alkane, the most stable conformation is the staggered form.

q=1
p+q=2+1=3

Final Answer: (3)

49)

50)

Answer : 5

PART-3 : MATHEMATICS
51)

Answer :

52)

Answer :

53)

answer :

54)

answer : 0

55)

Answer : 0

56)

length of major axis is 3

57)

B = (1, 0)

58)

The locus of mid-point of QR is x2 + y2 = a2

59)

Answer :

60)

Equation of circle passing through origin and touches the curve C at A is 4x2 + 4y2 + x – 41y =
0

61)

Answer : 7
62)

Answer : 2

63)

1 + x0 – x2

64)

P - 1, Q - 2, R - 3, S - 4

65)

P - 3, Q - 4, R - 1, S - 2

66)

y2 – 8y + 8x – 24 = 0

67)

x – 2y + 8 = 0

68)

Answer : 10

69) Let equation of ellipse is =1

then b = 4 and a = 6

Hence, ellipse is = 1 ⇒ 4x2 + 9y2 = 144

70)

We have,
16(x2 – 2x) –3(y2 – 4y) = 44

⇒ 16(x – 1)2 – 3(y – 2)2 = 48

⇒ – =1
This equation represents a hyperbola with eccentricity given by
e= =

71)

Answer : 4

72)

Answer : 1

73)

Answer : 4

74)

Answer : 2

75)

Answer : 54