4 Thermochemistry Proton mater ns Inde at he slo ine SS Mama Conceptual Problems ou Inciting 3785.15 Kn th AM; oft compa hat ake pin te ets te Inte and 2p, Dat a) ae aed sen ds ey ma No Atay tempt hr tn 798.15 th haps oa ements and compen ht wtih yi oth an outer tah na om rnctereFls 4.), expily iis \enpcrtelsoil a ne ortat? ‘This ater nth easel aes th elaine he nt waterbath or he est fe ‘ese Bene uprso he at as ee se, te so ha Mw bet en. [ree ctor ft oor at i el lo work & Se capri sy ah oe an ted epost sem, ete taving sont ome Hon ete Ho at incomes, The stn se wars F018) ‘The stn so nd lows: The nid force st tri 4 Dos te say mao of 10) huge ee ct ee) ant Os wt alte 10 Al mu an ot Arr sane gon he CO, ig) Wi AH Soe foe 4) C0, ig)-» HCO) hg ae aoe os cane oe ea of eto ‘The cay of emer 2 capo seine whe change cay a he tn in ‘nhc they ron rt i ml comp nadernet oho ‘vm we elon ned om he pose lo Sad reece ss he le ge) + ¥2046) + H,00 fle = Ai OAD = HOLOAD) = 142) U0) ‘he Hm cht ence which ae ot see tw erent Be We in Oy steer sans nett) mer than site aes of eer. Boe 81/,01,0()) a {hy ar dtd an eapernent nl thang ecco lhl alps SF Mtg) sod Ox) oul NOW ar un a Howe he be ealpy "H,O0) = A 0 +g) 2044p) wil age wenbne wh Be pe ‘us equcon. This cng n (90) bso til ince ene we ean oly se ‘hangs ently an ee, Asa pet an be ae CO). st 20 RennChapter 4 Thermochemistry ow eu To donate ht he hie se etnies fr denen as nt fet the econ ely, we ees i rte restenH, 01) + CD) > H,CO,) tens fase aie anf = He,c0,01)- M4, 010) - C045) = AHI H,COsI + HUE) +3040) + Clap) (217,010 + 69) +12H10,6¢9) ~(8H (0045) + Crab) + (089) = AH 1H,COsI) ~ AH (00) ~ AH (CO) Why ae ee inca nt sen Eqn 420) wn eye tac! easing A 298K? [Atcagh U7 oan ae a ay fener 280, Ay ae eye te a 298K nase ‘thy chnge ocd wit tng clenets al npr am 8K Wy rt apc feat prt eid ran of A alo engi? All rection temperate ler ta 298K ices th entaly change ssid with ign the ene at epee 28 ‘ste towing seme conea fut ewe et cone The supe 2 AM meas at ‘he spear meat he ei Ie le there ies gee safe ase at ‘Wy sa ad eps of any sec oft to ce hemp of eon tat he cs seni ey ph toe i ec an rod repre of whines pot ‘sero taste sane eo Ie cnt stay he pet of tet ns 1 25K ef unin 1 nll pene of 204K. Wy doen atop ie aft or meme 0, 24 Bec H i at nt ay path toenail pt pi which neat em ‘sure eile, arte same vase hen tal el tee, {ste ion aes? eo tcc ace cH) +05) -+ 019 ‘Sehr ers wear pear on hoc ‘The stent snr swine he ping of he stem othe amoung esl. The Steet ‘Boca thereon Ise) Ole) 500) seem he das ew + Maes emp ‘ee ne etc ite en card ot on ea ono. ‘The acs inh venie 2NO) + 0,6) > 2NOs (x inal a 298K. Why etn ety ‘he ame ia) etn asthe 8 a te ecto tne ot oe he ‘a ooo sends mene ny ae be epee epost 38 KO cae sent y pts betwen he ata eds pn wih nme ee Denese ise, ase sie vas fr en ia a el tps. i 21 Rr En aChapter 4 Thermochemistry 33 (2412 What th ning faite suming srs oes ab cr in emising be ny stfu ots Stee Mesures cn sane an be cried smc 4 ol caning aortic is ‘Sn esr do nat nix ioe stress ey st dane sential i amb lene ‘SeTwevo eset of aetna 5th ht bob erin. 2413 You wish mess the at ofshton of Nolin wae Wot the nti tela of cis ea a Si pest orn aan? Wy? ‘Cmts arin st cu fie see of ect ore i pon ad "chee tery noes Ct pra nos mae yo a (414 te wing stent come? fat coe it att cones Beas fe nay of meso = ens ia, A018) =O Te ton xy pre cement i oint st ie te 29815 Ker gan etn Sard feces (5) 9 0), sat A O30 (Q44S ithe a/7 re i op ied a aren ae meet ven empeti how in ‘old erp rom Egatinn 4195 Alfne =AMawisn + ACHAT (Q486 1st itlonng tenet const? an em i hat cares HA ceil eon Ges nt ‘hang apy nh engera te ea cpucti ec alOMS ait “The set i cnt Sr chal rend ot hang peal wih mp ‘Sin a ste ofrecer an pods ste al (Q417 —Unkerwhat codices a 17m fr reson ing esr gis see? Tisistecweif airy) =a. Doge fin wether pang. We he equation ee hs rans eat A HM) + 108 ally = ansstIW0r! [L194 ar tecking Sa I fl in ne a te venge 1 od apy in hs moll? xpi your en [No-The avenged ent te ava ie apes teste Hy) Ch CHa, ak CH) (0420 sumo toh pepo ew es eves of hs poses pend nthe ree iy? Peon cele elsve iy hn 108 he aie hui I, pep ‘he esr ete acelin ch ‘Numerical Problems PAL Gen hd n Tal (ApoB, Dn Table) a te flog frm, clea ingle nd ey Sram [ saa [ek [Sn@ | onwo [mre lanjadear) [treo | «579 | os [ms | -m | (pret 02015 Pw tnChapter 4 Thermochemisy The aes np bend ety iF ie flows: SR) - 0) + 250) ify =16149%0 m0" 2a) > 0) ily bean a) 0; = «00 ma She) Sig) +4"@) i= er vege St-F had ey ni = BEIM 5s ge rea iF tad ee init, = SMS 54s ‘Avera sta oa ery 1, Sig) -» 84+ 2088) 0, = 65708 mat! Sie) +59) AM, = 450K mo! 20,2) 4040) Mfg = 41213 mat Sic) 8) 40K) n= 1s mot! Awe sng ton entay nicl, = PRIPH pany wor vere iControl, = SHOE gaa mr Aven sng ond ena C, a) +00) +2510) Atfg= stam? e900) Athy = T7a ma 2 4) Atty = 4x 72443" cus) 0) +4) if, = 19900 m0 9 Msenr" Avene sg od ety in he = = 49 mr Aenean nc» OEM coppice 3 ertter 4 Thermochemistry ‘Avene sh neatly i wie =2mednw t= 25a Iwo) yim 3a) sity deratint” Ra) > Nig) +3) ‘wrest od ea i au" = air — aver kn xtra ah ve key 0 on@ fon sig" Jouey 089 ij 2020* 4270) hig 2294! Earn) ai =o Averge sage ond enti in oF, = SPE 5 2194) mor {OR mo" 2431 MEK 2DKISK = SN? Avenge OF ton ey no; = 29H 34m, mn) +i +86) y= 27m Jang 1140 any = 200m tyo-+%6 f= DAtier! ng) HF n= sh ot ‘Sle toe iF = Ss 83a KRM ISK © S6SK nar Ave sigh bn mya HE = S81) ma capege023 Pen56 Chapter 4 Thermochemistry PR2 At WALK, Ally» -12077AS mt fr the recon Ny) +3868) -+ 2NHa) wh Cpe = 3502 Sse 217 fe Nats) Hah aol Np rope. Cae 11) of Ma) a0. fom ‘is ikmatn Aste ha he et pce dee get. zn ky» "F acsenar am6s0% Form poten ba ape we se epee 7 ara.) + 9,87 177M ml +20) ~Cral 8) SX) ARTA al ASH KD Az17 25923. -0.K ouster an ga) = Lanna Pes A sample of) of mat 270 sedans ematical crn Te eons Sunt F591 Kan he mere temper te ar Nate bth coming SD 5 ar {DK Cc Aiyad 80 2x0)+ Lo 6.00) 274g “Taare : sie cheat = 961i mor e149 ma SZORISK = 3628 PLA Gaal 7 or NOKg 975K, sing tht the hepsi of eta and pies a esa over there naval eter 298.5 room sasuisns Pac 2)et 86,6000 Seta HaOn = 886-0552919-05%2938 3K mt! A = 103050. seisn-| o ase met = A180, 9.20618) 0327 ma ong ewe anChapter 4 Thermochemistry 31 PAS Theta sis ete art conte cam 338% km. Cafon in cess ia pot eis pinned ty mao pas ssn oe etn Cg) + 1,0) + Cl 040) 40x. Tomer uge eis fh reef lathe 4451 gh pr er. Cle hoa ‘tp sage eng Fo toy eon ato nth ona pe ale fC gene dat shoe isin P= barang? = 290K. ANF = AH ACH Davt~ 61408) ~ 6 10.9 127A Ada" 6393S mol 4 6285 Peet ie TRL \Wecscute ent tang er mole of sn te aoe es an ils DUI mata yn 710g wot 33510 = sence wet Pus Deve emu frat Re he etn O42) + 40x) -» COs) ssing tat he eats of ext and rd dol ange wh epee, AMAT) = AQQKISK- 8CyA (C036 ~ 914048 +[CrOOR) ~Craf0OHE)~ Her aOED 8) (PA Gna te ain Table and table te bn tay wey of fe owing: 1% Thee —Csinple boat nc, TheC=Catbe din ‘seo om par) tse prt an) Hg) +6) +44) a0 8) +AN(C8)~ SU) ‘Avengs Honey nc teu ur =n ar Wm h 298 15K = 1654bI Hot! ‘Aveags CH to en inci amet! (GIG) 2448) 8) ean hg) +2 jG2)-AH LC He) = 6x 2189 mot +2676 7k 840 =25k1 mer Ai = 6M ba ey + —CooentnyChapter 4 Thermochemistry C—Chendaatay = 2651 mca at = 329K au" = aH aner = DmSkb m7 AS mol TEAS = BON Mae 20" = 640-1 beaten + C— Chon ey (C—Chontongy = 2008b mot 641K mee" = 529K © Gtk) 92049) +149) AM = 2000 C.2) + AEE) AMC) Mfg = CH onl thy + C=C tod ety "= AH tr RGA mS ASU mK = 22008 wt Chonda = 200A wo! cAI! = SABA ‘sete ong 29815 1 cope pains siete) ream Joie ox) + 011 os 148) 40,6) > 040) cause Hie) + 2H) soe 0112) +204 woe 2 Oe) + Hie) +016) 1,048) + aH +048) 5 HyO4g) He) +H Assuming al pisbetviy, cle ify aA} ele eon. acum ornsteer tou ats Si) He) Season bow +00 bo one ong oama L223 4s moe TD0NISK = TANT 201 Re in