08-02-2026

1001CJA101022260001 JA

PART-1 : PHYSICS

SECTION-I

1) Two cylinders of same cross-section and length L but made of two material of densities d1 and d2
are cemented together to form a cylinder of length 2L. The combination floats in a liquid of density d
with a length L/2 above the surface of the liquid. If d1 > d2 then :-

(A) d < d1

(B)
> d1

(C)
> d1

(D)
d1 > d

2) A copper piece having internal cavity weights 264 gm in air and 212 gm in water. Find the volume
of the cavity. (Density of copper is 8.8 gm/cc).

(A) 13 cc
(B) 20 cc
(C) 22 cc
(D) 24 cc

3) Assertion : A hydrogen filled balloon stop rising after it has attained a certain height in the sky.
Reason : The atmospheric pressure decrease with height and become zero when maximum height is
attained

(A) If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.
(B) If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.
(C) If Assertion is True but the Reason is False.
(D) If both Assertion & Reason are false.

4) Water from a tap emerges vertically downwards with an initial speed of 1.0 m/s. The cross-
sectional area of tap is 10–4 m2. Assume that the pressure is constant throughout the flow of water
and that the flow is steady, the cross-sectional area of stream 0.15 m below the tap is :-

(A) 5.0 × 10–4 m2

(B) 1.0 × 10–4 m2
(C) 5.0 × 10–5 m2
(D) 2.0 × 10–5 m2
5) A piece of cork starts from rest at the bottom of a lake and floats up. Its velocity v is plotted
against time t. Taking into account viscosity of water which of the following best represents the
resulting curve?

(A)

(B)

(C)

(D)

6) Two plane mirrors are inclined at an angle of 60°. A light ray is incident at an angle 60° at point A
on mirror M1. Total deviation suffered by ray after all possible reflections is :

(A) 100°
(B) 180°
(C) 40°
(D) 240°

7) An observer moves towards a plane mirror with a speed of 2 m/s. The speed of the image with
respect to the observer is :-

(A) 1 m/s
(B) 2 m/s
(C) 4 m/s
(D) 8 m/s

8) A large cylindrical tank of cross-sectional area 1m2 is filled with water. It has a small hole at a
height of 1m from the bottom. A movable piston of mass 5 kg is fitted on the top of the tank such
that it can slide in the tank freely. A load of 45 kg is applied on the top of water by piston, as shown
in figure. The value of v when piston is 7m above the bottom is (g = 10 m/s2)

(A) m/s
(B) 10 m/s
(C) 1 m/s
(D) 11 m/s

9) Angle between two mirrors 'θ' and location of object is given in list-I and some possible number of

images are given in list-II.

List-I List-II

(P) θ = 30° and object is on bisector (1) 9

(Q) θ = 36° and object is on bisector (2) 11

(R) θ = 22.5° and object is on bisector (3) 8

(S) θ = 50° and object is on bisector (4) 15

(A) (P) → 1; (Q) → 2; (R) → 3; (S) → 4
(B) (P) → 4; (Q) → 2; (R) → 3; (S) → 1
(C) (P) → 2; (Q) → 4; (R) → 1; (S) → 1
(D) (P) → 2; (Q) → 1; (R) → 4; (S) → 3

10) A particle is oscillating according to the equation x = 7 cos 0.5πt, where t is in second. The point
moves from the position of equilibrium to maximum displacement in time

(A) 4.0 sec

(B) 2.0 sec
(C) 1.0 sec
(D) 0.5 sec

11) A particle executes linear simple harmonic motion with an amplitude of 2 cm. When the particle
is at 1 cm from the mean position the magnitude of its velocity is equal to that of its acceleration.
Then its time period in seconds is :-

(A)

(B)

(C)

(D)

12) A particle executes SHM about the point x = 0. At time t = 0 it has position x = A and zero

velocity. The angular frequency of oscillation is ω. The acceleration of the particle at t = is :-

(A) –Aω2

(B)

(C) Zero
(D)

13) A body of mass 4kg is suspended from a spring of spring constant 400 N/m. Another body of
mass 4 kg moving vertically upward with 2 m/s hits it & gets embedded in it. Amplitude of motion is

(A)
m

(B)
m

(C)
m

(D)
m

14) A block of mass m is connected with two ideal pulley and a massless spring of force constant k as
shown in fig. The block is slightly displaced from its equilibrium position, its time period of
oscillation is :-

(A)

(B)

(C)

(D)

15) Statement–1 : The motion of a simple pendulum is simple harmonic only for a ≈ ℓ.

Statement–2 : Motion of a simple pendulum is SHM for small angular

displacement.

Statement–1 is True, Statement–2 is True ; Statement–2 is a correct explanation for

(A)
Statement–1.
Statement–1 is True, Statement–2 is True ; Statement–2 is NOT a correct explanation for
(B)
Statement–1.
(C) Statement–1 is True, Statement–2 is False.
(D) Statement–1 is False, Statement–2 is True.

16) Two blocks of masses m and 2m are connected to a massless spring of force constant k. The
spring is stretched by x0 and the blocks are made to oscillate on a smooth horizontal surface. The

amplitude of motion of block of mass m is :-

(A) x0/3
(B) 2x0/3
(C) x0
(D) x0/6

17) A linear harmonic oscillator of force constant 2 × 106 N/m and amplitude 0.01m has a total
mechanical energy of 160 joule. Its :-

(A) maximum potential energy is 100 J.

(B) maximum kinetic energy is 100 J.
(C) minimum potential energy is 100 J.
(D) minimum potential energy is zero.

18) The variation in potential energy of a harmonic oscillator is as shown in fig. The spring constant

is :-

(A) 1 × 102 Nm–1

(B) 2 × 102 Nm–1
(C) 0.667 × 102 Nm–1
(D) 3 × 102 Nm–1

19) A pendulum is formed by pivoting a disc. What distance from center of mass, it should be pivoted
for minimum time period while performing SHM?

(A)

(B)

(C) R
(D) Zero

20) A light rigid wire of length 2ℓ is bent at centre, two identical particles each of mass m are
attached at two ends of the wire. If angle between two halves of wire is α and wire is hinged in a
vertical plane at centre, then find period of small oscillation of system in vertical plane containing

the wire.
(A)

(B)

(C)

(D)

SECTION-II

1) A glass rod of diameter d1 = 1.5 mm is inserted symmetrically into a glass capillary with inside
diameter d2 = 2.0 mm. Then the whole arrangement is vertically oriented and brought in contact
with the surface of water. To what height (in cm) will the water rise in the capillary? Take surface
tension of water 75 milli N/m.

2) A point source of light, S is placed at a distance L in front of the centre of plane mirror of width d
which is hanging vertically on a wall. A man walks in front of the mirror along a line parallel to the
mirror, at a distance 2L as shown below. The distance over which the man can see the image of the
light source in the mirror is n × d, then find n. Source S is placed symmetric to mirror.

3) A spring of force constant k = 300 N/m connects two blocks having masses 2 kg and 3 kg, lying on
a smooth horizontal plane. If the spring block system is released from a stretched position, the
number of complete oscillations in 1 minute is 6 × N, find the value of N. (Take .)

4) An object of mass 0.2 kg executes simple harmonic oscillations along the x–axis with a frequency
of (25/π) Hz. At the position x = 0.04 cm, the object has kinetic energy of 0.5 J and potential energy
0.4 J. Find the amplitude (in cm) of oscillations.

5) In a test experiment on a model aeroplane in wind tunnel, the flow speeds on the upper and lower
surfaces of the wings are 70 ms–1 and 65 ms–1 respectively. If the wing area is 2 m2 the lift of the wing
is _______ N. (Given density of air = 1.2 kg m–3)

PART-2 : CHEMISTRY

SECTION-I
1) The correct absolute configuration assigned for compound (I) and (II) respectively is :

(I) (II)

(A) R, R
(B) R, S
(C) S, S
(D) S, R

2) Total stereo isomers of

(A) 2
(B) 4
(C) 6
(D) 8

3)

Which of the following compound has plane of symmetry and center of symmetry?

(A)

(B)
(C)

(D) All of these

4) Which of the following will not show geometrical isomerism ?

(A)

(B)

(C)

(D)

5) Which of the following represents correct pair of isomers?

(A)

are Geometrical isomers

(B) & are metamers
(C) CH3CH2OH and CH3–O–CH3 are functional group isomers

(D)
and are tautomers

6) Which one of the following conformers of 3-amino-2-butanol is most stable :

(A)

(B)

(C)

(D)

7) Statement-I : All double bond containing compounds show geometrical isomerism.

Because
Statement-II : Alkenes have restricted rotation about the double bond.

(A) Statement-I is True, Statement-II is True ; Statement-II is a correct explanation for Statement-I
Statement-I is True, Statement-II is True ; Statement-II is NOT a correct explanation for
(B)
Statement-I
(C) Statement-I is True, Statement-II is False.
(D) Statement-I is False, Statement-II is True.

8) Which of the following is correct for I2Cl6 ?

(A) It is non-planar like Al2Cl6

(B) It has both 2c–2e¯ & 3c – 2e¯ bond
(C) Its monomeric form involves significant pπ-dπ interaction.
(D) It is planar and non polar

9)

Observe the following conversion and structure of B2H6 (Diborane) 2BH3(g) —→ B2H6(g)
 The correct statement is :
(A) ℓ1 > ℓ2
(B) θ1 > θ2
(C) B2H6 consists of 3c–2e bond and is a planar specie
The hybridisation state of Boron atom in B2H6 is not changed as compared to monomeric form of
(D)
BH3

10) Which of the following statement is correct for B2H6?

(A) When methylated, the product is Me6B2

(B) It give unsymmetrical cleavage with NH3
(C) Bridging bonds are formed by sp3-sp3-sp3 orbitals overlapping
(D) Hybridisation state of 'B' is changed when react with CO

11)

In the following compounds, the compound having doubtful existence is :

(A) PbCl4
(B) PbI4
(C) TℓI3
(D) BiF5

12) Which of the following odd electron species planar and polar.

(A)

(B)

(C) NO2
(D) ClO3

13) Correct statement for trimethyl amine and trisilyl amine.

(a) (CH3)3N: is good lewis base than (SiH3)3N:
(b) Hybridisation of nitrogen in (SiH3)3N: is sp3
(c) Back bonding present in both molecule
(d) Shape of (CH3)3N: is pyramidal w.r.t. Nitrogen

(A) a, d
(B) b, d
(C) a, c
(D) c, d
14)

List I List II

(Oxide) Nature of Oxide

(P) Cs2O (1) Acidic oxide

(Q) Cl2O7 (2) Basic oxide

(R) ZnO (3) Amphoteric oxide

(S) CO (4) Neutral oxide

(A) P → 2 , Q → 1 , R → 4 , S → 3
(B) P → 1 , Q → 2 , R → 4 , S → 3
(C) P → 2 , Q → 1 , R → 3 , S → 4
(D) P → 1 , Q → 3 , R → 2 , S → 4

15) A cylinder of compressed gas contains dinitrogen and dioxygen gas in molar ratio of 3: 1, if the
cylinder is known to contain 2.40 gm of oxygen. What is the total mass of gas mixture in the cylinder
?

(A) 8.7 g
(B) 7.2 g
(C) 6.8 g
(D) 6.3 g

16) Total number of protons in 32gm CH4 is -

[Given : Atomic mass of C = 12 amu, H = 1 amu, NA = Avogadro's constant]

(A) 2 NA
(B) 5 NA
(C) 10 NA
(D) 20 NA

17) Incorrect statement regarding 22 g of CO2 is :

(A) It occupies 11.2 L of volume at 1 atm and 0ºC

(B) It corresponds to one gram molecule of carbon dioxide
(C) It contains one gram atom of oxygen
(D) It contains 0.5 gram atom of carbon

18) A compound X with molar weight of 90 g is dissolved in a solvent Y of density of 0.58 g /ml,
Assuming no change in volume upon dissolution, the molarity of a 5 molal solution is.

(A) 2 M
(B) 0.65 M
(C) 2.9 M
(D) 1.5 M

19) 1 L of 0.5 M barium chloride (BaCl2) solution is mixed with 1 L of 0.2 M potassium chromate
(K2CrO4) solution. Assuming BaCrO4 is completely insoluble in water. Calculate the concentration of
the barium ions in solution when precipitation is completed
BaCl2(aq.) + K2CrO4(aq.) → BaCrO4 + KCl(aq.)

(A) 0.5 M
(B) 0.1 M
(C) 0.15 M
(D) 0.2 M

20) Element 'A' atoms form 3-D hexagonal close pack structure (HCP), then calculate number of
total voids in 10 milligrams sample of element 'A'. [Given : Atomic mass of 'A' = 100, NA = 6 × 1023]

(A) 1.2 × 1020

(B) 6 × 1020
(C) 1.8 × 1020
(D) 2.4 × 1020

SECTION-II

1) Calculate total numbers of ether possible for C5H12O molecular formula [Structural Isomer]

2) How many of the following statement is/are correct ?

(i) Aℓ > Mg (Ionisation energy)
(ii) N– > N (Ionisation energy)
(iii) Ne > He (Atomic radius)
(iv) N2O5 > N2O3 (Acidic strength)
(v) Mg > S (Effective nuclear charge)

3) How many of the following are planar

, , Be2H4 , B2H6 , I2Cl6 , Be2Cl4 , Al2H6 , NO2

4) An ionic compound (A+ B–) crystallizes in rock salt structure. The ionic radii of A+ and B– are 200
pm and 400 pm respectively. If the distance between two nearest cations is x A°, then find nearest
integer value of 10x.

5) When 10 ml of acetic acid (density = 0.8 g/ml) is mixed with 40 ml of water (density = 1 g/ml) at a

certain temperature, the final solution is found to have a density of g/ml. The percent change in
total volume on mixing is :
 PART-3 : MATHEMATICS

SECTION-I

1) Range of the function y = is -

(A)

(B)

(C)

(D)

2) Let ƒ(x) = ex & g(x) = x2, then number of solution of ƒog = goƒ is equal to -

(A) 0
(B) 1
(C) 2
(D) 3

3) Assertion (A) : If the function f : R – {1, –1} → A defined by f(x) = , is surjective, then A is
R – [–1, 0) Reason (R) : If a function is surjective then it is one-one and onto.

(A) A is correct but R is not correct

(B) A is not correct but R is correct
(C) Both A and R are correct but R is NOT the correct explanation of A
(D) Both A and R are correct and R is the correct explanation of A

4) If function ƒ : [–4, ∞) → B defined as ƒ(x) = x2 + 8x + 18 is bijective then set B is :-

(A) R
(B) [–2, ∞)
(C) [2, ∞)
(D) [–8, 2]

5) If ƒ(x) = x + 2 ∀ x ∈ [0, 2] and g(x) = 1 + tanx ∀ then range of ƒ(g(x)) is :-

(A) [3, ∞)
(B) [3, 4]
(C) R
(D) (–∞, 3]

6) The domain of function is equal to-

(A) (–∞,–2] ∪ [2,∞)

(B) [–4,4]
(C) [–4,–2] ∪ [2,4] ∪ {0}
(D) none of these

7) The number of ordered pairs (a, b) for which (x + a)2 + b (x2 – 3x – 2) + x + 1 = 0 is an identity in
x is

(A) 0
(B) 1
(C) 2
(D) 3

8) Least integer in the range of function is

(A) 0
(B) –4
(C) 4
(D) 1

9) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(A) ƒ : R → R, ƒ(x) = x|x| is (I) One one and into function

(B) g : R → R+ ∪ {0}, g(x) = is (II) Many one and onto function

(C) h : R → R, h(x) = x + [x] is (III) Many one and into function

(D) p : R → R, p(x) = |x – 1| is (IV) Odd function

[Note : [.] denotes the greatest integer less than or equal to x.]
(A) (A) – IV (B) – II (C) – III (D) – I
(B) (A) – IV (B) – II (C) – I (D) – III
(C) (A) – II (B) – III (C) – IV (D) – I
(D) (A) – II (B) – III (C) – I (D) – IV

10) If the domain of g(x) is [0, ∞) then the domain of g(6{x} – 8{x}2 – 1) is
({.} denotes fractional part function)

(A)
(B)

(C)

(D)

11) Consider the function ƒ : R – {1} → R – {2} given by ; then

(A) ƒ is one-one but not onto

(B) ƒ is onto but not one-one
(C) ƒ is neither one-one nor onto
(D) ƒ is both one-one and onto

12) If g(x) = x2 + x – 2

(gof) (x) = 2x2 – 5x + 2

then ƒ(x) is equal to :-

(A) 2x – 3
(B) 2x + 3
(C) 2x2 + 3x + 1
(D) 2x2 – 3x – 1

13) Domain to function is -

(A) (2, 3)
(B) [2, 3]
(C) [1, 2]
(D) [1, 3]

14) Least integer in the range of the function is

(A) 3
(B) 8
(C) 7
(D) 9

15) Consider the function f(x) such that f(x –1) + f(x + 3) = f(x + 1) and f(5) = 1.

Statement-I :
Statement-II : f(x) is a periodic function with period 12.
(A) Statement-I is true but Statement-II is false
(B) Both Statement-I and Statement-II are false
(C) Both Statement-I and Statement-II are true
(D) Statement-I is false but Statement-II is true

16) If f(x) = 2x3 + 7x –5 then f–1(4) is

(A) equal to 1
(B) equal to 2
(C) equal to 1/3
(D) non existent

17) If , then f(x) is given as

(A)

(B)

(C)
(D)

18) The number of solutions of the equation,

e2x + ex – 2 = [{x2 + 10x + 11}] is :-
(Where [.] denotes greatest integer function & {.} denotes fractional part function)

(A) 0
(B) 1
(C) 2
(D) 3

19)

If α and β are the roots of the equation x2 + 10x – 7 = 0 then the value
of is :

(A) 5
(B) –5
(C) 10
(D) –10

20) Consider the quadratic expression y = x2 – px + q where p, q ∈ R. If p < 0 & q < 0, then the
possible graph of y = x2 – px + q is -

(A)
(B)

(C)

(D)

SECTION-II

1) Number of integers in the domain of is (where {.} denotes fractional part

function)

2) Number of integral solution of the equation is

3) If function ƒ : {1, 2, 3, 4} → {1, 2} satisfying ƒ(1) + ƒ(2) + ƒ(3) + ƒ(4) = odd integer, then the least
value of ƒ(1) + ƒ(2) + ƒ(3) + ƒ(4) is equal to

4) Let , then value of x for which is

5) If '4' lies between the roots of the equation x2 – (3k – 1)x + 5k = 0, then minimum possible integral
value of k is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D C C C A D C D D C C B A D D B B B B C

SECTION-II

Q. 21 22 23 24 25
A. 6 3 25 6 810

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B C D C A D D B B B C A C A D B C C C

SECTION-II

Q. 46 47 48 49 50
A. 6 2 5 85 2

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C A C B C A D B C D A B B D A B B B B

SECTION-II

Q. 71 72 73 74 75
A. 3 6 5 10 3
 SOLUTIONS

PART-1 : PHYSICS

1)
m1g + m2g = FB

d1ALg + d2ALg =

(d1 + d2) ALg =

∴ d1 > d2 So

ie

2)
Fb = (264–212)g = 52g
Volume of water displaced

⇒
Volume of cavity = Vtotal – Vcopper
⇒ 52 – 30 ⇒ 22cc

3) Explain question:
Two statements regarding the rising of balloons and variation of atmospheric pressure with
height are given. We have to select the correct statements.

Concept:
Buoyant Force.

Solution:
The hydrogen–filled balloon initially rises in the air because the weight of the displaced air i.e.,
upthrust is greater than the weight of the hydrogen and the balloon. This force is similar to the
force experienced when an empty container is dipped in water.
The different in densities causes the less dense object to be pushed above. Since the density of
air decreases with height therefore the balloon halts at a particular height. At this particular
point, the density to the air will be equal to the density of the hydrogen inside the balloon.
The force acting on the balloon downwards that is the weight of the balloon will be balanced
by the buoyant force acting on the balloon at this particular point. Hence the net force acting
on the balloon will be cancelled out and the balloon stops rising.
So, the assertion is correct. However, the reason is incorrect since the atmospheric pressure
does not reach zero at that height. It just decreases such that the density of the atmosphere
equals the density of the hydrogen inside the balloon.

Final answer: option (3)

4)

5) As the cork moves up, the force due to buoyancy remains constant. As its speed increases,
the retarding force due to viscosity increases, being proportional to the speed. Thus the
acceleration gradually decreases. The acceleration is variable, and hence the relation between
velocity and time is not linear.

6)
s = 2 × 60 + 2 × 60 = 240

7)

The speed with which man is approaching the mirror

vOM = –viM
v0 – vM = – [vi – vM]
v0 = –vi [∵ vM = 0]

vPO = vi – v0 = 2 – (–2) = 4 m/s

8)
9) Question Explanation :
Determine which numbers in List-II match the actual number of images produced by two plane
mirrors inclined at angle θ for the given object location.
Concept : Number of images formed by two incline mirror
Solution :

For (P) = 12 ⇒ Number of images = 11

For (Q) = 10 ⇒ Number of images = 9

For (R) = 16 ⇒ Number of images = 15

For (S) = 7.2, as it is not exactly divisible therefore we have to draw and check number
of images = 8
Final Answer : The correct option is (D).

10) Particle is oscillating according to the equation x = 7 cos 0.5 πt

x = A cos ωt (general equation of SHM)
On comparing
ω = 0.5π

To move from the position of equilibrium to maximum displacement time needed is

11)
|a| = ω2x
12)
Δϕ = ω·Δt

a = –ω2x

13)

ω2 = 50

14) When one displaces the block by y, the pulley A will go down by y/2. Accordingly the pulley
B goes down by y/4. So spring will stretch by y/4.
Thus and 2T = T1

The restoring force, and acceleration,

15) Conceptual based.

16) If Δx1 and Δx2 are their respective amplitude of motion, then
mΔx1 + 2m(–Δx2) = 0 ........(i)
and Δx1 + Δx2 = x0 ........(i)

After solving above equations, we get

17) ;
,

18) 04 =
19)

Question Explanation:
Given a disc oscillating as compound pendulum. We have to find the location where it should
be pivoted so that the time period is minimum.

Concept:
Calculation of time period of compound pendulum, and when it becomes minimum.

Solution:

For rigid body

(Suppose ℓ is distance of point of pivoting from COM)

Leff = should be minimum for T to be minimum

Final Answer:
The correct option is (2)

20) T =
21)
F1 = T (π) d2
F2 = T (π) d1
F1 + F2 = mg

Tπ (d1 + d2) =

22) By similar triangles, ΔAEC≈ΔIHA

y=d
total distance

= 3d
so n = 3

23)

sec
nT = 60 sec

N = 25

24) Total energy E = m ω2 A2

 0.5 + 0.4 = × 0.2 A2 ⇒ 9 = (50)2 A2 ⇒ A = 0.06 m

25)

= 810 N

PART-2 : CHEMISTRY

26)

27) Explanation: Asking about the total number of stereoisomers.

Concept: This question is based on counting of stereoisomers.
Solution: In unsymmetrical molecules total number of stereoisomers = 2n where n = number
of stereoisomers generating center.

Total number of stereoisomers generating center = 2

Total number of stereoisomers = 2n = 22 = 4

28)

The correct answer is option (C)

29)

Ans Option (A), (D)

Concept :- Conditions for G-I
Condition no 1:- Restricted rotation must be present.
Condition no 2 :- The two groups at each end of restricted bond must be different.
Condition no 3 :- Terminal valency present in the same plane. G.I is also observed in case of
substituted cycloalkanes
Option (A) incorrect because
Terminal valency around restricted rotation are not same on the two double bonds in the two
branches hence it will show G.I.
option (B) Incorrect ; because

it will show G.I according to substituted cycloalkane

Option (C) Incorrect ; because it show G.I according to condition no 2

Option (D) Correct because it doesn't show G.I

30)

Explain the question : To select correct pair of isomers with their relationship.

Concept : This question is based on structural isomerism and Geometrical isomerism

Solution :-

(1) are position isomers

(2) are identical

(3) CH3–CH2–OH & CH3–O–CH3 are functional isomers

(4) are not tautomer.

31)

The correct answer is option (A)

32)

Question Explanation : The question evaluates whether every compound with a double bond
exhibits geometrical isomerism and if that behavior is due to restricted rotation.
Concept: Geometrical Isomerism, Restricted Rotation, Alkene Structure
 Solution: All alkenes have restricted rotation about the C=C bond because of the π‑bond.
However, not all double‑bonded compounds show geometrical isomerism. For this isomerism
to occur, each carbon of the double bond must have two different substituents. If identical
groups are attached to one or both carbons, no cis–trans forms exist. Therefore, Statement‑I is
false, though Statement‑II is true—the second statement correctly describes a general
property of alkenes but doesn’t make the first one true.

33) I2Cl6 is planer & Al2Cl6 is non planer

34)

Theory based

35)

The correct answer is option (B)

36)

PbI4 does not exist.

37) Question Explanation: Identify an odd-electron molecule that is both planar and polar.

Concept: Molecular Geometry and Polarity of Radicals.

Solution:

A. :​ The methyl radical has sp2 hybridization and a planar geometry, but it is non-polar due
to its symmetrical structure.
B. :​ The trifluoromethyl radical has sp3 hybridization and a pyramidal geometry (non-planar)
because of the high electronegativity of Fluorine.
C. NO2​: Nitrogen dioxide is an odd-electron species (17 valence electrons) with sp2 hybridization.
It has a bent geometry, which is planar (all three atoms lie in one plane) and polar due to the
net dipole moment.
D. ​: The chlorate radical is sp3 hybridized and has a pyramidal geometry.

38)

The correct answer is option (A)

39) (P) Cs2O — Basic oxide
(Q) Cl2O7 — Acidic oxide
(R) ZnO — Amphoteric oxide
(S) CO — Neutral oxide

40) Given :

x = 6.3
Total mass = (N2 + O2) = (6. 3 + 2.4) = 8.7 gm

41)

Correct answer is option (D)

42)

Correct answer is option (B)

43)

n2 = 5
W1 = 1 kg = 1000

d1 = 0.52 =

Molarity =
= 2.9 M.

44) Question Explanation:

Calculate the concentration of the barium ions in solution.
Concept:
Mixing of solution
Solution:
BaCl + K2CrO4 → BaCrO4↓ + 2 KCl
1L, 0.5 M 1L1, 0.2M
= 0.5 mol = 0.2 mol
(I.R)
0.3 mol 0 – 0.4 mol

45)
Atoms = × NA = 6 × 1019 atoms
Voids = 3 × (6 × 1019) = 18 × 1019 atoms.

46) Explain question : to find out no. of structurally isomeric ethers with mol. for C5H12O
Concept : This question is based on no. of structural isomers.
Solution : There will be 6 structurally isomeric ethers are possible with C5H12O
C5H12O structure isomer of ether

(i) (ii)

(iii) (iv)

(v) (vi)

47) Mg has more IE than Aℓ due to more penetration effect of 3s electrons.

48) The correct answer is 5

49) B– is present at corners and face centres.

A+ is present at edge centres and body centre.

from

50) wtsol = wtacetic acid + wtwater

or Vsol ×
⇒ Vsol = 49 mL
∴ Percentage decrease in volume

=
PART-3 : MATHEMATICS

51) y =
⇒ y = sinx but sin4x ≠ 0 ⇒ 4x ≠ nπ

52)

ƒ(g(x)) = g(ƒ(x))

⇒ x2 = 2x
⇒ x = 0,2

53) f : R – {±1} —→ A
x2 ∈ [0, ∞) – {1}
x2 – 1 ∈ [–1, ∞) – {0}
1 – x2 ∈ (–∞, 1] – {0}
1 – x2 ∈ (–∞, 0) ∪ (0, 1]

∈ (–∞, 0) ∪ [1, ∞)

–1 + ∈ (–∞, –1) ∪ [0, ∞)

Range = A = R – [–1, 0)

54) ƒ(x) = (x + 4)2 + 2

as x ≥ –4 ⇒ ƒ(x) ≥ 2

55) ƒ(g(x)) = 3 + tanx,

0≤x≤
0 ≤ tanx ≤ 1 ⇒ 3 ≤ 3 + tanx ≤ 4
Correct Answer is (B)

56)

Question Explanation: Determining the domain of a function involving square roots and
inverse trigonometry.

Concept: Domain of Square Root and Inverse Sine Functions

Solution: Necessary conditions

⇒–4<x<4
(1) ⇒ |x| > 2 ⇒ x ∈ (–∞,–2] ∪ [2,∞)
or |x| < 0 ⇒ x = 0 ∴ common values x ∈ [–4, –2] ∪ [2, 4] ∪ {0}

Final Answer: [–4,–2] ∪ [2,4] ∪ {0}

57)

(x + a)2 + b(x3 – 3x – 2) + x + 1 = 0
(x2 + 2ax + a2) + (bx2 – 3bx – 2b) + x + 1 = 0
x2(1 + b) + x (2a – 3b + 1) + (a2 – 2b + 1) = 0
for identity,
1 + b = 0 ⇒ b = –1
2a – 3b + 1 = 0
⇒ 2a + 3 + 1 = 0 ⇒ a = –2
a2 – 2b + 1 = 0
⇒ a2 + 2 + 1 = 0
⇒ a2 = – 3 not possible
Number of ordered pairs = 0

58) =
4
⇒ f(x) = x , x > 0
∴ Range = (0, ∞)
∴ least integer = 1

59) (A)
Invertible function, odd function

(B)
Many one and onto function

(C)
One one and into function

(D)
Many one and into function
60) 6{x} – 8{x}2 – 1 ≥ 0
8{x}2 – 6{x} + 1 ≤ 0

n+ ≤x≤n+ , n∈I

61) is one-one function, range ∈ R ~ {2}

62) g(x) = x2 + x – 2
⇒ (gof) (x) = g[ƒ(x)] = [ƒ(x)]2 + ƒ(x) – 2

Given, (gof) (x) = 2x2 – 5x + 2.

∴ [ƒ(x)]2 + ƒ(x) – 1 = 2x2 – 5x + 2

⇒ [ƒ(x)]2 + ƒ(x) = 4x2 – 10x + 6
⇒ ƒ(x) [ƒ(x) + 1] = (2x – 3) [(2x – 3) + 1]
⇒ ƒ(x) = 2x – 3

63)

Let f(x) =
Case 1 Case 2

x (5 – x) > 0
2
5x – x ≥ 6 x ∈ (0, 5)
x2 – 5x + 6 ≤ 0
(x – 2) (x – 3) ≤ 0
x ∈ [2, 3]

Now, case1 case 2

x ∈ [2, 3]

64)

f(x) = ....... (1)

3x > 0

3x + >
f(x) > 7
⇒ Range = (7, ∞)
∴ Least integer in the range = 8

65) f(x – 1) + f(x + 3) = f(x + 1) ....(i)

Replacing x by x + 2
f(x + 1) + f(x + 5) = f(x + 3) ....(ii)
from (i) and (ii)
f(x – 1) + f(x + 5) = 0
Replacing x by x + 1
⇒ f(x) + f(x + 6) = 0
⇒ f(x) = – f(x + 6) ....(iii)
Replacing x by x + 6
f(x + 6) = – f(x + 12)
⇒ f(x) = f(x + 12)
hence f(x) is periodic function with period 12

Now = 91
hence Statement-I is false and Statement-II is true.

66) let f–1(4) = a

⇒ f(a) = 4
⇒ 2a3 + 7a – 5 = 4
⇒ 2a3 + 7a –9 = 0
⇒ (a–1) (2a2+2a+9) = 0
⇒ a = 1 (2a2 + 2a + 9 ≠ 0 as D < 0)
So, f–1(4) = 1

67) Given f(x) + 2f(1 – x) = x2 + 2 .....(i)

Replacing x by 1 – x in eq.(i), then
f(1 – x) + 2f(x) = (1 – x)2 + 2 .....(ii)
Now, multiplying in eq. (i) and in eq. (ii) by 2, then each other subtracting, we get
–3f(x) = x2 + 2 – 2(1 – x)2 – 4
or 3f(x) = – (–x2 + 4x – 4)
= x2 – 4x + 4
= (x – 2)2

68) We know that, {f(x)} ∈ [0,1)

⇒ [{f(x)}] = 0
∴ e2x + ex –2 = 0 ⇒ (ex + 2) (ex–1) = 0
 ∴ ex = 1 is only solution

69)

= –5

70) y = x2 – px + q
given p < 0 , q < 0
∵Sum = p < 0
product = q < 0
⇒ One root is negative and other is positive and also since sum is negative
⇒ Magnitude of (–ve) root is greater than (+ve) root
∴ correct option is (B) Ans.

71) {x2} – x2 + 3 > 0

⇒ –[x2] + 3 > 0
⇒ [x2] < 3 ⇒ [x2] = 0,1,2
⇒ x2 ∈ [0,3)

⇒
⇒ x = –1,0,1

72) Solution :
Let
⇒ x – 1 = t2
⇒ x = t2 + 1
⇒

⇒
⇒|t – 2| + |t – 3| = |t – 2 – (t–3)|
If |x| + |y| = |x – y| ⇒ xy ≤ 0
⇒ (t – 2) (t – 3) ≤ 0
t∈[2, 3]
⇒
⇒ x – 1 ∈ [4, 9]
⇒ x∈[5, 10]
∵ Integral value of x = {5, 6, 7, 8, 9, 10}
Number of integral solution = 6

Final Answer: 6

73) 1 odd + 3 even

⇒ ƒ(1) + ƒ(2) + ƒ(3) + ƒ(4) = 1 + 2 + 2 + 2 = 7
3 odd + 1 even
⇒ ƒ(1) + ƒ(2) + ƒ(3) + ƒ(4) = 1 + 1 + 1 + 2 = 5

74)
x↔y
⇒
⇒
Take log both side
⇒
⇒
⇒

f(x) & f–1(x) intersect at x = 10.

75) a.f(4) < 0 ⇒ 1[16 – (3k – 1)4 + 5k] < 0

⇒ –7k + 20 < 0

minimum integral value of k is 3