inl Rheochem (Pty) Ltd ag Na DUO Unit 7, 8 Read Place, Maxmead P.O Box 744, Westville, 3630 1034 700 3700 » Fax 031 700 3730 « email: gen@[Link] MATERIAL SAFETY DATA SHEET PISS RHEOFLOC 5113XI Mo 4 THIS PRODUCT MUST NOT, UNDER ANY CIRCUMSTANCES, BE MIXED WITH SODIUM HYPOCHLORITE. DOING SO WILL RESULT IN A SPONTANEOUS REACTION AND AN IMMEDIATE RELEASE OF NOXIOUS: GAS SUPPLIER'S NAME RHEOCHEM (PTY) LTD. SUPPLIER'S ADDRESS P.O BOX 744 WESTVILLE 3630 SUPPLIER'S TEL. NO, 031 700 3700 EMERGENCY TEL. NO. 082 880 2184 CONTACT PERSON J. SWART. CURRENT ISSUE DATE JANUARY 2017 MANUFACTURER'S NAME : RHEOCHEM (PTY) LTD MANUFACTURER'S ADDRESS. UNIT 9 REED PLACE 8 REED ROAD, MAXMEAD, 3610 4, IDENTIFICATION OF THE SUBSTANCE TRADE NAME: RHEOFLOC §113X! CHEMICAL NAME: ALUMINIUM CHLORIDE, BASIC (POLYALUMINIUM CHLORIDE) 2. COMPOSITION/INFORMATION ON INGREDIENTS, CAS NO.: 1827-41-9 ALUMINIUM CHLORIDE, BASIC IDENTIFICATION NUMBER (S): EINECS NO.: 216-477-2 ADDITIONAL INFORMATION: MOLECULAR FORMULA; ACIS MOLECULAR WEIGHT: 241.43 3, HAZARD IDENTIFICATION CLASSIFICATION OF THE SUBSTANCE OR MIXTURE CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008: VvoID CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR DIRECTIVE 1999//45/EC: NOT APPLICABLE INFORMATION CONCERNING PARTICULAR HAZARDS FOR HUMAN AND ENVIRONMENT: NOT APPLICABLE WP0S2 - RHEOFLOC 613K Revision: 03 Date: January 2017, Page 1 of63. HAZARD IDENTIFICATION (CONTINUED) LABEL ELEMENTS: LABELLING ACCORDING TO REGULATION (EC) NO 1272/2008: HAZARDS PICTOGRAMS: VOID SIGNAL WORD: VOID HAZARD DETERMINING COMPONENTS OF LABELLING: VOID HAZARD STATEMENTS: VOID LABELLING ACCORDING TO EU GUIDELINES: ‘THE SUBSTANCE IS NOT SUBJECT TO CLASSIFICATION ACCORDING TO EU LISTS AND OTHER SOURCES OF LITERATURE KNOWN TO US, OBSERVE GENERAL SAFETY REGULATIONS WHEN HANDLING CHEMICALS. FIRST AID MEASURES GENERAL INFORMATION: INHALATION: SKIN CONTACT: EYE CONTACT: SWALLOWING: INFORMATION FOR DOCTOR: NOTE: Fi TING MEASURES SUITABLE EXTINGUISHING AGENTS: PROTECTIVE EQUIPMENT: NO SPECIAL MEASURES REQUIRED REMOVE PERSON TO NON-CONTAMINATED AIR. GET IMMEDIATE MEDICAL ATTENTION. WASH SKIN THOROUGHLY WITH SOAP AND WATER, REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION SHOULD DEVELOP. IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO. ENSURE FLUSHING OF THE ENTIRE SURFACE. WASHING WITHIN ONE MINUTE IS ESSENTIAL TO ACHIEVE MAXIMUM EFFECTIVENESS, SEEK MEDICAL ATTENTION. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL HELP IMMEDIATELY. IF POSSIBLE GIVE LARGE AMOUNTS. OF WATER TO DRINK. IF VOMITING SHOULD OCCUR SPONTANEOUSLY, KEEP AIRWAYS CLEAR. ALUMINIUM SOLUBLE SALTS MAY CAUSE GASTROENTERITIS IF INGESTED. TREATMENT INCLUDES ‘THE USE OF DEMULCENTS. CONSIDERATION SHOULD BE GIVEN TO THE POSSIBILITY ‘THAT OVEREXPOSURE TO MATERIALS OTHER THAN THIS PRODUCT MAY HAVE OCCURRED. PRODUCT DOES NOT BURN. USE WATER TO KEEP CONTAINERS COOL, FIREFIGHTERS SHOULD WEAR FULL-FACE, SELF CONTAINED BERATING APPARATUS AND IMPERVIOUS PROTECTIVE CLOTHING. FIREFIGHTERS SHOULD AVOID INHALING ANY COMBUSTION PRODUCTS. [weoa2- RHEOFLOG s115x1_—_| Revision: 03 Date: January 2017, Page 2 of 6ACCIDENTAL RELEASE MEASURES (SPILLAGE) PERSONAL SAFETY PRECAUTIONS: ENVIRONMENTAL PRECAUTIONS: MEASURES FOR CLEANING/COLLECTING: FOR LARGE SPILLS: FOR SMALL SPILLS: ADDITIONAL INFORMATION: HANDLING AND STORAGE HANDLING: INFORMATION FOR SAFE HANDLING: INFORMATION ABOUT FIRE - AND EXPLOSION PROTECTION: STORAGI REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES: INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY: FURTHER INFORMATION ABOUT ‘STORAGE CONDITIONS: ‘SPECIFIC APPLICATIONS: PRODUCT IS AN IRRITANT TO EYES AND A SENSITIZER TO. SKIN, USE ALL NECESSARY MEANS TO CLEAN UP SPILL. SAFELY. PROVIDE ADEQUATE VENTILATION TO SPILL AREA, APPROVE BREATHING APPARATUS MAY BE NECESSARY, (00 NOT ALLOW TO ENTER SEWERS/SURFACE OR GROUND WATER. STOP LEAKS. CLEAN UP SPILL IMMEDIATELY. BUILD DIKES AS NECESSARY TO CONTAIN FLOW OF LARGE SPILLS, DO NOT ALLOW LIQUID TO ENTER STREAM OR WATERWAYS. USE SODA ASH TO NEUTRALIZE, AND INERT MATERIAL TO ABSORB, OR WASH PRODUCT TO A CHEMICAL SEWER NO DANGEROUS SUBSTANCES ARE RELEASED. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING MISTS AND SPRAYS. USE ADEQUATE VENTILATION AND EMPLOY RESPIRATORY PROTECTION WHERE MIST OR SPRAY MAY BE GENERATED. WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. MAY BE HARMFUL IF SWALLOWED OR INHALED. KEEP AWAY FROM HEAT AND OPEN FLAME. NO SPECIAL MEASURES REQUIRED. STORE IN A COOL, DRY PLACE AWAY FROM DIRECT HEAT. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE, STORE AWAY FROM INCOMPATIBLE MATERIALS. DO NOT STORE IN UNLINED METAL CONTAINERS. IT IS MAINLY USED IN THE PURIFICATION OF THE DRINKING WATER, INDUSTRY WATER, OIL FIELD RECYCLING WATER AND VARIOUS KINDS OF SEWERS. EXPOSURE CONTROL/PERSONAL PROTECTION ADDITIONAL INFORMATION ABOUT DESIGN ‘OF TECHNICAL FACILITIES: PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO. MINIMIZE WORKER EXPOSURE. \WPO82 - RHEOFLOC 51 13K! ‘ate: January 2017 Revision. 03, Page 3 of 6EXPOSURE CONTROL/PERSONAL PROTECTION (CONTINUED) INGREDIENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE: NOT REQUIRED ADDITIONAL INFORMATION: PERSONAL PROTECTIVE EQUIPMENT: GENERAL PROTECTIVE AND HYGIENIC MEASURES: RESPIRATORY PROTECTION: PROTECTION OF HANDS: PENETRATION TIME OF GLOVE MATERIAL: EYE PROTECTION: BODY PROTECTION: ‘THE LISTS VALID DURING THE MAKING WERE USED AS BASIS AVOID PROLONGED INHALATION OF HEATED VAPORS. WEAR STANDARD WORK CLOTHING AND WORK SHOES. A SAFETY SHOWER AND EYE WASH SHOULD BE LOCATED IN THE IMMEDIATE AREA. WHEN EXPOSURES EXCEED THE PEL, USE NIOSH/MSHA. APPROVED RESPIRATOR IN ACCORDANCE WITH OSHA RESPIRATORY PROTECTION REQUIREMENTS UNDER 29 CFR 1910.134. PROTECTIVE GLOVES. THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ THE SUBSTANCE? THE PREPARATION. MATERIAL OF GLOVES: THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL, BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO MANUFACTURER. THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY MANUFACTURER OF THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED. SAFETY GLASSES WITH SIDE SHIELD WORK CLOTHING SUFFICIENT TO PREVENT ALL SKIN CONTACT SHOULD BE WORN, SUCH AS COVERALLS AND LONG SLEEVES. 9, PHYSICAL DATA AND CHEMICAL PROPERTIES PHYSICAL STATE: ‘COLOUR’ ‘ODOUR: FLASH POINT: DANGER OF EXPLOSION. SPECIFIC GRAVITY: SOLUBILITY IN/MISCIBILITY WITH WATER: pH-VALUE AT 20°C: ADDITIONAL INFORMATION: CLEAR LIQUID COLORLESS TO LIGHT YELLOW NO APPRECIABLE ODOUR NOT APPLICABLE PRODUGT DOES NOT PRESENT AN EXPLOSION HAZARD. 4.19 - 1.21 GICME SOLUBLE 25-35 MISCIBILITY — MISCIBLE IN WATER \WE032 - RHEOFLOG 5113 Revision: 03, Date: January 2017 Page 4 of10. REACTIVITY AND STABILITY ‘THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED: CORROSIVE LIQUID! AVOID STORAGE IN UNLINED METAL CONTAINERS. PRODUCT MAY SLOWLY CORRODE IRON, BRASS, COPPER, ALUMINIUM AND MILD STEEL. MATERIALS TO AVOID: ALKALIS DANGEROUS REACTIONS: NO DANGEROUS REACTIONS KNOWN DANGEROUS DECOMPOSITION PRODUCTS: ‘THERMAL DECOMPOSITION MAY RELEASE TOXIC AND/OR HAZARDOUS GASES SUCH AS CHLORINE AND HYDROCHLORIC ACID. 44, TOXICOLOGICAL INFORMATION ACUTE TOXICITY: LD/LC50 VALUES RELEVANT FOR CLASSIFICATION: ORAL / LD50 / >2000 MG/KG (RAT) PRIMARY IRRITANT EFFECT: SKIN: MAY CAUSE MILD SKIN IRRITATION EYE IRRITATING EFFECT SENSITIZATION: NO SENSITIZING EFFECTS KNOWN ADDITIONAL TOXICOLOGICAL INFORMATION: «WHEN USEDAND HANDLED ACCORDING TO SPECIFICATIONS, THE PRODUCT DOES NOT HAVE ANY HARMFUL EFFECTS TO OUR EXPERIENCE AND THE INFORMATION PROVIDED TO US. «THE SUBSTANCE IS NOT SUBJECT TO CLASSIFICATION ACCORDING TO THE LATEST OF THE EU VERSIONS ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY): ‘SKIN: DERMATITUS EYE: IRRITATION AND BURNS INHALATION: NOSE AND RESPIRATORY IRRITATION INGESTION: TOXIC, NAUSEA, VOMITING, DIAHORREA, BURNS TO MUCOUS MEMBRANE, LIVER AND KIDNEY DAMAGE. CMR EFFECTS (CARCINOGENICITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION) NOT LISTED AS A CARCINOGEN BY ACGIH, IARC, NIOSH, NTP, OSHA, OR CPA PROP 65 12, ECOLOGICAL INFORMATION. NOT AVAILABLE 13. DISPOSAL CONSIDERATION PRODUCT: RECOMMENDATION: WASTES MUST BE TESTED USING METHODS DESCRIBED IN 40 CFR PART 261 TO DETERMINE IF IT MEETS APPLICABLE DEFINITIONS. ‘WP032 - RHEOFLOG 113KI Revision: 03, Date: January 2017, Page 6 of 643, DISPOSAL CONSIDERATION (CONTINUED) UNCLEANED PACKAGING: RECOMMENDATION: CONTAIN AND COLLECT USING ABSORBENT MATERIAL IF NEEDED. PLACE COLLECTED MATERIAL INTO PROPERLY LABELLED, SUITABLE CONTAINERS FOR PROPER DISPOSAL. DISPOSE OF WASTEMATERIAL ACCORDING TO LOCAL, STATE, FEDERAL AND PROVINCIAL ENVIRONMENTAL REGULATIONS, 14, TRANSPORT INFORMATION LAND TRANSPORT ADRIRID (CROSS-BORDER): ADRIRID CLASS: 7 MARITIME TRANSPORT IMDG: IMDG CLASS: - MARINE POLLUTANT: No ‘AIR TRANSPORT ICAO-TI AND IATA-DGR: ICAOMATA CLASS: - UN “MODEL REGULATION’: - 15. REGULATORY INFORMATION CHEMICAL SAFETY ASSESSMENT: ACHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT NATIONAL REGULATIONS: OTHER REGULATIONS, LIMITATIONS AND PROHIBITIVE REGULATIONS SUBSTANCES OF VERY HIGH CONCERN (SVHC) ACCORDING TO REACH, ARTICLE §7: ‘THE SUBSTANCE IS NOT LISTED AS SVHC. 16, OTHER INFORMATION USAGE / APPLICATION OF THE SUBSTANCE / THE PREPARATION: IT IS MAINLY USED IN THE PURIFICATION OF THE DRINKING WATER, INDUSTRY WATER, OIL FIELD RECYCLING WATER AND VARIOUS KINDS OF SEWAGES. DISCLAIMER RHEOCHEM (PTY) LTD PROVIDES THE INFORMATION CONTAINED HEREIN IN GOOD FAITH BUT MAKES NO REPRESENTATION AS TO ITS COMPREHENSIVENESS OR ACCURACY. THIS DOCUMENT IS. INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PROPERLY TRAINED PERSON USING THIS PRODUCT. INDIVIDUALS RECEIVING THE INFORMATION MUST EXERCISE THEIR INDEPENDENT JUDGMENT IN DETERMINING ITS APPROPRIATENESS FOR A PARTICULAR PURPOSE. RHEOCHEM (PTY) LTD MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS, ACCORDINGLY, RHEOCHEM (PTY) LTD WILL NOT BE RESPONSIBLE FOR DAMAGES. RESULTING FROM USE OR RELIANCE UPON THIS INFORMATION (Weose - RHEOFLOG 6173x1 Revision: 03, [Lost senuary 2017 Page 6 of 6