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Redox Potential Analysis at Air Itam Dam

This document discusses redox potential measurements taken at five sites in Air Itam Dam. Redox potential indicates electron activity in water and controls chemical processes. The measurements show redox potential generally decreases near the surface due to less sunlight and oxygen, then increases from 3-10 meters as photosynthesis peaks. Redox potential is most stable at site 4, the deepest site, but most variable at the shallow site 2 due to sediment disturbances and gas exchange. Overall the center site 3 has the highest redox potential.

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0% found this document useful (1 vote)
328 views8 pages

Redox Potential Analysis at Air Itam Dam

This document discusses redox potential measurements taken at five sites in Air Itam Dam. Redox potential indicates electron activity in water and controls chemical processes. The measurements show redox potential generally decreases near the surface due to less sunlight and oxygen, then increases from 3-10 meters as photosynthesis peaks. Redox potential is most stable at site 4, the deepest site, but most variable at the shallow site 2 due to sediment disturbances and gas exchange. Overall the center site 3 has the highest redox potential.

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© Attribution Non-Commercial (BY-NC)
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  • Introduction to Redox Potential
  • Understanding Redox Potential
  • Study Sites Overview
  • Depth versus Redox Potential Analysis
  • Site-Specific Observations
  • Conclusion

REDOX

POTENTIAL
( Air Itam Dam )

By : Fong Liang and Ayun


Redox Potential :
 Electrode – dependant parameter
 Giving measure of electron activity in waters
 Largely control the chemical process occur in
nature
 Decrease in redox potential can brought by
anaerobic biological process
 Measure the competing process of electron
(reduction) or acceptance (oxidation)
Site 3
Site 4
Site 1 Site 2 Site 5
Depth vs Redox Potential

Redox Potential (mV)


0 200 400 600
0

10 s
Depth Zone 2
(m) 15 Zone 3
Zone 4
20

25

30
Site 2
 Reading are rather fluctuated
 Site are more exposed to sunlight compare to site
3 and site 4
 At surface, redox potential reading drops due to
minimum gaseous exchange
 2-4m, redox potential increase, photosynthesis at
maximum rate
 > 4m, aerobic process reduce, DO getting less,
redox potential drops
Site 3
 Strong sunlight penetration on surface, redox potential
decrease from 0-3m
 At 3-6m, reading increase rapidly and remain up to 11m.
Sunlight penetration and water temperature at optimal
level for photosynthesis
 Redox potential reduced slightly, fluctuating ranging
between 414-420mV at depth 12-20m ‘cause aerobic
activities slow down
 Reading increase after 20m depth and shoot up at 25m.
DO increase, there’s underflow from river 2 (site 5) at
bottom site 3
Site 4
 Higher temperature and strong sunlight penetration,
redox potential decrease at 0-2m
 Between 2-10m, redox potential increase rapidly.
Photosynthesis at maximum rate
 Sunlight no longer penetrate deep into water at 10-15m,
redox potential decrease
 Redox potential stay at 360mV at 15-27m. It’s the
largest constant range, also the deepest site. Water
temperature and DO almost constant
 Due to underflow from river 2 (site 5), there’s increasing
of redox potential after 27m
Conclusion
 Generally, redox potential reading decreases at the
surface area and increases after 3m from surface
 Site 2 has the most fluctuated redox potential
between the 3 sites because it is the shallowest site.
Sedimentation and gaseous changes are not constant
 Site 3 has the highest redox potential reading among
3 sites. It is the centre of the lake and rather deep.
Aquatic animals tends to move around from one end
to another end of the lake will bypass the center

Common questions

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Underflow from connecting rivers, such as river 2 at Site 5, introduces fresh water with different chemical properties that can increase the DO levels at the lake's various sites, particularly at greater depths, subsequently enhancing the redox potential. At Site 3, the underflow causes redox potential to increase after 20 meters due to the influx of oxygen-rich water, while similar effects are observed at Site 4 beyond 27 meters, contributing to fluctuations at deeper depths .

Site 3 has the highest redox potential due to its location at the center of the lake, which is deeper and more stable compared to other sites. This central position facilitates enhanced photosynthetic activity because optimal sunlight penetration and water temperature exist at certain depths. Additionally, the movement of aquatic life and the underflow from river 2 contribute to fluctuations that increase dissolved oxygen levels and maintain a high redox potential .

At Site 4, redox potential remains constant between 15-27 meters, indicating a stable aquatic environment where water temperature and DO levels are maintained. This stability can be attributed to the reduced influence of sunlight and photosynthesis beyond 10 meters and the consistent water conditions due to minimal external disturbances and a balance between aerobic and anaerobic processes .

Decreases in redox potential near the surface of water bodies are primarily due to limited gaseous exchange and increased temperatures that reduce DO availability. Strong sunlight accelerates these conditions by enhancing biological activity that consumes more oxygen, leading to lower redox potential values. Additionally, fluctuations in sedimentation can introduce variations in available electrons, causing further reductions in redox potential .

Site 2 experiences the most fluctuated redox potential owing to its shallowness, which means sedimentation and gaseous changes are not constant. The exposure to sunlight further contributes to these fluctuations, making the redox potential less stable compared to Sites 3 and 4, where the depth and environmental conditions allow for a more consistent redox profile .

Maximum photosynthesis rates, occurring at specific depths such as 2-10 meters at Site 4, significantly increase redox potential. Optimal conditions of sunlight and temperature enable higher rates of oxygen production, enhancing electron acceptance and raising redox potential levels. This phenomenon indicates zones of robust ecological activity crucial for maintaining balanced aquatic ecosystems by supporting aerobic organisms and mediating chemical processes .

Changes in dissolved oxygen levels directly impact redox potential, as oxygen is a powerful electron acceptor in oxidation-reduction reactions. At shallower depths, such as 0-4 meters, redox potential decreases due to reduced DO from limited gaseous exchange and high temperatures. As one moves deeper, DO levels rise due to optimal photosynthesis, increasing redox potential. However, at depths beyond optimal photosynthesis levels, such as >10 meters at Site 4, a decrease in sunlight and DO reduces redox potential until other factors, like underflow, increase DO again at greater depths .

The geographical location and depth of a site in a lake significantly influence its redox potential profile. Shallow sites, like Site 2, experience greater fluctuations due to variable sedimentation and gaseous exchange. Sites like Site 3, located centrally and deeper, maintain higher redox potential due to consistent aquatic activity, optimal sunlight penetration, and DO levels. Geographical factors like proximity to inflows (e.g., underflow from river 2 at Site 5) also introduce variations at greater depths, enhancing redox potential .

At Site 2, the redox potential readings are fluctuated due to the site's exposure to sunlight and its shallow depth, which affects sedimentation and gaseous exchanges. At the surface, the redox potential drops because of minimal gaseous exchange. Between 2-4 meters, the redox potential increases as photosynthesis achieves its maximum rate. Beyond 4 meters, aerobic processes decrease, leading to a reduction in dissolved oxygen (DO) and a subsequent drop in redox potential .

Sunlight penetration affects the redox potential by influencing photosynthesis rates. At all sites, strong sunlight at the surface initially reduces redox potential due to increased temperature and direct exposure. As depth increases, optimal sunlight penetration between certain depths stimulates maximum photosynthesis rates, leading to a higher redox potential as observed between 3-6 meters at Site 3, and 2-10 meters at Site 4. Beyond these depths, reduced sunlight decreases photosynthesis and thus redox potential decreases until settling at deeper levels .

 
 
REDOX 
POTENTIAL
 ( Air Itam Dam ) 
By : Fong Liang and Ayun
Redox Potential :
Electrode – dependant parameter
Giving measure of electron activity in waters
Largely control the ch
 
 
Site 2
Site 3
Site 4
Site 1
Site 5
Site 2
Site 3
Site 4
Site 1
Site 5
 
 
Depth vs Redox Potential
0
5
10
15
20
25
30
0
200
400
600
Redox Potential  (mV)
Depth
(m)
Zone 2
Zone 3
Zone 4
s
Site 2
Reading are rather fluctuated
Site are more exposed to sunlight compare to site 
3 and site 4
At surface, redox
Site 3
Strong sunlight penetration on surface, redox potential 
decrease from 0-3m
At 3-6m, reading increase rapidly an
Site 4
Higher temperature and strong sunlight penetration, 
redox potential decrease at 0-2m
Between 2-10m, redox poten
Conclusion
Generally, redox potential reading decreases at the 
surface area and increases after 3m from surface
Site 2

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