CHAPTER 9:
CHEMICAL
QUANTITIES
Lets Start with a CHAPTER 8 Review
9.1 Grilled Cheese Problem
I want to have a grilled cheese party. They
require two slices of bread and one slice
of cheese. So how many grilled cheese
can I make if I have 5 slices of cheese
and a loaf of bread with 10 slices?
Step 1: Write Out the Recipe
Step 2: Find the Quantity and Ratios
Step 3: Use the Ratio to Obtain Units
SMORES STOICHIOMETRY
Equation
We have...
So we can make...
Lab Information: Calculations
CuSO4 * X H2O (s) CuSO4 (s) + X H2O (g)
You know empty crucible + cover
You know mass of blue vitriol
You know final mass after heating
Follow empirical formula steps
% Yield vs. % Error
Lab Information: Discussion
CuSO4 * X H2O (s) CuSO4 (s) + X H2O (g)
Describe two sources of error
One should be the heating process
The other could be from your procedure
Describe how they impact your data
DO NOT TALK ABOUT THE SCALE!
C3H8 (g) +
Molecules:
Moles:
Molecule #:
Grams:
O2 (g)
CO2 (g) +
H2O (l)
2 H2 (g) + 1 O2 (g) 2 H2O (l)
We can make many mole ratios here, 6 to be exact
9.2 C3H8 (g) +
O2 (g)
CO2 (g) +
H2O
(l) with oxygen, how many
If 2 moles of propane react
moles of water will be produced?
If 2.5 moles of oxygen react, how many moles of
carbon dioxide will be produced?
Intro to STOICHIOMETRY
Mole Ratios = a unit conversion, comes from
coefficients in a balanced equation, gets us from A to B
Stoichiometry = THE PROCESS, the calculation of
quantities of reactants and products in reactions
MOLEMOLE CALCULATIONS
Convert moles of starting
substance to moles of
desired substance
How many moles of O2 are required to make 0.75 moles H2O?
H2 (g) + O2 (g) H2O (l)
1. Always start with a balanced equation!
2. Convert moles of (A) to moles of desired substance (B) using
your coefficients as a ratio
3. Convert the moles of (B) to the units in the problem
How many moles of H2 are needed to react with 0.35 moles of oxygen?
2 H2 (g) + 1 O2 (g) 2 H2O (l)
STOICHIOMETRY
Lets Review Mole-Mole Problems!
9.4 MOLEMASS CALCULATIONS
1) Convert quantity of starting substance from
grams into moles
2) Convert moles of starting substance to moles of
desired substance using a molar ratio!
How many grams of water is produced when 3.68 mol NH3
combines with oxygen according to the following equation?
NH3 (g) +
O2 (g)
NO(g) + H2O(g)
STOICHIOMETRY
Lets Review Mole-Mass Problems!
9.5 MASSMASS CALCULATIONS
Convert quantity of starting substance
to moles (if moles are not given)
Convert moles of starting substance to
moles of desired substance
Convert moles of desired substance to
the units specified in the problem
STOICHIOMETRY
Lets Review Mass-Mass Problems!
9.6 LIMITING REACTANTS
9.6 LIMITING REACTANTS
The reactant which limits how much product can form
It is also the reactant completely used up in the reaction
1. Calculate the mols of reactants
2. Choose mols of one substance, and
determine the mols needed of the other
3. Determine limiting reactant by
comparing the mols to needed #
4. Carry out calculations based on which
is the limiting reactant
You have 10g H2 and 100g O2, which is LR & XS? How many g H2O?
2 H2 + O2 2 H2O
Some of the acid in acid rain is produced by the following reaction:
3 NO2 (g) + H2O (l) 2 HNO3 (aq) + NO (g)
If a falling raindrop of 0.050 grams comes into contact with 1.0 mg of NO2, how
many grams of HNO3 can be produced?
How to Write a Scientific Lab Report
1. Follow your rubric to see what is required.
2. Turn in all required materials with your lab, on time
3. Your purpose should be explaining how the lab
related to class material, and new equipment used.
For example: The purpose was to find the formula of blue vitriol.
We heated it and evaporated the water VS...
Our purpose was to dehydrate the cupper sulfate, using some
new tools such as the crucible, cover, and clay triangle. We also
found the percent error. We used our knowledge of moles and
empirical formula to solve the question of chemical formula
How to Write a Scientific Lab Report
1. Your pre-lab questions need to be complete
2. Observations should be thorough, and specific
3. Calculations should be clear, circled, thought out
For example: It was blue. Then it turned white VS.
The CuSO4 was a brilliant cerulean blue, with jagged edges,
and a mirror-like surface. Halfway through heating, it appeared
to lose much of its color, turning a greyish white. At the end of
the heating, it appeared to be very chalky and all white.
How to Write a Scientific Lab Report
The discussion is the MAIN part of your report, it should be the
longest, most thought out and intensive part. Sources cited.
Errors not only explained in depth, but related back to data.
For example: We knocked over our crucible and it was bad VS
We left the cover off our crucible for a short period of time
before weighing our CuSO4 after the first heating. A small
amount of water may have reabsorbed into the compound,
changing our data so that the percent of water would be greater
in the compound, and would lead to a greater percent error
PERCENTAGE YIELD
Most reactions fail to give us 100% yield
Theoretical how much we could get
Actual how much we actually get
Percent the ratio of difference
STOICHIOMETRY
Lets Review LR & XS Problems!
STOICHIOMETRY DEMO
Vinegar + Baking Soda Balloon Race
How many grams of Fe3O4 can be obtained by reacting 16.8g Fe with
10.0g water? Which substance is the LR and which is the XS?
3 Fe(s) + 4 H2O (g) Fe3O4 (s) + 4 H2 (g)
Concept Review
Reactants & Products
Empirical Formula
Balancing Equations
Molecular Formula
Moles
Mole Ratios
Particles
Stoichiometry
Molar Mass
Percent Yield
Percent Calculations
Limiting Reactant
Cookie Problem
Cookie Monster Needs 100 Cookies STAT! You find this old recipe
4 Tablespoons Unsalted Butter
1/3 Cup Brown Sugar
1/3 Cup White, Granulated Sugar
1 Egg
1 Cup All Purpose Flour
1 Tablespoon Cornstarch
1/2 teaspoon Baking Soda
1/4 teaspoon Kosher Salt
Makes 20 cookies USE STOICHIOMERY!
Ingredients for one batch
Batches
Total Amount
9.1 Cookie Problem
Grocery List
4 Tablespoons Unsalted Butter
x5
20 Tbsp Unsalted Butter
1/3 Cup Brown Sugar
x5
5/3 Cup Brown Sugar
1/3 Cup White, Granulated Sugar
x5
5/3 Cup White, Granulated Sugar
1 Egg
x5
5 Eggs
1 Cup All Purpose Flour
x5
5 Cups All Purpose Flour
1 Tablespoon Cornstarch
x5
5 Tbsp Cornstarch
1/2 teaspoon Baking Soda
x5
2.5 tsp Baking Soda
1/4 teaspoon Kosher Salt
x5
1.25 tsp Kosher Salt