Sample no 1 2 3 4 5 6 7

Major elements

SiO2 70.54 68.87 71.56 70.59 71.52 72.86 75.74

TiO2 0.68 0.81 0.61 0.23 0.65 0.09 0.21
Al2O3 11.85 11.84 11.85 10.86 11.44 11.89 11.88
Fe2O3 6.12 6.61 5.08 5.71 5.08 2.85 2.21
FeO
MnO 0.1 0.11 0.07 0.1 0.08 0.06 0.04
MgO 0.87 0.87 0.77 2.21 0.99 1.68 0.49
CaO 3.37 4.12 2.53 2.62 2.94 3.35 1.83
Na2O 2.05 2.15 2.88 1.98 3.09 2.98 3.08
K2O 2.69 2.36 2.88 3.55 2.63 2.27 2.51
P2O5 0.49 0.6 0.39 0.92 0.51 0.17 0.1

Total 98.76 98.34 98.62 98.77 98.93 98.2 98.09

Trace Elements (ppm)

Sc 9 12 8 17 10 5 7
V 17 22 14 40 22 25 6
Cr 21 20 23 32 22 25 26
Co 11 13 9 20 12 9 3
Ni 9 10 8 11 9 6 5
Cu 2 3 1 4 2 2 1
Zn 122 138 101 104 124 42 44
Ga 50 48 54 98 69 62 40
Rb 100 72 70 155 77 80 68
Sr 200 210 228 378 336 496 131
Y 41 40 61 70 66 11 64
Zr 42 27 29 17 26 31 107
Nb 23 27 29 17 26 3 9
Cs 0.31 0.13 0.03 0.14 0.07 0.04 0.07
Ba 1426 1287 1606 3588 2128 2002 678
La 36 34 75 140 72 32 36
Ce 77 76 150 298 153 56 76
Pr 9 9 16 33 18 6 9
Nd 39 39 66 131 76 21 42
Sm 9 9 13 25 16 4 10
Eu 2.4 2.5 2.5 3.7 3.2 1.4 2
Gd 7.2 7.1 11 18.3 12.3 2.7 8.7
Tb 1.2 1.1 1.8 2.5 1.9 0.3 1.6
Dy 7.4 7 11.1 13.7 11.9 2 11.3
Ho 0.8 0.8 1.2 1.4 1.3 0.2 1.3
Er 2.5 2.6 3.9 4.4 4.1 0.7 4.2
Tm 0.3 0.3 0.5 0.5 0.5 0.1 0.5
Yb 3.1 3.1 4.5 4.5 4.8 1 5
Lu 0.5 0.5 0.7 0.7 0.8 0.2 0.8
Hf 1.2 0.8 1.2 0.8 1.1 0.8 3.1
Ta 1.2 1.3 1 0.6 0.9 0.1 0.3
Th 8.6 0.8 3.8 6.1 2.5 2.6 0.9
U 0.15 0.04 0.1 0.15 0.05 0.23 0.64

Mg# 24 23 25 46 30 57 33
ASI 1 0.9 1 1 0.9 0.9 1.1
K2O/ Na2O 1.3 1.1 1 1.8 0.9 0.8 0.8
(La/Sm)N 2.5 2.3 3.5 3.5 2.8 4.6 2.2
(Gd/Yb)N 1.8 1.8 2 3.2 2 2.4 1.5
(La/Yb)N 7.7 7.3 11.2 20.8 10 24.3 5.3
Eu/Eu* 0.9 0.9 0.6 0.5 0.7 1.3 0.7
REE tot 196 191 358 677 375 128 207
K/Rb 224 271 342 190 283 234 308
Rb/Sr 0.5 0.3 0.3 0.4 0.2 0.2 0.5
La/Th 4 40 20 23 29 12 38
Th/U 56 22 38 41 52 11 1
Sr/Y 5 5 4 5 5 44 2
La/Nb 2 1 3 8 3 13 4
 8 9 10 11 12 13 14 15 16 17

73.98 65.88 66.41 70.98 63.34 56.65 59.46 58.27 60.69 62.13
0.25 1.15 0.46 0.25 0.99 1.23 0.88 1.03 1.03 0.63
11.88 11.85 11.97 11.87 16.38 13.67 18.15 16.4 14.48 15.8
3.38 7.56 5.59 3.48 5.72 8.71 4.63 6.24 7.87 6.3

0.05 0.13 0.1 0.05 0.12 0.13 0.05 0.08 0.1 0.09
1.11 1.25 3.24 1.82 0.76 4.04 2.65 3.27 2.34 2.51
2.34 4.56 4.52 3.69 3.57 8.25 4.15 4.81 5.3 3.55
2.63 2.54 3.93 4.11 3.11 3.33 4.55 3.86 3.39 3.68
2.74 2.39 1.76 1.83 3.9 1.49 2.73 3.09 0.75 2.36
0.07 0.83 0.37 0.19 0.55 0.21 0.52 0.48 0.25 0.22

98.43 98.14 98.35 98.27 98.44 97.71 97.76 97.53 96.2 97.27

7 15 12 6 5 10 3 5 9 7
23 50 52 28 14 62 29 28 52 37
34 21 58 29 17 56 21 36 23 69
10 23 22 12 5 23 9 9 10 13
7 14 13 7 5 13 6 7 7 10
4 3 3 3 1 3 2 3 1 4
53 182 102 75 56 57 40 46 51 45
51 61 34 37 48 20 33 41 19 38
139 76 36 38 84 48 113 83 6 101
622 311 506 584 216 109 371 390 104 243
16 51 32 13 33 26 12 27 33 17
20 25 27 15 40 158 18 54 98 106
5 34 14 8 23 9 13 18 13 14
0.36 0.14 0.02 0.01 0.25 1.83 0.7 0.33 0.02 0.37
1474 1681 566 761 1371 249 627 1100 254 833
19 59 51 25 64 20 81 71 49 43
32 130 108 45 126 43 128 137 90 76
3 15 12 5 12 4 10 13 8 7
11 66 48 18 49 20 36 52 33 27
3 13 9 4 8 4 5 8 6 5
1.5 2.9 1.4 1.1 0.3 0.1 0.1 0.3 0.2 0.2
2.2 10.4 6.7 2.7 7 4 4.2 6.9 5.8 3.7
0.4 1.6 1 0.4 0.7 0.5 0.3 0.7 0.7 0.4
2.6 9.6 5.7 2.2 5.9 4.5 2.3 5 5.8 3
0.3 1 0.6 0.2 0.5 0.4 0.2 0.4 0.5 0.3
1 3.3 2 0.8 2 1.5 0.8 1.6 2 1.1
0.1 0.4 0.2 0.1 0.2 0.1 0.1 0.1 0.2 0.1
 1.4 3.7 2.5 1 2.4 2 0.8 1.8 2.6 1.5
0.2 0.6 0.4 0.2 0.2 0.2 0.1 0.2 0.3 0.2
0.6 0.9 1 0.5 1.3 4.6 0.5 2 2.9 3.1
0.1 1.5 0.5 0.1 1.7 1.1 0.9 0.8 0.8 1.5
0.4 1.3 1.5 0.1 6.6 7.8 22.4 21.5 13.9 15.7
0.15 0.23 0.07 0.05 0.1 0.66 0.08 0.09 0.17 0.16

42 27 56 54 23 51 56 54 40 47
1 0.8 0.7 1 1.1 0.6 1 0.9 0.9 1.1
1 0.9 0.4 0.4 1.3 0.4 0.6 0.8 0.2 0.6
3.9 2.8 3.7 4.2 4.7 2.8 10.7 5.2 4.9 5.8
1.4 2.5 2.6 2.4 4.1 2.9 7.5 5.5 3.1 3.6
10.6 12 16.3 19 31.5 11.9 122.5 47.9 22.2 35.3
1.8 0.8 0.6 1.1 0.1 0.1 0.1 0.1 0.1 0.1
78 317 248 104 279 105 268 298 204 168
163 260 408 399 385 260 201 309 1095 194
0.2 0.2 0.1 0.1 0.4 0.4 0.3 0.2 0.1 0.4
51 47 35 212 10 3 4 3 4 3
3 6 20 2 67 12 273 232 84 96
40 6 16 46 7 4 31 14 3 14
4 2 4 3 3 2 6 4 4 3
 18 19 20 21 22 23 24 25 26 27

66.46 54.27 64.95 63.86 55.81 62.55 64.63 65.83 61.97 63.28
0.36 1.01 0.34 0.36 0.8 0.32 0.45 0.36 0.61 0.53
16.78 19.37 17.31 17.63 21.47 10.21 12.94 15.99 16.54 16.6
3 8.52 3.54 3.8 3.95 3.22 6.15 3.51 4.04 4.08

0.05 0.13 0.06 0.07 0.07 0.16 0.08 0.05 0.06 0.08
1.13 2.83 1.33 1.42 1.14 3.03 2.99 1.88 2.41 1.69
3.14 4.68 3.68 4.69 5.86 16.23 4.81 3.28 3.85 4.15
4.19 4.35 4.24 4.21 3.9 1.46 4.02 3.39 3.77 2.34
2.85 2.33 3.02 1.63 3.67 1.1 1.72 3.89 3.83 4.75
0.17 0.39 0.23 0.17 0.68 0.32 0.3 0.24 0.42 0.37

98.13 97.88 98.7 97.84 97.35 98.6 98.09 98.42 97.5 97.87

2 9 3 3 4 6 8 4 4 5
15 51 15 14 22 17 28 19 25 23
23 35 25 26 12 58 67 32 25 21
5 9 4 4 4 10 24 7 7 4
3 8 4 3 4 10 18 5 4 4
1 2 2 1 1 1 6 2 2 2
21 49 26 24 41 51 46 29 28 34
29 37 51 29 65 16 39 47 47 72
58 34 46 17 79 11 57 100 88 98
278 436 603 396 12 190 401 366 417 730
7 28 9 8 16 43 25 20 12 27
47 5 31 15 38 70 67 22 8 80
7 7 5 5 24 12 12 8 8 18
0.09 1.44 0.04 0.02 1.03 0.43 0.17 0.06 0.52 0.05
646 955 1608 598 2039 80 539 1427 1469 2425
23 14 24 21 58 33 67 34 23 61
40 29 44 38 105 72 124 69 44 128
4 3 4 3 10 7 11 7 4 13
14 14 17 14 39 32 44 29 17 55
3 4 4 3 7 6 7 6 4 10
0.1 0.2 0.2 0.1 0.3 0.2 0.2 0.2 0.2 0.4
2 3.1 2.3 2 4.7 5.6 5.8 4.2 2.5 7.3
0.2 0.4 0.2 0.2 0.4 0.7 0.6 0.4 0.3 0.7
1.4 4.3 1.6 1.5 3 6.7 4.5 3.5 2.1 5.2
0.1 0.4 0.1 0.1 0.2 0.6 0.4 0.3 0.2 0.4
0.4 1.7 0.5 0.5 0.1 2.5 1.4 1.2 0.7 1.6
0 0.2 0 0 0.1 0.2 0.1 0.1 0.1 0.1
 0.5 2.5 0.6 0.6 1.1 3.5 1.6 1.4 0.8 1.7
0.1 0.3 0.1 0.1 0.1 0.4 0.2 0.1 0.1 0.2
1.5 0.2 1 0.7 1.3 3.3 2.1 0.9 0.3 2.6
0.5 0.4 0.3 0.3 1.7 1.2 0.9 0.4 0.6 1.3
7.7 0.4 0.1 0.7 3.8 8.7 11.4 9.2 3.6 1.7
0.08 0.06 0.04 0.03 0.27 3.72 0.62 0.04 0.06 0.09

45 42 45 45 39 68 52 54 57 48
1.1 1.1 1 1 1.1 0.3 0.8 1 1 1
0.7 0.5 0.7 0.4 0.9 0.8 0.4 1.1 1 2
5.3 2.4 4 5.1 5.4 3.4 6.1 3.7 3.9 3.7
5.5 1.7 5.3 4.9 5.7 2.2 4.9 4.1 4.2 6.2
53.4 6.5 46.2 43.6 58.8 10.7 47.8 28.1 32.1 44
0.2 0.2 0.2 0.2 0.2 0.1 0.1 0.1 0.2 0.1
88 76 99 85 229 170 268 156 99 285
407 565 542 815 386 834 252 324 360 404
0.2 0.1 0.1 0 6.8 0.1 0.1 0.3 0.2 0.1
3 31 181 29 15 4 6 4 6 36
93 7 3 26 14 2 18 210 65 19
38 16 69 48 1 4 16 18 35 27
3 2 4 4 2 3 5 4 3 3
 28 29 30 31 32 33 34 35 36 37

59.96 67.78 73.59 72.69 73.85 79.42 71.55 73.64 65.07 69.9
0.6 1.18 0.32 0.23 0.31 0.21 0.5 0.47 0.4 0.27
18.98 10.96 11.98 11.65 11.73 9.6 11.72 11.62 13.97 16.32
6.39 7.8 3.09 3.31 3.35 2.01 4.88 3.7 4.76 2.12
4.28 1.91
0.18 0.19 0.04 0.05 0.05 0.04 0.1 0.06 0.08 0.02
0.12 1 0.64 1.78 0.55 0.54 0.5 0.83 2.59 0.85
2.97 3.67 1.88 2.77 2.1 1.05 2.26 1.92 3.6 3.54
4.19 2.18 3.07 3.26 3.48 1.92 3.06 3.19 3.77 5.17
4.85 2.67 3.77 2.73 2.95 3.37 3.22 3.22 3.87 1.34
0.17 0.81 0.21 0.24 0.23 0.1 0.36 0.34 0.28 0.1

98.41 98.24 98.59 98.21 98.6 98.26 98.15 98.99 98.38 99.42

4 7 4 4 4 3 6 4
3 21 6 16 6 4 6 8
11 44 41 46 39 62 36 43
1 15 5 9 5 3 6 6
5 16 6 8 7 4 11 8
1 2 1 2 1 1 2 1 0 2
57 98 36 30 41 28 63 47 55 17
67 61 68 45 75 46 85 71 17 8
41 109 109 125 103 157 134 142 85 9.6
128 186 206 263 250 186 206 196 781 647
29 81 59 22 43 8 65 55 13 2.2
44 40 61 33 30 74 38 71 107 59
26 30 24 8 20 11 32 26 1.6 1.3
0.03 0.15 0.11 0.32 0.08 0.38 0.27 0.18
2102 1406 1803 999 2037 1238 2274 1842 1219 465
27 58 58 60 33 80 67 68 26 4.79
64 129 127 110 74 147 145 143 50 8.1
8 14 13 10 8 12 15 14
42 63 61 37 38 45 68 63 18 3.3
9 13 12 6 9 6 13 11 4.3 0.67
1.5 0.4 0.4 0.2 0.4 0.2 0.5 0.4 1.6 0.31
6.8 11.4 9.9 4.7 6.7 4.4 10.5 9.2 3.4 0.53
0.8 1.5 1.2 0.5 0.8 0.4 1.3 1.1
6.2 13.4 10.9 3.9 7.8 2 11 9.4 2.5 0.41
0.5 1.3 1 0.3 0.7 0.1 1 0.8 0.34 0.07
2 5 3.7 1.3 2.7 0.6 4 3.2 1.2 0.2
0.2 0.4 0.3 0.1 0.2 0 0.3 0.3
 3.1 6.4 4.1 1.4 3.2 0.7 4.9 3.7 1.05 0.16
0.4 0.7 0.4 0.1 0.3 0.1 0.5 0.4 0.12 0.02
1.1 1.9 2.2 0.9 1.1 2.2 1.4 2.2 n.a. n.a.
1 2.5 1.1 0.3 1.2 1 2.1 1.9 0.5 0.12
0.1 3 3.1 39.4 1.6 11.5 9 6.6 0.92 b.d.
0.07 1.21 0.75 1.73 0.82 1.09 1.12 1.34 0.35 b.d.

4 22 31 54 27 37 18 33
1.1 0.9 1 1 0.9 1.1 1 1
1.2 1.2 1.2 0.8 0.8 1.8 1.1 1
1.8 2.7 2.9 6.4 2.4 8.7 3.2 3.6 3.8 4.5
2.7 2.4 3.3 4.5 2.8 8.8 2.8 3.4 2.7 2.7
9.1 10.1 16.1 47.7 11.7 134.1 15.2 21.2 17.4 21
0.2 0.1 0.1 0.1 0.2 0.1 0.1 0.1 1.3 1.63
170 317 303 236 186 298 342 328
979 204 288 181 238 178 199 188
0.3 0.6 0.5 0.5 0.4 0.8 0.7 0.7
207 19 18 2 21 7 7 10
2 3 4 23 2 10 8 5
4 2 4 12 6 22 3 4
1 2 2 8 2 7 2 3
 38 39 40 41 42 43 106-22 106-23 106-33 I-63-4-07

64.64 65.06 66.09 62.27 64.87 61.22 74.52 57.85 60.12 64.45
0.5 0.79 0.43 0.56 0.94 0.45 0.48
14.81 15.12 15.6 15.35 15.09 11.58 12.2 19.22 18.2 15.71
5.23 4.86 3.73 6.16 6.28 9.02 3.1 5.54 5.79 4.41
4.71 4.37 3.35 5.54 2.79 4.98 5.21
0.07 0.06 0.06 0.07 0.04 0.16 0.06 0.13 0.12 0.07
2.59 1.74 2.12 2.49 0.92 2.68 0.86 2.42 0.84 1.43
3.92 3.43 4.05 4.32 4.05 6.55 2.37 6.51 3.07 2.74
3.65 3.81 4.7 3.72 3.43 2.85 2.84 4.67 3.52 3.88
3.61 3.89 1.93 3.52 3.53 3.45 2.98 2.69 6.08 5.77
0.24 0.41 0.17 0.25 0.49 0.9 0.04 0.11 0.19 0.11

99.26 99.17 98.87 98.71 99.61 98.86 99.19 99.49 98.8 99.33

36 122 7.2 14.3 23

20 14 36 82 11 66
10 15 1 38
53 24 25
8 18 3 9 0 12
57 25 12 47 3 1 16
59 49 63 60 45 54 58 75
19 19 19 21 20 53 20 17 22
88 109.3 31 87.5 42 65 63.4 57.4 122.4 126
651 685 710 616 477 491 259 526 494 497
20.9 14.9 9.7 21.4 37 57 14.6 14.1 31.9
128 203 88 152 16 68 166 131 876 246
9.1 19.8 2.9 11.4 24 31 8.4 6.7 34.9

1272 1380 940 1389 856 744 3128 1113

42.28 54.71 16.5 52.53 135.66 20.83 58.14 35
83.6 102.1 37 100.2 243.2 35.8 114.8 88

36.6 35 15 38.9 80.6 16.2 45.1

6.83 5.61 2.9 6.68 10.96 3.42 8.68
1.6 1.68 1.25 1.77 1.22 1.23 3.13
5.25 3.93 2.1 5.2 6.73 2.97 7.6

3.95 2.71 1.75 4.06 3.63 3 6.79

0.77 0.52 0.22 0.78 0.65 0.6 1.3
2.04 1.43 0.8 2.19 1.59 1.69 3.69
 1.77 1.35 0.7 1.97 1.35 1.6 3.49
0.26 0.21 0.08 0.29 0.19 0.24 0.58
n.a. n.a. n.a. n.a.
0.34 1.38 0.5 0.68 2.57 1.84 1.97
0.21 1.51 0.69 0.04 32.37 4.95 8.6
0.12 0.25 0.41 0.13 0.4 0.42 0.88

3.9 6.1 3.6 4.9 7.7 3.8 4.2

2.4 2.4 2.5 2.2 4.1 1.5 1.8
16.8 28.4 16.6 18.8 70.8 9.1 11.7
0.83 1.11 1.57 0.93 0.44 1.2 1.2
I-102-1-07

63.72
1.02
11.66
11.24

0.11
3.48
4.25
2.04
1.89
0.06

99.56

204
161

52

57

35
188

364

854
31
50
 sandstone
Sample no U-1 B-1 B-2 B-3 B-4 B-5 B-6 B-7 B-8

Major Elements

SiO2 74.17 84.81 78.98 83.15 83.27 84.37 73.53 81.49 83.72
Al2O3 19.94 13.39 18.37 14.59 14.45 13.79 22.9 17.19 14.93
TiO2 0.94 0.33 0.48 0.27 0.43 0.4 0.78 0.49 0.3
Fe2O3 4.43 1.32 1.83 1.78 1.66 1.3 1.65 0.71 0.91
MnO 0.03 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01
MgO 0.09 0.01 0.07 0.06 0.01 0.01 0.19 0.01 0.01
CaO 0.08 0.03 0.05 0.04 0.03 0.02 0.07 0.02 0.02
Na2O 0.01 0.01 0.01 0.01 0.01 0.01 0.29 0.01 0.01
K2O 0.22 0.08 0.12 0.09 0.12 0.09 0.11 0.06 0.09
P2O5 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01

Total 99.9 99.96 99.88 99.97 99.97 99.97 99.51 99.96 99.97

Trace Element

Sc 5.81 4.72 5.49 4.97 6.26 5.45 5.75 3.61 3.66

V 75 37 44 37 42 37 51 25 26
Cr 13.2 47.8 39.7 44.4 37.4 36.4 49.7 33.9 60.2
Co 3.95 1.94 2.44 1.98 2.21 1.86 2.54 1.44 1.68
Ni 26.8 17.5 19.3 19.2 21.2 17.6 15 10.9 30.2
Cu 30.8 14.6 14.8 32.3 14.6 13.3 13.5 11.6 12.9
Zn 44.6 19.6 22.1 19.7 22.5 21.1 31.8 20.9 12.7
Ga 11.7 8.76 9.9 8.72 10.79 10.31 12.36 8.01 6.6
Rb 8.49 4.37 5.01 4.23 7.33 5.47 3.02 1.95 3.33
Sr 13.91 8.16 8.67 7.57 9.58 8.65 9.2 6.36 6.74
Y 11.16 6.81 7.92 9.84 7.61 6.47 6.86 4.42 5.06
Zr 671 1357 1605 1302 1410 1422 1483 1381 1276
Nb 19.35 4.89 5.93 3.3 6.15 5.76 9.42 5.01 3.25
Cs 25.27 1.42 1.64 1.46 2.06 1.68 1.01 0.89 1.2
Ba 59.8 45.3 51.5 43.3 46.5 44.5 45.4 38.6 44.8
La 32.65 14.22 15.68 29.84 19.66 22.51 15.03 6.94 9.53
Ce 75.36 21.19 19.56 50.47 25.82 27.78 21.03 9.63 17.9
Pr 4.22 2.26 2.67 5.85 2.82 3.12 2.62 1.23 1.61
Nd 18.36 7.03 8.44 19.62 8.01 9.1 8.11 3.73 5.03
Sm 3.36 1.11 1.31 2.94 1.21 1.25 1.21 0.55 0.79
Eu 0.59 0.19 0.26 0.25 0.23 0.16 0.23 0.13 0.15
Gd 2.8 1.08 1.43 2.94 1.26 1.3 1.2 0.61 0.74
Tb 0.32 0.19 0.24 0.43 0.2 0.19 0.21 0.12 0.13
Dy 2.45 1.24 1.51 2.11 1.3 1.19 1.37 0.74 0.86
Ho 0.47 0.25 0.3 0.38 0.28 0.24 0.28 0.16 0.19
Er 1.28 0.78 0.94 1.03 0.86 0.78 0.84 0.63 0.63
Tm 0.3 0.16 0.18 0.16 0.17 0.16 0.18 0.12 0.12
Yb 1.79 1.02 1.19 1.13 1.1 0.99 1.11 0.79 0.81
Lu 0.3 0.18 0.2 0.18 0.19 0.18 0.22 0.14 0.15
Hf 37.63 35.11 40.75 32.92 35.59 35.6 38.1 35.05 32.36
Ta 5.36 0.31 0.39 0.24 0.41 0.38 0.55 0.29 0.27
Pb 2.08 7.96 8.65 8.48 8.47 8.97 9.29 7.59 7.23
Th 9.02 4.5 5.19 11.71 6.49 7.13 7.6 2.77 3.97
U 0.84 0.61 0.67 0.67 0.66 0.6 0.69 0.48 0.54

Th/Sc 1.74 0.96 0.95 2.36 1.04 1.31 1.32 0.77 1.08
La/Sc 6.31 3.02 2.86 6 3.14 4.13 2.61 1.92 2.6
La/Co 8.26 7.32 6.42 15.1 8.9 12.08 5.92 4.81 5.66
Co/Th 0.44 0.43 0.47 0.17 0.34 0.26 0.33 0.52 0.42
Cr/Th 1.46 10.61 7.65 3.79 5.77 5.11 6.53 12.26 15.18
Zr/Sc 1.3 288 292 262 225 261 258 383 349
Th/U 10.76 7.44 7.76 17.6 9.87 11.9 10.97 5.73 7.42
La/Yb CN 12.65 9.71 9.11 18.27 12.42 15.7 0.44 6.06 8.16
La/Sm CN 6.08 8.05 7.48 6.35 10.14 11.2 7.79 7.96 7.56
Gd/Yb CN 1.29 0.88 0.99 2.15 0.95 1.09 0.9 0.64 0.76
Eu/Eu* CN 0.59 0.54 0.58 0.26 0.57 0.39 0.57 0.67 0.58
La/Sm UN 1.47 1.95 1.81 1.54 2.46 2.72 1.89 1.93 1.83
Gd/Yb UN 0.77 0.52 0.59 1.27 0.56 0.65 0.53 0.38 0.45
Lu/Ho UN 1.71 1.91 1.77 1.28 1.84 1.99 2.03 2.23 2.1
Eu/Eu*UN 0.84 0.77 0.82 0.37 0.81 0.55 0.82 0.96 0.82
P-1 P-2 P-3 P-4

85.65 87.89 85.56 82.2

12.77 10.58 12.77 15.95
0.34 0.29 0.33 0.32
0.99 1.08 1.15 1.34
0.01 0.01 0.01 0.01
0.05 0.01 0.01 0.01
0.05 0.04 0.05 0.03
0.01 0.01 0.01 0.01
0.11 0.09 0.1 0.12
0.01 0.01 0.01 0.01

99.96 99.96 99.96 99.97

4.38 3.65 4.78 4.22

31 31 31 31
47.6 44.7 45.7 36.6
2.01 1.85 2.07 1.72
21.1 19.9 19.4 16.1
20.3 18.2 20.9 17.5
25.9 17.1 20.9 16
8.63 6.38 9.63 7.09
5.41 3.69 5.43 3.52
9.5 7.43 9.11 6.53
4.9 4.37 5.59 4.23
205 184 206 183
4.45 3.85 4.83 3.43
0.74 0.45 0.72 0.47
43.9 37.1 44.1 37.9
20 12.17 18.7 12.42
22.68 18.7 23.2 17.3
2.55 1.93 2.57 1.51
7.2 6.23 7.58 4.45
1 1.04 1.26 0.7
0.16 0.16 0.19 0.15
1.08 0.96 1.23 0.69
0.17 0.16 0.19 0.13
0.93 0.89 1.14 0.83
0.19 0.18 0.23 0.15
0.56 0.48 0.64 0.51
0.1 0.09 0.11 0.09
0.64 0.57 0.67 0.57
 0.1 0.1 0.11 0.09
6.33 5.65 6.36 5.32
0.25 0.19 0.23 0.2
12.04 10.87 12.56 11.25
4.38 3.31 4.36 2.42
0.4 0.4 0.52 0.39

1 0.91 0.91 0.57

4.56 3.34 3.92 2.94
9.94 6.57 9.03 7.21
0.46 0.56 0.48 0.71
10.87 13.53 10.48 15.16
47 51 43 43
10.98 8.27 8.45 6.19
21.6 14.91 19.39 15.14
12.51 7.33 9.31 11.18
1.39 1.4 1.52 1.01
0.47 0.5 0.46 0.67
3.03 1.78 2.26 2.71
0.83 0.83 0.9 0.6
1.39 1.45 1.3 1.63
0.68 0.71 0.66 0.95
Sample no mudstone
B-9 P-5 P-6
Major Elements

SiO2 63.1 60.43 62.33

Al2O3 30.7 32.77 32.05
TiO2 1.22 1.5 1.37
Fe2O3 4.07 4.51 3.67
MnO 0.01 0.01 0.01
MgO 0.12 0.13 0.09
CaO 0.08 0.2 0.14
Na2O 0.12 0.01 0.01
K2O 0.18 0.22 0.17
P2O5 0.01 0.07 0.01

Total 99.59 99.83 99.83

Trace Element

Sc 13.44 14.51 12.47

V 144 155 144
Cr 299.9 276.1 247.5
Co 4.82 3.95 3.48
Ni 27.5 34.4 28.2
Cu 30 32.7 26.5
Zn 45.6 44.1 39.3
Ga 27.49 28.52 27.07
Rb 5.62 6.48 4.61
Sr 15.37 17.44 10.75
Y 10.18 15.78 13.77
Zr 681 289 360
Nb 13.7 14.81 14.11
Cs 0.92 0.46 0.4
Ba 73.9 88.7 80.4
La 15.79 67.29 33.05
Ce 20.34 96.03 57.29
Pr 2.86 13.15 5.89
Nd 9.97 45.84 20.58
Sm 1.79 7.18 3.1
Eu 0.44 1.29 0.52
Gd 1.57 5.71 2.79
Tb 0.31 0.78 0.44
Dy 2.03 3.62 2.49
Ho 0.46 0.72 0.56
Er 1.34 2 1.61
Tm 0.23 0.26 0.25
Yb 1.71 1.92 1.95
Lu 0.27 0.28 0.3
Hf 17.07 7.8 9.79
Ta 0.84 0.75 0.85
Pb 22.4 28.26 26.78
Th 10.17 11.51 10.03
U 1.37 2.09 1.15

Th/Sc 0.76 0.79 0.8

La/Sc 1.17 4.64 2.65
La/Co 3.27 17.02 9.5
Co/Th 0.47 0.34 0.35
Cr/Th 29.49 23.99 24.68
Zr/Sc 51 20 29
Th/U 7.4 5.51 8.7
La/Yb CN 6.4 24.31 11.74
La/Sm CN 5.51 5.86 6.67
Gd/Yb CN 0.76 2.46 1.18
Eu/Eu* CN 0.8 0.61 0.53
La/Sm UN 1.34 1.42 1.62
Gd/Yb UN 0.45 1.46 0.7
Lu/Ho UN 1.6 1.04 1.44
Eu/Eu*UN 1.14 0.87 0.76
 granite

SAMPLE ID 105-46 SI10-80 SI10-84 SI10-101 SI10-102 SI10-105 SI10-107 106-76 105-22
SL 1 2 3 4 5 6 7 8 9

MAJOR ELEMENTS

SiO2 70.55 75.23 71.43 71.07 75.09 73.58 72.81 73.06 73.46
Al2O3 15.32 13.65 15.81 14.48 14.09 14.4 14.69 12.14 13.64
Fe2O3 2 0.98 1.75 2.45 0.83 1.41 1.16 3.67 1.66
FeO 1.8 0.88 1.57 2.2 0.75 1.27 1.04 3.3 1.49
MgO 0.55 0.13 0.68 1.03 0.08 0.35 0.16 0.29 0.3
CaO 2.29 0.71 2.63 2.34 0.9 1.63 0.98 1.45 1.2
Na2O 4.05 3.29 4.98 4.12 3.88 4.14 2.38 2.18 2.57
K2O 3.8 5.75 2.27 3.66 5.05 4.09 6.7 5.55 5.96
TiO2 0.19 0.1 0.21 0.24 0.07 0.11 0.12 0.41 0.17
P2O5 0.08 0.1 0.11 0.11 0.05 0.08 0.05 0.08 0.09
MnO 0.04 0 0.05 0.04 0.04 0.04
Total 98.88 100.45 100.41 99.93 100.34 100.34 100.01 98.87 99.56

K2O/Na2O

REE elements

La 13.5 n.a. n.a. n.a. n.a. n.a. 177.34 n.a.

Ce 26 56.1 20.3 28.5 49.2 16.5 17 307.2 96.7
Nd 6 18.5 8.3 11.6 17 7.1 6.1 108 34.2
Sm 0.96 3.19 1.46 2.3 3.01 1.46 1.29 19.2 5.69
Eu 1.3 0.45 0.78 0.66 0.42 0.49 1.27 2.62 1.07
Gd 1.3 2.54 0.96 1.75 2.24 1.47 0.96 15.43 3.83
Dy 1.2 1.88 0.57 1.37 1.47 1.3 0.59 13.68 2.56
Ho 0.16 0.31 0.09 0.26 0.25 0.29 0.1 2.74 0.47
Er 0.6 0.7 0.18 0.67 0.51 0.82 0.29 7.52 1.17
Yb 0.6 0.42 0.15 0.64 0.33 0.85 0.28 6.25 1.04
Lu 0.08 0 0 0.02 b.d. 0.13 b.d. 0.87 0.08

Trace elements
Rb 67 231.9 25.9 130 238.9 83.9 145.8 148.3 127.4
Ba 1853 690 1302 1915 319 1192 1092 1610 938
Sr 947 n.a. n.a. n.a. n.a. n.a. n.a. 137 n.a.
Th 0.4 26.25 0.17 5.07 54.03 1.92 38.1 58.89 38.63
U 0.79 3.67 0.07 1.85 9.92 0.27 6.05 1.02 0.87
Zr 96 88 87 99 74 77 149 493 133
Hf n.a. 2.9 2.2 2.8 3.2 2.6 5.3 n.a. 3.7
Ta 1 0.7 0.4 1 1.2 0.5 0.8 0.96 0.6
Y 6 9 2.8 7.5 6.4 8.6 2.9 68.2 12.1
Nb 4.8 7.6 1.5 6.1 10.4 3.4 6 23.9 1.6
Sc 3.2 b.d. b.d. b.d. b.d. b.d. b.d. 8.7 b.d.
Cr 9 b.d. b.d. 41 b.d. b.d. b.d. 2 b.d.
Ni 4 b.d. 11 20 b.d. 3 b.d. 1 2
Co 51 98 76 94 98 103 117 53 101
V 27 11 18 33 b.d. 17 b.d. 11 10
Ga 16 18 18 17 26 15 19 24 14
Zn 29 21 30 52 18 26 19 36 31
Cu 9 b.d. 19 19 22 b.d. 9 3 8
La/YbN 15.8 19.9
La/SmN 8.8 5.8
Ce/YbN 11.4 35.1 35.5 11.7 39.1 5.1 15.9 12.9 24.4
Gd/YbN 1.8 5 5.3 2.3 5.6 1.4 2.8 2 3
Eu/Eu* 3.61 0.49 2.04 1.02 0.5 1.04 3.54 0.47 0.71
M16 HM HM HM HM HM HM I-178-1-07 I-255-1-07
10 11 12 13 14 15 16 17 18

72.6 66.21 67.5 69.78 71.94 72.41 75.08 69.87 63.67

14.96 15.79 14.99 15.12 14.41 13.77 13.11 13.82 17.63
1.43 5.77 4.82 5.09 3.77 3.14 2.32 3.44 3.1

0.37 0.88 0.86 0.71 0.42 0.31 0.32 0.48 0.68

1.36 3.92 2.74 1.82 1.6 1.41 1.4 1.67 1.94
3.6 3.54 3.11 2.71 2.83 2.64 2.12 3.48 4.33
5.72 3.98 5.02 5 5.11 5.84 6.01 5.32 6.29
0.04 0.39 0.2 0.21 0.16 0.13 0.09 0.46 0.71
0.06 0.2 0.11 0.1 0.05 0.02 0.007 0.1 0.14
0.07 0.06 0.05 0.03 0.05 0.01 0.04 0.05 0.02
100.5 100.74 99.4 100.57 100.34 99.68 100.56 99.32 98.97

1.12 1.61 1.85 1.81 2.21 2.83 1.53 1.45

147.3 154.5 182.5 183 189.8 193.4 103 219

298.3 306.5 369.5 364 387.3 396.1 221 412
110.8 115.5 136 136 141.5 144.3
19 19.8 22.1 22.4 22.8 23.1
1.5 1.5 1.5 1.6 1.5 1.5
18 17.6 19.3 19.5 20.7 21.5
20 18.7 17 19.6 20 21.5

13.6 12.2 9.7 12.2 12.4 13.7

13.8 12.5 9.6 12.4 12.3 13.7
2 1.8 1.2 1.7 1.6 1.7

98 114 97 110 115 124 112 111

893 541 694 618 586 535 1115 2377
280 422 341 272 106 104 186 515

224 246 196 210 212 186 467 654

50 45 47 48 45 42
29 29 30 31 28 31
 27 37
26 29 24 22 22 25
41 70 40 51 39 36 47 34
PEGMATITE
SAMPLE ID SI10-175
1

MAJOR ELEMENTS

SiO2 59.73
Al2O3 14.74
Fe2O3 9.15
FeO 8.23
MgO 1.33
CaO 2.76
Na2O 1.58
K2O 9.08
TiO2 0.57
P2O5 0.73
MnO 0.08
Total 100.63

REE elements

La n.a.
Ce 134.6
Nd 59.1
Sm 11.72
Eu 2
Gd 11
Dy 9.5
Ho 1.88
Er 5.29
Yb 4.84
Lu 0.68

Trace elements
Rb 335.8
Ba 1339
Sr n.a.
Th 7
U 3.84
Zr 1
Hf 24
Ta 0.8
Y 53.6
Nb 11.5
Sc 14
Cr b.d.
Ni 12
Co 63
V 44
Ga 18
Zn 77
Cu 50
La/YbN
La/SmN
Ce/YbN 7.3
Gd/YbN 1.9
Eu/Eu* 0.55
Sivamalai nepheline syenites.

Rock Mesocratic nepheline syenite

Sample No 25 BNS 1/A BHNS 1 BHNS 27 HNS 17 HNS
Sl No 1 2 3 4 5

Major Elements
SiO2 52.12 52.97 53.52 55.76 55.94
TiO2 0.25 1.43 1.15 1.05 0.54
Al2O3 22.37 18.42 17.37 16.03 21.44
Fe2O3 6.72 8.49 8.18 9.66 4.72
MnO 0.05 0.07 0.07 0.12 0.06
MgO 0.41 1.76 1.24 0.74 0.34
CaO 1.4 7.28 7.6 3.02 3.41
Na2O 9.79 6.41 6.49 5.84 8.39
K2O 5.23 1.68 1.72 5.67 3.81
P2O5 0.41 0.49 0.58 0.75 0.54
LOI 0.52 1.86 1.86 0.73 0.46
Na2O+K2O/Al2O3 0.67 0.43 0.47 0.72 0.57
K2O/Na2O 0.53 0.26 0.27 0.97 0.45
Na2O+K2O 15.02 8.09 8.22 11.52 12.2
Sum 99.28 100.86 99.78 99.38 99.65

Trace element
Sc 1.34 2.03 10.35 10.47 2.74
V 3.29 162.36 109.14 8.38 8.18
Cr 38.86 10.37 31.92 26.33 30.08
Co 5.78 4.67 21.52 7.93 5.98
Ni 8.34 2.82 15.73 9.44 8.9
Cu 6.98 5.68 25.6 11.16 8.57
Zn 51.81 111.95 175.57 65.03 47.45
Ga 14.61 16.25 15.58 15.47 13.63
Rb 58.63 17.07 18.85 65.64 30.85
Sr 667.05 1652.13 1776.8 322.44 2124.57
Y 4.53 13.8 11.98 17.77 12.21
Zr 53.38 95.31 111.69 141.97 125.6
Nb 17.22 10.95 11.41 30.03 21.48
Cs 0.29 0.28 0.34 0.43 0.22
Ba 396.66 551.32 611.62 992.84 1225.95
La 10.31 19.96 21.31 35.59 30.83
Ce 23.7 36.87 43.84 76.3 62.51
Pr 3.09 3.33 4.87 9.04 6.78
Nd 11.18 14.14 18.1 33.64 23.54
Sm 1.92 3.7 3.49 6.15 4.14
Eu 0.82 3.13 2.95 3.28 3.64
Gd 1.39 3.12 2.89 4.7 3.11
Tb 0.16 0.45 0.38 0.6 0.41
Dy 0.82 2.44 2.09 3.16 2.16
Ho 0.14 0.45 0.4 0.58 0.4
Er 0.29 1 0.9 1.21 0.86
Tm 0.04 0.12 0.12 0.14 0.1
Yb 0.23 0.65 0.7 0.87 0.6
Lu 0.03 0.08 0.09 0.11 0.08
Hf 1.61 2.72 2.99 4.04 3.77
Ta 1.08 0.9 2.32 3.27 1.3
Pb 21.41 11.11 58.9 12.19 10.88
Th 0.46 4.48 4.52 3.32 1.95
U 0.37 1.06 1.22 0.95 0.61
TREE 54.12 89.43 102.14 175.38 139.14
Nb/Ta 15.99 12.2 4.93 9.17 16.54
Zr/Hf 33.2 35.04 37.38 35.1 33.36
Ta/Yb 4.76 1.39 3.3 3.77 2.15
Th/Yb 2.04 6.93 6.45 3.73 3.23
Nb/La 1.67 0.55 0.54 0.84 0.7
La/Yb 45.59 30.88 30.4 41.03 51.05
Zr/Y 11.79 6.91 9.33 7.99 10.29
Nb/Y 3.8 0.79 0.95 1.69 1.76
La/SmN 3.3 3.76 3.75 3.56 4.58
Gd/YbN 4.89 3.28 3.29 4.32 4.09
Ba/Rb 6.77 32.29 32.46 15.13 39.74
Rb/Sr 0.09 0.01 0.01 0.2 0.01
Leucocratic nepheline syenite M 14
26 LNS 22 LNS 24 LNS 3 LNS 23 LNS 2 LNS Sy
6 7 8 9 10 11 12

54.22 54.53 54.53 56.68 57.4 58.2 65.34

0.1 0.1 0.17 0.07 0.08 0.13 0.05
22.08 22.37 22.3 23.1 22.36 20.57 18.09
6.18 6.31 6 3.32 3.29 6.06 0.51
0.06 0.07 0.05 0.03 0.04 0.04 0.06
0.22 0.2 0.6 0.13 0.12 0.27 0.33
0.87 0.94 1.09 0.76 0.53 0.64 1.59
9.8 9.17 9.08 9.35 10.34 7.83 2.58
5.71 5.04 5.35 5.45 5.22 5.15 10.62
0.14 0.18 0.23 0.05 0.03 0.02 0.22
0.46 0.48 0.39 0.43 0.43 0.36 0.91
0.7 0.64 0.65 0.64 0.7 0.63
0.58 0.55 0.59 0.58 0.5 0.66
15.51 14.21 14.43 14.8 15.55 12.98
99.83 99.38 99.8 99.36 99.82 99.27 100.9

1.62 2.04 1.34 0.9 0.78 1.08 1.39

4.54 3.53 3.32 5.3 3.84 7.89
34.69 32.46 48.02 32.43 42.06 32.55 3.77
3.52 3.81 3.75 3.02 2.48 4.41
11.95 11.66 14.85 14.51 10.77 14.4 1.77
18.25 15.57 5.83 30.58 15.97 17.81
223.08 144.95 131.57 182.51 134.09 245.79
22.87 21.61 16.23 20.82 21.64 19.99 15.3
82.66 79.48 71.01 92.37 66.68 67.87 329
104.95 90.5 121.08 127.14 12.75 143.67 513
1.82 2.3 1.66 1.03 1.11 1.57 5.96
49.72 63.57 32.39 19.12 26.64 37.64 0.115
13.43 13.07 8.17 16.51 8.75 35.18 0.621
0.49 0.41 0.23 0.58 0.29 0.37
130.7 111.57 106.01 125.95 123 157.49 3440
3.72 5.01 2.86 2.03 1.95 2.9 26
8.15 11.04 6.84 4.05 3.93 5.83 51.5
1 1.36 0.94 0.43 0.42 0.62 5.22
3.54 4.95 3.54 1.47 1.45 2.1 17
0.64 0.89 0.65 0.26 0.28 0.39 2.58
0.27 0.34 0.27 0.15 0.19 0.27 1.06
0.46 0.64 0.47 0.22 0.22 0.32 1.08
0.06 0.08 0.06 0.03 0.03 0.05 0.236
 0.31 0.4 0.29 0.16 0.18 0.26 1.17
0.06 0.08 0.05 0.04 0.04 0.05 0.227
0.15 0.17 0.12 0.11 0.11 0.14 0.585
0.02 0.02 0.02 0.02 0.02 0.02 0.0782
0.16 0.19 0.13 0.11 0.11 0.13 0.448
0.03 0.03 0.02 0.01 0.01 0.02 0.0632
1.35 1.85 1.08 0.38 0.66 1.02 0.115
0.31 0.17 0.32 0.34 0.27 1.4
52.05 48.94 16.53 44.56 46.62 55.46 62.1
0.69 1.32 1.36 0.75 0.46 0.78 2.77
0.61 0.64 0.21 0.44 0.47 0.6 0.726
18.58 25.2 16.26 9.09 8.94 13.11
43.79 77.48 25.51 49.18 32.14 25.13
36.86 34.31 29.99 50.46 2.46 36.83
1.87 0.89 2.48 3.06 2.46 10.71
4.22 6.96 2.8 6.85 4.19 5.99
3.61 2.61 2.86 8.13 4.48 12.13
22.69 26.46 22.11 18.51 17.6 22.18
27.27 27.59 19.5 18.59 24.05 23.99
7.37 5.67 4.92 16.05 7.9 22.42
3.56 3.47 2.68 4.73 4.28 4.53
2.23 2.67 2.86 1.62 1.6 1.98
1.58 1.4 1.49 1.36 1.84 2.32
0.79 0.88 0.59 0.73 0.55 0.47
 marble

Sample M3 M4 M5 M6 M7 M8 M9 M 10

SiO2 13 26.2 0.05 1.59 29.48 29.4 20.2 19.7

TiO2 0.1 0.22 0.01 0.03 0.08 0.31 0.2 0.2
Al2O3 1.83 4.78 0 0.07 1.19 5.13 3.52 3.66
Fe2O3 1.65 2.17 0.87 0.99 1.54 2.68 2.32 2.2
MnO 0.08 0.09 0.1 0.1 0.1 0.11 0.09 0.09
MgO 0.83 1.23 1.51 2.14 11.72 2.02 2.19 2.27
CaO 57.8 41.13 73.08 71.04 35.47 40.25 48.63 49.12
Na2o 0.21 0.52 0 0 0.08 0.7 0.8 0.51
K2O 1.46 2.18 0.03 0.15 0.94 1.14 0.77 0.71
P2O5 0.07 0.07 0.04 0.06 0.08 0.14 0.06 0.02
LOI 22.06 17.06 24.03 23.18 19.98 18.04 20.32 20.37
Sum 99.39 95.96 99.96 99.65 100.91 100.22 99.39 99.19

Sc 2.77 4.81 0.813 0.916 2.25 5.21 4.68 4.45

Cr 13.5 30.7 1.82 2.64 8.36 38.1 28.3 27
Co 2.8 4.66 0.784 0.892 2.75 5.29 5.1 5.04
Ni 8.38 11.2 5.36 5.64 5.13 15.2 14.7 14.7
Ga 2.22 5.99 0.0985 0.171 2.48 4.82 4.2 4.39
Rb 65.6 96.7 2.08 2.24 51.1 25 26.4 22.5
Sr 119 104 121 110 61.9 233 190 217
Y 8.76 8.08 5.16 4.56 4.92 14.9 8.05 7.72
Zr 17.6 68.5 0.428 1.99 6.14 99.7 41.4 36.9
Nb 2.41 3.82 0.0888 0.228 1.22 4.52 2.75 2.89
Ba 265 364 42.7 48 91.8 123 136 165
Hf 0.499 1.59 0.0125 0.0603 0.24 2.43 1.12 1.03
Ta 0.166 0.3 0.00602 0.0156 0.0702 0.323 0.2 0.202
Pb 4.67 5.67 3.86 4.83 2.47 13.6 8.12 6.95
Th 2.45 3.91 1.16 0.99 0.38 4.43 2.15 2.93
U 0.431 0.93 0.11 0.0833 0.0928 1.26 0.833 0.762
La 10.2 8.92 3.6 3.8 2.65 19.6 9.25 9.62
Ce 17.6 15.3 5.05 5.33 4.11 38.1 19 19.5
Pr 2.28 2.02 0.752 0.805 0.675 4.16 2.2 2.22
Nd 8.39 7.65 3.02 3.19 2.83 15 8.34 8.22
Sm 1.66 1.54 0.619 0.628 0.602 2.94 1.74 1.66
Eu 0.363 0.331 0.141 0.137 0.137 0.585 0.353 0.363
Tb 0.225 0.225 0.102 0.096 0.102 0.426 0.25 0.236
Gd 1.54 1.46 0.675 0.637 0.658 2.68 1.57 1.5
Dy 1.38 1.31 0.603 0.568 0.59 2.53 1.48 1.38
Ho 0.281 0.27 0.12 0.12 0.126 0.525 0.305 0.287
Er 0.781 0.756 0.349 0.324 0.343 1.517 0.867 0.809
Tm 0.116 0.113 0.048 0.456 0.0477 0.231 0.129 0.123
Yb 0.751 0.731 0.289 0.282 0.288 1.509 0.837 0.786
Lu 0.11 0.109 0.04 0.407 0.427 0.22 0.125 0.116
M 11 M 12

5.5 15.3
0.2 0.13
1.01 0.73
1.38 1.79
0.09 0.1
9.17 2.85
56.89 56.07
0 0.14
0 0.02
0.22 0.22
23.96 21.85
98.42 99.48

2.17 2.23
9.26 5.44
1.36 3.38
5.7 11.7
0.969 1.08
0.11 1.28
268 728
11.9 51.9
14.7 7.41
0.73 0.607
31.1 111
0.41 0.21
0.0844 0.0469
10.3 11.2
0.879 6.91
0.475 2.37
11.4 234
20.8 312
2.69 26.7
10.5 78.5
2.25 10.9
0.494 1.72
0.339 1.23
2.22 8.6
2 6.92
0.408 1.52
1.11 4.53
0.159 0.7
0.979 4.58
0.141 0.661
 Gneiss

SL No 1 2 3 4 5 6 7 8 9
Sample M 17 M 18 M 19 M 20 105-45 105-68 105-69 I-231-1-07 I-351-1-10

SiO2 70.08 69.4 60.26 65.24 47.76 44.02 53.41 58.94 64.25
TiO2 0.44 0.49 0.6 0.58 0.64 1.04 0.23 0.63 0.61
Al2O3 14.43 14.36 16.62 14.41 11.71 17.17 13.98 14.22 14.87
Fe2O3 3.54 3.96 5.07 5.34 12.45 8.17 7.19 7.76 4.87
MnO 0.14 0.15 0.18 0.12 0.19 0.15 0.12 0.11 0.05
MgO 0.52 0.55 3.01 2.39 12.03 12.51 9.38 4.1 2.36
CaO 1.62 1.71 14.87 3.56 11.86 13.78 12.79 4.83 3.06
Na2O 3.4 3.45 0.41 3.93 2.26 1.31 1.63 3.14 3.39
K2O 5.96 5.76 0.03 3.33 0.65 0.32 0.21 3.87 3.9
P2O5 0.11 0.13 0.16 0.29 0.06 0.15 0.09 0.34 0.16
LOI 0.34 0.16 0.9 0.73
Total 100.9 100.5 100.5 100.6 99.9 99.24 99.47 98.91 97.72

Sc 5.91 6.99 11.1 11.9 40.2 29.3

Cr 8.57 73.4 80.3 73 521 538 243 67
Co 48 66 67
Ni 3.37 31.4 25.3 27 327 258 27 24
Ga 17.8 18.9 18 21 22 17
Rb 141 1.82 115 4.5 4 1.8 93 137
Sr 131 219 405 39 516 315 625 364
Y 33.9 21.7 29.6 21.4 23.1 4.9
Zr 644 183 275 30 48 8 87 150
Nb 14.6 11.2 17.5 11.4 9.5 0.8
Ba 1280 105 775 30 176 51 1703 826
Hf 14.9 5.03 6.65
Pb 24.8 6.64 23.7
Th 17.2 13 37.1
U 1.11 4.18 1.82
La 78.3 29 65 2.5 6.5 2 38 60
Ce 147 59.8 127 16 31 15 125 139
Pr 16.7 6.91 13.7
Nd 60.9 25.4 47.7 5.5 11 2.6 nd 46
Sm 10.6 5.09 8.63 2.1 3.2 0.77
Eu 1.97 0.983 1.3 0.62 0.72 0.42
Tb 1.26 0.753 1.01
Gd 8.51 4.58 6.8 2.4 3.2 0.8
Dy 6.87 4.48 5.5 3.3 4 1
Ho 1.41 0.964 1.11 0.52 0.6 0.15
Er 3.83 2.75 3.02 2 2.2 0.6
Tm 0.559 0.418 0.446
Yb 3.61 2.73 2.75 2 2.1 0.65
V 112 nd
Lu 0.548 0.412 0.388 0.23 0.23 0.07
Z 76 57
La/YbN 0.9 2.2 2.2
La/SmN 0.7 1.3 1.6
Ce/YbN 2.1 3.9 6.1
Gd/YbN 1 1.3 1
Eu/Eu* 0.86 0.7 1.66
 10 11 12 13 14 15 16 17 18 19
I-29-2-07 I-40-2-07 I-45-2-07 I-52-1-07 I-286-1-10 I-294-1-10 I-314-1-10 I-322-1-10 I-33-1-07 I-46-1-07

60.24 70.33 57.35 73.15 71.88 68.48 66.97 71.69 64.42 67.25
1.15 0.22 0.99 0.18 0.21 0.51 0.43 0.41 0.92 0.42
16.25 15.44 16.55 14.47 15.29 13.56 14.68 13.14 15.07 15.08
6.75 1.89 7.95 1.59 1.49 4.5 4.52 3.04 5.69 3.67
0.07 0.02 0.1 0.02 0.01 0.05 0.04 0.02 0.09 0.02
2.18 0.68 2.6 0.6 0.47 1.69 1.07 0.93 0.94 0.7
4.42 2.73 5.32 2.54 1.81 1.86 3.14 1.39 3.08 1.51
4.05 5.49 4.06 4.78 5.56 3.31 3.17 2.74 2.74 3.07
2.94 1.39 3.46 1.4 2.46 3.79 3.54 4.21 5.38 6.36
0.3 0.08 0.53 0.07 0.07 0.14 0.21 0.05 0.25 0.23

99.38 98.88 99.38 99.4 99.406 98.131 98.023 97.787 99.18 99.11

bdl bdl 19 bdl bdl 78 5 26 bdl bdl

bdl bdl 7 bdl bdl 22 bdl bdl bdl bdl

55 27 71 51 41 95 125 173 113 111

602 635 601 239 590 339 400 216 314 698

308 109 215 91 76 161 267 241 353 676

1419 520 1537 199 819 1524 1512 768 2181 5396

49 bdl 58 24 bdl 43 56 35 52 297

135 33 142 27 48 150 191 105 178 681

nd nd nd nd bdl 30 41 13 nd nd

139 22 133 25 nd nd nd nd 77 53
59 30 74 28 30 44 17 47 64 43
 20 21 22 23 24 25 26 27 28 29
I-58-1-07 I-62-1-07 I-73-1-07 I-119-1-07 I-124-2-07 I-131-1-07 I-293-1-10 I-323-1-10 I-375-1-10 I 41-1-07

71.06 68.75 67.42 61.62 64.22 59.5 69.84 68.65 57.75 71.61
0.47 0.63 0.58 1.42 1.08 1.49 0.58 0.66 0.78 0.73
13.1 13.24 15.16 13.66 13.94 14.31 13.4 13.28 18.72 11.05
3.18 3.87 3.43 8.62 6.29 9.71 3.93 4.88 4.25 7.87
0.04 0.06 0.05 0.12 0.07 0.17 0.05 0.05 0.03 0.15
0.57 0.73 0.56 1.42 1.2 1.53 0.7 0.6 0.86 0.5
1.25 1.93 1.95 4.11 3.2 4.7 2.35 2.66 2.99 2.8
3.23 3.02 3.07 2.92 2.95 2.86 2.49 2.39 3.98 2.23
5.29 5.53 6.35 4.07 4.36 3.39 5.07 4.21 7.05 2.99
0.12 0.22 0.13 0.44 0.34 0.54 0.16 0.18 0.2 0.18

98.81 98.78 99.43 98.75 98.43 98.77 98.76 97.787 97.38 100.3

bdl bdl bdl bdl bdl bdl bdl bdl bdl bdl

bdl 13 5 bdl 6 8 bdl bdl bdl bdl

265 186 133 90 85 128 116 211 166 76

126 199 303 255 355 278 180 175 653 134

349 378 488 654 500 547 298 402 885 494

621 1071 1167 1680 1819 1744 1175 1391 5522 967

82 82 34 49 80 75 66 23 36 38
148 193 111 143 188 158 183 130 394 99

nd nd nd nd nd nd 50 24 45 nd

28 44 28 97 88 104 nd nd nd 31
51 53 57 82 63 110 43 61 28 55
 30 31 32
I 41-2-07 I-53-1-07 I-57-4-07

70.83 73 72.68
0.76 0.46 0.64
10.75 10.78 11.31
8.03 5.79 4.97
0.15 0.13 0.09
0.51 0.66 0.51
2.62 4.08 2.05
2.04 1.66 2.17
3.6 1.39 4.03
0.18 0.1 0.13

99.5 98.76 98.78

3 bdl 2

bdl bdl 11

100 42 168
135 79 139

516 466 650

1108 583 1742

38 74 73
106 118 208

nd nd nd

39 13 32
60 118 105
 Carbonate-silicate

Sample M1

SiO2 35.68
TiO2 0.26
Al2O3 6.1
Fe2O3 2.83
MnO 0.09
MgO 1.44
CaO 36.52
Na2o 0.52
K2O 2.61
P2O5 0.08
LOI 13.55
Sum 99.99

Sc 5.67
Cr 40.8
Co 4.92
Ni 10.9
Ga 7.27
Rb 126
Sr 101
Y 7.74
Zr 44.6
Nb 4.37
Ba 510
Hf 1.27
Ta 0.332
Pb 4.89
Th 6.05
U 1.11
La 8.15
Ce 14.1
Pr 1.84
Nd 6.87
Sm 1.4
Eu 0.302
Tb 0.207
Gd 1.32
Dy 1.25
Ho 0.263
Er 0.752
Tm 0.114
Yb 0.76
Lu 0.115
Domain Western Madurai Domain
Age Late-Neoarchaean-early-Palaeoproterzoic basement
Rock Charno-enderbites
Sample I 76-1-07 I-104-1-07 I-109-10-07 I-177-1-07 I-180-1-07 I-188-1-07 I-206-1-07 I-239-1-07 I-252-1-07

SiO2 68.05 67.47 67.94 59.19 69.78 68.98 61.91 63.33 66.92
TiO2 0.46 0.37 0.42 0.76 0.33 0.3 0.62 0.63 0.48
Al2O3 14.55 16.4 14.46 14.87 14.77 14.97 14.25 16.83 14.73
Fe2O3 4.08 3.16 5.05 6.54 3.04 2.91 9.08 5.01 3.77
MnO 0.04 0.04 0.07 0.08 0.03 0.03 0.1 0.07 0.07
MgO 1.54 0.91 1.84 4.06 0.81 0.77 4.18 2.26 1.51
CaO 2.61 3.42 4.41 4.54 3.17 2.32 2.58 6.04 2.46
Na2O 3.38 5.17 4.17 3.63 3.33 3.53 2.37 4.31 4.1
K2O 4.32 2.17 0.92 4.32 3.24 4.6 2.7 0.55 4.15
P2O5 0.16 0.18 0.1 0.5 0.09 0.09 0.03 0.21 0.17
LOI 1.07 0.49 0.47 0.76 0.41 0.9 0.1037454 0.3 0.52
total 99.45 99.78 99.85 99.25 99 99.4 98.026 99.54 98.88

V 64 34 75 135 27 39 nd 97 58
Cr 34 bdl 30 139 bdl 13 222 36 49
Ni 5 bdl 7 41 bdl bdl 97 16 11
Zn 42 65 47 62 27 34 64 51 59
Rb 138 24 2 151 59 107 78 1 85
Sr 539 1002 288 690 295 531 306 318 373
Zr 197 244 119 248 258 226 188 209 245
Ba 1309 1486 248 1639 2052 1259 1050 536 1376
La 77 29 26 49 88 82 30 31 51
Ce 140 139 36 138 223 166 111 41 140
Nd nd nd nd nd nd nd 28 nd nd

Fe Nr 0.7044817 0.7575511 0.711778997 0.591742 0.7715344 0.7727553 0.6615435 0.6660756 0.6919779

K2O/Na2O 1.2781065 0.4197292 0.220623501 1.1900826 0.972973 1.3031161 1.1392405 0.1276102 1.0121951
 Mid-Neoproterozoic intrusions
Porphyritic charno-enderbites
I-282-10 I-309-1-10 I-321-1-10 I-335-1-10 I-335-2-10 I-342-1-10 I-348-6-10 I-354-1-10 I-111-1-07 I 246-1-07

54.68 70.55 71.27 63.96 62.75 71.39 66.23 60.23 69.89 59.26
1.06 0.15 0.55 0.45 0.53 0.36 0.5 0.91 0.55 0.45
14.44 15.25 11.35 14.23 14.99 14.3 15.49 15.36 13.09 18.96
10.36 1.81 5.24 5.53 5.07 2.77 4.51 8.01 4.69 4.12
0.16 0.02 bdl 0.07 0.06 0.03 0.06 0.1 0.06 0.05
5.15 0.84 1.82 2.73 2.38 1.01 1.99 2.25 0.47 1.31
8.44 2.63 3.55 4.08 4.17 3.53 4.65 6.18 2.58 2.87
3.23 5.28 2.65 3.61 3.69 3.73 4.75 3.49 2.7 4.21
0.32 1.36 1.77 3.51 3.78 1.39 0.36 0.6 4.18 7.28
0.19 0.07 0.07 0.2 0.25 0.08 0.14 0.34 0.17 0.24
0.2361857 0.1560679 0.0404571 0 0.0510074 0.1649852 0.03 0.0263613 0.61 1.11
98.124 98.102 98.555 98.587 97.945 98.749 98.774 97.663 98.99 99.09

nd nd nd nd nd nd nd nd 35 55
197 bdl 22 69 75 bdl 24 26 bdl bdl
97 bdl bdl 15 18 bdl 13 13 21 6
127 37 83 60 55 37 35 78 42 59
bdl 29 72 99 100 19 bdl bdl 94 141
266 617 122 511 651 306 489 410 259 561
122 102 477 168 176 92 171 349 444 535
180 535 886 1056 1458 1001 197 901 1586 1483
bdl bdl 38 35 31 bdl 13 32 319 142
22 34 152 116 129 68 22 109 176 287
19 bdl 57 32 29 12 15 35 nd nd

0.6441386 0.6597314 0.7214976 0.6457257 0.6571586 0.7116301 0.6709709 0.762091 0.8997881 0.7388969
0.0990712 0.2575758 0.6679245 0.9722992 1.0243902 0.3726542 0.0757895 0.1719198 1.5481481 1.7292162
 eastern domain
roterozoic intrusions Mid-Neoproterozoic intrusions
c charno-enderbites Porphyritic charno-enderbites
I 250-1-07 I-261-1-07 I-355-1-10 I-38-1-07 I-38-3-07 I-43-1-07 I-43-2-07 I-82-1-07 I-84-1-07 I-161-1-07

69.52 65.82 59.73 73.82 61.54 62.49 62.12 65.78 63.17 65.03
0.64 0.94 1.19 0.36 1.51 1.25 1.32 0.93 1.12 0.77
13.23 13.37 12.64 12.63 13.9 14.13 14.34 14.01 14.07 15.46
5.25 6 7.89 1.93 8.95 8.12 8.49 6.43 8.45 5.45
0.06 0.1 0.1 0.04 0.13 0.12 0.13 0.08 0.12 0.07
0.47 0.77 2.3 0.37 1.67 1.26 1.37 0.88 1.07 0.62
2.13 2.93 4.82 1.6 4.6 4.13 4.41 3.77 4.01 2.26
3.36 2.88 1.96 2.66 2.82 2.66 2.89 2.27 2.5 3.81
4.3 4.81 6.3 5.35 3.34 3.97 3.88 4.55 3.92 5.58
0.18 0.26 0.5 0.06 0.47 0.42 0.44 0.28 0.35 0.19
0.69 0.43 0.0900994 0.48 0.44 0.06 0 0.23 0.12 0.35
99.49 98.31 98.136 99.3 99.37 98.61 99.39 99.21 98.9 99.59

27 58 nd 10 127 96 99 56 74 33
bdl bdl 46 bdl bdl bdl 3 bdl bdl bdl
bdl bdl 37 bdl bdl bdl bdl bdl 7 bdl
73 60 76 23 99 91 86 79 92 70
63 73 90 118 72 102 98 134 108 136
346 424 1508 172 275 299 323 263 262 279
531 626 587 236 537 457 405 499 613 806
2140 2915 4080 1451 1427 1730 1865 1987 1622 1821
113 65 149 10 49 79 45 55 45 89
244 236 500 82 150 143 152 151 140 250
nd nd 139 nd nd nd nd nd nd nd

0.9095101 0.8751783 0.7553041 0.8243627 0.828246 0.8529133 0.8479349 0.8679811 0.876633 0.8877607
1.2797619 1.6701389 3.2142857 2.0112782 1.1843972 1.4924812 1.3425606 2.0044053 1.568 1.4645669
I-296-1-10 I-297-1-10 I-298-1-10 I-299-1-10 I-300-1-10 I-328-1-10

67.85 62.29 65.67 69.85 66.83 60.02

0.58 1.34 0.63 0.24 0.64 1.4
12.47 13.23 13 13.96 14.32 14.87
5.75 7.84 6.47 1.97 4.49 8.85
0.1 0.11 0.09 0.03 0.07 0.14
0.39 1.32 0.32 0.44 0.91 1.48
2.04 4.6 3.47 1.66 2.34 4.87
2.6 2.54 2.59 3.49 3.37 2.74
5.35 3.62 3.96 4.67 4.33 3.57
0.15 0.58 0.2 0.07 0.21 0.43
0.0530522 0.0895847 0 0.0659417 0.0444219 0
97.655 97.885 96.776 96.595 97.768 98.667

nd nd nd nd nd nd
bdl bdl bdl bdl bdl 9
bdl 5 bdl bdl bdl 9
106 101 86 30 55 112
110 68 86 108 102 104
106 212 177 320 297 299
698 705 561 208 389 404
2297 2463 2447 1431 1311 1715
41 157 33 32 115 39
203 423 222 146 249 177
42 106 57 42 63 42

0.9299047 0.8423774 0.9478972 0.8011395 0.8161654 0.843274

2.0576923 1.4251969 1.5289575 1.3381089 1.2848665 1.3029197