L e BINA MOHIT MEMORIAL SCHOOL PRE-BOARD EXAMINATION SESSION : 2024-25 CLASS : X II science EM.:70 ‘SUBJECT : Chemistry TIME: 3 br GENERAL INSTRUCTIONS: Read the following instructions carefully. {a) There are 33 questions in this question paper with internal choice. {b) SECTION A consists of 16 multiple-choice questions carrying 1 mark each. (c) SECTION B consists of 5 short answer questions carrying 2 marks each. (d) SECTION C consists of 7 short answer questions carrying 3 marks each. (e) SECTION D consists of 2 case-based questions carrying 4 marks each. (f) SECTION E consists of 3 long answer questions carrying 5 marks each. (8) All questions are compulsory. {h) Use of log tables and calculators is not allowed. SECTION A ic NH, NaNo,/HCl Pres, 2 GH,NH, —MNOMHC, x ay y Cosy 2 in above sequence, Zis a. Cyanoethane b. Ethanamide c. Methanamine d. Ethanamine / 2. Which one of the following has the highest dipole moment? a. CHF “ b. CHC! . CHal 0. CHBr '[Link] of the following pair of species will yield carbylamine? a. CHsCH,Br and KCN b, CH,CH,Br and NH3 (excess) 7 [Link] and AgCNd. CHsCH,NH, and HCHO. / 4. Which of the following statements about the catalyst is true? a. A catalyst accelerates the rate of reaction by bringing down the activation energy. b. A catalyst does not participate in reaction mechanism. A catalyst makes the reaction feasible by making AG more negative, d. A catalyst makes equilibrium constant more favourable for forward reaction. '[Link] of the following biomolecules is insoluble in water? a. a-Keratin b. haemoglobin, ¢. ribonuclease d. adenine [Link] elements form alloys easily because they have a, Same atomic number 'b, Same electronic configuration c. Nearly same atomic size d. None of the above 7The half life of the first order reaction having rate constant K = 12th b.o7h e113h 4.1.8h .7 x 10%s* is, [Link] of the following compound gives an oxime with hydroxylamine: a. CHCOCHs b. CH;COOH“ . (CHsCO):0 4. CH,Codl [Link], can be converted into [Link]; by a. NaBHs 7 b. Hr Pd/C ¢. UAIHS [Link]-He/HCl 10,The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol. The mixture shows a. no deviation from Raoult’s Law. b. positive deviation from Raoult’s Law. negative deviation from Raoult’s Law. ~d. that the solution is unsaturated. 11. Match the properties given in column | with the metals in column I! Column I ‘Column IL (i) Actinoid having configuration [Rn] 5f’6d'7s* |(A) Ce (ii) Lanthanoid which has 4f" electronic (B) Lu configuration in +3 oxidation state. (Cc) Cm (iii) Lanthanoid which show +4 Oxidation state a. (i)+(C), (i)-(B) (il)-(A) 'b. (i)-(C), (ii)-(A), (il)-(B) . (H(A), (H-(8),(Ili)-(C) 4. (I-18), (ii)-(A), (ili)-(C) 12. Formulation of Cobalt(IiI) Chloride-Ammonia Complexes Colour Formula Solution conductivity corresponds to Yellow [Co(NH,),|"3Ct Y Purple {CoClNH,}s!"2Cr 1:2 electrolyte Green x 1:1 electrolyte X and/‘¥’in the above table are: a. X={Co(NH)."3Ct, Y= 1:3 bb. X= [Co(NHs)ChI'CL-¥. (Co(NHs),ChI’Cr, :o(NHs) Ni** (aq) + 2Ag(s), E* = 1,05 V (1F = 96500 C mol?) SECTION D 29, Read the passage and answer the following For the reaction 2NO(g) + Clx(g) -> 2NOCI(g) the following data were collected. All the measurements were taken at 263 K:Experiment No. [Initial [NOJ(M) [Initial [Cl.](M) [nitial rate of the disappearance of Cla (M/min) te 0.15 0.15 0.60 2. 0.15 0.30 1.20 0.30 0.15 2.40 4. 0.28 0.25 2 (a) Write the expression for rate law. {b) Calculate the value of rate constant and spe (c) What is the initial rate of disappearance of Clz in exp. 4? 30. Read the passage and answer the following Basicity of amines can be defined as their capacity to donate the lone pair of electrons on the N atom. This makes the amines' basic’ as they can easily donate that pair to an electron-deficient centre. Amines tend to have a tetrahedral geometry because of the sp’ hybridisation. How would you account for the following : (a) Electrophilic susbstitution in case of aromatic amines takes place more readily than benzene. (b) Ethanamide is a weaker base than ethanamine. (c) Primary amine is more basic than tertiary amine. SECTION E [Link] a coordination compound CrCls.6H.0 is mixed with AgNO, solution, 3 moles of AgCl are precipitated per mole of the compound. Write : {a) Structural formula of the complex (b) 1UPAC name of the complex (c) Magnetic and spin behaviour of the complex. OR (a) For the complex ion [Fe(en):Cih]’ write the hybridization type and magnetic behaviour. Draw one of the geometrical isomer of the complex lon which is optically active. [Atomic No.: Fe = 26] (b) Draw the crystal field energy level diagram for the 3d orbital of this complex. 32. (a) Write the products of the following reactions : ° 3 I a > =O +NH, —NH—C—NH, — > Gi) CHMgBr + CO, —Dasither_,, ‘ H30* (iii) CH,CH,COOH + Br, Red Phosphons_, Z(b) Write simple chemical tests to distinguish between the following pairs of ‘compounds (i) Propanal and propanone (ii) Benzaldehyde and Benzoic acid. ‘OR (a) How will you convert: (i) Benzene to acetophenone (i) Propanone t° 2-Methylpropan-2-ol (b) Give reasons : (i) Electrophilic substitution in benzoic acid takes place at meta position. (ii) Carboxylic acids are higher boiling Tiquids than aldehydes, ketones and alcohols of comparable molecular masses. (ii) Propanal is more reactive than propanone in nucleophilic addition reactions 33, (a) Define the following terms = (i) deat solution (i) Osmotic pressure {b) Calculate the bolling point elevation for a solution prepared by adding 10 ¢ CaCl: to 2006 of water, ‘assuming that CaCl is completely dissociated. (kb) for water = 0.512 Kkg mol"; Molar mass of CaCh = 111 g mot”) OR (a) 30 gof urea (M = 60g mold) is istolved in 846 g of water Calculate the vapour pressure of water for this solution If vapour pressure of pure water 2 298 K is 23,8 mm He. (b) Write two differences between ‘deal solutions arid non-ideal solutions. {c} Explain why on adaition of 1 mol glucose f2 { litre water the boiling point of water Increases. _