P(psia) 250 Kpa 1723.75 Bar 17.
24137931
T (°F) 80 °C 26.66666667 °K 299.8166667
zi ki x y
metano 0.5 10
etano 0.1 2.075
propano 0.2 0.68
n-butano 0.2 0.21
V/F propuesto xi=zi/(1+vf(ki-1)
xmetano xetano xpropano xn-butano sumatoria (1)
0.8 0.06097561 0.053763441 0.268817204 0.543478261 0.927034516
0.84 0.058411215 0.052548607 0.273522976 0.594530321 0.979013119
0.85 0.057803468 0.052253429 0.274725275 0.608828006 0.993610178
0.855 0.057504313 0.05210708 0.275330396 0.616237868 1.001179657
0.856 0.057444853 0.052077909 0.275451741 0.617741537 1.002716039
v/f
yi=kixi
ymetano yetano ypropano yn-butano sumatoria(1)
0.6097560976 0.1115591398 0.1827956989 0.114130435 1.0182413711
0.5841121495 0.1090383605 0.1859956236 0.124851367 1.0039975011
0.5780346821 0.1084258654 0.1868131868 0.127853881 1.0011276156
0.5750431282 0.1081221911 0.1872246696 0.129409952 0.9997999412
0.5744485294 0.1080616602 0.1873071838 0.129725723 0.9995430962
monogramas
t(˚F) 70 V 0.2 0.8
P(PSIA) ?
zi zi ki(monograma) xi
etano 0.01 8.5
propano 0.05 2.5
isobutano 0.5 1.05
n butano 0.44 0.74
1
V ya está
xi(1)
etano propano isobutano
nbutano
0.004 0.03846153846154 0.49504950495 0.4641350211
yi(1)
0.034 0.09615384615 0.51980198 0.34345992
gramas
P Xi(1)
100 1.11
50 1.023
48 0.98
49 1.02656
46 1.011
44 1.0016
sumatoria(1)
1.001646064509
0.993415742
menor que T tprom T(K) R
acetona(1) prom T(C) 73.63 346.78 1.987
metanol(2) P(kpa) 101.33
agua(3)
𝑣1/𝑣2
Ec. Wilson
ɑ12 ɑ21
acetona (1) 74.05 -161.88 583.11 Constantes de
metanol(2) 40.73 a
acetona(1) 74.05 291.27 1448.01 acetona 14.3145
agua (3) 18.07 metanol 16.5785
metanol(2) 40.73 107.38 469.55 agua 16.3872
agua (3) 18.07
Teb©
Ʌ11 1 acetona 56.2001696
Ʌ12 0.6956948837 metanol 64.7001891
Ʌ13 0.1599012686 agua 99.9991105
Ʌ21 0.7799899977
Ʌ22 1 Se pasa 157, hay que baja
Ʌ23 0.3796334322
Ʌ31 0.5010920706
Ʌ32 1.1402735481
Ʌ33 1
menor que T Propuesta T(K) R
acetona(1) prom T(C) 60.935 334.085 1.987
metanol(2) P(kpa) 101.33
agua(3)
𝑣1/𝑣2 Ec. Wilson
ɑ12 ɑ21
acetona (1) 74.05 -161.88 583.11 Constantes de
metanol(2) 40.73 a
acetona(1) 74.05 291.27 1448.01 acetona 14.3145
agua (3) 18.07 metanol 16.5785
metanol(2) 40.73 107.38 469.55 agua 16.3872
agua (3) 18.07
Teb©
Ʌ11 1 acetona 56.2001696
Ʌ12 0.7019333207 metanol 64.7001891
Ʌ13 0.1573533346 agua 99.9991105
Ʌ21 0.7553069223
Ʌ22 1 Tiene que ser una temperatura mas ba
Ʌ23 0.3773919958
Ʌ31 0.4626339312 La temperatura es 60.935 en grados Ce
Ʌ32 1.1111258709
Ʌ33 1
x1 x2
0.3 0.4
Constantes de Antoine
b c P
2756.22 228.06 lngamma1 lngamma2 lngamma3
3638.27 239.5 0.40595061 0.04500334 0.48762472
3885.7 230.17
T prom(3) © Pisat
177.445114 157.35295923
73.633156406943 142.533507
36.4889803
pasa 157, hay que bajarle la temperatura
x1 x2
0.3 0.4
Constantes de Antoine
b c P
2756.22 228.06 lngamma1 lngamma2 lngamma3
3638.27 239.5 0.42200879 0.04795006 0.50527997
3885.7 230.17
y1 0.53627598
T prom(3) © Pisat PRESION y2 0.36123313
118.776262 101.3301413 y3 0.10249089
60.935 87.2251619
20.8863402
a temperatura mas baja para que llegue a 101.33
s 60.935 en grados Celsius y en grados Kelvin 334.085
x3
0.3
gamma1 gamma2 gamma3
1.50072844 1.04603135 1.62844361
x3
0.3
gamma1 gamma2 gamma3
1.52502192 1.04911826 1.65744949
Dew T:P=101.33kpa,y1=0.3,y2=0.4
menor que T tprom T(K)
acetona(1) prom T(C) 73.63 346.78
metanol(2) P(kpa) 101.33
agua(3)
𝑣1/𝑣2
𝑣1/𝑣2
Ec. Wilson
ɑ12 ɑ21
acetona (1) 74.05 -161.88 583.11
metanol(2) 40.73
acetona(1) 74.05 291.27 1448.01 acetona
agua (3) 18.07 metanol
metanol(2) 40.73 107.38 469.55 agua
agua (3) 18.07
yi
Ʌ11 1 0.3 acetona
Ʌ12 0.69569488 0.4 metanol
Ʌ13 0.15990127 0.3 agua
Ʌ21 0.77999
Ʌ22 1
Ʌ23 0.37963343
Ʌ31 0.50109207
Ʌ32 1.14027355
Ʌ33 1
nuevo
Dew T:P=101.33kpa,y1=0.3,y2=
menor que T
acetona(1)
metanol(2)
𝑣1/𝑣2
agua(3)
acetona (1)
metanol(2)
acetona(1)
agua (3)
metanol(2)
agua (3)
Ʌ11
Ʌ12
Ʌ13
Ʌ21
Ʌ22
Ʌ23
Ʌ31
Ʌ32
Ʌ33
R x1
1.987 0.3
iterativo
lngamma1
Constantes de Antoine
a b c 0.96324328
14.3145 2756.22 228.06
16.5785 3638.27 239.5
16.3872 3885.7 230.17
Con la Tprom y proponiendo gam
Teb© T prom(3) © Pisat debemos aumentar la temperat
56.2001696 177.445114 101.33kpa
64.7001891 73.6331564 142.533507
99.9991105 36.4889803
w T:P=101.33kpa,y1=0.3,y2=0.4
menor que T tprom T(K) R
prom T(C) 73.91 347.06 1.987
P(kpa) 101.33
𝑣1/𝑣2 Ec. Wilson
ɑ12 ɑ21
74.05 -161.88 583.11 Constantes de Antoine
40.73 a b
74.05 291.27 1448.01 acetona 14.3145 2756.22
18.07 metanol 16.5785 3638.27
40.73 107.38 469.55 agua 16.3872 3885.7
18.07
yi Teb© T prom(3) ©
1 0.3 acetona 56.2001696
0.69556304 0.4 metanol 64.7001891 73.91
0.15995581 0.3 agua 99.9991105
0.78052271
1
0.37968116
0.50194234
1.14090061
1
x2 x3
0.4 0.3
Trocio
lngamma2 lngamma3 gamma1 gamma2 gamma3 P(kpa)
1 1 1 78.6245016
0.17393125 0.16432869 2.6201807 1.18997376 1.17860165 100.206847
la Tprom y proponiendo gamma como ideal, nos da la presion de 100.206847 por lo cual
emos aumentar la temperatura hasta que lleguemnos a nuestra presion que es de
x1 x2 x3
0.3 0.4 0.3
iterativo
lngamma1 lngamma2 lngamma3
es de Antoine
c 0.96125114 0.17322817 0.16465416
228.06
239.5
230.17
Con la Tprom y proponiendo gamma como ideal, nos da la
Pisat debemos aumentar la temperatura hasta que lleguemnos a
178.937576 101.33kpa
144.003905
36.9163625 La temperatura es de 73.91 grados celcius y así llegamos a
Tprom,celsius P
74 101.70648
correcta 73.91 101.33686
x1 x2 x3
0.13292758 0.22064847 0.64642394
or lo cual
Trocio
gamma1 gamma2 gamma3 P(kpa) x1 x2
1 1 1 79.4865639 0.13326418 0.22079002
2.6149661 1.1891374 1.17898531 101.319065
amma como ideal, nos da la presion de 100.206847 por lo cual
atura hasta que lleguemnos a nuestra presion que es de
ados celcius y así llegamos a 101.33kpa
x3
0.6459458
Pburbuja,t=65 grados C,x1= 0.7 , x2=0.3
T(kelvin) X1 X2
T(Celsius) 60 333.15 0.7 0.3
R(CAL/MOL) 1.978
𝑣1/𝑣2 Ec. Wilson
ɑ12 ɑ21
metanol (1) 40.73 -31.19 813.18
metilacetato(2) 79.84
metilacetato(2) 79.84 291.27 1448.01
metanol (1) 40.73
metanol
metilacetato
lngamma1 lngamma2
Ʌ11 1 0.08299143 0.07105478
Ʌ12 2.05523685981425
Pburbuja 112.803186
Ʌ21 0.14851413760245 117.261772
Ʌ22 1
Pisat
acetona
metanol 83.9890958
metilacetato 112.745257
Constantes de Antoine
a b c
16.5785 3638.27 239.5
14.2456 2662.78 219.69
gamma1 gamma2
1.08653249 1.07364003
Pburbuja,t=65 grados C,xi=0.3,x2=0.4,x3=0.3
T(kelvin) y1 y2
T(Celsius) 60 333.15 0.4 0.6
R(CAL/MOL) 1.978
𝑣1/𝑣2 Ec. Wilson
ɑ12 ɑ21
metanol (1) 40.73 -31.19 813.18
metilacetato( 79.84
metilacetato( 79.84 291.27 1448.01
metanol (1) 40.73 metanol
metilacetato
ITERATIVO HASTA QUE LA PRESION SEA IGUAL
Ʌ11 1 lngamma1 lngamma2
Ʌ12 2.05523686
0.12288065 0.00825553
Ʌ21 0.14851414 0.25614797 0.44382657
Ʌ22 1 -0.77031341 #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
Ʌ33
La presion de rocio es 69.1842631
iterativo pburbuja procio
Pisat
metanol 83.9890958
metilacetato 112.745257
Constantes de Antoine
a b c
16.5785 3638.27 239.5
14.2456 2662.78 219.69
N SEA IGUAL
gamma1 gamma2 P(kpa) x1 x2
1 1 99.1644932 0.47227318 0.52772682
1.13074946 1.0082897 105.376216 0.44382657 0.55617343
1.29194389 1.55866014 140.832726 0.51915497 0.48084503
0.46286798 #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
presion de rocio es 69.1842631
T(kelvin) z1 z2
T(Celsius) 65 338.15 0.3 0.4
R(CAL/MOL) 1.978
𝑣1/𝑣2 Ec. Wilson
ɑ12 ɑ21
acetona (1) 74.05 -161.88 583.11
metanol(2) 40.73
acetona(1) 74.05 291.27 1448.01
agua (3) 18.07 acetona
metanol(2) 40.73 107.38 469.55 metanol
agua (3) 18.07 agua
Ʌ11 1 lngamma1 lngamma2 lngamma3
Ʌ12 0.70064627
Ʌ13 0.1578738
Ʌ21 0.76031667
Ʌ22 1
Ʌ23 0.37785171
Ʌ31 0.47029139
Ʌ32 1.11705659
Ʌ33 1
pburbuja procio psistema(kpa)
z3 117.261772 69.1842631 93.22301755
0.3 Pisat
acetona 135.575914
metanol 102.530309
agua 25.101354
Constantes de Antoine
a b c
14.3145 2756.22 228.06
16.5785 3638.27 239.5
16.3872 3885.7 230.17
gamma1 gamma2 gamma3 k1 k2 k3
1 2 3 0