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Solution Properties in Mixtures Tutorial

This document contains solutions to two questions: Q1 solves for the molar fractions of liquid and vapor in a multicomponent system using phase equilibrium equations. Q2 defines three types of properties in solutions - solution properties represent the mixture as a whole, partial properties belong to individual species in the solution, and pure species properties are those of individual species without other species present at the same pressure and temperature. It then proves values for the infinite dilution partial molar volumes of two species in a solution at different molar fractions.

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4 views6 pages

Solution Properties in Mixtures Tutorial

This document contains solutions to two questions: Q1 solves for the molar fractions of liquid and vapor in a multicomponent system using phase equilibrium equations. Q2 defines three types of properties in solutions - solution properties represent the mixture as a whole, partial properties belong to individual species in the solution, and pure species properties are those of individual species without other species present at the same pressure and temperature. It then proves values for the infinite dilution partial molar volumes of two species in a solution at different molar fractions.

Uploaded by

RafiHunJian
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Tutorial 4 Solution

Q1

L +V=1
L is moles of
liquid/molar fraction
of liquid, with mole
fraction xi
V is moles of
vapor/molar fraction
of vapor, with mole
fraction yi.

Xi=yi/Ki
0.578/10=0.0578
0.1083/2.05=0.0528
0.1862/0.67=0.2779
0.1279/0.21=0.609
Sum xi=1

Q2:
Solution properties: properties that represent the solution as a whole mixture.
Partial properties: properties belong to the species that exist in the solution.
Pure species properties: properties of the individual species as they exist in the pure state without
the presence of other species at the same P and T of the solution.
1

Q2
(i)

Prove the values

V1 ( x1 0.01) 14 x13 20 x12 2 x1 128


V1 127.8cm 3 / mol
V 2 ( x1 0.99) 70 x12 14 x13
V 2 84.7cm 3 / mol

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