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CH 5

physical chemistry

Transféré par

Apple Wu
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© All Rights Reserved
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6 vues24 pages

CH 5

physical chemistry

Transféré par

Apple Wu
Copyright
© All Rights Reserved
Nous prenons très au sérieux les droits relatifs au contenu. Si vous pensez qu’il s’agit de votre contenu, signalez une atteinte au droit d’auteur ici.
Formats disponibles
Téléchargez aux formats PDF ou lisez en ligne sur Scribd
Entropy and the Second and Third Laws of Thermodynamics Pron ub nis inde ht tion inhi Std Sine Mama Conceptual Problems (051 Under a condo AS «0 fra ponte? Fer pertinon oth, A+ Suman > A ptt poanons FAS <0 ely AS *0 34 Sune > Sh 052 Wyse Se Sd AS arn Fe 1 avs poste. nent hes rast, eg sie escer tees ta 0 oan guetta pad ety me Ar Ti AS 3 hatte 4 os oss es est ose ‘Chapter $ Entropy and the Second and Thad Laws of Thermodynamics ‘Unie wontons she caty 9» i net A ease d= Mz, teeny Nt fas =A Tone 8 eve pe cst psi sth wing semen fie? fs ips sta se The ey ofa ys camet ae, Theenopy fase cma nerase Ina ves ads ees. ‘Which fe owing pecs sonnei? ‘There tal xpi fan ie. 1 The veyron of spend water 12°C © Thecona resnr aeing ofe w i nrmlirng pein by he dono nena qty whoa (©) esstgemamecat eae th pte and ond ea qin ding ves oe (0) esponannas tometer lender te denn (© snot pena eset proses reveifte aman intemal (@) _ssponannustesnse at euro he day os unio doug scene One je of work is neo ye, ang te epertur y one epee Can is ae a temper be wise So cme je of wr Expl No, bese nol te the seca aw of ermal. Het aD one wok WA 10 ise ‘Yor mrmat ei ol Khe by pei i 1 wt at work ithe igri tlie he rom tesa cnn he rm Noll ee at he ‘agen es peer tan ica ane icon ee ego etn 10% oe fete wile hae roam However th rege mnt es indo dc at tiated eri pte ol am rege, Wl hs satay wet? Epa your ‘Ana psy madi esta VACHS, Sri A ASag pe pn er Papin erro Demme AF = ferbespnien oan gs Mb avacim, AS =i WL > 0 Bet Saray cilia ing the sl tow i the sere, Scan BS * 85 + BS > When ast ton of ti cok a inte cysts cu he extopy of the seystlne ‘recipe peace ane etd? Ena wy tt prc ens, Fomine le ett proces fr Which AS <9. Hove Syringe gd weer meg 20 at SS 8S > 8 ming te pce tas ‘Actes hangs a cosa antral iret pty oof wh eevee fede ter of wich ines, What cn you sat te eave magne OF dna ‘ecae Sisa sate ncn, 85 ine sane reverie an a vile pt tne hee nd Fl sate Hower dace in Secon Agra f= TS 0 oi 28) Pin (Chapter $ Entropy andthe Second und Third sis ste os as es os sof Thermodynamics 15 An ign pti dns wh aah wal unezce a xpsicn ain cet ‘teal rt ATE ASS tl ASPs negate, or? Exp yoar rescig Deca he proce aie, AS 39" Ar AS 8 > Iethesqation som the rs atl S08, AS * 0 Boe ‘(Sears fbar cy . Th Bev v9 ot ra ie st Nn Dose ad aetna ty a bene fie tea ‘Wy ete tomy Cunt es enga te ern ote tk fanaa eg ‘Thi cne esa mario wor at edn he sarondagsin he expan ga iin a ‘wo velo ome, pei, nd enprr th caning A ae nected na What the ‘hang ncn tanh soe peat tig bang he evolu? Ste mee ese gt onesie of he ae, AS = este the indir moo te ge Insp However theo gue bea. AS > O Roa he ming he es Wie ing eatin, emia woy AS fr ir sis donned y he epee epee ofS stan rand Tehnge esl think ofS = 1) Desa care ery te wit amy ans in er tan for el a iors ny cans a So i! nal cttw the sarong every ml at th sora ming pitt etn ae i et spe pe oe 25 = Mie ma pce, Sag =. Say 88 = lt 9 ‘mnt hing he rp an exp of opener ing he Mag se ‘iconioning eg? 1 be pla example of cope ag he ing sent the waste eat om ih Podson tds het he bling rat clef cope Wace se ce Mratchoureis te tito he cng Numerical Problems rs Cos he mat of gene lm an doi nate, ha he ain te ptt pce: (Osta) + HO) > tO) + CO. “The fllovng ble ineaion wl ln working thi rem Pome COW HOD CMO Osta) wwe 335 BLT Oy smart) ass no 02 2052 Cralimer mm a3 2 Da opr 0200 Pn aan ns 6 Chapter $ Entropy and the Second end Third Laws of Thermodynamics Cake te ety nd ety cane ris chil gue at '=208K 7 =H0K. Cae aso te eo cage fe ond ive toh empresas a he ste Saremsns wet see engra = 209294 mol 65 205201 62138 te = 6 7009 9-204) mot! alt =n. amt —6e91 SAU 62858 wot = 28 240x101 na! 45S “AS #455 = 2604! 966410 IK" na 94x10 wt! To cakaue 39 fr he ste, te suroung te une a T= SOK, we mus tke he Ret ilies ie cat | pe = ODDIE 21829 n= 67 = 6759" AS{OIGK) = ASHEMISKY + Hep w 2K A(310.K) = AH29818K) + 8G, AF 20.744 mo = 278810 WK oe S10. EIR = PPA aa a Sener = AShrante 45) = 274-9035 10 Kt =-900% 10 3K i anak), P&I The Chalk Pol, Mala, png son sap lee ower te Wahgun, DC, Uns wn hae a rs gmereg apt) of 710 NA (nega. Te eam pee 6 25710" Pa and We ‘upset ott tempos (T,) 40°C. Theses empetre (7,) 300°C. What et faerie Cae cae prague hs nos? te etciony of te Der 91.2% eel een of te bie whch Mela te Cant ‘cen nd omc fey i andthe he gent wi he ‘ey ofthe lng Anatrace rt pt ae) Cae ofte col brig as prtues 355M. How ay meee ns Mma = <1 a hour we ree to peat ni ats pak oma If the extpy ef combustion el oxi wxe" = Tae aTatt 1 BK gar (©) Toe tiny te perigee prado ini elie cope Rae En cao n (©. Theenegyenpt prow given by 385 W288 «1.27810 she telnet a AERIS saat ‘The manor ton of con nade le 2212107 IW 19.4 te Ba AP PSA lab AS* br sion 344g) +N) -4 IN) 75K, On he tpt sao tan TK! ate Gta) = 2266 + 434102 ros 10T 1 ma 0) nat— tase aan t0 Ee a Goa «29 0010? Ee aatonte Eat Re one sto Z sauonio? E30 mt") -[3081-1. sara Z + 23sec? 1K mat! z =fsevemc sane) ojos -oomel sani 2 tt 88 =D 8S) = Sal) sus Shar ss, S18 Using te epeion a5 = Fur - YB, cae he een pate hat se i228 als of eter a0. nd 165. ba eagles ari «ees ada poss. Ane app 6201 Pen a (Chapter § Entropy and the Second and Third Laws of Thermodynamics o-Sa-e ase fssegatenrtt =m cyt erry) wr,» LAU D*Eret, IO aot 1300 1651) 753K met ee i ©20)Re tn (Chapter $ Entropy and the Second and Third Laws of Thermodynamics 83 gg = 275 mn 2AM EOE, (SK =298K) = A724 105 Weng At = 275 mol ZEIT apg oy m0) 610x107 1300 rset SEN STK, "150 Th gs udu pation apt out ner prs fo tr wil he fd posi us oe tid of sina vale nk tal = ars mote a4 et cm SOE PSI7 Toe er orig ply Ald 36 a env oa heat ily Bld 80°F. IF Ahern epee 3, ty what ar wore expe texts he sane aon feat me ‘ie ha oh hig! Asune teh inthe ertrmance fever igo Fram Equation (5.4) 1 Te Toat Ime fem eI 23K Tm = Ht0-39 ran 2848 Two = 296-3738 2848 Fonte freon 9, = 24K, SR TE ‘Foxe ehigertor 1, = 274K 47, “he fees more expen ope ane eta by teat 1/P = 24 S18 Using youre fom Pm P57, cult, AU, and AP foreach tp ath eye nd arb tl le ob Aaa =O beome AF = 0 ane 9aeis bee ewe =LI2x104 tte 4 SH = AU WRT = 188005 cod AU =a =O Boome ar ano 396x105) Ae Ua watnoty tema g=0 AH = AM + WRAP =186104) ont = BANKIPS=296X 18 = 549510 =p ap 0201 Fo 84 Chapter $ Eniropy and the Second al Third Laws of Thermodynamics P&I Avbetmastinmperteof 954°, teensy oftnstn fo rants moat sar 0.3K mt” | Clit te extory franston nr ese conto ‘Att eng po, 119°, the eaey of un of mete suas 1.2583 Cala he enopyo isin. {© Thevabes given in ys) and) ae fr 1 ma ef sla: homee. a ystalne sngld suti, the roles preset tS Conver the ales feta ante isn pr) an (9) ‘se prea 5, Sn = peer BAS FORA VOIR ee" Spun = ls «AREA 3.4K wrt Se = Ee GTR) (9) Bachot ts 85 in ps) nd) shold bs ip 8 Spun = 281 SKI! S20 One me of van der Wa at 250°C eagerly and ees oe a il vane of (10m? wo [Link] yone of O0NSm. Fo he van der Wak (UG y= a2 Asn Qt 2 asset nt mal and ot B= 640% 10m ma Cale AU AUT a AS fr te roe. ee aw Ferner Wat 20 =f oi scltion si casnatiat stag gghg)sms Ghelehene) + 1,00) (Cake AS, Sprung 4 AS = 298K. Lil hema dt iow Ce wae] [anja =s12 60 =) SEU ma) ms Ton “mal ‘pO Rane a [Chapter Eniropy and he Second and Thied Laws of Thermodynamics 89 All, =2eS3121U ma Meet 24580 99"! = 26 Ent! ‘ss, 2AM 26M 5 gor Sc = H295 3K ma $8.09 a =O S29 Ox ne of H,0() isola © ~3.75°C a | br oni The ening epee of art is pete 1 OFC. The emma 100) HO) Hae teed ec By sali 3S, Sry fd AS eH) ot etme spray °C. The bet spi ae Sp © [Link] = 7539 ot ad Cy (HAS) =FIIK nol, a AM ae = B08 S Ob¥e “Aare tat te sumomdngs aa 17. [ne Coat pays {@ H,00,~ 398°C) > 1,0, 328°C) andl) HO, -3.7°C) > HOU, 0000) HOt, 0.90) > MyOG.375C) Boawes ease en AS metho nee rks] Facptny HyO{,— °C) HO, 0"C) > Hs, BIN) + H_O, 378°, 88a BIEE yl gn A ame rsim i IE EI + ma377 aK in SOO, = 10n11K"~ 900" -0s21 Rt «2148 Tecate Sirmione MEAL AH = 4. HATE) = AMIOODE) + (Cs) ~ Cota ANE-3280) = nel OI MOE 4 077 Bot KA = 7894 KD CRE at 8078 agg! Ss © LTR = 21485" = 000K > 0, Te pat prt P30 Calale 45, AS enti: AB Scum yf et cane he ered bem 5. ‘Sse al erent 6° ana te tr pte 320,700, an 10 degree Fru core 0,21.) at 6 ern Cage, pty soa =% ROW time = 3331 TOH UPS IGOSH 2 ed = 48510 ft =a) 63109 tat = $5400 as su a 4s, oe = SHERI aes eaoh st ar TR if BIKA DEIR 31 Thefloning at cages) dan ake ben ep fe ani fro w [x] o [a [we [ead wal) [04s [4s [as [aas9 | 9 os enefiz29 sas {Chapter $ Entropy and the Second and Third Laws of Thermodynamics ya epi eet caine rey fale aT = 30K Youn ate enn may agelieraspea dx pagan race‘ tie wn hig cnr neal Pan S. Te dan ely wis i acpi epeino e abna c Ce = 9460 «0976479509817? + gooteare4 tag 38 8 eat soa mo 8 ‘Totti he eopy a 900.5 wea teint 10617 -omnorser® 921 10729 4460 soso Wehner he cnt Satomi lw 10K are tent lal, Thi coibon Cite Set 8 AS fhe roses ese np) ad) Poe PI. Wh oe ‘woven le ance pct The sui of @e sumone! for ech pat at 200 K 1.0 be ‘Seman =D (and) bate 4 = 9 2 ASad 85+ Sang = 9 FO OT pce epee BAS 85+ Spiny “HSI (311%, Te prose pont, Arges peste ty 02549 (hp = 745 a) me teint he mained °C ak ‘hero terpenes, ht emai sk (a) an eee soe a ‘sete perme 36 of te mun heel va, Wht pe he ks pose ayn ‘reco of perma 00 005 ag rt 20 Nara Eat {Chapter $ Entropy andthe Second and Third Laws of Thermodynamics 9 ‘he mama et iat a ened te eld sense ge by oe nt ak ter ania empresa wl ee ln mete of pei = 02593 mw mie! P34 Ug yur for Prlone PSE nd PS, ate AS, AS yea fre Cane dred ae 52 AS ch ep in te ase AS = Sse = fet = OMY ag yt EIS ewer °C nd OC heh apc fH) igen by Cole AIF ml AS 12.25iole of Ha) fel ater om 00" w BLA ator 2 centri) = 225m 1085. GaL1S 2719) - 2472, GOL? 71S wot sess woe Laat Sale Sf -emenrtons- ania) at P36 Cle Samael Sig fr 6) of Pb P54 te pes onc? The ste of he scams T= 310K, P= 02300 ‘Toe ues revere tbr pion 310K aml presse oe the fs ital ala. man #o4 sal met CHR aT eas nant nnll atm Aa 2atmats(S)si Sg AS + Aang #20S8IKDNSSIK = ‘Thr mul deo of cans nis oc ben is evi opt Pann a 92 [Chapter Entropy and the Second and Third Laws of Thermodynamics 7537 caktueme copy oes nol of water pra IC an tering te infra, 17s, 0625} vomits mt 183 AA nS 3580 Tne 538 Thebetcmcty of eae is ve6y Coals) = dots aan Z toni Z Tenet « e ‘Thecofseoftermaexpmionenty f= 0.5580%10" Kat Y= 266m? mo, Cae AS, fete wastormaon quire (180°C 1m) > e-cure (20°C, 25am) Fm Ess 525528) ra, a8, een Exot ny [races roma -sasnar ans - = 22m! mat 03850010" a4 HOSP Phen eat oe 203K ma +196 2248 MOH 61K mat P5394 Calla AS if 00 mol ig wae heel fom O40 fo IC er comtn remne 5, The noting pit of water te pose of nt 5s OC and he ery of fin ie {010K ma The tog pits 1° aed teeny of pein 40.8 Mo Cae 5 fv teuastimube HO, 0107) HO, 1". etait mtbr tiem An Nal ssenfieare nant mah 783 et SE pe ln Icom “sSepng = Bann Li 4680.3 en Tagen SSIS SS. * AS AS + Sg = 2200 +1089 4 2H RISKS! pif 201 Pin ster § Entropy an the Second and Third Las of Thermody nami 93 21.05 gofston 973K aad 45 ef HO) a8 K aac ps Br he al sot ‘tonpsen stew oid a? Cai A fete pce. Aes tbe in ste id war i at ease, ate ep il bye a 373K tat Maan BET TOY RET, TE cat” myc vr Cera 205 955. ma TES MERTON 955 nc HH 24 wot Fag t0 el 4 UD 595g TRE 53m mak 6 SEEM arg mt Fong, 0 mor seat te noi ce an 7 asin ein war a SOF OSA Igy EK aims! Seca fr i wot Hoi fig he wae om 98K 9 328. 8 pl = 8 a RE IC! Sou =16ATIAC 1589 = 260), Tess sponte ‘sng your et fn Pre 531 expe heise of Line py condos, Te Nate bebe sonst eveen 7 = 0K an T= S10. K ‘We can ihr mpl he irs 310. K ig he se ofr or sume a te at py ‘Sha 30 le beeen 3. and SK jax 9162 076107 = 000195117 + 27640)«1047> sor - 7 vas20 se1nx) =remn ec "00k 198254 2714 = 13s tet “The mewn toa axa he Fats sie 6 209 Jen i. In soto so al, he ‘Repu rach tale of SCA hae oped ring fe clcter he t oero ‘oldest 208K. Clete he eh coe ee poe 10. ws Asam a eine ‘pers ate moma Ca fle 4 {Chapter $ Entropy and the Second and hind Laws of Thermodynamics pees eo. ie iy at” TKR oa wie OTT oT S43 An eal pepe conning 175 moe fr wich C9 ~ SR andre the lowing rei sss roses He nse characey T= 278 kasd P= Lr 44 Misepaned mel an aha the volun pes Wisrevesly ttf cout Yolen incense 275K © Teepemueitnrmetinar bate rene congrs nl = 190 Cade. 0A, td AS ewe pin teed etal ole (©) Thetenprmne a he eno te dire epuson csi, 4 =208K x6)" = 775K x0)™ = INK “ini ad al oh edt fl rer cl, 28, _ SmaI MPC DISK 21a? Sensei An 7K - 2K) = ASI AU =e aA 9175 mab o became AY = 0 BU = gn gh = Ls mar S282! 1 ans 177) = 386109 81 = phi = 15 nl ABSIT ag The preset ef proce iced nero 8. 7) = 499x104 pan wont ZBE «se 639 4238 601K" ‘rp 21 tae nin “Thin Laws of Thermosynmi 98 {Chapter Eniropy andthe Secon (9 Ail = 81 = Obenme 3-0 gs = 0425601744050 Bigg = ASIP 13.5610 140% 0 Mls =-ASEAIPS + 4541S 40= 0 5 = 04 16OIK 16038 Sao raat Repth cus comma cmt sa ty «Fan Pe tt te apy Thea lh Ss eae on ii eign preyerertnemrenirhy dpi: dayiainyrererteyrnirenmranal Settee toca “sat ak “Sun Mucor ae soereseeg saris ecbapeenerpepsiregrgente tempo pereeeitt peppy Se OF mown omer msg pc Aepust at Caney ‘Yau can pir he igrtin nema wing tw spent progr ose Sing ete a phage Gr Ene rb 0), xh 2019 Bsn ‘Chapter $ Entropy ad the Second and Tht Laws of Thermedyaamics Wetrat wp thee unde the rein rege am wath wh eC; A: Wen day 7 {er entangle sda eco a aly mip be ot ms Ts exe sponte te ‘leet teil et 7 ale ponte The raat 2 Jan Kt on Hera oom site poral gtr ors aK 35K SHIN SOUR osm SUR eg EC sete aon gsr UTA gsm Neg DUR osm! arate persia ae aI aK 627 coin These egy of Pe) 1 29815K 80K ma Ase ht he psy of PA) eg by Leal)

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